scholarly journals Carbon Dioxide Gas Sensor Based on Polyhexamethylene Biguanide Polymer Deposited on Silicon Nano-Cylinders Metasurface

Author(s):  
Muhammad Ali Butt ◽  
Nikolay Lvovich Kazanskiy ◽  
Svetlana Nikolaevna Khonina

In this paper, we have numerically investigated a metasurface based perfect absorber design established on the impedance matching phenomena. The paper comprises of two parts. In the first part, the device performance of the perfect absorber is studied which is composed of a silicon Nano-cylindrical meta-atoms periodically arranged on the thin gold layer. The device design is unique which works for both x-oriented and y-oriented polarized light, besides independent of the angle of incidence. In the second part of the paper, CO2 gas sensing application is explored by depositing a thin layer of functional host material polyhexamethylene biguanide polymer on the metasurface. The refractive index of the host material decreases due to the absorption of the CO2 gas. As a result, the resonance wavelength of the perfect absorber performs a prominent blueshift. With the help of the proposed sensor design based on metasurface, the CO2 gas concentration range of 0-524 ppm is detected. The maximum sensitivity of ~17.3 pm/ppm is acquired for the gas concentration of 434 ppm. The study presented in this work explores the opportunity of utilizing metasurface perfect absorber for gas sensing applications by employing the functional host materials.

Sensors ◽  
2021 ◽  
Vol 21 (2) ◽  
pp. 378
Author(s):  
Nikolay Lvovich Kazanskiy ◽  
Muhammad Ali Butt ◽  
Svetlana Nikolaevna Khonina

In this paper, we have numerically investigated a metasurface based perfect absorber design, established on the impedance matching phenomena. The paper comprises of two parts. In the first part, the device performance of the perfect absorber—which is composed of silicon nano-cylindrical meta-atoms, periodically arranged on a thin gold layer—is studied. The device design is unique and works for both x-oriented and y-oriented polarized light, in addition to being independent of the angle of incidence. In the second part of the paper, a CO2 gas sensing application is explored by depositing a thin layer of functional host material—a polyhexamethylene biguanide polymer—on the metasurface. The refractive index of the host material decreases due to the absorption of the CO2 gas. As a result, the resonance wavelength of the perfect absorber performs a prominent blueshift. With the help of the proposed sensor design, based on metasurface, the CO2 gas concentration range of 0–524 ppm was detected. A maximum sensitivity of 17.3 pm/ppm was acquired for a gas concentration of 434 ppm. The study presented in this work explores the opportunity of utilizing the metasurface perfect absorber for gas sensing applications by employing functional host materials.


Sensors ◽  
2018 ◽  
Vol 18 (10) ◽  
pp. 3206 ◽  
Author(s):  
Hsiang-Chang Hsu ◽  
Tso-Sheng Hsieh ◽  
Tzu-Hsuan Huang ◽  
Liren Tsai ◽  
Chia-Chin Chiang

In this study, we applied a double-sided inductively coupled plasma (ICP) process to nanostructure long-period fiber grating (LPFG) in order to fabricate a double-notched LPFG (DNLPFG) sensor with a double-sided surface corrugated periodic grating. Using the sol-gel method, we also added thymol blue and ZnO to form a gas sensing layer, thus producing a DNLPFG CO2 gas sensor. The resulting sensor is the first double-sided etching sensor used to measure CO2. The experimental results showed that as the CO2 concentration increased, the transmission loss increased, and that the smaller the fiber diameter, the greater the sensitivity and the greater the change in transmission loss. When the diameter of the fiber was 32 μm (and the period was 570 μm) and the perfusion rate of CO2 gas was 15%, the maximum loss variation of up to 3.881 dB was achieved, while the sensitivity was 0.2146 dB/% and the linearity was 0.992. These results demonstrate that the DNLPG CO2 gas sensor is highly sensitive.


Nanoscale ◽  
2022 ◽  
Author(s):  
Xiaocan Xu ◽  
Ruijia Xu ◽  
Yu-Sheng Lin

Vanadium dioxide (VO2) based metamaterial perfect absorbers (MPAs) have high potential application values in sensing gas molecules. However, such tuning mechanism via temperature manipulation lacks the compatibility to the electronic...


RSC Advances ◽  
2020 ◽  
Vol 10 (29) ◽  
pp. 17217-17227 ◽  
Author(s):  
Pritamkumar V. Shinde ◽  
Nanasaheb M. Shinde ◽  
Shoyebmohamad F. Shaikh ◽  
Damin Lee ◽  
Je Moon Yun ◽  
...  

