Hygroscopicity of organic compounds as a function of organic functionality, water solubility, molecular weight and organic oxidation level

<p>Hygroscopic properties of 23 organic compounds with different physico-chemical properties including carboxylic acids, amino acids, sugars and sugar alcohols were measured using a Hygroscopicity Tandem Differential Mobility Analyzer (HTDMA). We converted our experimental GF data of organics at 90% RH to κ to facilitate the comparison and we find that organic compounds with different molecular functionality present quite different hygroscopicity. Compounds with extra functional groups usually show higher hygroscopicity compared to their parental molecular compounds. Moreover, some compounds share the same molecular structure or functionality but vary differently in hygroscopicity. In general, the hygroscopicity of organics increase with functional groups in the following order: (-CH3/-NH2) < (-OH) < (-COOH/C=C/C=O). For highly soluble organics, the hygroscopicity decreases with molecular weight; while for slightly soluble organics which are not fully dissolved in aerosol droplets, their hygroscopicity can be divided into two categories. One is non-hygroscopic compounds, which may not fully deliquesce in the aerosol droplets. The other is moderate hygroscopic compounds, of which the hygroscopicity is mainly limited by their water solubility. Moreover, the hygroscopicity of organic compounds generally increased linearly with O:C ratios, although some of them have the same O:C ratio of but with different hygroscopicity. The experimental determined hygroscopicity are also compared with model predictions using the Extended Aerosol Inorganics Model (E-AIM) and the UManSysProp at 10-90% RH. Both models poorly represent the hygroscopic behavior of some organics, which may due to that the phase transition and intermolecular interactions are not considered in the simulations.</p>

Hygroscopic behavior and chemical reactivity of aerosols generated from mixture solutions of low molecular weight dicarboxylic acids and NaCl

Ambient sea spray aerosols (SSAs) have been reported to undergo reactions with low molecular weight dicarboxylic acids (LMW DCAs). In the present study, the hygroscopic behavior of aerosols generated from...

Molecular Dynamics Simulations Demonstrate That Nonideal Mixing Dominates Subsaturation Organic Aerosol Hygroscopicity

The microscopic properties that determine hygroscopic behavior are complex. The importance of hygroscopicity to many areas, and particularly atmospheric chemistry, in terms of aerosol growth and cloud nucleation, mandate the...

Hygroscopic behavior of aerosols generated from solutions of 3-methyl-1,2,3-butanetricarboxylic acid, its sodium salts, and its mixtures with NaCl

MBTCA (3-methyl-1,2,3-butanetricarboxylic acid), a low-volatile, highly oxidized, secondary-generation product of monoterpenes, is one of the most relevant tracer compounds for biogenic secondary organic aerosols (SOAs). In this study, laboratory-generated, micrometer-sized, pure-MBTCA, mono-/di-/trisodium MBTCA salts and MBTCA–NaCl mixture aerosol particles of four mixing ratios (molar ratios = 1 : 1, 1 : 2, 1 : 3, and 2 : 1) were examined systematically to observe their hygroscopic behavior by varying the relative humidity (RH) using in situ Raman microspectrometry (RMS) assembled with either a see-through impactor, where the particles were deposited on a Si wafer, or a levitation system. The pure MBTCA droplets effloresced at RH = ∼ 30 %–57.8 % and did not deliquesce until RH > 95 %. The mono- and disodium MBTCA salt aerosols did not show clear efflorescence RH (ERH) and deliquescence RH (DRH). In contrast, the trisodium MBTCA salt exhibited ERH = ∼ 44.4 %–46.8 % and DRH = ∼ 53.1 % during the hygroscopic experiment cycle. The mixture aerosols generated from solutions of MBTCA : NaCl = 1 : 1 and 2 : 1 showed no visible ERH and DRH in the see-through impactor because of the partial and total consumption of NaCl, respectively, through chemical reactions during the dehydration process. The mixture particles with a 1 : 1 molar ratio in the levitation system exhibited a clear DRH at ∼ 71 % and ERH at ∼ 50 %. This suggests less reaction between the mixtures and a larger portion of NaCl remaining in the levitation system. The other mixtures of MBTCA : NaCl = 1 : 2 and 1 : 3 displayed single-stage efflorescence and deliquescence at ERH = ∼ 45 %–50 % and DRH = ∼ 74 %, respectively, because of the considerable amount of NaCl present in the mixture aerosols in both systems. Observations and Raman analyses indicated that only monosodium MBTCA salt aerosols could be formed through a reaction between MBTCA and NaCl. The reaction occurred more rapidly with a more elevated concentration of either MBTCA or NaCl, and the controlling factor for the reactivity of the mixtures depended mostly on the availability of H+ dissociated from the MBTCA tricarboxylic acid. The lower degree of reaction of the mixture particles in the levitation system might be caused by the relatively airtight circumstance inside, i.e., less release of HCl. The study revealed that the interactions between the MBTCA and NaCl could modify the properties of the organic acid in the atmosphere, leading to enhanced capability of the probable heterogeneous chemistry in the aqueous aerosols.

