ECOLOGICAL PLASTICITY AND STABILITY OF PROSPECTIVE PEA LINES

The studies were carried out in order to assess the parameters of the adaptability of promising pea samples in terms of yield to identify the best genotypes for the conditions of middle Volga region. The work was carried out in 2018-2020 in the central zone of Ulyanovsk region. The object of the research was 10 pea samples, the standard was Ukaz variety. According to the methods of S.A. Eberhart, W.A. Russell, V.V. Khangildina and S.P. Martynova determined the adaptability of breeding samples using the following indicators: coefficient of variation (V%), homeostaticity (Hom), breeding value (Sc), stability index (Sj2), linear coefficient regression (bi), point stability estimate (Hi). On average, over three years of research, the greatest increase in yield, compared to the standard, was noted for Ulyanovskiy yubileiny variety - 0.43 t/ha. The genotypes of Ulyanovskiy yubileiny, Viridis and line 657/14 with the smallest values of the coefficients of variation - 14.6, 22.4, 23.4%, respectively, are attributed to the most stable in terms of the coefficient of variation V. The most valuable in terms of plasticity and stability were the Ukaz variety (bi=1.15 and Sj2=0.02) and line 559/11 (1.14 and 0.00 respectively). Line 621/14 (bi=1.42 and Sj2=0.15) was recognized as an intensive variety with very low phenotypic stability and line 752/14 (1.29 and 0.11 respectively), with a reduced variety. Lines 215/11, 533/14, 657/14 were distinguished by very high phenotypic stability (bi=0,91…1,07, Sj2=0,00…0,03). The highest level of homeostaticity in combination with breeding value was observed in the promising pea cultivar Ulyanovskiy Yubileiny (Hom=15.33 and Sc=1.67) and line 215/11 (Hom=7.74 and Sc=1.22). According to the point assessment of Hi stability, significant advantages were revealed in Ulyanovskiy yubileiny variety (Hi =4.22) and line 215/11 (1.33). According to the sum of the ranks of the six parameters of adaptability, the leading positions were occupied by lines 533/14 (27), 215/11 (32) and promising varieties Ulyanovskiy yubileiny (32), Viridis (32). According to the test results, two samples in 2020 were submitted for state variety testing

WSOC and Its Relationship with BC, Levoglucosan and Transition Metals in the PM2.5 of an Urban Area in the Amazon

Water-soluble organic carbon (WSOC) makes up a large mass fraction of the organic carbon in the aerosol and can influence important cloud processes in the atmosphere. The capacity of WSOC to form metallic complexes with transition metals is well known; however, its influence on the aerosol of urban areas in the Amazon region is not very well known. In this study, we investigated the relationship between WSOC, black carbon (BC), levoglucosan (LEV) and transition metals (Fe, Cu and Mn) present in the PM2.5 (particles with a diameter smaller than 2.5 µm) of an urban environment during the dry season in the central Amazon. Oxalic acid (C2) was used to identify the influence of transition metals on WSOC. The mean mass concentration value of the PM2.5 was 14.72 μg m-3 (2.11-31.68 μg m-3). The WSOC made up 58.34% of the PM2.5 mass, followed by BC (20.28%), and LEV (2.62%). The WSOC showed significant correlation with the transition metals analyzed (> 0.56), especially Mn with C2 (linear coefficient (R2 ) = 0.74). A multiple linear regression with WSOC, BC and LEV showed a strong linear correlation between them (R2 = 0.86), indicating the influence of biomass burning and vehicle traffic on the organic aerosol.

Рентгеновский детектор на основе CdZnTe в режиме поперечной и продольной фотопроводимости

The work considers "transverse" and "longitudinal" photoconductivity modes, regarding the direction of radiation, photoconductivity in semiconductor detectors of CdZnTe. Mathematical calculations were made from the representation of the internal area of the detector in the form of radiation absorption sites. The results of the calculations are compared with experimentally measured photocurrent of the detector with a cross section of 2x2 mm CdZnTe from the direction of its radiation by X-ray. From the ratio of photocurrents in the range of X-ray radiation energies 35-72 keV for these two cases, a linear coefficient of X-ray absorption by the CdZnTe detector is determined.

