Environmental impact of landfill on groundwater quality and agricultural soils in Nigeria

Physical, chemical and bacteriological analyses were carried out of water samples from three boreholes located near a landfill, and or soil samples at Akure, Nigeria, to ascertain the effect of the dumpsite on the groundwater and soil quality. The samples from borehole locations with radial distances of 50, 80, and 100 m, respectively, away from the landfill and twelve soil samples collected at distances 0 (dump centre), 10, 20, and 30 m away from the refuse dump were analysed. The parameters determined were the turbidity, temperature, pH, dissolved oxygen (DO), total dissolved solids (TDS), total hardness (TH), total iron, nitrate, nitrite, chloride, calcium and heavy metals like copper, zinc, and lead. Most of these parameters indicated pollution but were below the World Health Organization (WHO) limits for consumption. The pH ranged from 5.7 to 6.8 indicating toxic pollution, the turbidity values were between 1.6 and 6.6 NTU, and the temperature ranged from 26.5°C to 27.5°C. The concentrations of iron, nitrate, nitrite and calcium ranged from 0.9 to 1.4, 30 to 61, 0.7 to 0.9, and 17 to 122 mg/l, respectively. Out of heavy metals, zinc ranged between 3.3 and 5.4 mg/l and lead ranged from 1.1 to 1.2 mg/l. Soil water holding capacity, porosity, pH, organic matter, organic carbon and organic nitrogen ranged from 38 to 54, 44 to 48, 6.9–7.5, 2.44–4.27, 1.42–2.48, and 0.12–0.21%, respectively. Statistical analyses indicated significant differences at 95% level. The results showed that all the boreholes were not strongly polluted but require treatment before use while the soil is absolutely unsuitable for the crop production. Re-designing of sanitary landfills to prevent leachate from getting to the water table, adoption of clean technology for recycling greenhouse gases and a sustainable land management programme for reclamation are recommended.

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Levels of heavy metals in soils and food crops cultivated within selected mining sites in Ebonyi State, Nigeria

Health and Environment ◽

10.25082/he.2021.01.003 ◽

2021 ◽

Vol 2 (1) ◽

pp. 84-95

Author(s):

David Okechukwu Okeke ◽

◽

Jonathan Chinenye Ifemeje ◽

Keyword(s):

Heavy Metals ◽

Control Site ◽

Soil Samples ◽

World Health ◽

Food Crops ◽

Food Crop ◽

Mining Site ◽

Mining Sites ◽

Health Association ◽

Health Organization

The level of heavy metals (Fe, Cu, As, Pb, Cd, Mg, Ca, Hg, Ni, Cr, Zn, Ag, Co, Mo, Se and Al) in soils and food crops (okra, cassava and rice) cultivated within selected mining sites in Ebonyi State, Nigeria were determined using FS240AA Atomic Absorption Spectrophotometer (AAS) according to the method of American Public Health Association (APHA). Soil samples were collected from Enyigba mining site, Ikwo mining site, AmeriAmekamining site, Izza mining site, MkpumeAkwatakwa mining site and MpumeAkwaokuku mining site while the food crop samples (okra, cassava and rice) were collected from the farmlands within the mining sites. Control samples were collected 500m away from the mining destinations were there was no evidence of mining activities on the soils. A total of sixty sub-samples and six control soil samples were collected for this study. Generally, the values of all the heavy metals analyzed for soil and food crop samples were higher than the values recommended by the World Health Organization (WHO), and those from the control site suggesting possible mobility of the metals from mining sites to farmlands through leaching and runoffs. The findings in this study also revealed that the food crops contain heavy metals exceeding the maximum permissible concentration, and could be detrimental to human health when they are consumed.

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Review of Sewage Sludge as a Soil Amendment in Relation to Current International Guidelines: A Heavy Metal Perspective

Sustainability ◽

10.3390/su13042317 ◽

2021 ◽

Vol 13 (4) ◽

pp. 2317

Author(s):

Nuno Nunes ◽

Carla Ragonezi ◽

Carla S.S. Gouveia ◽

Miguel Â.A. Pinheiro de Carvalho

Keyword(s):

