scholarly journals Mineralogical and Geochemical Constraints on the Origin and Late-Stage Crystallization History of the Breivikbotn Silicocarbonatite, Seiland Igneous Province in Northern Norway: Prerequisites for Zeolite Deposits in Carbonatite Complexes

2018 ◽  
Author(s):  
Dmitry Zozulya ◽  
Kåre Kullerud ◽  
Erling Ravna ◽  
Yevgeny Savchenko ◽  
Ekaterina Selivanova ◽  
...  
Keyword(s):  
Trace Element ◽  
Tectonic Setting ◽  
Spatial Proximity ◽  
Geochemical Data ◽  
Chemical Compositions ◽  
Igneous Province ◽  
Magmatic Stage ◽  
Stage Crystallization ◽  
History Of ◽  
Late Magmatic Stage

The present work reports new mineralogical and whole rock geochemical data from the Breivikbotn silicocarbonatite (Seiland igneous province, North Norway), allowing conclusions to be drawn concerning its origin and the role of late fluid alteration. The rock shows a rare mineral association: calcite + pyroxene + amphibole + zeolite group minerals + garnet + titanite, with apatite, allanite, magnetite and zircon as minor and accessory minerals, and it is classified as silicocarbonatite. Calcite, titanite and pyroxene (Di36-46 Acm22-37 Hd14-21) are primarily magmatic minerals. Amphibole of hastingsitic composition has formed after pyroxene at a late-magmatic stage. Zeolite group minerals (natrolite, gonnardite, Sr-rich thomsonite-(Ca)) were formed during hydrothermal alteration of primary nepheline by fluids/solutions with high Si-Al-Ca activities. Poikilitic garnet (Ti-bearing andradite) has inclusions of all primary minerals, amphibole and zeolites, and presumably crystallized metasomatically during a late metamorphic event (Caledonian orogeny). Whole rock chemical compositions of the silicocarbonatite differs from the global average of calciocarbonatites by elevated silica, aluminium, sodium and iron, but show comparable contents of trace elements (REE, Sr, Ba). Trace element distributions indicate within-plate tectonic setting of the carbonatite. The spatial proximity of carbonatite and alkaline ultramafic rock (melteigite), the presence of “primary nepheline” in carbonatite together with the trace element distributions indicate that the carbonatite was derived from crystal fractionation of a parental carbonated foidite magma. The main prerequisites for the extensive formation of zeolite group minerals in silicocarbonatite are revealed.

scholarly journals Mineralogical and Geochemical Constraints on Magma Evolution and Late-Stage Crystallization History of the Breivikbotn Silicocarbonatite, Seiland Igneous Province in Northern Norway: Prerequisites for Zeolite Deposits in Carbonatite Complexes

Minerals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 537 ◽  
Author(s):  
Dmitry Zozulya ◽  
Kåre Kullerud ◽  
Erling Ravna ◽  
Yevgeny Savchenko ◽  
Ekaterina Selivanova ◽  
...  
Keyword(s):  
Trace Element ◽  
Tectonic Setting ◽  
Spatial Proximity ◽  
Geochemical Data ◽  
Chemical Compositions ◽  
Igneous Province ◽  
Magmatic Stage ◽  
Stage Crystallization ◽  
History Of ◽  
Late Magmatic Stage

The present work reports on new mineralogical and whole-rock geochemical data from the Breivikbotn silicocarbonatite (Seiland igneous province, North Norway), allowing conclusions to be drawn concerning its origin and the role of late fluid alteration. The rock shows a rare mineral association: calcite + pyroxene + amphibole + zeolite group minerals + garnet + titanite, with apatite, allanite, magnetite and zircon as minor and accessory minerals, and it is classified as silicocarbonatite. Calcite, titanite and pyroxene (Di36–46 Acm22–37 Hd14–21) are primarily magmatic minerals. Amphibole of mainly hastingsitic composition has formed after pyroxene at a late-magmatic stage. Zeolite group minerals (natrolite, gonnardite, Sr-rich thomsonite-(Ca)) were formed during hydrothermal alteration of primary nepheline by fluids/solutions with high Si-Al-Ca activities. Poikilitic garnet (Ti-bearing andradite) has inclusions of all primary minerals, amphibole and zeolites, and presumably crystallized metasomatically during a late metamorphic event (Caledonian orogeny). Whole-rock chemical compositions of the silicocarbonatite differs from the global average of calciocarbonatites by elevated silica, aluminium, sodium and iron, but show comparable contents of trace elements (REE, Sr, Ba). Trace element distributions and abundances indicate within-plate tectonic setting of the carbonatite. The spatial proximity of carbonatite and alkaline ultramafic rock (melteigite), the presence of “primary nepheline” in carbonatite together with the trace element distributions indicate that the carbonatite was derived by crystal fractionation of a parental carbonated foidite magma. The main prerequisites for the extensive formation of zeolite group minerals in silicocarbonatite are revealed.

