Ormosils of High Hardness

1994 ◽  
Vol 346 ◽  
Author(s):  
Takashi Iwamoto ◽  
John D. Mackenzie
Keyword(s):  
Theoretical Model ◽  
Nmr Spectroscopy ◽  
Ultrasonic Irradiation ◽  
Vickers Hardness ◽  
Liquid State ◽  
High Hardness ◽  
Experimental Results ◽  
Organically Modified Silicates ◽  
Organically Modified ◽  
Hardness Values

ABSTRACTOrganically modified silicates (ormosils) of high hardness were prepared by the reactions of tetraethoxysilane (TEOS) and polydimethylsiloxane (PDMS) aided by ultrasonic irradiation. The mechanisms leading to the hard ormosil formation were investigated by liquid state 29Si NMR spectroscopy. PDMS chains were found to be broken into shorter chains and/or 4-membered siloxane rings during the reaction and finally, all PDMS chains were chemically incorporated as short chains into silica networks. Vickers hardnesses of the hard ormosils were measured and compared with those of the hardest transparent plastics. Whereas the hardest transparent plastics have Vickers hardness values of less than 25 kg/mm2, the hard ormosils have Vickers hardnesses up to higher than 150 kg/mm2. A theoretical model was developed for the calculation of Vickers hardnesses of the hard ormosils and agreed well with experimental results. Predictions based on this theory indicate that even harder ormosils can be made when Al2O3, ZrO2 and TiO2 are substituted for SiO2. Results based on these new ormosils are also presented.

Rubbery Ormosils

1990 ◽  
Vol 180 ◽  
Author(s):  
Young J. Chung ◽  
Su-Jen Ting ◽  
John D. Mackenzie
Keyword(s):  
Nmr Spectroscopy ◽  
Structural Model ◽  
Rubber Elasticity ◽  
New Technique ◽  
Polydimethyl Siloxane ◽  
Gelation Process ◽  
Organically Modified Silicates ◽  
Organically Modified ◽  
A New Technique

ABSTRACTA new technique which permits the successful preparation of ORMOSILS (Organically Modified Silicates) with rubbery elasticity has been developed. Common alkoxides were reacted with polydimethyl siloxane (PDMS) and the microstructures were carefully controlled. Large monoliths of the porous rubbery ORMOSILS have been prepared. Gelation process was studied by 29Si liquid NMR spectroscopy. A structural model for rubber elasticity of ORMOSILS was proposed.

Modeling of Temperature-Dependent Hardness for Pure FCC and HCP Metals

2020 ◽  
Vol 12 (02) ◽  
pp. 2050022
Author(s):  
Niandong Xu ◽  
Weiguo Li ◽  
Jianzuo Ma ◽  
Yong Deng ◽  
Haibo Kou ◽  
...  
Keyword(s):  
Theoretical Model ◽  
Melting Point ◽  
Present Model ◽  
Experimental Results ◽  
Effect Of Temperature ◽  
Temperature Dependent ◽  
Different Temperatures ◽  
Pure Metals ◽  
Experimental Values ◽  
Hardness Values

In this study, a theoretical model is developed to characterize the quantitative effect of temperature on the hardness of pure FCC and HCP metals. The model is verified by comparison with the available experimental results of Cu, Al, Zn, Mg, Be, Zr, Ni, Ir, Rh, and Ti at different temperatures. Compared with the widely quoted Westbrook model and Ito–Shishokin model which need piecewise fitting to describe experimental values, the present model merely needs two hardness values at different temperatures to predict the experimental results, reducing reliance on conducting lots of experiments. This work provides a convenient method to predict temperature-dependent hardness of pure metals, and it is worth noting that it can be applied to a wide temperature range from absolute zero to melting point.

The Effect of Ultrasonic Radiation on Gelation and Properties of Ormosils

1992 ◽  
Vol 271 ◽  
Author(s):  
Kazuki Monta ◽  
Yi Hu ◽  
John D. Mackenzie
Keyword(s):  
Specific Surface ◽  
Liquid State ◽  
Sol Gel ◽  
Exothermic Reaction ◽  
Ultrasonic Radiation ◽  
Surface Areas ◽  
Organically Modified Silicates ◽  
Organically Modified ◽  
Specific Surface Areas ◽  
Hydrolysis And Polycondensation

ABSTRACTUltrasound has been applied to organically modified silicates (ORMOSILs) solutions during gelation. A series of silica and polydimethylsiloxane (PDMS) composites have been prepared by the sol-gel method. Tetraethoxysilane (TEOS), PDMS, water and a HC1 catalyst were mixed and exposed to 20 kHz ultrasonic radiation under different conditions. Ultrasonic radiation made it possible to obtain wet gels in 5 to 30 min. without solvent (e.g. alcohol, and THF). And exothermic reaction was observed due to hydrolysis and polycondensation of TEO S. The reaction process was examined by liquid state 29Si NM R. Densities of obtained sono-ORMOSILs were observed to be higher than those produced by ordinary processes. Some sono-ORMOSIL samples demonstrated extremely low porosity and low specific surface areas.

