Electric Field Induced Control of Thin Film Diblock Copolymer Domain Orientation

1996 ◽  
Vol 461 ◽  
Author(s):  
T. L. Morkved ◽  
W. A. Lopes ◽  
M. Lu ◽  
A. M. Urbas ◽  
H. M. Jaeger ◽  
...  

ABSTRACTLocal control of domain orientation in diblock copolymer thin films is demonstrated through the use of external electric fields. Thin films of a polystyrene-polymethylmethacrylate diblock copolymers, denoted P(S-b-MMA), were spin coated onto silicon nitride membrane substrates with prefabricated in-plane electrodes, forming cylindrical PMMA microdomains. Films annealed under an applied electric field (E ≤ 37V/μm) at 250°C for 24h under an argon atmosphere showed an alignment of the cylindrical microdomains parallel to the electric field lines. A quantitative measure of the degree of alignment was obtained by correlating the local field strength, E, and direction with the observed cylinder orientation. The alignment was found to saturate above E≈30V/μm, and to decrease rapidly as E falls below this value.

2015 ◽  
Vol 21 (S4) ◽  
pp. 84-89
Author(s):  
H. Wollnik ◽  
F. Arai ◽  
Y. Ito ◽  
P. Schury ◽  
M. Wada

AbstractIons that are moved by electric fields in gases follow quite exactly the electric field lines since these ions have substantially lost their kinetic energies in collisions with gas atoms or molecules and so carry no momenta. Shaping the electric fields appropriately the phase space such ion beams occupy can be reduced and correspondingly the ion density of beams be increased.


2021 ◽  
Vol 925 ◽  
Author(s):  
Kaushlendra Dubey ◽  
Sanjeev Sanghi ◽  
Amit Gupta ◽  
Supreet Singh Bahga

We present an experimental and numerical investigation of electrokinetic instability (EKI) in microchannel flow with streamwise conductivity gradients, such as those observed during sample stacking in capillary electrophoresis. A plug of a low-conductivity electrolyte solution is initially sandwiched between two high-conductivity zones in a microchannel. This spatial conductivity gradient is subjected to an external electric field applied along the microchannel axis, and for sufficiently strong electric fields an instability sets in. We have explored the physics of this EKI through experiments and numerical simulations, and supplemented the results using scaling analysis. We performed EKI experiments at different electric field values and visualised the flow using a passive fluorescent tracer. The experimental data were analysed using the proper orthogonal decomposition technique to obtain a quantitative measure of the threshold electric field for the onset of instability, along with the corresponding coherent structures. To elucidate the physical mechanism underlying the instability, we performed high-resolution numerical simulations of ion transport coupled with fluid flow driven by the electric body force. Simulations reveal that the non-uniform electroosmotic flow due to axially varying conductivity field causes a recirculating flow within the low-conductivity region, and creates a new configuration wherein the local conductivity gradients are orthogonal to the applied electric field. This configuration leads to EKI above a threshold electric field. The spatial features of the instability predicted by the simulations and the threshold electric field are in good agreement with the experimental observations and provide useful insight into the underlying mechanism of instability.


2016 ◽  
Vol 34 (1) ◽  
pp. 55-65 ◽  
Author(s):  
A. D. M. Walker ◽  
G. J. Sofko

Abstract. When studying magnetospheric convection, it is often necessary to map the steady-state electric field, measured at some point on a magnetic field line, to a magnetically conjugate point in the other hemisphere, or the equatorial plane, or at the position of a satellite. Such mapping is relatively easy in a dipole field although the appropriate formulae are not easily accessible. They are derived and reviewed here with some examples. It is not possible to derive such formulae in more realistic geomagnetic field models. A new method is described in this paper for accurate mapping of electric fields along field lines, which can be used for any field model in which the magnetic field and its spatial derivatives can be computed. From the spatial derivatives of the magnetic field three first order differential equations are derived for the components of the normalized element of separation of two closely spaced field lines. These can be integrated along with the magnetic field tracing equations and Faraday's law used to obtain the electric field as a function of distance measured along the magnetic field line. The method is tested in a simple model consisting of a dipole field plus a magnetotail model. The method is shown to be accurate, convenient, and suitable for use with more realistic geomagnetic field models.


2020 ◽  
Author(s):  
Paolo Raiteri ◽  
Peter Kraus ◽  
Julian Gale

Molecular dynamics simulations of the liquid-liquid interface between water and 1,2-Dichloroethane in the presence of weak external electric fields.<div>The effect of the use of 3D periodic Ewald summation and the effect of the simulation setup are discussed.</div><div>A new simple geometric method for designing the simulation cell is proposed. This method was thoroughly tested shown that it mitigates any artefacts to the use of 3D Ewald summation with external electric field.</div>


2020 ◽  
Author(s):  
L. Martinez ◽  
A. Dhruv ◽  
L. Lin ◽  
E. Balaras ◽  
M. Keidar

