Sub-Half Micron Elevated SourceDrain NMOSFETS by Low Temperature Selective Epitaxial Deposition

1996 ◽  
Vol 429 ◽  
Author(s):  
J. Sun ◽  
R. F. Bartholomew ◽  
K. Bellur ◽  
P. A. O'Neil ◽  
A. Srivastava ◽  
...  

AbstractIn this paper we report the first NMOSFETs with elevated S/D selectively deposited by ultra high vacuum rapid thermal chemical vapor deposition (UHV-RTCVD). The deposition process included an in-situ vacuum prebake (750 °C for 10 sec) followed by selective epitaxial growth (SEG) at 800 °C. Si2H6 was used as the silicon gas source instead of the more commonly used SiH4 and SiH2Cl2 in order to achieve high growth rates at low pressure. To prevent nucleation from occurring on insulator surfaces during growth, an etching mechanism was introduced by the addition of Cl2. The gases included 100 sccm of 10% Si2H6 in H2 and 2 sccm of Cl2 at a process pressure of 24 mTorr. An epitaxial growth rate of 160 nm/min has been achieved. The final epi thickness was around 0.1 μm. The S/D junctions were formed via ion implantation into the epi. The subsequent RTA (10 sec at 950 °C) resulted in an effective junction depth about 75 nm beneath the starting Si substrate. Process and device simulations reveal the importance of maintaining a shallow LDD junction for deep submicron devices by using low temperature selective deposition. MOSFETs exhibit good subthreshold characteristics with subthreshold swing of 86 mV/dec at a drain bias of 2.5 V, and threshold variations due to charge sharing and drain-induced-barrierlowering (DIBL) were moderate for Leff down to 0.35 μm. The gate-induced junction leakage current is below 2 pA/μm at a bias of 2.5 V.

1995 ◽  
Vol 387 ◽  
Author(s):  
P. L. Huang ◽  
K. Seastrand ◽  
K. E. Violette ◽  
J. Wolf ◽  
M. C. Öztürk

AbstractIn this paper, we present an application of ultra high Vacuum Rapid Thermal Chemical Vapor Deposition (UHV-RTCVD) to MOSFET channel engineering. MOSFETs were fabricated on ultra-thin (200 Å), moderately doped (l×1017 - 6×1018 cm−3) p-type epitaxial layers selectively grown in active areas defined by standard LOCOS isolation. The selective epitaxy was achieved using a novel Si2H6Cl2/B2H6 process at 800°C and at a total pressure under 30 mtorr. Low thermal budget processing techniques were emphasized to minimize spread in the channel doping profile. Threshold voltages below 0.6 V were obtained. Transistors with effective channel lengths of 0.45 μm exhibit subthreshold slopes from 78 to 92 mV/decade determined by the epitaxial channel doping density. We have found that by using ultra-thin channels, expected transconductance degradation at high channel doping densities can be minimized. Furthermore, ultra-thin channels help reduce the sensitivity of the threshold voltage on substrate bias. The results show that low temperature selective silicon epitaxy can be used to form ultra-shallow channel doping profiles that can enhance the performance of MOSFETs in the deep submicron regime.


1999 ◽  
Vol 557 ◽  
Author(s):  
Toshihiro Kamei ◽  
Akihisa Matsuda

AbstractWe have developed a new type of ultra-high vacuum plasma-enhanced chemical vapor deposition (UHV/PECVD) system. According to high sensitivity secondary ion mass spectrometry, device quality hydrogenated amorphous silicon (a-Si:H) films deposited at 250°C at a deposition rate of 1 Å/s contains 1015 cm-3 of O, 1015 cm-3 of C, and 1014 cm-3 of N impurities, while low defect hydrogenated microcrystalline silicon (μc-Si:H) films deposited at 200°C at a very low rate of 0.1 Å/s include 1016 cm-3 of O, 1015 cm-3 of C and 1016 cm-3 of N. These are the lowest concentrations of atmospheric contaminants for these kinds of materials observed so far. The essential features of the present UHV/PECVD system are an extremely low outgassing rate of 8×10-9 Torr·s, extremely low partial pressure of contaminant gas species <10-12 Torn, and purification of feed gas SiH4 at “point of use”. These efforts are quite important not only for clarifying the microscopic mechanism of photo-induced degradation in a-Si:H, but also for enlarging the crystalline grain size in μc-Si:H. μc-Si:H with a grain size of ≍1000 Å as determined by Scherrer's formula can be obtained at the higher rate of 1.5 Å/s by utilizing a VHF (Very High Frequency) plasma. The specific origins of impurities in the films are also discussed.


