scholarly journals A Study of the Pore Surface State of Porous TiNi-based Materials Obtained by SHS at Various Ignition Temperatures

2017 ◽  
Vol 2 (1) ◽  
pp. 25
Author(s):  
S.G. Anikeev ◽  
V.N. Khodorenko ◽  
M.R. Mukhamedov ◽  
V.E. Gunther
Keyword(s):  
Surface Layer ◽  
Chemical Composition ◽  
Porous Material ◽  
Variable Thickness ◽  
Secondary Phase ◽  
Structural Features ◽  
Alloy Formation ◽  
Pore Surface ◽  
P 75 ◽  
Phase And Chemical Composition

Structural features of porous TiNi-based materials obtained by SHS at temperatures of synthesis beginning of400 Cand600 Chave been investigated. It is found that finely porous material with a porosity P=75 % was obtained at the temperature of400 C. A surface of pore walls contains a dendritic relief, oxycarbidenitride layer and a multitude of secondary phase particles. Phase and chemical composition of the material is non-uniform. SHS material obtained at the synthesis beginning temperature of600 °Cis characterized as a coarse-porosity one P=65 %. Nano- and micropores are practically absent. The oxycarbidenitride surface layer with a variable thickness is substantially free of secondary inclusions due to the more complete processes of alloy formation. This layer has an own substructure based on carbonitride and oxynitride layers.

Structural features and strength behavior of TRIP/TWIP steels

2020 ◽  
pp. 5-18
Author(s):  
D. V. Prosvirnin ◽  
◽  
M. S. Larionov ◽  
S. V. Pivovarchik ◽  
A. G. Kolmakov ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Thermomechanical Processing ◽  
Maximum Load ◽  
Structural Features ◽  
Stacking Fault ◽  
Stacking Fault Energy ◽  
Structural And Functional Properties ◽  
Twip Steels ◽  
The Creation

A review of the literature data on the structural features of TRIP / TWIP steels, their relationship with mechanical properties and the relationship of strength parameters under static and cyclic loading was carried out. It is shown that the level of mechanical properties of such steels is determined by the chemical composition and processing technology (thermal and thermomechanical processing, hot and cold pressure treatment), aimed at achieving a favorable phase composition. At the atomic level, the most important factor is stacking fault energy, the level of which will be decisive in the formation of austenite twins and / or the formation of strain martensite. By selecting the chemical composition, it is possible to set the stacking fault energy corresponding to the necessary mechanical characteristics. In the case of cyclic loads, an important role is played by the strain rate and the maximum load during testing. So at high loading rates and a load approaching the yield strength under tension, the intensity of the twinning processes and the formation of martensite increases. It is shown that one of the relevant ways to further increase of the structural and functional properties of TRIP and TWIP steels is the creation of composite materials on their basis. At present, surface modification and coating, especially by ion-vacuum methods, can be considered the most promising direction for the creation of such composites.

scholarly journals Optimization of Magnetic Properties of Magnetic Microwires by Post-Processing

Processes ◽  
2020 ◽  
Vol 8 (8) ◽  
pp. 1006
Author(s):  
Valentina Zhukova ◽  
Paula Corte-Leon ◽  
Lorena González-Legarreta ◽  
Ahmed Talaat ◽  
Juan Maria Blanco ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Chemical Composition ◽  
Hysteresis Loops ◽  
Structural Features ◽  
Post Processing ◽  
Soft Magnetic ◽  
Magnetic Microwires ◽  
Prepared State ◽  
Induced Magnetic Anisotropy ◽  
Selection Of

The influence of post-processing conditions on the magnetic properties of amorphous and nanocrystalline microwires has been thoroughly analyzed, paying attention to the influence of magnetoelastic, induced and magnetocrystalline anisotropies on the hysteresis loops of Fe-, Ni-, and Co-rich microwires. We showed that magnetic properties of glass-coated microwires can be tuned by the selection of appropriate chemical composition and geometry in as-prepared state or further considerably modified by appropriate post-processing, which consists of either annealing or glass-coated removal. Furthermore, stress-annealing or Joule heating can further effectively modify the magnetic properties of amorphous magnetic microwires owing to induced magnetic anisotropy. Devitrification of microwires can be useful for either magnetic softening or magnetic hardening of the microwires. Depending on the chemical composition of the metallic nucleus and on structural features (grain size, precipitating phases), nanocrystalline microwires can exhibit either soft magnetic properties or semi-hard magnetic properties. We demonstrated that the microwires with coercivities from 1 A/m to 40 kA/m can be prepared.

scholarly journals Structural Features of Ingots Made of Al-Cu-Li System Alloys Depending on its Chemical Composition

2016 ◽  
Author(s):  
Н.И. Колобнев ◽  
◽  
Е.Н. Рябова ◽  
Л.Б. Хохлатова ◽  
М.С. Оглодков ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Structural Features

scholarly journals The laboratory tests of hybrid layers combining hardfacing and nitriding dedicated to increase the durability of forging tools in hot forging processes

2019 ◽  
Vol 91 (2) ◽  
Author(s):  
Paweł Widomski ◽  
Zbigniew Gronostajski ◽  
Marcin Kaszuba ◽  
Jagoda Kowalska ◽  
Mariusz Pawełczyk
Keyword(s):  
Surface Layer ◽  
Chemical Composition ◽  
Laboratory Tests ◽  
Hot Forging ◽  
Composition Analysis ◽  
Wear Resistant ◽  
Gas Nitriding ◽  
Use Wear ◽  
Different Types ◽  
Hybrid Layers

In response to the growing need to use wear-resistant layers that increase durability of tools in forging pro-cesses, hybrid layers have been proposed that combine hardfacing with nitriding treatment. This article presents the results of laboratory tests of surface wear-resistant layers made with a new hybrid technology Gas-Shielded Metal Arc surfacing (hardfacing) with ZeroFlow gas nitriding. Specimens made with hardfacing or nitriding were prepared and examined. Analysis covered the thorough microstructure study, EDX chemical composition analysis and microhardness analysis. In experiment, 3 different types of nitrided layers were proposed for alpha, gamma prim and epsilon nitrides in the surface layer. The results of metallographic research in the surface layer was presented. The analysis of chemical composition in the particular overlay welds was performed to determine the content of alloying elements in the particular overlay welds. The susceptibility to nitriding of used weld materials as well as the ability to form particular types of nitrides on selected welded substrates was also tested.

