scholarly journals Immiscible liquid-liquid displacement in capillary tubes: viscoelastic effects

Author(s):  
Edson José Soares ◽  
Paulo R. de Souza Mendes ◽  
Márcio da S. Carvalho
2005 ◽  
Vol 127 (1) ◽  
pp. 24-31 ◽  
Author(s):  
E. J. Soares ◽  
M. S. Carvalho ◽  
P. R. Souza Mendes

We analyze the liquid-liquid displacement in capillary tubes. The goal is to determine the amount of displaced liquid that remains attached to the tube wall and the configuration of the liquid-liquid interface at different operating parameters. The study encompasses both numerical and experimental approaches. The finite element method is used to solve the governing equations and, in order to validate the predictions, visualization experiments are performed to capture images of the interface. The numerical results were obtained for the assumption of negligible inertia, and the effects of viscosity ratio and capillary number are investigated. The predictions and experimental observations are in good agreement.


1962 ◽  
Vol 2 (02) ◽  
pp. 156-164 ◽  
Author(s):  
H.D. Outmans

Abstract In steady vertical flow, the interface of an immiscible liquid-liquid displacement is horizontal for any flow rate below the critical in non-vertical flow, however, the shape of the interface in the steady state does depend on the flow rate, and the purpose of this paper is to calculate the unsteady interfaces during the transition of one steady state of flow to another. A knowledge of these transient interfaces is of considerable importance in reservoir engineering where the calculation of breakthrough recovery depends on the instant the interface reaches the producing wells and on the shape of the interface at that time. Although the emphasis is put on transient interfaces, which eventually approach stable equilibrium, it is shown that if the displacement exceeds a critical rate no equilibrium is possible. The interface is then unstable and viscous fingers are formed during the displacement. The critical rate and the shape of the transient and equilibrium interfaces are affected by the effective interfacial tension; but since this effective inter facial tension appears in the calculations only in combination with the in verse square of the thickness of the medium, its effect in the reservoir would appear to be negligible compared to its significance in model experiments. Introduction Stability criteria and the early growth of interfacial disturbances in a plane parallel to the boundaries of a dipping formation in which oil is displaced by an incompressible fluid were described in a previous paper. This type of instability is significant in thin reservoirs. However, if the reservoir has appreciable thickness, then interfacial stability in vertical planes, normal to the upper and lower boundaries, also becomes important (the displacement is supposed to be parallel to these vertical planes). The difference between the two stability problems is that, in the first case, the intersections of the interface with planes parallel to the boundaries are normal to the direction of the displacement; in the second case, the intersections, this time with vertical planes, are not normal to the displacement. Instead, they are tilted at an angle which depends on the displacement rate. The tilt of steady interfaces was calculated by Dietz who also determined the critical rate of displacement for stability in the vertical plane by assuming that this rate would coincide with an interfacial tilt equal to the dip of the formation. The critical rate thus calculated is the same as has been found for thin reservoirs (see Eq. 1.1 of Ref. 1 and of the present paper). Dietz's calculation of the stable tilt was verified by laboratory experiments and the agreement was found to be fairly good. It is doubtful, however, that stable tilts actually exist in the reservoir because a change in production rate is not followed by an instantaneous adjustment of the interface to the new rate but, rather, by a transition period during which the interface changes from one equilibrium tilt to the other. The principal objective of this paper has been to describe these transient interfaces without putting any restrictions on the flow conditions or the shape of the interface, as had been done previously. The second objective was to compute the critical velocity, taking into account capillary effects, and the third was to evaluate, at least qualitatively, the shape of the front at rates above the critical, again without making the simplifying assumptions introduced by previous investigators. In the following sections two examples are given of the calculation of interfacial motion. The first describes this motion for an initially horizontal interface in a dipping layer, and the second for a vertical interface in a horizontal layer. The mathematical formulation of the problem is non linear in the boundary conditions, and this prohibits its solution in closed form. Instead, the solution is obtained in the form of higher-order approximations. SPEJ P. 156^