1995 ◽  
Vol 387 ◽  
Author(s):  
Katherine E. Violette ◽  
Mehmet C. Öztürk ◽  
Patricia A. O'Neill ◽  
Kim Christensen ◽  
Dennis M. Maher

In this paper we present for the first time the use of the Si2H6/H2/Cl2 chemistry for selective silicon epitaxy in a rapid thermal CVD reactor. Depositions were carried out in an ultra-high vacuum rapid thermal chemical vapor deposition (UHV-RTCVD) system designed and constructed at North Carolina State University. Experiments were performed over a temperature range of 650°C to 850°C and over a pressure range of 22 to 25 mTorr using a flow rate 100 sccm of 10% Si2H6 in H2 and 0 to 10 sccm of Cl2. Deposited layer thicknesses were evaluated using a combination of interferometry and profilometry. Without Cl2 over the range of 650°C to 850°C, the growth rate is approximately constant at 160 nm/min. exhibiting a weak dependence on temperature. A clear advantage of Si2H6 is that high growth rates compatible with single wafer manufacturing can be obtained at very low pressures thus minimizing the introduction of contaminants by the process gases. With the addition of C12, the growth rate is suppressed at temperatures below 800°C, but, at 800°C and above, it is affected only slightly for Cl2 flow rates below 5 sccm. As the Cl2 flow rate is increased past 5 sccm, the growth rate at higher temperatures becomes a strong function of Si2H6:Cl2 ratio. Excellent selectivity with respect to patterned SiO2 and Si3N4 was obtained over the entire Cl2 flow rate range suggesting that even lower Cl levels may be sufficient for selective deposition. This implies that selectivity can be obtained with Si:Cl ratios much lower than those introduced by the more commonly used SiH2Cl2 chemistry. Furthermore, because Si2H6 can provide high growth rates at very low pressures, the total partial pressures of Cl2 and resulting chlorinated species can be significantly lower than typically required for selectivity. Our results indicate that C12 successfully enhances selectivity and yields highly selective depositions for process durations well within the practical limits of single wafer manufacturing.


1999 ◽  
Vol 569 ◽  
Author(s):  
K. Nozawa ◽  
K. Katayama ◽  
Y. Kanzawa ◽  
Q. Sugahara ◽  
T. Saitoh ◽  
...  

ABSTRACTReal-time spectroscopic ellipsometry (RTSE) method was applied to study thermal cleaning process of silicon surfaces for epitaxial growth by ultra-high vacuum chemical vapor deposition (UHV-CVD). For the first time, in-situ observation of oxide decomposition process under Si2H6 ambience was carried out. The substrates with thin oxide formed by wet chemical treatment were heated up by infrared heater under UHV or under Si2H6 ambience in an UHV-CVD chamber and the oxide decomposition processes were observed by RTSE. Ellipsometric parameters Psi and Delta increase with the progress of oxide decomposition process and become constant with the completion of the decomposition. It was found that the oxide decomposition process consists of two phases and rate-determing processes are different in each phase. It was also found that Si2H6 lowers the activation energies of oxide decomposition process in each phase.


2000 ◽  
Vol 621 ◽  
Author(s):  
Zheng Chen ◽  
Yonhua Tzeng ◽  
Chao Liu

ABSTRACTFabrication and characterization of carbon nanotubes deposited on microstructured Ni substrate are presented. The highly active surface-area of the microstructured Ni substrate provides highdensity nucleation sites for carbon nanotubes. Coated fine Ni powder also serves as a catalyst for the nanotube growth. Hydrocarbon mixtures were used as the carbon source for the chemical vapor deposition process. Carbon nanotubes deposited on the microstructured Ni substrate were examined by SEM. An ultra high vacuum chamber was used to characterize the field emission properties of carbon nanotube coatings.


1993 ◽  
Vol 334 ◽  
Author(s):  
Katherine E. Violette ◽  
Mahesh K. Sanganeria ◽  
Mehmet C. Öztürk ◽  
Gari Harris ◽  
Dennis M. Maher

AbstractSilicon nucleation on silicon dioxide and selective silicon epitaxial growth (SEG) were studied in an ultra high vacuum rapid thermal chemical vapor deposition (UHV-RTCVD) reactor. Experiments were performed using 10% Si2H6 in H2 in a pressure range of 10 - 100 mTorr at 760°C. Under these conditions, the growth rate ranged from 75 to 330 nm/minute. Loss of selectivity via Si island formation on SiO2 was studied using scanning electron microscopy (SEM) and atomic force microscopy (AFM) revealing a strong dependence on deposition pressure. Cross sectional transmission electron microscopy (XTEM) was employed to study the vertical oxide/epitaxy interface where faceting can occur. The incubation time for nucleation was found to increase from 10s to 70s as pressure is reduced from 100 mTorr to 10 mTorr, allowing thicker selective epitaxial film growth in spite of the reduced growth rates. This was attributed to the reduction in gas phase supersaturation of the Si containing species resulting in a lower density of adsorbed atoms on the SiO2 surface. This process shows a potential for chlorine free selective epitaxial growth and provides insight to the surface morphology of polycrystalline films deposited at low pressures.


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