scholarly journals Magmatic-Hydrothermal Processes Associated with Rare Earth Element Enrichment in the Kangankunde Carbonatite Complex, Malawi

Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 442 ◽  
Author(s):  
Frances Chikanda ◽  
Tsubasa Otake ◽  
Yoko Ohtomo ◽  
Akane Ito ◽  
Takaomi D. Yokoyama ◽  
...  
Keyword(s):  
Rare Earth ◽  
Geochemical Data ◽  
Carbonatite Complex ◽  
Compositional Zoning ◽  
Ree Mineralization ◽  
Hydrothermal Processes ◽  
Magmatic Stage ◽  
Isotope Study ◽  
Late Magmatic Stage ◽  
Element Enrichment

Carbonatites undergo various magmatic-hydrothermal processes during their evolution that are important for the enrichment of rare earth elements (REE). This geochemical, petrographic, and multi-isotope study on the Kangankunde carbonatite, the largest light REE resource in the Chilwa Alkaline Province in Malawi, clarifies the critical stages of REE mineralization in this deposit. The δ56Fe values of most of the carbonatite lies within the magmatic field despite variations in the proportions of monazite, ankerite, and ferroan dolomite. Exsolution of a hydrothermal fluid from the carbonatite melts is evident based on the higher δ56Fe of the fenites, as well as the textural and compositional zoning in monazite. Field and petrographic observations, combined with geochemical data (REE patterns, and Fe, C, and O isotopes), suggest that the key stage of REE mineralization in the Kangankunde carbonatite was the late magmatic stage with an influence of carbothermal fluids i.e. magmatic–hydrothermal stage, when large (~200 µm), well-developed monazite crystals grew. The C and O isotope compositions of the carbonatite suggest a post-magmatic alteration by hydrothermal fluids, probably after the main REE mineralization stage, as the alteration occurs throughout the carbonatite but particularly in the dark carbonatites.

Peridotites and basaltic rocks within an ophiolitic mélange from the SW igneous province of Puerto Rico: relation to the evolution of the Caribbean Plate

2016 ◽  
Vol 154 (1) ◽  
pp. 96-118
Author(s):  
NADJA OMARA CINTRON FRANQUI ◽  
SUNG HI CHOI ◽  
DER-CHUEN LEE
Keyword(s):  
Puerto Rico ◽  
Tectonic Setting ◽  
Geochemical Data ◽  
Transform Fault ◽  
Caribbean Plate ◽  
Basaltic Rocks ◽  
The North ◽  
Ophiolitic Mélange ◽  
Igneous Province ◽  
The Caribbean

AbstractThe geology of Puerto Rico is divided into three regions: the north, central and SW igneous provinces. Characterized by its Jurassic ophiolitic mélange basement, lithology of the SW Igneous Province (SIP) is not related to either of the other two provinces. The ophiolitic mélange is exposed in three peridotite belts: Monte del Estado, Rio Guanajibo and Sierra Bermeja. We present geochemical data to identify the tectonic setting of the SIP peridotite formation and its relation to the evolution of the Caribbean Plate. Comparisons of spinel Cr no. (13–21), Mg no. (63.3–69.6) and TiO2suggest an abyssal peridotite origin; however, only Sierra Bermeja presents high TiO2characteristics of a mid-ocean-ridge-basalt- (MORB-) like melt reaction. Temperatures determined with two-pyroxene geothermometers indicated a cold thermal regime ofc. 800–1050°C, with characteristics of large-offset transform fault abyssal peridotites. The geochemistry and Sr–Nd–Hf–Pb isotopic compositions of basalts within the mélange were also analysed. Las Palmas amphibolites exhibited normal-MORB-like rare earth element (REE) and trace-element patterns, whereas metabasalts and Lower Cajul basalts exhibited island-arc tholeiitic-like patterns. Highly radiogenic Sr isotopes (0.70339–0.70562) of the basalts suggest seawater alteration; however, Pb–Pb and Nd–Hf isotope correlations represent the primary compositions of a Pacific/Atlantic MORB source for the amphibolites, metabasalts and Lower Cajul basalts. We propose that the SIP ophiolitic mélange was formed along a large-offset transform fault, which initiated subduction and preserved both proto-Pacific and proto-Caribbean lithospheric mantle. Younger Upper Cajul basalts exhibited enriched-MORB-like geochemical and isotopic signatures, which can be attributed to a tectonized Caribbean ocean plateau.