AbstractThis paper presents a numerical model to investigate the deformation of biological cells by applying external electric fields operating at or near cell resonant frequencies. Cells are represented as pseudo solids with high viscosity suspended in liquid media. The electric field source is an atmospheric plasma jet developed inhouse, for which the emitted energy distribution has been measured.Viscoelastic response is resolved in the entire cell structure by solving a deformation matrix assuming an isotropic material with a prescribed modulus of elasticity. To investigate cell deformation at resonant frequencies, one mode of natural cell oscillation is considered in which the cell membrane is made to radially move about its eigenfrequency. An electromagnetic wave source interacts with the cell and induces oscillation and viscoelastic response. The source carries energy in the form of a distribution function which couples a range of oscillating frequencies with electric field amplitude.Results show that cell response may be increased by the external electric field operating at or near resonance. In the elastic regime, response increases until a steady threshold value, and the structure moves as a damped oscillator. Generally, this response is a function of both frequency and magnitude of the source, with a maximum effect found at resonance. To understand the full effect of the source energy spectrum, the system is solved by considering five frequency-amplitude couplings. Results show that the total solution is a nonlinear combination of the individual solutions. Additionally, sources with different signal phases are simulated to determine the effect of initial conditions on the evolution of the system, and the result suggests that there may be multiple solutions within the same order of magnitude for elastic response and velocity. Cell rupture from electric stress may occur during application given a high energy source.SignificanceCold atmospheric plasma jets (CAPJs) have been widely researched for their potential applications in cancer therapy. Existing research has focused mainly on the ability of CAPJs to deliver a mixture of reactive species which can be absorbed by cancer cells and induce cell death. The objective of our study is to investigate the mechanical effect of CAPJ electromagnetic (EM) waves on interacting cells. By coupling the EM waves associated with plasma frequency and cell viscoelastic response, we have developed a numerical tool to investigate cell damage either by mechanical or thermal loads. This work is motivated by the promise of EM waves to function as a sensitizing agent for cancer cells in preparation for chemotherapy.


2004 ◽  
Vol 22 (4) ◽  
pp. 1233-1250 ◽  
Author(s):  
P. Janhunen ◽  
A. Olsson ◽  
H. Laakso

Abstract. The aim of the paper is to study how auroral potential structures close at high altitude. We analyse all electric field data collected by Polar on auroral field lines in 1996–2001 by integrating the electric field along the spacecraft orbit to obtain the plasma potential, from which we identify potential minima by an automatic method. From these we estimate the associated effective mapped-down electric field Ei, defined as the depth of the potential minimum divided by its half-width in the ionosphere. Notice that although we use the ionosphere as a reference altitude, the field Ei does not actually exist in the ionosphere but is just a convenient computational quantity. We obtain the statistical distribution of Ei as a function of altitude, magnetic local time (MLT), Kp index and the footpoint solar illumination condition. Surprisingly, we find two classes of electric field structures. The first class consists of the low-altitude potential structures that are presumably associated with inverted-V regions and discrete auroral arcs and their set of associated phenomena. We show that the first class exists only below ~3RE radial distance, and it occurs in all nightside MLT sectors (RE=Earth radius). The second class exists only above radial distance R=4RE and almost only in the midnight MLT sector, with a preference for high Kp values. Interestingly, in the middle altitudes (R=3–4RE) the number of potential minima is small, suggesting that the low and high altitude classes are not simple field-aligned extensions of each other. This is also underlined by the fact that statistically the high altitude structures seem to be substorm-related, while the low altitude structures seem to correspond to stable auroral arcs. The new finding of the existence of the two classes is important for theories of auroral acceleration, since it supports a closed potential structure model for stable arcs, while during substorms, different superposed processes take place that are associated with the disconnected high-altitude electric field structures. Key words. Magnetospheric physics (electric fields; auroral phenomena) – Space plasma physics (electrostatic structures)


2020 ◽  
Vol 6 (21) ◽  
pp. eaaz2915 ◽  
Author(s):  
Zdenek Futera ◽  
John S. Tse ◽  
Niall J. English

In a superionic (SI) ice phase, oxygen atoms remain crystallographically ordered while protons become fully diffusive as a result of intramolecular dissociation. Ice VII’s importance as a potential candidate for a SI ice phase has been conjectured from anomalous proton diffusivity data. Theoretical studies indicate possible SI prevalence in large-planet mantles (e.g., Uranus and Neptune) and exoplanets. Here, we realize sustainable SI behavior in ice VII by means of externally applied electric fields, using state-of-the-art nonequilibrium ab initio molecular dynamics to witness at first hand the protons’ fluid dance through a dipole-ordered ice VII lattice. We point out the possibility of SI ice VII on Venus, in its strong permanent electric field.


2004 ◽  
Vol 22 (2) ◽  
pp. 511-525 ◽  
Author(s):  
K. Oksavik ◽  
F. Søraas ◽  
J. Moen ◽  
R. Pfaff ◽  
J. A. Davies ◽  
...  

Abstract. In this paper we discuss counterstreaming electrons, electric field turbulence, HF radar spectral width enhancements, and field-aligned currents in the southward IMF cusp region. Electric field and particle observations from the FAST spacecraft are compared with CUTLASS Finland spectral width enhancements and ground-based optical data from Svalbard during a meridional crossing of the cusp. The observed 630nm rayed arc (Type-1 cusp aurora) is associated with stepped cusp ion signatures. Simultaneous counterstreaming low-energy electrons on open magnetic field lines lead us to propose that such electrons may be an important source for rayed red arcs through pitch angle scattering in collisions with the upper atmosphere. The observed particle precipitation and electric field turbulence are found to be nearly collocated with the equatorward edge of the optical cusp, in a region where CUTLASS Finland also observed enhanced spectral width. The electric field turbulence is observed to extend far poleward of the optical cusp. The broad-band electric field turbulence corresponds to spatial scale lengths down to 5m. Therefore, we suggest that electric field irregularities are directly responsible for the formation of HF radar backscatter targets and may also explain the observed wide spectra. FAST also encountered two narrow highly structured field-aligned current pairs flowing near the edges of cusp ion steps. Key words. Ionosphere (electric fields and currents). Magnetosphere physics (magnetopause, cusp, and boundary layers; auroral phenomena)


2017 ◽  
Vol 19 (47) ◽  
pp. 31958-31964 ◽  
Author(s):  
Feng-Wei Gao ◽  
Hong-liang Xu ◽  
Zhong-Min Su

Different strengths of external electric fields enhance the stability, control the inter-molecular charge transfer and strengthen the nonlinear optical responses of a π-dimer.


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