scholarly journals The Effect of CaO Catalyst Mass from Golden Snail Shell (Pomacea Canaliculata Lamarck) on Transesterification Reaction

2021 ◽  
Vol 4 (2) ◽  
pp. 88-92
Author(s):  
Fachtur Rahman ◽  
Siti Rodiah
Keyword(s):  
Alternative Energy ◽  
Waste Cooking Oil ◽  
Transesterification Reaction ◽  
Molar Ratio ◽  
Pomacea Canaliculata ◽  
Optimum Amount ◽  
Environment Friendly ◽  
Snail Shell ◽  
Cooking Oil ◽  
Gas Chromatography Mass Spectroscopy

Biodiesel derived from waste encourages the development of environment-friendly alternative energy. One of the wastes that can be used as biodiesel is waste cooking oil. Biodiesel from waste cooking oil has some advantages such as non-toxic, less Carbon monoxide (CO), and environment-friendly. The produce of biodiesel from waste cooking oil was through transesterification reaction using CaO catalyst derived from golden snail shell. This study aimed to determine the optimum amount of catalyst that produced the highest yield. In this study, methanol was used as solvent by the molar ratio of methanol/waste cooking oil of 30:1, reaction temperature of 65˚C, reaction time for 2 hour, and variations of amount catalyst 3%, 5% and 7% by weight waste cooking oil. Biodiesel was analyzed by Gas Chromatography-Mass Spectroscopy showed that the highest yield achieved using 7% catalyst amounts was 93.28%.

Application of Calcium Methoxide as Solid Base Catalyst for Biodiesel Production from Waste Cooking Oil

2016 ◽  
Vol 723 ◽  
pp. 594-598 ◽  
Author(s):  
Nichaonn Chumuang ◽  
Vittaya Punsuvon
Keyword(s):  
Reaction Temperature ◽  
Catalyst Concentration ◽  
Waste Cooking Oil ◽  
Transesterification Reaction ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Solid Base ◽  
Base Catalyst ◽  
Solid Base Catalyst ◽  
Cooking Oil

In this study, the biodiesel production of waste cooking oil using calcium methoxide as solid base catalyst was investigated. The calcium methoxide catalyst was synthesized from calcined quick lime reacted with methanol. The XRD result showed that the catalyst was successfully synthesized with sufficient purity. The strength of catalyst was examined on the transesterification reaction of waste cooking oil and methanol. Parameters affecting on transesterification such as the catalyst concentration, methanol-to-oil-molar ratio, reaction time and reaction temperature were investigated. The results showed that the percentage of fatty acid methyl ester conversion of 99.06%. The optimum conditions were achieved within 3 h using 3wt% catalyst concentration, 12:1 methanol-to-oil molar ratio and 65°C reaction temperature. In addition, the kinetic study of transesterification reaction was carried out at the temperature from 30°C to 65°C. The pseudo-first order was good agreement with the experiment results. The reaction rate constant (k) and activated energy (Ea) were determined as 0.023 min-1 and 55.77 kJ/mol, respectively.

scholarly journals Modified CaO Catalyst from Golden Snail Shell (Pomacea canaliculata) for Transesterification Reaction of Used Cooking Oil

Al-Kimia ◽  
2020 ◽  
Vol 8 (1) ◽  
Author(s):  
Siti Rodiah ◽  
Desti Erviana ◽  
Fachtur Rahman ◽  
Anissa Widya Budaya
Keyword(s):  
Fly Ash ◽  
Earth Metal ◽  
High Strength ◽  
Transesterification Reaction ◽  
Pomacea Canaliculata ◽  
X Ray Diffraction ◽  
Snail Shell ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
Low Solubility

One of alkaline earth metal oxide is calcium oxide, CaO has more attention because it has high strength, low solubility in methanol, and can be synthesized from sources that are easy to obtain. One of the sources of CaO and showed its catalytic properties was the golden snail shell. In this study, synthesize ash golden snail shell modified with fly ash leached and non-leached as a source of silicate (SiO2) has been investigated. The CaO/fly ash catalyst was applied to the transesterification reaction of used cooking oil. There are three catalysts have synthesized, namely golden snail shell calcined (CK), 75% golden snail shell calcined modified by 25% fly ash (CKFA), and by 25% fly ash leached (CKFAL). Based on the results of characterization with spectrophotometer X-Ray Diffraction (XRD), golden snail shell calcined at 900 ˚C containing 93.94% Ca (OH)2. Modified CaO catalyst from golden snail shell and fly ash were active to convert used cooking oil become biodiesel.