Magmatic processes leading to the 1650 CE explosive eruption at the Kolumbo submarine volcano, Greece.

2021 ◽  
Author(s):  
Filippo Mastroianni ◽  
Iacopo Fantozzi ◽  
Chiara Maria Petrone ◽  
Georgios E. Vougioukalakis ◽  
Eleonora Braschi ◽  
...  
Keyword(s):  
Storage System ◽  
Geochemical Data ◽  
Chemical Compositions ◽  
African Plate ◽  
Rhyolitic Magma ◽  
Mafic Enclaves ◽  
History Of ◽  
Compositional Variability ◽  
Mafic Magmas ◽  
And Storage

<p>Kolumbo is the largest of twenty submarine volcanic cones, tectonically aligned in the transtentional Anydros basin, one of the most seismically active zones in the South Aegean Volcanic Arc, whose magmatism is related to the subduction of the African Plate beneath the Aegean microplate. Kolumbo explosively erupted in 1650 CE, causing the death of 70 people on Santorini, which is only 7 km SW of Kolumbo. Explorative cruises employing ROVs discovered a high temperature (220°C) hydrothermal field with CO2-rich discharges and accumulation of acidic water at the bottom of the crater (505 m b.s.l.), increasing the related hazard. A possible magma chamber was recognized below the crater at depth 9-6 km by seismic data [Dimitriadis et al. 2009]. Geochemical data [Klaver et al. 2016] suggest that Kolumbo have a different mantle source and storage system from Santorini. It is fundamental to understand the behaviour of this volcano, and how its storage and plumbing system works, to correctly assess risk for nearby islands.</p><p>We present petrographic, geochemical and isotopic data of samples collected during the cruises and by divers. Most samples represent the juvenile products of the 1650 CE activity, characterizing different magmas interacting before the eruption. They consist of white rhyolitic pumices with grey and black bands, also including basaltic-andesitic enclaves. Plagioclase, biotite, pyroxenes are the main mineral phases; olivine is found in the mafic enclaves. Minerals show quite complex zoning and a large compositional variability. Fresh lithic lavas were sampled; they also have amphibole and can be subdivided in three groups with distinctive petrographic textures that are well reflected in their different chemical compositions. They give information on the early history of the volcano and on how the rhyolitic magma could have been generated.</p><p>Our data suggest the presence of a complex storage system where the most evolved magma differentiated by assimilation and fractional crystallization, undergoing several inputs of mafic magmas. Early batches of new melts initially mixed with the resident ones, whereas later arrivals only mingled with the rhyolitic magma, thus possibly representing the final trigger of the eruption.</p>

scholarly journals Discovery of Ancient Volcanoes in the Okhotsk Sea (Russia): New Constraints on the Opening History of the Kurile Back Arc Basin

Geosciences ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 442
Author(s):  
Reinhard Werner ◽  
Boris Baranov ◽  
Kaj Hoernle ◽  
Paul van den Bogaard ◽  
Folkmar Hauff ◽  
...  
Keyword(s):  
Trace Element ◽  
Island Arc ◽  
Kurile Island ◽  
Geochemical Data ◽  
Magma Source ◽  
Published Data ◽  
Kurile Island Arc ◽  
History Of ◽  
Spreading Rates ◽  
Back Arc

Here we present the first radiometric age and geochemical (major and trace element and isotope) data for samples from the Hydrographer Ridge, a back arc volcano of the Kurile Island Arc, and a newly discovered chain of volcanoes (“Sonne Volcanoes”) on the northwestern continental slope of the Kurile Basin on the opposite side of the arc. The 40Ar/39Ar age and geochemical data show that Hydrographer Ridge (3.2–3.3 Ma) and the “Sonne Volcanoes” (25.3–25.9 Ma) have very similar trace element and isotope characteristics to those of the Kurile Island Arc, indicating derivation from a common magma source. We conclude that the age of the “Sonne Volcanoes” marks the time of opening of the Kurile Basin, implying slow back arc spreading rates of 1.3–1.8 cm/y. Combined with published data from the Kurile fore arc, our data suggest that the processes of subduction, Kurile Basin opening and frontal arc extension occurred synchronously and that extension in the rear part and in the frontal part of the Kurile Island Arc must have been triggered by the same mechanism.