Heavy Metals ◽

Sewage Sludge ◽

Crop Production ◽

Agricultural Soils ◽

World Health ◽

Bioenergy Crops ◽

Critical Parameters ◽

Degraded Land ◽

Inorganic Matter ◽

Wide Range

Overexploitation of resources makes the reutilization of waste a focal topic of modern society, and the question of the kind of wastes that can be used is continuously raised. Sewage sludge (SS) is derived from the wastewater treatment plants, considered important underused biomass, and can be used as a biofertilizer when properly stabilized due to the high content of inorganic matter, nitrate, and phosphorus. However, a wide range of pollutants can be present in these biosolids, limiting or prohibiting their use as biofertilizer, depending on the type and origin of industrial waste and household products. Long-term applications of these biosolids could substantially increase the concentration of contaminants, causing detrimental effects on the environment and induce hyperaccumulation or phytotoxicity in the produced crops. In this work, some critical parameters for soils and SS agronomic use, such as organic matter, nitrogen, phosphorous, and potassium (NPK), and heavy metals concentration have been reviewed. Several cases of food crop production and the accumulation of heavy metals after SS application are also discussed. SS production, usage, and legislation in EU are assessed to determine the possibility of sustainable management of this bioresource. Additionally, the World Health Organization (WHO) and Food and Agriculture Organization (FAO) guidelines are addressed. The opportunity to produce bioenergy crops, employing sewage sludge to enhance degraded land, is also considered, due to energy security. Although there are numerous advantages of sewage sludge, proper screening for heavy metals in all the variants (biosolids, soil, food products) is a must. SS application requires appropriate strict guidelines with appropriate regulatory oversight to control contamination of agricultural soils.

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Assessment of some heavy metals concentrations in soil and groundwater around refuse dumpsite in Ibadan Metropolis, Nigeria

Nigerian Journal of Technology ◽

10.4314/njt.v39i1.33 ◽

2020 ◽

Vol 39 (1) ◽

pp. 301-305

Author(s):

I.O. Saheed ◽

S.O. Azeez ◽

A.A. Jimoh ◽

V.A. Obaro ◽

S.A. Adepoju

Keyword(s):

Heavy Metals ◽

Ground Water ◽

Atomic Absorption Spectrophotometry ◽

Soil Samples ◽

World Health ◽

Heavy Metal Concentrations ◽

Absorption Spectrophotometry ◽

Dug Wells ◽

Health Organization

This study reports the determination of some heavy metals’ concentration in soil and groundwater around refuse dumpsites in five locations in Ibadan Metropolis, Nigeria. Five samples were collected from each soil and ground water locations and analysed for heavy metals(Cd, Co, Pb, Cr, Zn, Mn and Ni)using Atomic Absorption Spectrophotometry. The soil samples were obtained in triplicates at 25cm depth intervals whereas the water samples were obtained from hand dug wells less than 10 m deep. The range of the values of heavy metal concentrations obtained in water is Co (0.01-0.04), Pb (0.01-0.02), Cr (0.02-0.05), Zn (0.40-0.70), Mn (0.02-0.05) and Ni (0.02-0.05), but Cadmium was not detected. The concentrations of Pb and Ni in ground water obtained from Arapaja, Aleshinloye and Alafara were higher than the World Health Organization (WHO) and Standard Organisation of Nigeria (SON) limits. The results obtained showed that the concentrations of Cd, Co, Pb, Ni and Cr in soil exceeded the WHO and SON permissible limits. However, Zn and Mn were below the limit. Keywords: Heavy metals, Dumpsite, Groundwater, Soil samples, Concentrations.

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Assessment of Heavy Metals Concentration in Swampy Agricultural Soil of Nasarawa West, Nigeria

Asian Journal of Advanced Research and Reports ◽

10.9734/ajarr/2019/v3i129786 ◽

2019 ◽

pp. 1-9

Author(s):

Abbas Abdullahi Auta ◽

Umar Ibrahim ◽

Abdullahi Abubakar Mundi ◽

Idris Mohammed Mustapha ◽

Musa Usman Sarki

Keyword(s):