Структурный переход и температурные зависимости коэффициентов теплового расширения NaNO-=SUB=-3-=/SUB=-, внедренного в нанопористое стекло

The temperature evolution of the crystal structure of a nanocomposite material obtained by introducing sodium nitrate NaNO3 from a melt under pressure into a nanoporous alkali borosilicate glass with an average pore diameter of 7 nm has been studied by the method of diffraction of synchrotron radiation in a wide temperature range upon heating. Analysis of the experimental diffraction patterns revealed a significant decrease in the temperature of the structural (orientational) transition by more than 50 K (up to 496 K) compared to bulk sodium nitrate. From the temperature dependence of the intensity of the superstructure peak (113), the dependence of the critical exponent β (T) for this transition was obtained and a significant difference from the critical exponent for a bulk material was found in the temperature range from 455 K to the transition temperature. Analysis of the broadening of Bragg reflections made it possible to estimate the average size (~ 40 nm) of sodium nitrate nanoparticles into the pores. An increase in the linear coefficient of thermal expansion in the [001] direction was found in NaNO3 nanoparticles in comparison with bulk material at temperatures above 450 K.

NESEA-Rice10: high-resolution annual paddy rice maps for Northeast and Southeast Asia from 2017 to 2019

An accurate paddy rice map is crucial for ensuring food security, particularly for Southeast and Northeast Asia. MODIS satellite data are useful for mapping paddy rice at continental scales but have a mixed-pixel problem caused by the coarse spatial resolution. To reduce the mixed pixels, we designed a rule-based method for mapping paddy rice by integrating time series Sentinel-1 and MODIS data. We demonstrated the method by generating annual paddy rice maps for Southeast and Northeast Asia in 2017–2019 (NESEA-Rice10). We compared the resultant paddy rice maps with available agricultural statistics at subnational levels and existing rice maps for some countries. The results demonstrated that the linear coefficient of determination (R2) between our paddy rice maps and agricultural statistics ranged from 0.80 to 0.97. The paddy rice planting areas in 2017 were spatially consistent with the existing maps in Vietnam (R2=0.93) and Northeast China (R2=0.99). The spatial distribution of the 2017–2019 composite paddy rice map was consistent with that of the rice map from the International Rice Research Institute. The paddy rice planting area may have been underestimated in the region in which the flooding signal was not strong. The dataset is useful for water resource management, rice growth, and yield monitoring. The full product is publicly available at https://doi.org/10.5281/zenodo.5645344 (Han et al., 2021a). Small examples can be found from the following DOI: https://doi.org/10.17632/cnc3tkbwcm.1 (Han et al., 2021b).

Thermal Fringe Formation During a Hologram Recording Using a Dry Photopolymer

In this study we investigated the undesired but possible fringe formation during the recording of large size holographic optical elements (HOE) using a dry photopolymer. We identified the deformation of the recording element during hologram exposure as the main source for this fringe formation. This deformation is caused mainly by the one-sided heating of the recording element, namely, the dry photopolymer–recording plate stack. It turned out that the main source for this heating was the heat of polymerization in the dry photopolymer released during the exposure interval. These insights were translated into a physical model with which quantitative predictions about thermal fringe formation can be made depending on the actual HOE recording geometry, recording conditions and characteristics of the dry photopolymer. Using this model, different types of large size HOEs, used as components to generate a steerable confined view box for a 23” diagonal size display demonstrator, could be recorded successfully without thermal fringe formation. Key strategies to avoid thermal fringe formation deduced from this model include balancing the ratio of lateral recording plate dimension R to its thickness h, recording the power density P or equivalently the exposure time texp at a fixed recording dosage E, and most importantly recording the the linear coefficient of thermal expansion (CTE) of the recording plate material. Suitable glass plates with extremely low CTE were identified and used for recording of the above-mentioned HOEs.

Flexible N-Type Thermoelectric Composites Based on Non-Conductive Polymer with Innovative Bi2Se3-CNT Hybrid Nanostructured Filler

This research is devoted to the fabrication of polyvinyl alcohol (PVOH) based n-type thermoelectric composites with innovative hybrid bismuth selenide-multiwalled carbon nanotube (Bi2Se3-MWCNT) fillers for application in flexible thermoelectric devices. Hybrid fillers were synthesized by direct deposition of Bi2Se3 on multiwalled carbon nanotubes using a physical vapor deposition method, thus ensuring direct electrical contact between the carbon nanotubes and Bi2Se3. The Seebeck coefficient of prepared PVOH/Bi2Se3-MWCNT composites was found to be comparable with that for the Bi2Se3 thin films, reaching −100 µV·K−1 for the composite with 30 wt.% filler, and fluctuations of the resistance of these composites did not exceed 1% during 100 repetitive bending cycles down to 10 mm radius, indicating the good mechanical durability of these composites and proving their high potential for application in flexible thermoelectrics. In addition, other properties of the fabricated composites that are important for the use of polymer-based materials such as thermal stability, storage modulus and linear coefficient of thermal expansion were found to be improved in comparison with the neat PVOH.