Minette bodies and cognate mica-clinopyroxenite xenoliths from the Milk River area, southern Alberta: records of a complex history of the northernmost part of the Archean Wyoming craton

2000 ◽  
Vol 37 (11) ◽  
pp. 1629-1650 ◽  
Author(s):  
Arndt L Buhlmann ◽  
Patricia Cavell ◽  
Ronald A Burwash ◽  
Robert A Creaser ◽  
Robert W Luth
Keyword(s):  
Igneous Rocks ◽  
Coarse Grained ◽  
Geochemical Data ◽  
Tectonic Zone ◽  
Igneous Complex ◽  
Wyoming Craton ◽  
Mantle Enrichment ◽  
Southern Alberta ◽  
Igneous Province ◽  
History Of

Minettes exposed in southern Alberta near the Milk River are the northern outliers of the Eocene Sweet Grass Hills igneous complex of the Montana alkalic igneous province. These minettes often contain coarse-grained xenoliths of phlogopite + clinopyroxene ± apatite. The parent magmas of the minettes were generated at pressures [Formula: see text]17 kbar in equilibrium with clinopyroxene + phlogopite ± olivine. Fractional crystallization and mixing provided a spectrum of evolved minettes and cumulates, the latter of which were sampled by subsequent minette magmas as xenoliths. Two xenoliths were dated at 49.0 ± 0.8 Ma and 52 ± 1.7 Ma. The host dyke of the latter xenolith gave an age of 50 ± 0.3 Ma. The minettes and their xenoliths have overlapping values of 87Sr/86Sri, εNdT, 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb, similar to those of alkaline igneous rocks from farther south in the Montana alkalic igneous province. The Sweet Grass Hills lie north of the Great Falls Tectonic Zone, previously interpreted as a Proterozoic suture zone separating the Archean Medicine Hat block from the Archean Wyoming craton to the south. Geochemical data for the Milk River minettes provide evidence for a history of the mantle underneath the Medicine Hat block, similar to that found previously for mantle-derived rocks of the Wyoming craton, including a significant Proterozoic mantle enrichment event. Given this similarity, we suggest that the Wyoming craton extends into southern Alberta, and that the Great Falls Tectonic Zone does not represent a Proterozoic suture of two Archean blocks.

scholarly journals Formation mechanisms of macroscopic globules in andesitic glasses from the Izu–Bonin–Mariana forearc (IODP Expedition 352)

2020 ◽  
Vol 176 (1) ◽  
Author(s):  
Raúl O. C. Fonseca ◽  
Lina T. Michely ◽  
Maria Kirchenbaur ◽  
Julie Prytulak ◽  
Jeffrey Ryan ◽  
...  
Keyword(s):  
Stable Isotope ◽  
Trace Element ◽  
Isotope Fractionation ◽  
Experimental Studies ◽  
Trace Element Analysis ◽  
Geochemical Data ◽  
Formation Mechanisms ◽  
Chemical Compositions ◽  
Stable Isotope Fractionation ◽  
Textural Evidence