Experimental Measurement of Isothermal Sorption, Microbiological and Physicochemical Analysis of Dried Tomatoes Cultivated in Adrar, Algeria

The fresh tomato is a very perishable product in arid regions for that the drying is an indsipendable technique to preserve this product and used at all times, in this study the fresh tomatoe was sampled from different farms in Adrar and subjected to the drying method using an indirect dryer solar. The dried tomatoes were screened for microbiological and physicochemical analysis including E. coli, Staphylococcus aureus, Salmonella Typhi, anaerobic sulfito- redactors, molds and yeasts in addition, the value of pH, water activity, dry matter, and assay of ash. The obtained results showed the presence of mesophilic aerobic total bacteria, and coliform total, the absence of Salmonella Typhi, Staphylococcus aureus, Clostridium perfringens and spores of anaerobic sulfito reducting and some colonies of yeasts, for the pH value, activity water, dray matter and assay of ash, the results were (4.10), (0.41), (9.63%) and (5.71%) respectively, which do not affect the final quality of the dried products and satisfactory to norms imposed by the commercial legislation of Algerian. On the other hand, the isothermal sorption is indispensable step to mastering the process of drying tomatoes, and to know the distribution and the intensity of the water connections in the products as a result, this experimental study aims to determine the physicochemical components' and the desorption isotherms curves for tomato harvested from the Touat region, in South-West Algeria, using the saturated salt solution method. The experiment is carried out for three temperature values 40℃, 50℃ and 60℃, to study the influence of the temperature on the equilibrium curves of the product and finally to describe the isothermal moisture desorption for tomato product for three temperatures using known models of GAB, GAB, modified BET who showing the best models isotherms sorption to model at and predict hygroscopic behavior during drying and storage. The results of this research can be used to determine characteristic drying curves and to have optimal storage conditions.

Sorption isotherms of ingredients and diets for poultry

This study aimed to determine sorption isotherms of ingredient and poultry diet. The samples were encapsulated in capsules and dehydrated by oven-drying in a desiccator for more than 24 hours. The samples were transferred to desiccator containing water in the base and placed in the oven, with one sample of each material being removed at incremental intervals. The sample was weighed and for determination of water activity and for dry matter. The moisture and water activity data were evaluated by eight mathematical models. The GAB mathematical model fitted the experimental data to constitute the isotherm for each material. Type II sorption isotherms were found, except for BHT: demonstrated values that did not fit the isotherm determination. The hygroscopic behavior of the ingredients in ascending order were: L- threonine, limestone, BHT, DL- methionine, L-valine, L- tryptophan, phosphate, kaolin, vitamin supplement, salt, mycotoxin deactivator, pelleted rooster diet, mash rooster diet, mash layer diet, pelleted layer diet, corn, bacitracin zinc, vitamin mineral supplement, phytase, rice bran, wheat bran, mineral supplement, soybean meal, coccidiostat, L- Lysine HCl and choline chloride. Ingredients and diets have different hygroscopic behavior: can lead to deterioration and low accuracy in nutritional values of diet, since formulation is based on as-is fed basis.