scholarly journals Ligand Assisted Control of Photoluminescence in Organometal Perovskite Nanocrystals

2021 ◽  
Vol 23 (2) ◽  
pp. 89
Author(s):  
K.S. Sekerbayev ◽  
G.K. Mussabek ◽  
Ye. Shabdan ◽  
Ye.T. Taurbayev

Organometal perovskite nanocrystals have shown remarkable properties not only in photovoltaics, but also in light-emitting devices. In this work colloidal nanocrystals of organometal perovskite CH3NH3PbBr3 (MAPBr) with effective visible photoluminescence were synthesized by the ligand assisted reprecipitation method. The studies were carried out by photoluminescence spectroscopy and optical transmission spectroscopy. Analysis of the photoluminescence and transmission spectra showed that by changing the concentration of the ligands oleylamine and octylamine, it is possible to control the size of nanocrystals and the photoluminescence wavelength due to the quantum confinement effect. It was shown that the increase in ligands concentration in MAPBr perovskite nanocrystals (NCs) solutions decreases the width of the peak which indicates a better quality of the obtained nanocrystals. An increase in the band gap indicates a decrease in the size of the nanocrystals. Replacing the ligands in the colloidal perovskite NCs solutions leads to shift of the photoluminescence peak from 456 to 535 nm.


Nanomaterials ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 459 ◽  
Author(s):  
Lung-Chien Chen ◽  
Zong-Liang Tseng ◽  
Dai-Wei Lin ◽  
Yu-Shiang Lin ◽  
Sheng-Hui Chen


2020 ◽  
Vol 6 (17) ◽  
pp. eaaz5961 ◽  
Author(s):  
Michael Worku ◽  
Yu Tian ◽  
Chenkun Zhou ◽  
Haoran Lin ◽  
Maya Chaaban ◽  
...  

Metal halide perovskite nanocrystals (NCs) have emerged as new-generation light-emitting materials with narrow emissions and high photoluminescence quantum efficiencies (PLQEs). Various types of perovskite NCs, e.g., platelets, wires, and cubes, have been discovered to exhibit tunable emissions across the whole visible spectrum. Despite remarkable advances in the field of perovskite NCs, many nanostructures in inorganic NCs have not yet been realized in metal halide perovskites, and producing highly efficient blue-emitting perovskite NCs remains challenging and of great interest. Here, we report the discovery of highly efficient blue-emitting cesium lead bromide (CsPbBr3) perovskite hollow NCs. By facile solution processing of CsPbBr3 precursor solution containing ethylenediammonium bromide and sodium bromide, in situ formation of hollow CsPbBr3 NCs with controlled particle and pore sizes is realized. Synthetic control of hollow nanostructures with quantum confinement effect results in color tuning of CsPbBr3 NCs from green to blue, with high PLQEs of up to 81%.



2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Philippe Tamarat ◽  
Lei Hou ◽  
Jean-Baptiste Trebbia ◽  
Abhishek Swarnkar ◽  
Louis Biadala ◽  
...  

AbstractCesium lead halide perovskites exhibit outstanding optical and electronic properties for a wide range of applications in optoelectronics and for light-emitting devices. Yet, the physics of the band-edge exciton, whose recombination is at the origin of the photoluminescence, is not elucidated. Here, we unveil the exciton fine structure of individual cesium lead iodide perovskite nanocrystals and demonstrate that it is governed by the electron-hole exchange interaction and nanocrystal shape anisotropy. The lowest-energy exciton state is a long-lived dark singlet state, which promotes the creation of biexcitons at low temperatures and thus correlated photon pairs. These bright quantum emitters in the near-infrared have a photon statistics that can readily be tuned from bunching to antibunching, using magnetic or thermal coupling between dark and bright exciton sublevels.



Nanoscale ◽  
2018 ◽  
Vol 10 (43) ◽  
pp. 20131-20139 ◽  
Author(s):  
Fei Zhang ◽  
Zhi-Feng Shi ◽  
Zhuang-Zhuang Ma ◽  
Ying Li ◽  
Sen Li ◽  
...  

CsPbBr3 QDs/silica composites with substantially improved stability were applied as the color-converting layer for high-performance white LED fabrication.



2014 ◽  
Vol 1056 ◽  
pp. 42-46 ◽  
Author(s):  
Kai Wu ◽  
Wei Xia Gu ◽  
Chen Wu ◽  
Jin Lou Ma ◽  
Xi Ying Ma

We designed MoS2/SiO2one-dimensional (1D) photonic crystal using the concept of photonic crystal and investigated the light transfer properties by means of transfer-matrix method. We found that the transfer properties of photonic crystal can be modified by the period of photonic crystal, the thickness of dielectric layer, and the number of the defect layers. The number of photonic band gaps (PBGs) reduces with the decrease of the thickness of dielectric layer, and the position of PBGs in the spectra rapidly moves to short wavelength direction. For defect photonic crystal, the width of the PBGs obviously become larger, and the transmittance spectra oscillate more intensely, similar to the characteristics of Bragg gratings. These properties will give good instructor for the preparation of 1D MoS2quantum well light emitting devices and solar cells.



Author(s):  
Songyan Yuan ◽  
Xinran Zhang ◽  
Wenjing Cao ◽  
Yuhang Sheng ◽  
Cihui Liu ◽  
...  

Enhancing the fluorescence of perovskite nanocrystals (PNCs) will not only boost the development of perovskite light-emitting devices (LEDs), but also broaden their applications in various photoelectronic areas.



2018 ◽  
Vol 9 (7) ◽  
pp. 1573-1583 ◽  
Author(s):  
Jia Sun ◽  
Jeehye Yang ◽  
Jong Ik Lee ◽  
Jeong Ho Cho ◽  
Moon Sung Kang


Nanoscale ◽  
2021 ◽  
Author(s):  
Guangrong Jin ◽  
Tanghao Liu ◽  
Yuanzhao Li ◽  
Jiadong Zhou ◽  
Dengliang Zhang ◽  
...  

Quasi-2D metal halide perovskites are promising candidates for light-emitting application owing to their large exciton binding energy and strong quantum confinement effect. Usually, quasi-2D perovskites are composed of multiple phases...



2020 ◽  
Vol 12 (48) ◽  
pp. 53891-53898
Author(s):  
Takayuki Chiba ◽  
Jun Sato ◽  
Shota Ishikawa ◽  
Yoshihito Takahashi ◽  
Hinako Ebe ◽  
...  


1996 ◽  
Vol 422 ◽  
Author(s):  
J. Michel ◽  
B. Zheng ◽  
J. Palm ◽  
E. Ouellette ◽  
F. Gan ◽  
...  

AbstractWe report on the excitation and de-excitation processes of erbium implanted in silicon and the integration of Si:Er light emitting devices (LED) with standard CMOS technology. We find two deexcitation processes, an Auger process below 100 K and a phonon mediated energy backtransfer above 100 K. We present the first optical voice link with a silicon LED as the emitter. Optical transmission system performance with our LED is possible below 200 K.



Sign in / Sign up

Export Citation Format

Share Document