Commercialization Status of Ni3Al-Based Alloys

1996 ◽  
Vol 460 ◽  
Author(s):  
V. K. Sikka

ABSTRACTThe Ni3Al-based alloys have been under development at the Oak Ridge National Laboratory (ORNL) and other research institutions in the United States and around the world for the last ten years. The incremental developments of composition, melting process, casting methods, property data, corrosion data, weldability development, and prototype component testing under production-like operating conditions have pushed the ORNL-developed Ni3Al-based alloys closer to commercialization. This paper will present the highlights of incremental technical developments along with the approach and current status of commercialization. It is concluded that cast components are the primary applications of Ni3Al-based alloys, and applications range from heat-treating fixtures to forging dies. It is also concluded that the commercialization process is accelerated when technology is licensed to an organization that can produce the alloy, has component manufacturing capability, and is also a user.

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 607
Author(s):  
Tommy R. Powell ◽  
James P. Szybist ◽  
Flavio Dal Forno Chuahy ◽  
Scott J. Curran ◽  
John Mengwasser ◽  
...  

Modern boosted spark-ignition (SI) engines and emerging advanced compression ignition (ACI) engines operate under conditions that deviate substantially from the conditions of conventional autoignition metrics, namely the research and motor octane numbers (RON and MON). The octane index (OI) is an emerging autoignition metric based on RON and MON which was developed to better describe fuel knock resistance over a broader range of engine conditions. Prior research at Oak Ridge National Laboratory (ORNL) identified that OI performs reasonably well under stoichiometric boosted conditions, but inconsistencies exist in the ability of OI to predict autoignition behavior under ACI strategies. Instead, the autoignition behavior under ACI operation was found to correlate more closely to fuel composition, suggesting fuel chemistry differences that are insensitive to the conditions of the RON and MON tests may become the dominant factor under these high efficiency operating conditions. This investigation builds on earlier work to study autoignition behavior over six pressure-temperature (PT) trajectories that correspond to a wide range of operating conditions, including boosted SI operation, partial fuel stratification (PFS), and spark-assisted compression ignition (SACI). A total of 12 different fuels were investigated, including the Co-Optima core fuels and five fuels that represent refinery-relevant blending streams. It was found that, for the ACI operating modes investigated here, the low temperature reactions dominate reactivity, similar to boosted SI operating conditions because their PT trajectories lay close to the RON trajectory. Additionally, the OI metric was found to adequately predict autoignition resistance over the PT domain, for the ACI conditions investigated here, and for fuels from different chemical families. This finding is in contrast with the prior study using a different type of ACI operation with different thermodynamic conditions, specifically a significantly higher temperature at the start of compression, illustrating that fuel response depends highly on the ACI strategy being used.


Author(s):  
Peter H Beckman

On 1 October 2004, the most ambitious high-performance Grid project in the United States—the TeraGrid—became fully operational. Resources at nine sites—the San Diego Supercomputer Center, the California Institute of Technology, the National Center for Supercomputing Applications, the University of Chicago/Argonne National Laboratory, Pittsburgh Supercomputing Center, Texas Advanced Computing Center, Purdue University, Indiana University and Oak Ridge National Laboratory—were joined via an ultra-fast optical network, unified policies and security procedures and a sophisticated distributed computing software environment. Funded by the National Science Foundation, the TeraGrid enables scientists and engineers to combine distributed, multiple data sources with computation at any of the sites or link massively parallel computer simulations to extreme-resolution visualizations at remote sites. A single shared utility lets multiple resources be easily leveraged and provides improved access to advanced computational capabilities. One of the demonstrations of this new model for using distributed resources, Teragyroid, linked the infrastructure of the TeraGrid with computing resources in the United Kingdom via a transatlantic data fibre link. Once connected, the software framework of the RealityGrid project was used to successfully explore lattice-Boltzmann simulations involving lattices of over one billion sites.


1994 ◽  
Vol 24 (1) ◽  
pp. 180-184 ◽  
Author(s):  
David A. Lortz ◽  
David R. Betters ◽  
Lynn L. Wright

Short-rotation woody-crop Populus spp. plantations have the potential to produce large amounts of biomass in short time periods, typically 4–8 years. A production function equation is shown to predict yields for such plantations. The equation is based, in part, on information from biomass production experiments conducted across the United States. These experimental plots are sponsored by the Biofuels Feedstock Development Program of Oak Ridge National Laboratory. The equation uses nine parameters including both cultural practices and climatic and soil site conditions as independent variables. The equation (R2 = 0.86) is accurate and applicable to a wide range of conditions.