Heavy Metals ◽

Agricultural Soil ◽

Agricultural Soils ◽

International Standards ◽

World Health ◽

State University ◽

High Concentration ◽

Sampling Locations ◽

Regulatory Standard ◽

Health Organization

Aim: This research was carried out to investigate the concentration of heavy metals in swampy agricultural soil of Nasarawa west, Nigeria. Study Design: To compare the swampy soil heavy metal concentrations with regulatory standard or allowable values by the World Health Organization (WHO) and other National and International standards. Place and Duration of Study: Department of Physics, Nasarawa State University Keffi between January, 2018 and October, 2018. Methodology: Ten soil samples from each of thefive sampling locations (Karu, Keffi, Kokona, Nasarawa, and Toto) were randomly collected. A total of fifty (50) soil sampleswere collected within the period of one week. The collected samples were stored in polyethylene bag and labeled properly and taken to the Center for Energy Research and Development (CERD) at Obafemi Awolowo University Ile- ife Osun State, Nigeria. At CERD, elemental analysis was carried out for the fifty sample using X- ray fluorescent spectrometry analyzer. Results: The range of mean concentration of Zn, As, Cd, Pb, Fe, Ni, and Cu (in KR, KF, KK, NS, and TT locations) are 243.60- 502.80 mg/kg, 7.40- 37.00mg/kg, 260.90- 524.50 mg/kg, 167.80- 336.60 mg/kg, 20222.90- 58170.50 mg/kg, 342.20- 555.10 mg/kg, and 266.60- 515.90 mg/kg respectively. The average mean of all the sample locations are found to be higher than the WHO allowable concentration limits of As (20 mg/kg), Pb (100 mg/kg), Cd (3 mg/kg), Zn (300 mg/kg), Fe (n.a), Ni (50 mg/kg), and Cu (100 mg/kg)respectively. There is high concentration Zn, As, Cd, Pb, Fe, Ni, and Cu in the swampy soil. Conclusion: The results indicates that the swampy agricultural soils of Nasarawa west (Karu, Keffi, Kokona, Nasarawa, and Toto) are contaminated with toxic metals (Zn, As, Cd, Pb, Fe, Ni, and Cu).

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Assessment of Irrigation Quality of Disposal Water of Ashuganj-Polash Agro-Irrigation Project, Brahmanbaria Bangladesh

Journal of AgriSearch ◽

10.21921/jas.v4i04.10205 ◽

2017 ◽

Vol 4 (04) ◽

Author(s):

ABDUR RAZZAK ◽

PARSA SANJANA ◽

BELAL HOSSAIN ◽

DEBJIT ROY ◽

BIDHAN CHANDRA NATH

Keyword(s):

Soil Sample ◽

Water Samples ◽

Crop Production ◽

Soil Samples ◽

Chemistry Laboratory ◽

Total Hardness ◽

Sodium Absorption ◽

Irrigation Project ◽

Crop Field ◽

Initial Soil

The study was conducted at Ashuganj-Polash agro-irrigation project (APAIP), Brahmanbaria,aim to determine the chemical properties of power plant disposal water and to assess its suitability for irrigation. Initial soil samples (before irrigating crop field) and final soil samples (after crop harvesting) were collected. During irrigation ten water samples (six from crop field and four from irrigation canals) were collected for analysis. All soil samples were analyzed in Humboldt soil testing laboratory and water samples in bio-chemistry laboratory of Bangladesh Agricultural University and compared to FAO irrigation standard. Results show thatthe sodium absorption ratio (SAR) (0.53 to 0.88), residual sodium bi-carbonate (0.8 to 1.3meq L-1), Kelly’s ratio (0.31 to 0.6) and total hardness (85 to 150) found in normal range and largely suitable for irrigation. Soluble sodium percentage values found in satisfactory (20.26 to 41.1) level and magnesium absorption (57.1 to 76.4) found unsuitable for irrigation. Statistically similar value of pH, EC, total nitrogen, organic carbon, calcium, magnesium and phosphorus in initial and final soil sample were observed. But potassium and sulfur value reduced in final soil sample from initial soil. The water samples fall within the permissible limit and found suitable for crop production

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Describing Phosphorus Sorption Processes on Volcanic Soil in the Presence of Copper or Silver Engineered Nanoparticles

Minerals ◽

10.3390/min11040373 ◽

2021 ◽

Vol 11 (4) ◽

pp. 373

Author(s):

Jonathan Suazo-Hernández ◽

Erwin Klumpp ◽

Nicolás Arancibia-Miranda ◽

Patricia Poblete-Grant ◽

Alejandra Jara ◽

...

Keyword(s):

Organic Matter ◽

Crop Production ◽

Agricultural Soils ◽

Ph Value ◽

Consumer Products ◽

Soil Samples ◽

Engineered Nanoparticles ◽

P Availability ◽

Agricultural Crop ◽

Phosphorus Sorption

Engineered nanoparticles (ENPs) present in consumer products are being released into the agricultural systems. There is little information about the direct effect of ENPs on phosphorus (P) availability, which is an essential nutrient for crop growthnaturally occurring in agricultural soils. The present study examined the effect of 1, 3, and 5% doses of Cu0 or Ag0 ENPs stabilized with L-ascorbic acid (suspension pH 2–3) on P ad- and desorption in an agricultural Andisol with total organic matter (T-OM) and with partial removal of organic matter (R-OM) by performing batch experiments. Our results showed that the adsorption kinetics data of H2PO4− on T-OM and R-OM soil samples with and without ENPs were adequately described by the pseudo-second-order (PSO) and Elovich models. The adsorption isotherm data of H2PO4− from T-OM and R-OM soil samples following ENPs addition were better fitted by the Langmuir model than the Freundlich model. When the Cu0 or Ag0 ENPs doses were increased, the pH value decreased and H2PO4− adsorption increased on T-OM and R-OM. The H2PO4− desorption (%) was lower with Cu0 ENPs than Ag0 ENPs. Overall, the incorporation of ENPs into Andisols generated an increase in P retention, which may affect agricultural crop production.