scholarly journals Biodiesel Synthesis From Waste Cooking Oil Using CaO.SrO Catalyst By Transesterification Reaction In Batch Reactor

2018 ◽  
Vol 7 (2) ◽  
pp. 136-141
Author(s):  
Nuni Widiarti ◽  
Ismi Arinal Haq ◽  
F. Widhi Mahatmanti ◽  
Harjito Harjito ◽  
Cepi Kurniawan ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Surface Area ◽  
Catalyst Surface ◽  
Batch Reactor ◽  
Waste Cooking Oil ◽  
Transesterification Reaction ◽  
Molar Ratio ◽  
Cooking Oil ◽  
Biodiesel Synthesis ◽  
And Shifts

CaO is a very good catalyst for oil transesterification reactions into biodiesel, but requires a reaction time of 2 hours to obtain equilibrium. The time of CaO catalysis reaction can be accelerated by modifying the CaO catalyst with SrO. Synthesis biodiesel of waste cooking oil has been successfully conducted by transesterification reaction that used batch reactor assisted by CaO.SrO catalyst. The aim of this study is to determine the characteristics and catalytic activity of catalyst in the transesterification reaction. Catalysts have been successfully synthesized by coprecipitation method with oil to methanol molar ratio of 1:1, and its calcined at 800oC for 3 hours. Catalyst was characterized by XRD to determine the crystallinity. The smaller catalyst crystallinity obtained as the decline in intensity and shifts diffraction angles of CaO modified SrO catalyst. Surface area of catalyst characterized by SAA, that allow surface area between CaO modified SrO by 10.217 m2/g. Transesterification reaction performed on variation time (30, 60, 90, 120, 150 minutes), and the catalysts amount (1, 2, 4, 6, 8% w/v). The optimum condition of catalytic activity in reaction for 2 hours and the catalyst amount is 1% w/v of reactants that produce yield of biodiesel is 96.4%.

scholarly journals Production of Biodiesel by Transesterification Reaction of Waste Cooking Oil

2020 ◽  
pp. 1-12
Author(s):  
Donald Raoul Tchuifon Tchuifon ◽  
Serges Bruno Lemoupi Ngomade ◽  
George Nche Ndifor-Angwafor ◽  
Paul Alain Nanssou Kouteu ◽  
Tchoumboue Nsah-Ko ◽  
...  
Keyword(s):  
Physicochemical Characterization ◽  
Calorific Value ◽  
Physicochemical Characteristics ◽  
Waste Cooking Oil ◽  
Acid Number ◽  
Transesterification Reaction ◽  
Molar Ratio ◽  
Homogeneous Catalyst ◽  
Cooking Oil ◽  
Living Organisms

Waste cooking oils are an agro-food waste with adverse effects on the health of living organisms and the environment. The main objective of this work is to valorize waste cooking oil for the synthesis and physicochemical characterization of biodiesel. The method used is based on the transesterification reaction of the oils using methanol and a basic homogeneous catalyst. In this study we employ waste from refined palm oil used for frying doughnuts. After optimization a reaction time of 2 hours, KOH catalyst, and a molar ratio of 9:1 were selected to obtain a good quality biodiesel. Physicochemical characterization was performed on the biodiesel to obtain its density, viscosity, calorific value, acid number, saponification index and IR spectral features. The analysis shows that the biodiesel obtained after transesterification has physicochemical characteristics similar to those of diesel and is consistent with American standards.