1966 ◽  
Vol 6 (03) ◽  
pp. 247-253 ◽  
Author(s):  
Necmettin Mungan

Abstract A study was made of the effects of wettability and interfacial tension the immiscible displacement of a liquid by another liquid for porous media. The influence of viscosity ratio was also investigated. Porous media used were polytetrafluoroethylene (TFE) cores prepared by compressing TFE powder under different pressures. It is shown that displacement of a wetting by a nonwetting liquid is always less efficient than the displacement of a nonwetting by a wetting fluid, all other things being equal. In the former case, the recovery efficiency can be increased substantially by either reducing the interfacial tension or increasing the viscosity of the displacing fluid. A qualitative discussion is given on the implications of this work to the recovery of crude oil by waterflooding. Introduction The high cost of oil exploration and new recovery schemes makes it imperative that waterflooding be conducted under conditions favoring most efficient oil recovery. To improve oil recovery by waterflooding, it is essential that the role played by interfacial forces in the entrapment of residual oil be studied and understood. Interfacial phenomena in natural rock, connate water and crude oil systems are very complicated because of the complexity of the natural liquids found in petroleum reservoirs, because of our inability to adequately describe the geometrical structure of the porous media and because of a lack of understanding of physical and chemical interactions between the liquids and surface of the pores. The problem becomes further complicated when one tries to elucidate the role of interfacial phenomena in fluid flow. Numerous studies of the displacement of oil by water under different interfacial tension or wettability conditions have been made. These studies have been performed in silica, alundum or sandstone systems using water and paraffin oil and also some surface active material to control the interfacial tension or and the contact angle. Unfortunately, the high energies of various interfaces involved favor adsorption and orientation of the surface active material at the intrafaces. Also the surface active material concentration at the interfaces exceeds that in the bulk of the liquid phases. Such surface excess may cause the surfactant distribution, the contact angle and the interfacial tension to differ from their measured static equilibrium values and makes interpretation of the displacement experiments difficult. Furthermore, as changes in also lead to changes in cos, the role played individually by one of these parameters in the displacement becomes obscured by the effect of the other. To circumvent these difficulties, a low surface energy solid and true solutions or pure liquids should be used. Use of a low surface energy solid minimizes adsorption and orientation effects at the solid-liquid interfaces. By controlling and cos through use of selected pairs of pure liquids or true solutions rather than by surfactants, the adsorption effects at liquid-liquid interfaces are eliminated. In the present study TFE cores were used as me porous media. Liquids used were water sucrose solutions, paraffin oils and benzyl, n-butyl and isobutyl alcohols. The interfacial tension was varied from 40 to 1.1 dynes/cm by suitably choosing the liquid pair. A surface above material was added to the water-oil system only in the case where interfacial tension of 0.5 dynes/ cm was desired. No precise changes of cos were attempted. However, either the displaced or the displacing liquid could be made the one which preferentially wets the TFE surface. Using sucrose solutions and blends of paraffin oils proved to be a convenient way of changing the viscosity ratio between the displaced and displacing liquids. The present investigation examines the effect of interfacial tension, wettability and viscosity ratio on the immiscible liquid-liquid displacement from porous media. SPEJ P. 217ˆ


Soil Research ◽  
1988 ◽  
Vol 26 (3) ◽  
pp. 451 ◽  
Author(s):  
NW Menzies ◽  
LC Bell

Soil solutions were extracted by immiscible liquid displacement with trichlorotrifluoroethane and by centrifuge drainage from surface and subsoil samples having a wide range of chemical and physical properties. Extractions were performed on field-moist samples and on air-dry samples which were re-wetted to different matric suctions and for different lengths of time. The composition of the soil solution obtained was the same with both methods of extraction when samples had been pre-wet to a matric suction of 0-1 bar. Immiscible liquid displacement extracted solution from a krasnozem surface soil at suctions as great as 15 bar; in contrast, centrifuge drainage failed to extract solution from this soil at >3 bar. The concentration of ions in solutions extracted by displacement from soils with increasing matric suction rose to a far greater extent than that anticipated if concentration was the only mechanism operating. In re-wet air-dry samples, major cations and anions were at equilibrium levels in solution after incubation for 1 day; longer incubation times resulted in an artificial elevation of ionic strength through mineralization of organic matter in some surface samples. The levels achieved after 1 day were similar to those present in solutions extracted from field-moist samples.


2009 ◽  
Vol 641 ◽  
pp. 63-84 ◽  
Author(s):  
EDSON J. SOARES ◽  
RONEY L. THOMPSON

The motion of two immiscible liquids in a capillary tube is analysed, theoretically and numerically, for the case in which a residual film confines the displacing liquid to the core of this tube. The theoretical analysis has shown that the three flow regimes predicted by Taylor (J. Fluid Mech., vol. 10, 1961, pp. 161–165), for the case of gas-displacement, can only be achieved when the ratio of the viscosity of the displaced fluid to that of the displacing one is greater than 2. An elliptic mesh generation technique, coupled with the Galerkin finite-element method, is used to compute the velocity field and the configuration of the interface between the two fluids. A map of cases in the Cartesian space defined by the capillary number (Ca) and the viscosity ratio (Nμ) is constructed in order to locate the different flow patterns the problem exhibits. The critical capillary number at which the flow enters the transition range between the bypass regime and the full-recirculating one is given. While a decrease of the fraction of mass attached to the wall is achieved by decreasing Ca or increasing Nμ, bypass flow patterns are formed as a consequence of high values of the capillary number and viscosity ratio.


2020 ◽  
Vol 32 (1) ◽  
pp. 013105
Author(s):  
P. R. Varges ◽  
P. E. Azevedo ◽  
B. S. Fonseca ◽  
P. R. de Souza Mendes ◽  
M. F. Naccache ◽  
...  

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