Author(s):  
Paul T. Williams ◽  
Shengjun (Sean) Yin ◽  
B. Richard Bass

The Heavy-Section Steel Technology (HSST) Program at Oak Ridge National Laboratory (ORNL) performed a probabilistic structural mechanics (PSM) analysis of the damaged Davis Besse reactor pressure vessel head in support of the United States Nuclear Regulatory Commission’s ongoing forensic investigations. This paper presents a summary of the results of that PSM analysis, including a description of the Davis-Besse wastage-area damage model, the technical basis for the model, and the results of sensitivity studies based on a cladding capacity analysis (CCA) and an Accident Sequence Precursor (ASP) investigation of the wastage cavity. A companion paper describes the HSST experimental program carried out at ORNL in parallel with the PSM analysis.


Author(s):  
Pin-Chiun Huang ◽  
Hsoung-Wei Chou ◽  
Yuh-Ming Ferng

This paper is to study the effects of copper and nickel content variations on the fracture probability of the pressurized water reactor (PWR) pressure vessel subjected to pressurized-thermal-shock (PTS) transients. The probabilistic fracture mechanics (PFM) code, FAVOR, which was developed by the Oak Ridge National Laboratory in the United States, is employed to perform the analyses. A Taiwan domestic PWR pressure vessel with varied copper and nickel contents of beltline region welds and plates is investigated in the study. Some PTS transients analyzed from Beaver Valley Unit 1 for establishing the USNRC’s new PTS rule are applied as the loading conditions. It is found that the content variation of copper and nickel will significantly affect the radiation embrittlement and the fracture probability of PWR pressure vessels. The results can be regarded as the risk incremental factors for comparison with the safety regulation requirements on vessel degradation as well as a reference for the operation of PWR plants in Taiwan.


Alloy Digest ◽  
1984 ◽  
Vol 33 (9) ◽  

Abstract CROLOY 9V is a ferritic steel modified with columbium. It was developed at Oak Ridge National Laboratory under contract from the U.S. Department of Energy (DOE). Compared with Croloy 9M (the 9Cr-1Mo alloy) Croloy 9V provides improved strength, toughness and fatigue life with good oxidation and corrosion resistance at elevated temperatures. The alloy should be of interest to designers of a wide variety of equipment used to produce energy. Impressive test data indicate that Croloy 9V is capable of meeting the requirements of a variety of other applications. This datasheet provides information on composition, physical properties, microstructure, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SA-402. Producer or source: Babcock & Wilcox Company.


Author(s):  
John C. Petrykowski

Improved utilization of nuclear fuels, burning of actinides and advancements in safety have brought about renewed interest in sodium cooled fast reactor technology. In regards to this and in light of recent events which have focused attention on new concerns involving safety, analyses have recently been performed addressing beyond design basis accident conditions for which the existence of large quantities of vaporized fuel and coolant have been postulated. Specifically, for very low probability, but highly energetic core disruptive accidents in sodium cooled fast reactors, molten and vaporized fuel in contact with coolant can bring about a fuel coolant interaction leading to transformation of a significant inventory of coolant from liquid to vaporforme, with a potential for subsequent release of fuel as aerosol from the reactor vessel due to transport of fuel fragments and fuel aerosol by the vaporized fuel and coolant. Because general statements concerning the nature of these events were largely speculative, out-of-reactor experiments were conducted in the mid 1980’s in the FAST-CRI-III facility at Oak Ridge National Laboratory to study the transport in sodium of aerosol-bearing UO2 vapor bubbles. Although codes featuring detailed multi-physics models [1] were in various stages of development at the time of program cessation, a simplified thermo-mechanical model, free of requirements for detailed thermophysical property data, has recently been developed for purposes of evaluating FAST outcomes. The model consists of a hydrodynamic module which is used to predict the movement of a pulsatile, aerosol-bearing vapor bubble through the surrounding coolant and a heat transfer module which accounts for thermal interactions as the bubble thermally radiates to the surrounding coolant. The model predictions are consistent with key experimental trends, namely: (1) significantly reduced aerosol release as the coolant level increased, (2) greatly reduced aerosol release in sodium tests compared to release levels measured in a series of baseline water tests. The consistency of these trends is discussed in terms of thermo-mechanical characteristics of the respective coolants. Specifically, the inertia of the surrounding coolant impedes bubble transport to the free surface which addresses the first point above, and, relative to the second point, bubble lifetimes are sufficiently short relative to time estimates for transit to the free-surface, due principally to the effectiveness of quenching by radiation which is particularly pronounced in the case of sodium, owing to high reflectivity values. Additionally, pool subcooling was found to have a cross-cutting influence on aerosol release. Only in tests in which pool subcooling was reduced to ∼10 Kelvin was significant aerosol release detected. For those tests, which occurred in water, measurements suggest that coolant vaporization occurred at intensities above 3000 kg/m2-s, well beyond what has generally been reported from fuel coolant interaction studies in which the coolant interactions are with molten fuel forms. This set of findings will permit a more general assessment of the implications of fuel coolant interactions on the progression of core disruptive accidents, particularly with regards to assessing probable modes of in-vessel aerosol transport within sodium cooled reactors.