Actuation and dynamic mechanical characteristics of a core free flat dielectric electro-active polymer soft actuator

2020 ◽  
Vol 14 (4) ◽  
pp. 7396-7404
Author(s):  
Abdul Malek Abdul Wahab ◽  
Emiliano Rustighi ◽  
Zainudin A.
Keyword(s):  
Theoretical Model ◽  
Resonance Frequency ◽  
Dynamic Testing ◽  
Experimental Results ◽  
Percentage Error ◽  
Initial Tension ◽  
Average Percentage ◽  
Soft Actuator ◽  
Average Percentage Error ◽  
Mechanical Dynamics

Various complex shapes of dielectric electro-active polymer (DEAP) actuator have been promoted for several types of applications. In this study, the actuation and mechanical dynamics characteristics of a new core free flat DEAP soft actuator were investigated. This actuator was developed by Danfoss PolyPower. DC voltage of up to 2000 V was supplied for identifying the actuation characteristics of the actuator and compare with the existing formula. The operational frequency of the actuator was determined by dynamic testing. Then, the soft actuator has been modelled as a uniform bar rigidly fixed at one end and attached to mass at another end. Results from the theoretical model were compared with the experimental results. It was found that the deformation of the current actuator was quadratic proportional to the voltage supplied. It was found that experimental results and theory were not in good agreement for low and high voltage with average percentage error are 104% and 20.7%, respectively. The resonance frequency of the actuator was near 14 Hz. Mass of load added, inhomogeneity and initial tension significantly affected the resonance frequency of the soft actuator. The experimental results were consistent with the theoretical model at zero load. However, due to inhomogeneity, the frequency response function’s plot underlines a poor prediction where the theoretical calculation was far from experimental results as values of load increasing with the average percentage error 15.7%. Hence, it shows the proposed analytical procedure not suitable to provide accurate natural frequency for the DEAP soft actuator.

scholarly journals Understanding the Links between the Composition-Processing-Properties in New Formulations of HEAs Sintered by SPS

Metals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 888
Author(s):  
Paula Alvaredo-Olmos ◽  
Jon Molina-Aldareguía ◽  
Alvaro Vaz-Romero ◽  
Estela Prieto ◽  
Jesús González-Julián ◽  
...  
Keyword(s):  
High Hardness ◽  
Processing Parameters ◽  
Heating Rates ◽  
High Entropy ◽  
Plasma Sintering ◽  
Mechanical Study ◽  
Spark Plasma ◽  
Processing Properties ◽  
Bcc Phase ◽  
Hardness Values

This work presents two new compositions of high entropy alloys (HEAs) that were designed with the aim of obtaining a body-centered cubic (BCC) phase with high hardness values and a moderate density. Sintering was performed using Spark Plasma Sintering (SPS) with different heating rates to determine the influence of the processing parameters on the phase formation. The microstructural study revealed that the presence of Ni in the composition promoted phase separation, and the mechanical study confirmed a clear influence on the mechanical properties of both the composition and heating rate. The combination of microscopy with compression and nanoindentation tests at room and high temperature made it possible to advance our understanding of the relationships between the composition, processing, and properties of this emerging group of alloys.

Influential factors on hardness uniformity of Vickers hardness blocks for high hardness range

Measurement ◽  
2016 ◽  
Vol 78 ◽  
pp. 358-365 ◽  
Author(s):  
Tamara Aleksandrov Fabijanić ◽  
Mladen Franz ◽  
Željko Alar
Keyword(s):  
Vickers Hardness ◽  
High Hardness ◽  
Influential Factors

Evaluation of Mechanical Properties of Dental Feldsphatic Porcelains for Metal and Zirconia Core

2012 ◽  
Vol 727-728 ◽  
pp. 1104-1107
Author(s):  
Antonio Alves de Almeida-Junior ◽  
Gelson Luis Adabo ◽  
Beatriz Regalado Galvão ◽  
Diogo Longhini ◽  
Claudinei dos Santos
Keyword(s):  
Fracture Toughness ◽  
Flexural Strength ◽  
Vickers Hardness ◽  
High Hardness ◽  
Hardness Test ◽  
Dental Prostheses ◽  
Significant Incidence ◽  
Significant Difference ◽  
Fixed Dental Prostheses ◽  
Intermediate Value

Studies has been reported a significant incidence of chipping of the feldspathic porcelain veneer in zirconia-based restorations. The purpose of this study was to compare the three-point flexural strength (MPa), Weibull parameters, Vickers hardness (VHN) and Vickers indentation fracture toughness (MPa/mm1/2) in feldspatic porcelains for metal and for zirconia frameworks. Bar specimens were made with the porcelains e.MaxCeram (EM) and VitaVM9 (V9) for zirconia core, and Duceragold (DG) and VitaVMK95 (VK) for metal core (n= 15). Kruskal-Wallis and Dun test were used for statistical analysis. There was no significant difference (p=0.31) among the porcelains in the flexural strength (Median= 73.2; 74.6; 74.5; 74.4). Weibull calculation presented highest reliability for VK (10.8) followed by EM (7.1), V9 (5.7) and DG (5.6). Vickers hardness test showed that EM (536.3), V9 (579.9) and VK (522.1) had no difference and DG (489.6) had the lowest value (p.001). The highest fracture toughness was to VK (1.77), DG (1.58) had an intermediate value while V9 (1.33) and EM (1.18) had the lowest values (p.001). Despite of the suitable flexural strength, reliability and high hardness, the porcelains used to zirconia-based fixed dental prostheses showed lower fracture toughness values.

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