Identification of Methyl Ester Content from Waste Cooking Oil Using Gas Chromatographic Method

2014 ◽  
Vol 660 ◽  
pp. 297-300
Author(s):  
Nor Hazwani Abdullah ◽  
Sulaiman Hassan
Keyword(s):  
Gas Chromatography ◽  
Methyl Ester ◽  
Acid Methyl Ester ◽  
Waste Cooking Oil ◽  
Molar Ratio ◽  
Ionization Detector ◽  
Cooking Oil ◽  
Ester Content ◽  
Flame Ionization ◽  
Acid Methyl

Waste cooking oil has always been an environment problem in food factories and one method of effect disposing this oil without effecting the environment is to convert it to fatty acid methyl ester (FAME) using small scale pilot plant. The conversion of waste cooking oil with sodium hydroxide as a catalyst in conversional process at 22kHz speed. The reaction of time, molar ratio, speed, catalyst and amount of catalyst will be effect in FAME quality. The quality of biodiesel define is total ester content using gas chromatography. Gas chromatography analysis is a one of technique for identification and quantitation of compounds in a biodiesel sample. From biodiesel sample can identification of contaminants and fatty acid methyl ester. In this research biodiesel sample were analyses using a gas chromatography-flame ionization detector ( Perkin Elmer GC Model Clarus 500) equipped with a DB-5 HT capillary column ( 0.53mm x 5 m) J&W Scientific. The analytic conditions for ester content were as follow by: column temperature used 2100C, temperature flame ionization detector (FID) of 2500C, pressure of 80kPa, flow carrier gas of 1ml/min, temperature injector of 2500C, split flow rate of 50ml/min, time for analysis 20 minute and volume injected of 1 μl. The ester content (C), expresses as a mass fraction in present using formula (EN 14103, 2003a) calculation. Conversion of triglyceride (TG) to FAME using conversional process obtained 96.54 % w.t with methanol to oil molar ratio 6:1, 1%w.t acid sulphuric and 1% w.t sodium hydroxide catalyst.

Production of Biodiesel from Waste Cooking Oil via Ultrasonic-Assisted Catalytic System

2014 ◽  
Vol 699 ◽  
pp. 552-557 ◽  
Author(s):  
Norzita Ngadi ◽  
Lai Nyuk Ma ◽  
Hajar Alias ◽  
Anwar Johari ◽  
Roshanida Abd Rahman ◽  
...  
Keyword(s):  
Calcium Oxide ◽  
Catalyst Concentration ◽  
Waste Cooking Oil ◽  
Molar Ratio ◽  
Catalyst Amount ◽  
Cooking Oil ◽  
Used Oil ◽  
Ultrasonic Assisted ◽  
Transesterification Method ◽  
Percentage Conversion

In this study, production of biodiesel from waste cooking oil (WCO) was carried out via ultrasonic-assisted transesterification method. Calcium oxide (CaO) was used as a catalyst. The effects of methanol to oil molar ratio, reaction temperature and the catalyst amount towards the percentage conversion of oil to biodiesel were investigated. The biodiesel produced was analyzed using GC-FID method. The results obtained showed that 82 % of oil was successfully converted into biodiesel. This indicates that the used oil (WCO) has the potential to be the future source of biodiesel. Catalyst concentration of 3 w/w%, methanol to oil molar ratio of 15:1 and temperature of 65°C are the best condition for the conversion of oil to biodiesel. The result obtained was found out that, methanol to oil molar ratio and catalyst amount has given significant effect on the conversion of oil. However, temperature ranged from (35 to 75) °C apparently, showed no significant effect on percentage conversion of oil.

scholarly journals Konsentrasi Katalis dan Suhu Optimum pada Reaksi Esterifikasi menggunakan Katalis Zeolit Alam Aktif (ZAH) dalam Pembuatan Biodiesel dari Minyak Jelantah

2013 ◽  
Vol 14 (3) ◽  
pp. 219 ◽  
Author(s):  
Dwi Kartika ◽  
Senny Widyaningsih
Keyword(s):  
Physical Properties ◽  
Natural Zeolite ◽  
Oil And Gas ◽  
Catalyst Concentration ◽  
Waste Cooking Oil ◽  
Effect Of Temperature ◽  
Molar Ratio ◽  
Cooking Oil ◽  
Biodiesel Synthesis ◽  
Directorate General