First principle methods for calculating the linear coefficient of thermal expansion of quasi-binary eutectic systems

To calculate the linear coefficient of thermal expansion (LCTE) and its temperature dependence, a combination of the method of a priori pseudopotential and quasi-harmonic approximation (author's methods) is used. After approximating the results obtained for metal-like materials (carbides, borides, silicides), the LCTE is presented in an analytical form. In the case of quasi-binary eutectic systems based on carbides, borides, silicides, to estimate the interaction energy of the elements of two components, the concept of a virtual crystal (with a virtual cell) along the line of contact of two components is introduced. A virtual cell is assigned a volume average between the volume of a unit cell of two components, taking into account their concentration ratio. The components that make up the eutectic retain their crystal structure, their LCTE can be estimated as for pure components. Without taking into account the influence of interphase interaction, the LCTE of the eutectic system is determined using the rule of mixtures based on the LCTE components, taking into account their volume fraction. Taking into account the influence of the interface on thermal expansion is estimated by the virtual cell assigned to it. To determine the LCTE of the eutectic system, a ratio is proposed that connects the LCTE components and the docking boundaries through the concentration ratio. This method more realistically describes the structure of a quasi-binary eutectic. There is a consistency between the calculated and experimental data. Keywords: electron-ion system energy, interatomic interaction potential, quasiharmonic approximation, linear coefficient of thermal expansion, eutectic temperature.

Fracture of Be and Its Alloys - Webb Space Telescope Revisited

NASA/ESA/CSA joint venture James Webb Space Telescope is about to be launched. It is hypothesized to operate in near-infrared range. It is also hypothesized to unveil early star formation, galaxies, and universe due to its orbit, point in orbit and orbital motion. It has been under manufacturing for over 20 years at a staggering cost of 10 billion US dollars (most expensive scientific experiment in history). Beryllium (Be) is chosen to be element for construction of its main mirrors due to its high stiffness, low density, low linear coefficient of thermal expansion (α) in cryogenics and high thermal conductivity. It is followed by gold (Au) layer deposition on its (Be) surface to enhance its sensitivity towards infrared radiation as later is hypothesized to bear superior properties. However, serious mistakes have been made in selecting this material for this application. Owing to its crystal structure (hexagonal close packed (hcp)), slip planes (basal, prismatic and pyramidal) and mechanisms of their activation, Be necessitates easy fracture at cryogenic temperature. It has anisotropic properties and prone to transverse fracture under tensile loading. Furthermore, its ductile to brittle transition temperature is very low making it entirely unsuitable for such an application. It is one of most expensive metals on planet. This study constitutes revisiting these fundamental properties and mechanisms which were entirely ignored during materials selection thus rendering whole project useless.

Numerical Investigation of Unsteady Flow Dynamics in a Packed Bed

Numerical simulation of unsteady flow of a compressible fluid in a fixed bed filled with porous elements has been performed. The research was carried out via ANSYS Fluent software. The scientific substantiation and verification of the physical and mathematical approaches incorporated in ANSYS Fluent for the problem of unsteady flow in a fixed bed has been carried out. For the computational domain, the interfaces of the flow area and the surface of porous particles are coupled by combining the contacts into a component part. The numerical results were verified using experimental data. The study was carried out in the range of velocity from 0.25 to 3.25 m/s. An expression is proposed for determining the pressure drop in a fixed bed, in which the pressure drop depends on the velocity, flow properties and the linear coefficient of local resistance. The values of the linear coefficient of local resistance are determined for the most common nozzle shapes in the industry: cylinder, Raschig ring, convex cylinder with 7 holes, sphere with 7 holes. It was found that with an increase in velocity, the value of the linear coefficient of local resistance decreases.