Author(s):  
Wendy J. Matthews ◽  
Karren L. More ◽  
Larry R. Walker

Haynes alloy HR-120 (Haynes and HR-120 are trademarks of Haynes International, Inc.) forms a protective oxide scale when exposed to the harsh operating environment of a microturbine primary surface recuperator. Primary surface recuperators manufactured from HR-120 are currently in use on the Capstone C65 MicroTurbine (MicroTurbine is a registered trademark of Capstone Turbine Corporation). Long-term microturbine tests of this alloy are currently being conducted at an elevated turbine exit temperature (∼100°F higher than that in a normal operation) at Capstone Turbine Corporation. Alloy samples that have been tested under steady-state microturbine operating conditions are removed after predetermined exposure intervals for characterization by Capstone Turbine Corporation in collaboration with Oak Ridge National Laboratory. Such evaluations include the characterization of surface oxide scales and the associated alloy compositional changes following a steady-state operation ranging from 1800 h to 14,500 h. Results from the microstructural and compositional analyses of these long-term steady-state engine-tested HR-120 samples are used to illustrate the progression of alloy oxidation in the microturbine operating environment.


CORROSION ◽  
1966 ◽  
Vol 22 (7) ◽  
pp. 194-197 ◽  
Author(s):  
L. K. MATSON ◽  
E. F. STEPHAN ◽  
P. D. MILLER ◽  
W. K. BOYD ◽  
R. P. MILFORD

Abstract Corrosion is a major problem in the Fluoride Volatility Process for recovery of nuclear fuel. Relatively large scale pilot plant developments are under way by the Chemical Technology Division of the Oak Ridge National Laboratory. In this process fuel is dissolved by hydrogen fluoride in a molten bath consisting of mixtures of such salts as NaF-LiF-ZrF4. Usual operating temperatures are near 1200 F (649 C). Because metals such as stainless steel and zirconium are to be dissolved in this process it is obvious that the salt mixture must be quite corrosive. This is particularly true because HF is sparged through the bath continuously. Experiments were carried out at Battelle on a laboratory scale to determine the feasibility of using cathodic protection to reduce the attack in process vessels. Polarization curves were developed under simulated operating conditions for the materials of interest, i.e., Inor-8, Zircaloy and graphite. Polarization characteristics were obtained by use of a potentiostat using platinum as a reference electrode and graphite as an anode. Experiments using rectangularly shaped coupons were carried out to determine the amount of protection furnished by the impressed current technique in the most corrosive salt composition. Specimens were made cathodic at current densities ranging from 3 to 50 amp/ft2. Excellent protection was furnished to the submerged portions of the specimens. However, severe attack occurred at the interface at reasonable current densities.


Author(s):  
Brian C. Kelleher ◽  
Kieran P. Dolan ◽  
Paul Brooks ◽  
Mark H. Anderson ◽  
Kumar Sridharan

Li 2 BeF 4 , or flibe, is the primary candidate coolant for the fluoride-salt-cooled high-temperature nuclear reactor (FHR). Kilogram quantities of pure flibe are required for repeatable corrosion tests of modern reactor materials. This paper details fluoride salt purification by the hydrofluorination–hydrogen process, which was used to regenerate 57.4 kg of flibe originating from the secondary loop of the molten salt reactor experiment (MSRE) at Oak Ridge National Laboratory (ORNL). Additionally, it expounds upon necessary handling precautions required to produce high-quality flibe and includes technological advancements which ease the purification and analysis process. Flibe batches produced at the University of Wisconsin are the largest since the MSRE program, enabling new corrosion, radiation, and thermal hydraulic testing around the United States.


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