scholarly journals Probing Phonons in Plutonium

2003 ◽  
Vol 802 ◽  
Author(s):  
Joe Wong ◽  
Michael Krisch ◽  
Daniel L. Farber ◽  
Florent Occelli ◽  
Adam J. Schwartz ◽  
...  

Plutonium (Pu) is well known to have complex and unique physico-chemical properties [1]. Notably, the pure metal exhibits six solid-state phase transformations with large volume expansions and contractions along the way to the liquid state: α → β → γ → δ → δ' → ε→ liquid. Unalloyed Pu melts at a relatively low temperature ∼640 °C to yield a higher density liquid than that of the solid from which it melts, (Figure 1). Detailed understanding of the properties of plutonium and plutonium-based alloys is critical for the safe handling, utilization, and long-term storage of these important, but highly toxic materials. However, both technical and and safety issues have made experimental observations extremely difficult.

Author(s):  
L. N. Lazareva ◽  
◽  
L. I. Shtangret ◽  
J. V. Shapoval ◽  
O. S. Koval ◽  
...  

Проаналізовано 30 зразків меду бджолиного довготривалого зберігання (з 2009 по 2018 р.). Установлено, що діастазна активність меду падає. Так у 6 зразках меду діастазне число нижче ніж 10 од. Готе, ці зразки не відповідають вимогам державних стандартів. Виявлено, що при аналізі зразків меду бджолиного з 2009 по 2015 р. вміст гідроксиметилфурфуролу (ГМФ) був понад 25 мг/кг, що не відповідає вимогам ДСТУ. Зразки терміном зберігання з 2016 по 2018 р. відповідають за показниками якості меду першого ґатунку. Показано, що найбільше значення вмісту проліну відмічається у меді зразка № 11 2015 року – 773,0 мг/кг, а найнижчий показник вмісту проліну був у зразку № 25 2013 р. Електропровідність зразків меду тривалого зберігання становила від 0,128 до 0,524 мС/см, що відповідає вимогам щодо якості меду. Ключові слова: мед бджолиний, діастаза, ГМФ (гідроксиметилфурфурол), пролін, електропровідність.


Author(s):  
N. M. Morozova

During long-term storage, climatic and atmospheric factors affect the agricultural machine, which cause changes in the physical and chemical properties of structural materials, technical fluids, lubricants. Therefore, the development of technical and organizational measures related to improving the storage efficiency of combine harvesters is an urgent scientific task that the leading scientific institutes of the country are engaged in.


2021 ◽  
Vol 94 ◽  
pp. 65-75
Author(s):  
A. M. Kuzminskaya ◽  
◽  
M. V. Buzaeva ◽  
O. V. Ageeva ◽  
◽  
...  

Introduction. With long-term storage of gasoline in large-capacity tanks, the problem associated with their volatility becomes urgent. Evaporation of petroleum products and gasoline leads to a change in their physical and chemical properties, a decrease in the yield of light petroleum products during oil refining, and a deterioration in the performance characteristics of engines. In this regard, it becomes difficult to start engines, their reliability, fuel consumption increases and the service life is reduced. Lost light hydrocarbons pollute the environment and increase the fire hazard of enterprises. The aim of the work is to identify effective, inexpensive and safe methods for reducing the volatility of oil products, including gasoline, when stored in tanks. Research methods. A retrospective analysis of studies on the problems of reducing losses of petroleum products during their storage, transportation and use is carried out. Technical and organizational methods for reducing the evaporation of fuels and the use of chemical additives as an inexpensive and effective method for solving the problem of the volatility of gasolines are considered. The conclusion about the efficiency of using chemical additives to fuels to reduce volatility has been substantiated. Results and their discussion. Conclusions are made about the possibility of using surfactants as additives to reduce the evaporation of gasolines during long-term storage in tanks. The analysis of the main components and methods for the synthesis of surfactant compositions capable of creating a surfactant film at the liquid-atmosphere interface, which protects the liquid from evaporation. Conclusion. Reducing the volatility of gasoline with the use of inexpensive and effective additives introduced into the fuel in small quantities, not only reduces the explosion and fire hazard during storage in large tanks, reduces losses, but also prevents the negative impact on the environment from the ingress of low molecular hydrocarbons into it. Key words: volatility of petroleum products, losses during storage of gasoline, methods of reducing volatility, additives.