Effect of Chemical Composition of Glassy Phase of Porcelain Stoneware on Product Brittleness

2020 ◽  
Vol 989 ◽  
pp. 254-259
Author(s):  
Irina A. Pavlova ◽  
A.S. Kiyko ◽  
Elena Farafontova
Keyword(s):  
Chemical Composition ◽  
Brittle Failure ◽  
Glassy Phase ◽  
High Price ◽  
Firing Process ◽  
Small Object ◽  
Quenching Temperature ◽  
Floor Tiles ◽  
Increased Strength ◽  
Phase And Chemical Composition

During the operation of porcelain stoneware sometimes there is a type of defects associated with crumbling from the edge of tile. In addition, cracks occur when a small object is fallen and during transportation of the products. Compared to conventional ceramic floor tiles, porcelain stoneware has increased strength, which explains its high price. The brittle failure is most likely, due to the hardening of glassy phase of tiles during cooling stage of the firing process. As a rule, the quenching temperature depends on the chemical composition of the glassy phase formed during firing. Both the phase and chemical composition of porcelain stoneware, and the chemical composition of the glassy phase are determined.

scholarly journals Structural features underlying recognition and translocation of extracellular polysaccharides

2019 ◽  
Vol 9 (2) ◽  
pp. 20180060 ◽  
Author(s):  
Jochen Zimmer
Keyword(s):  
Energy Source ◽  
Chemical Composition ◽  
Cell Surface ◽  
Cell Attachment ◽  
Structural Features ◽  
Living Systems ◽  
Extracellular Polysaccharides ◽  
Transport Mechanisms ◽  
Complex Carbohydrates ◽  
Insoluble Polymers

Essentially all living systems produce complex carbohydrates as an energy source, structural component, protective coat or adhesive for cell attachment. Many polysaccharides are displayed on the cell surface or are threaded through proteinaceous tunnels for degradation. Dictated by their chemical composition and mode of polymerization, the physical properties of complex carbohydrates differ substantially, from amphipathic water-insoluble polymers to highly hydrated hydrogel-forming macromolecules. Accordingly, diverse recognition and translocation mechanisms evolved to transport polysaccharides to their final destinations. This review will summarize and compare diverse polysaccharide transport mechanisms implicated in the biosynthesis and degradation of cell surface polymers in pro- and eukaryotes.

scholarly journals Lake water and talik groundwater interaction in continuous permafrost, Central Yakutia

2019 ◽  
Vol 98 ◽  
pp. 07024
Author(s):  
Nadezhda Pavlova ◽  
Liudmila Lebedeva ◽  
Vladimir Efremov
Keyword(s):  
Chemical Composition ◽  
Air Temperature ◽  
Lake Water ◽  
Structural Features ◽  
Downward Trend ◽  
Hydrological Data ◽  
Hydrochemical Data ◽  
Continuous Permafrost ◽  
Solids Content ◽  
Winter Air Temperature

Structural features of a lake talik associated with eolian relief are discussed. Analysis of hydrochemical and hydrological data for 2010-2017 showed that talik groundwater feeds lake and maintains perennial outflow from the lake. Variations in the chemical composition of the lake and outflowing creek are characterized on an annual and interannual basis. Seasonal comparison of hydrochemical data indicates a downward trend in dissolved-solids content of the lake water over the last six years, suggesting an increasing contribution of suprapermafrost groundwater to the lake and lake talik. Probable reason of enhanced suprapermafrost flow is increase of its duration due to observed rise of winter air temperature.

High Temperature Sulphidation Behavior of Fe20Cr6Al-Y,Hf Steel

2008 ◽  
Vol 595-598 ◽  
pp. 763-768
Author(s):  
Martah Homa ◽  
Zbigniew Żurek
Keyword(s):  
High Temperature ◽  
Chemical Composition ◽  
Vapor Pressure ◽  
Phase Analysis ◽  
High Temperature Corrosion ◽  
Vapor Pressures ◽  
Scale Layer ◽  
Phase And Chemical Composition ◽  
Xrd Techniques ◽  
Scale Surface

The high temperature corrosion behavior of Fe20Cr6Al-Y,Hf steel was studied in the range of temperature 800-1000oC in H2/H2S atmospheres at pS2=10-2 ,10-3 and 10-4 Pa sulphur vapor pressures. Kinetics depend on the temperature and sulphur vapor pressure. After 24 hours the whole specimen was practically consumed because the samples were 0,06 cm thick. Morphology of the scales have been performed by SEM techniques. Phase and chemical composition have been studied by EDX and XRD techniques. It was found that scale formed on Fe20Cr6Al-Y,Hf alloy was built with porosity sulphides layer. EDX analysis of the scale surface show that the any aluminum, hafnium and yttrium sulfides were found in the formed scale layer, however small amounts of Al2S3 was detected in scale/steel interface. Also internal sulphidation was observed. A phase analysis of the formed scale revealed that it is composed mainly of an FeS, Fe7S8 phases and CrS, Cr5S6. Result were compared with data obtained on the pure Fe and Cr samples.

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