AbstractThe Izu–Bonin–Mariana volcanic arc is situated at a convergent plate margin where subduction initiation triggered the formation of MORB-like forearc basalts as a result of decompression melting and near-trench spreading. International Ocean Discovery Program (IODP) Expedition 352 recovered samples within the forearc basalt stratigraphy that contained unusual macroscopic globular textures hosted in andesitic glass (Unit 6, Hole 1440B). It is unclear how these andesites, which are unique in a stratigraphic sequence dominated by forearc basalts, and the globular textures therein may have formed. Here, we present detailed textural evidence, major and trace element analysis, as well as B and Sr isotope compositions, to investigate the genesis of these globular andesites. Samples consist of $$\hbox {K}_2\hbox {O}$$ K 2 O -rich basaltic globules set in a glassy groundmass of andesitic composition. Between these two textural domains a likely hydrated interface of devitrified glass occurs, which, based on textural evidence, seems to be genetically linked to the formation of the globules. The andesitic groundmass is Cl rich (ca. $$3000\, \mu \hbox {g/g}$$ 3000 μ g/g ), whereas globules and the interface are Cl poor (ca. $$300\, \mu \hbox {g/g}$$ 300 μ g/g ). Concentrations of fluid-mobile trace elements also appear to be fractionated in that globules and show enrichments in B, K, Rb, Cs, and Tl, but not in Ba and W relative to the andesitic groundmass, whereas the interface shows depletions in the latter, but is enriched in the former. Interestingly, globules and andesitic groundmass have identical Sr isotopic composition within analytical uncertainty ($$^{87}\hbox {Sr}/^{86}\hbox {Sr}$$ 87 Sr / 86 Sr of $$0.70580 \pm 10$$ 0.70580 ± 10 ), indicating that they likely formed from the same source. However, globules show high $$\delta ^{11}$$ δ 11 B (ca. + 7$$\permille$$ ‱ ), whereas their host andesites are isotopically lighter (ca. – 1 $$\permille$$ ‱ ), potentially indicating that whatever process led to their formation either introduced heavier B isotopes to the globules, or induced stable isotope fractionation of B between globules and their groundmass. Based on the bulk of the textural information and geochemical data obtained from these samples, we conclude that these andesites likely formed as a result of the assimilation of shallowly altered oceanic crust (AOC) during forearc basaltic magmatism. Assimilation likely introduced radiogenic Sr, as well as heavier B isotopes to comparatively unradiogenic and low $$\delta ^{11}\hbox {B}$$ δ 11 B forearc basalt parental magmas (average $$^{87}\hbox {Sr}/^{86}\hbox {Sr}$$ 87 Sr / 86 Sr of 0.703284). Moreover, the globular textures are consistent with their formation being the result of fluid-melt immiscibility that was potentially induced by the rapid release of water from assimilated AOC whose escape likely formed the interface. If the globular textures present in these samples are indeed the result of fluid-melt immiscibility, then this process led to significant trace element and stable isotope fractionation. The textures and chemical compositions of the globules highlight the need for future experimental studies aimed at investigating the exsolution process with respect to potential trace element and isotopic fractionation in arc magmas that have perhaps not been previously considered.

scholarly journals Geochemical signatures of mineralizing events in the Juomasuo Au–Co deposit, Kuusamo belt, northeastern Finland

2021 ◽  
Author(s):  
Mikael Vasilopoulos ◽  
Ferenc Molnár ◽  
Hugh O’Brien ◽  
Yann Lahaye ◽  
Marie Lefèbvre ◽  
...  
Keyword(s):  
Trace Element ◽  
Sulfur Isotope ◽  
Mineral Chemistry ◽  
Chemical Compositions ◽  
Metasedimentary Rocks ◽  
Metavolcanic Rocks ◽  
Icp Ms ◽  
Stage 1 ◽  
Host Rocks ◽  
Relationship Of

AbstractThe Juomasuo Au–Co deposit, currently classified as an orogenic gold deposit with atypical metal association, is located in the Paleoproterozoic Kuusamo belt in northeastern Finland. The volcano-sedimentary sequence that hosts the deposit was intensely altered, deformed, and metamorphosed to greenschist facies during the 1.93–1.76 Ga Svecofennian orogeny. In this study, we investigate the temporal relationship between Co and Au deposition and the relationship of metal enrichment with protolith composition and alteration mineralogy by utilizing lithogeochemical data and petrographic observations. We also investigate the nature of fluids involved in deposit formation based on sulfide trace element and sulfur isotope LA-ICP-MS data together with tourmaline mineral chemistry and boron isotopes. Classification of original protoliths was made on the basis of geochemically immobile elements; recognized lithologies are metasedimentary rocks, mafic, intermediate-composition, and felsic metavolcanic rocks, and an ultramafic sill. The composition of the host rocks does not control the type or intensity of mineralization. Sulfur isotope values (δ34S − 2.6 to + 7.1‰) and trace element data obtained for pyrite, chalcopyrite, and pyrrhotite indicate that the two geochemically distinct Au–Co and Co ore types formed from fluids of different compositions and origins. A reduced, metamorphic fluid was responsible for deposition of the pyrrhotite-dominant, Co-rich ore, whereas a relatively oxidized fluid deposited the pyrite-dominant Au–Co ore. The main alteration and mineralization stages at Juomasuo are as follows: (1) widespread albitization that predates both types of mineralization; (2) stage 1, Co-rich mineralization associated with chlorite (± biotite ± amphibole) alteration; (3) stage 2, Au–Co mineralization related to sericitization. Crystal-chemical compositions for tourmaline suggest the involvement of evaporite-related fluids in formation of the deposit; boron isotope data also allow for this conclusion. Results of our research indicate that the metal association in the Juomasuo Au–Co deposit was formed by spatially coincident and multiple hydrothermal processes.

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