Transesterification of waste cooking oil into biodiesel using KOH catalyst with and without esterification process usingactivated natural zeolite (ZAH) catalyst has been carried out. Activation of the zeolite was done by refluxing with HCl 6Mfor 30 min, followed calcining and oxydized at 500oC for 2 hours, consecutively. The transesterification without esterificationprocess were done using KOH catalyst 1% (w/w) from oil and methanol weight and oil/methanol molar ratio 1:6 at 60oC. Theesterification reaction was also done using ZAH catalyst then continued by transesterification using KOH catalyst inmethanol media. In order to study the effect of ZAH catalyst concentration at constant temperature, the catalysts werevaried, i.e. 0, 1, 2, and 3% (w/w). To investigate the effect of temperature, the experiments were done at various temperaturefrom 30, 45, 60, and 70oC at constant catalyst concentration. The conversion of biodiesel was determined by 1H-NMRspectrometer and physical properties of biodiesel were determined using ASTM standard methods. The results showedthat the transesterification using KOH catalyst without esterification produced biodiesel conversion of 53.29%. The optimumcondition of biodiesel synthesis via esterification process were reached at 60oC and concentration of ZAH catalyst of2% (w/w), that could give biodiesel conversion = 100.00%. The physical properties were conformed with biodiesel ASTM2003b and Directorate General of Oil and Gas 2006 specification.

scholarly journals Optimization of Waste Cooking Oil’s FFA as Biodiesel Feedstock

Teknomekanik ◽  
2021 ◽  
Vol 4 (1) ◽  
pp. 14-21
Author(s):  
Sri Rizki Putri Primandari ◽  
Andril Arafat ◽  
Harumi Veny
Keyword(s):  
Irradiation Time ◽  
Control Variable ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Cooking Oil ◽  
Biodiesel Feedstock ◽  
Temperature Irradiation ◽  
Acid Esterification ◽  
Central Composite

Waste cooking oil has high Free Fatty Acid (FFA). It affected on decreasing a biodiesel production. FFA reduction is one of important processes in biodiesel production from waste cooking oil. Thus, this study aimed to examine the optimum condition in FFA reduction. The process is assisted by using ultrasonic irradiation on acid esterification. Variables of the process are acid concentration, molar ratio of methanol and oil, and irradiation time. Meanwhile temperature irradiation on 45oC is a control variable. Process optimization is conducted by Response Surface Methodology (RSM) with Central Composite Design (CCD). The optimum conditions of response were 7.22:1 (methanol to oil molar ratio), 0.92% wt H2SO4, 26.04 minutes (irradiation time), and 45oC (irradiation temperature). Ultrasonic system reduced FFA significantly compared to conventional method.

scholarly journals Evaluation of Shell-Derived Calcium Oxide Catalysts for the Production of Biodiesel Esters from Cooking Oils

2021 ◽  
pp. 20-27
Author(s):  
Ngee Sing Chong ◽  
Francis Uchenna Okejiri ◽  
Saidi Abdulramoni ◽  
Shruthi Perna ◽  
Beng Guat Ooi
Keyword(s):  
Calcium Oxide ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
X Ray ◽  
Cooking Oil ◽  
Biodiesel Synthesis ◽  
Cooking Oils ◽  
The Cost ◽  
Percentage Conversion

Due to the high cost of feedstock and catalyst in biodiesel production, the viability of the biodiesel industry has been dependent on government subsidies or tax incentives. In order to reduce the cost of production, food wastes including eggshells and oyster shells have been used to prepare calcium oxide (CaO) catalysts for the transesterification reaction of biodiesel synthesis. The shells were calcined at 1000 °C for 4 hours to obtain CaO powders which were investigated as catalysts for the transesterification of waste cooking oil. The catalysts were characterized by Fourier Transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), X-ray powder diffraction (XRD), and X-ray fluorescence (XRF) spectroscopy. Reaction parameters such as methanol-to-oil molar ratio, CaO catalyst concentration, and reaction time were evaluated and optimized for the percentage conversion of cooking oil to biodiesel esters. The oyster-based CaO showed better catalytic activity when compared to the eggshell-based CaO under the same set of reaction conditions.

scholarly journals Determination of Transesterification Reaction Parameters Giving the Lowest Viscosity Waste Cooking Oil Biodiesel

2015 ◽  
Vol 195 ◽  
pp. 2492-2500 ◽  
Author(s):  
Atilla Bilgin ◽  
Mert Gülüm ◽  
İhsan Koyuncuoglu ◽  
Elif Nac ◽  
Abdülvahap Cakmak
Keyword(s):  
Waste Cooking Oil ◽  
Transesterification Reaction ◽  
Reaction Parameters ◽  
Cooking Oil
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