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An analysis of heavy metals contamination and estimating the daily intakes of vegetables from Uganda

Toxicology Research and Application ◽

10.1177/2397847320985255 ◽

2021 ◽

Vol 5 ◽

pp. 239784732098525

Author(s):

Keneth Iceland Kasozi ◽

Eric Oloya Otim ◽

Herbert Izo Ninsiima ◽

Gerald Zirintunda ◽

Andrew Tamale ◽

...

Keyword(s):

Heavy Metals ◽

Daily Intake ◽

Principal Component ◽

Absorption Spectrometry ◽

Cross Sectional Study ◽

Essential Elements ◽

World Health ◽

Cross Sectional ◽

Health Organization ◽

Daily Intakes

Background: Environmental contamination with elevated levels of copper (Cu), cobalt (Co), iron (Fe), zinc (Zn), lead (Pb), chromium (Cr6+), cadmium (Cd), and nickel (Ni)—all states of which are found in Uganda—raises health risk to the public. Pb, Cr6+, Cd, and Ni for instance are generally considered nonessential to cellular functions, notwithstanding the importance of the oxidative state of the metals in bioavailability. As such, we aimed in this study (i) to evaluate heavy metal concentrations in four vegetables from a typical open-air market in Uganda, (ii) to assess the safety of consuming these vegetables against the World Health Organization (WHO) recommended limits of heavy metals consumption, and (iii) to formulate a model of estimated daily intake (EDI) among consumers in the country. Methods: This was a cross-sectional study conducted in five georeferenced markets of Bushenyi district in January 2020. Amaranthus, cabbages, scarlet eggplants, and tomatoes were collected from open markets, processed, and analyzed by atomic absorption spectrometry. Modeled EDI, principal component (PCA) and cluster analysis (CA) were conducted to identify relationships in the samples. Results: The levels of essential elements in the four vegetables were found to fall from Co > Cu > Fe > Zn. Those of non-essential metals were significantly higher and followed the pattern Cd > Cr > Pb > Ni. The highest EDI values were those of Cu in scarlet eggplants, Zn in amaranthus, Fe in amaranthus, Co in amaranthus, Pb in cabbages, total Cr in scarlet eggplant, Cd in cabbages and tomatoes, and Ni in cabbages. In comparison to international limits, EDIs for Zn, Cu, Co and Fe were low while Ni in cabbages were high. PCA showed high variations in scarlet eggplant and amaranthus. The study vegetables were found to be related with each other, not according to the location of the markets from where they were obtained, but according to their species by CA. Conclusion: The presence of non-essential elements above WHO limits raises policy challenges for the consumption and marketing of vegetables in the study area. Furthermore, low EDIs of essential elements in the vegetables create demand for nutritious foods to promote healthy communities.

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Evaluation of Groundwater Quality in the Vicinity of Khurrianwala Industrial Zone, Pakistan

Water ◽

10.3390/w10101321 ◽

2018 ◽

Vol 10 (10) ◽

pp. 1321 ◽

Cited By ~ 7

Author(s):

Muhammad Aleem ◽

Cao Shun ◽

Chao Li ◽

Arslan Aslam ◽

Wu Yang ◽

...

Keyword(s):