2007 ◽  
Vol 40 (4) ◽  
pp. 796-798 ◽  
Author(s):  
Bingyun Ao ◽  
Xiaolin Wang ◽  
Yongjun Wei ◽  
Yanzhi Zhang

In order to help resolve unknowns regarding aging effects of uranium during long-term storage of tritium, a number of experiments have been carried out by several researchers. However, almost no literature is available on the structural change of uranium tritide, mainly because its high toxicity and air-sensitivity render appropriate experiments very difficult. In this paper, a simple hermetic sample holder that fits the Philips X'Pert Pro X-ray diffractometer is described. It may be used to study the aging effects of uranium tritide during storage. The sample holder mainly consists of an aluminium container for sample storage and a Mylar window for X-ray measurements. This sample holder can also be used with other air-sensitive, radioactive and toxic materials. In this paper, the first results obtained from X-ray diffraction analysis of uranium hydride are presented.


2019 ◽  
Vol 178 (3) ◽  
pp. 67-70
Author(s):  
Anna MATUSZEWSKA ◽  
Marlena OWCZUK

Fuels that do not meet the requirements of quality standards cannot be used to power vehicle engines. The work involved physico-chemical analyses of non-normative fuel and its effect on the operational properties of the powered vehicle. The research fuels were two gasolines, characterized by a reduced resistance to oxidation processes due to their long-term storage. The results were compared to the properties of conventional fuels that met all normative requirements. The studies have shown that the fuel slightly deviating from the standard parameters does not noticeably affect the useful properties of the vehicle.


Biomedicines ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 50
Author(s):  
Andreas Ouranidis ◽  
Theofanis Vavilis ◽  
Evdokia Mandala ◽  
Christina Davidopoulou ◽  
Eleni Stamoula ◽  
...  

In the quest for a formidable weapon against the SARS-CoV-2 pandemic, mRNA therapeutics have stolen the spotlight. mRNA vaccines are a prime example of the benefits of mRNA approaches towards a broad array of clinical entities and druggable targets. Amongst these benefits is the rapid cycle “from design to production” of an mRNA product compared to their peptide counterparts, the mutability of the production line should another target be chosen, the side-stepping of safety issues posed by DNA therapeutics being permanently integrated into the transfected cell’s genome and the controlled precision over the translated peptides. Furthermore, mRNA applications are versatile: apart from vaccines it can be used as a replacement therapy, even to create chimeric antigen receptor T-cells or reprogram somatic cells. Still, the sudden global demand for mRNA has highlighted the shortcomings in its industrial production as well as its formulation, efficacy and applicability. Continuous, smart mRNA manufacturing 4.0 technologies have been recently proposed to address such challenges. In this work, we examine the lab and upscaled production of mRNA therapeutics, the mRNA modifications proposed that increase its efficacy and lower its immunogenicity, the vectors available for delivery and the stability considerations concerning long-term storage.


2014 ◽  
Vol 32 (No. 6) ◽  
pp. 595-600 ◽  
Author(s):  
L. Vrbiková ◽  
Š. Schmidt ◽  
F. Kreps ◽  
L. Tmáková ◽  
M. Čertík ◽  
...  

We investigated the influence of long-term storage (10 months) at an average ambient temperature of 25°C on oxidative stability of sunflower oils (made in Slovakia, Czech Republic, Austria, and Hungary) and their nutrients. Chemical properties were determined and changes in oxidative stability monitored. Oil samples were collected and analysed for the content of tocopherols and β-carotene. Degradation of nutrients depends on chemical composition of oils and storage conditions. It was found that the concentration of both antioxidants decreased in all the samples with the increase in storage time. According to the results, losses of total tocopherols and β-carotene in refined sunflower oils stored in transparent 5-l PET bottles and exposed to daylight at ambient temperature were found to be 52–64% and 63–65%, respectively. The country of origin had no statistically significant impact on the oxidative stability of stored sunflower oils.  


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4108
Author(s):  
Adrian Chlanda ◽  
Krystian Kowiorski ◽  
Marcin Małek ◽  
Ewa Kijeńska-Gawrońska ◽  
Monika Bil ◽  
...  

Graphene and its derivatives have attracted scientists’ interest due to their exceptional properties, making them alluring candidates for multiple applications. However, still little is known about the properties of as-obtained graphene derivatives during long-term storage. The aim of this study was to check whether or not 14 months of storage time impacts graphene oxide flakes’ suspension purity. Complementary micro and nanoscale characterization techniques (SEM, AFM, EDS, FTIR, Raman spectroscopy, and elemental combustion analysis) were implemented for a detailed description of the topography and chemical properties of graphene oxide flakes. The final step was pH evaluation of as-obtained and aged samples. Our findings show that purified flakes sustained their purity over 14 months of storage.


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