Water Quality ◽

Groundwater Quality ◽

Anthropogenic Activities ◽

World Health ◽

Total Hardness ◽

Industrial Zone ◽

High Concentration ◽

Physico Chemical ◽

Health Organization ◽

National Environmental

The industrial augmentation and unguided anthropogenic activities contaminate water sources in most parts of the world especially in developing countries like Pakistan. High concentration of pollutants in groundwater affects human, soil, and crop health badly. The present study was conducted to investigate groundwater quality for drinking and irrigation purposes in an industrial zone of Pakistan. A GIS tool was used to investigate the spatial distribution of different physico-chemical parameters. In this study, the average results exceeding World Health Organization (WHO) and National Environmental Quality Standards (NEQS) were found for pH 7.84, total dissolved solids (TDS) 1492 mg/L, phosphate 0.51 mg/L, dissolved oxygen (DO) 9.92% saturation, F-coli 6.48 colonies/100 mL, Na+ 366 mg/L, HCO3− 771 mg/L, sulfate 251 mg/L, chlorides 427 mg/L, total hardness (as CaCO3) 292 mg/L, electrical conductivity (EC) 2408 μS/cm, iron (Fe) 0.48 mg/L, chrome (Cr) 0.50 mg/L, arsenic (As) 0.04 mg/L, total phosphorus (TP) 0.17 mg/L, sodium adsorption ratio (SAR) 9.76 (in meq/L), residual sodium carbonate (RSC) 9.28 meq/L, % ion balance 14.4 (in meq/L), percentage sodium ion (% Na+) concentration 58.9 meq/L, and water quality index (WQI) 69.0. The trend of cations and anions were (in meq/L) Na > Mg > Ca > K and HCO3 > Cl > CO3 > SO4 respectively. Although the results of the present study showed poor conditions of the groundwater for drinking as WQI but and irrigation purposes as SAR, it needs to improve some more conditions for the provision of safe drinking water and irrigation water quality.

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Assessment of heavy metals in soils of a vineyard region with the use of principal component analysis

Scientia Agricola ◽

10.1590/s0103-90162009000300011 ◽

2009 ◽

Vol 66 (3) ◽

pp. 361-367 ◽

Cited By ~ 7

Author(s):

Gustavo Souza Valladares ◽

Otávio Antônio de Camargo ◽

José Ruy Porto de Carvalho ◽

Alessandra Maria Cia Silva

Keyword(s):

Heavy Metals ◽

Principal Component Analysis ◽

Agricultural Soils ◽

Principal Component ◽

Component Analysis ◽

Soil Samples ◽

Metal Concentrations ◽

Zn Content ◽

Heavy Metals In Soils ◽

Cu And Zn

Agricultural management with chemicals may contaminate the soil with heavy metals. The objective of this study was to apply Principal Component Analysis and geoprocessing techniques to identify the origin of the metals Cu, Fe, Mn, Zn, Ni, Pb, Cr and Cd as potential contaminants of agricultural soils. The study was developed in an area of vineyard cultivation in the State of São Paulo, Brazil. Soil samples were collected and GPS located under different uses and coverings. The metal concentrations in the soils were determined using the DTPA method. The Cu and Zn content was considered high in most of the samples, and was larger in the areas cultivated with vineyards that had been under the application of fungicides for several decades. The concentrations of Cu and Zn were correlated. The geoprocessing techniques and the Principal Component Analysis confirmed the enrichment of the soil with Cu and Zn because of the use and management of the vineyards with chemicals in the preceding decades.

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Ghanaians Might Be at Risk of Excess Dietary Intake of Potassium Based on Food Supply Data

Journal of Nutrition and Metabolism ◽

10.1155/2018/5989307 ◽

2018 ◽

Vol 2018 ◽

pp. 1-9 ◽

Cited By ~ 1

Author(s):

David Oscar Yawson ◽

Michael Osei Adu ◽

Benjamin Ason ◽

Frederick Ato Armah ◽

Emmanuel Boateng ◽

...

Keyword(s):

Dietary Intake ◽

Food Supply ◽

Crop Production ◽

Production Systems ◽

Balance Sheet ◽

Food Composition ◽

World Health ◽

Noncommunicable Diseases ◽

K Deficiency ◽

Health Organization

The World Health Organization (WHO) has highlighted the beneficial role of adequate intake of potassium (K) in combating the global burden of noncommunicable diseases (NCDs), mainly hypertension and cardiovascular diseases. Diets are the main source of K supply to humans and can contribute to both K deficiency (hypokalemia) and excess (hyperkalemia). While global attention is currently devoted to K deficiency, K excess can be even more dangerous and deserves equal attention. The objectives of this paper were to (i) estimate the K intake of Ghanaian population using food supply and food composition data and (ii) compare this estimate with the WHO-recommended requirement for K in order to assess if there is a risk of inadequate or excess K intake. Food supply data (1961–2011) were obtained from the Food Balance Sheet (FBS) of the Food and Agriculture Organization of the United Nations to derive trends in food and K supply. The average food supply in the FBS for 2010 and 2011 was used in assessing the risk of inadequate or excess dietary intake of K. The K content of the food items was obtained from food composition databases. Based on 2010-2011 average data, the K supply per capita per day was approximately 9,086 mg, about 2.6-fold larger than the WHO-recommended level (3,510 mg). The assessment suggests a potentially large risk of excess dietary K supply at both individual and population levels. The results suggest the need for assessing options for managing K excess as part of food security and public health strategies. The results further underscore a need for assessment of the K status of staple food crops and mixed diets, as well as K management in food crop production systems in Ghana.

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