Room-temperature (27 °C) synthesis and carbon dioxide (CO2)-gas-sensing applications of bismuth oxide (Bi2O3) nanosensors obtained via a direct and superfast chemical-bath-deposition method (CBD) with different surface areas and structures.


2020 ◽  
Vol 12 (3) ◽  
pp. 88
Author(s):  
Muhammad Ali Butt ◽  
Nikolai Lvovich Kazansky

We presented a numerical investigation of a metamaterial narrowband perfect absorber conducted via a finite element method based on commercially available COMSOL software. The periodic array of silicon meta-atoms (MAs) are placed on 80 nm thick gold layer. The broadband light at normal incidence is blocked by the gold layer and silicon MAs are used to excite the surface plasmon by scattering light through it. Maximum absorption of 95.7 % is obtained at the resonance wavelength of 1137.5 nm due to the perfect impedance matching of the electric and magnetic dipoles. The absorption is insensitive to the wide-angle of incidence ranging from 0 to 80 degrees. We believe that the proposed metamaterial device can be utilized in solar photovoltaic and biochemical sensing applications. Full Text: PDF ReferencesY. Cheng, X.S. Mao, C. Wu, L. Wu, R.Z. Gong, "Infrared non-planar plasmonic perfect absorber for enhanced sensitive refractive index sensing", Optical Materials, 53, 195-200 (2016). CrossRef S. S. Mirshafieyan, D.A. Gregory, "Electrically tunable perfect light absorbers as color filters and modulators", Scientific Reports,8, 2635 (2018). CrossRef D.M. Nguyen, D. Lee, J. Rho, "Control of light absorbance using plasmonic grating based perfect absorber at visible and near-infrared wavelengths", Scientific Reports, 7, 2611 (2017). CrossRef Y. Sun, Y. Ling, T. Liu, L. Huang, "Electro-optical switch based on continuous metasurface embedded in Si substrate", AIP Advances, 5, 117221 (2015). CrossRef H. Chu, Q. Li, B. Liu, J. Luo, S. Sun, Z. H. Hang, L. Zhou, Y. Lai, "A hybrid invisibility cloak based on integration of transparent metasurfaces and zero-index materials", Light: Science & Applications, 7, 50 (2018). CrossRef S. K. Patel, S. Charola, J. Parmar, M. Ladumor, "Broadband metasurface solar absorber in the visible and near-infrared region", Materials Research Express, 6, 086213 (2019). CrossRef Q. Qian, S. Ti, C. Wang, "All-dielectric ultra-thin metasurface angular filter", Optics Letters, 44, 3984 (2019). CrossRef P. Yu et al., "Broadband Metamaterial Absorbers", Advanced Optical Materials, 7, 1800995 (2019). CrossRef Y. J. Kim et al., "Flexible ultrathin metamaterial absorber for wide frequency band, based on conductive fibers", Science and Technology of advanced materials, 19, 711-717 (2018). CrossRef N.L. Kazanskiy, S.N. Khonina, M.A. Butt, "Plasmonic sensors based on Metal-insulator-metal waveguides for refractive index sensing applications: A brief review", Physica E, 117, 113798 (2020). CrossRef H. E. Nejad, A. Mir, A. Farmani, "Supersensitive and Tunable Nano-Biosensor for Cancer Detection", IEEE Sensors Journal, 19, 4874-4881 (2019). CrossRef


2019 ◽  
Vol 17 (43) ◽  
pp. 49-57
Author(s):  
Dunia Yas

Abstract Semiconductor-based gas sensors were prepared, that use n-type tin oxide (SnO2) and  tin oxide: zinc oxide composite (SnO2)1-x(ZnO)x at different x ratios using pulse laser deposition at room temperature. The prepared thin films were examined to reach the optimum conditions for gas sensing applications, namely X-ray diffraction, Hall effect measurements, and direct current conductivity. It was found that the optimum crystallinity and maximum electron density, corresponding to the minimum charge carrier mobility, appeared at 10% ZnO ratio. This ratio appeared has the optimum NO2 gas sensitivity for 5% gas concentration at 300 °C working temperature.


2021 ◽  
Vol 2015 (1) ◽  
pp. 012102
Author(s):  
R S Olarve ◽  
H M Dela Torre ◽  
J R Foronda ◽  
M G Santos ◽  
N J Sajor ◽  
...  

Abstract Detection of aldehydes such as pentanal, hexanal, octanal, and nonanal are studied with the use of nanostructured zinc oxide (ZnO) as sensing element. ZnO nanowires synthesized at optimized growth parameters using horizontal vapor phase growth (HVPG) technique was used due to its unique properties in gas sensing applications. Scanning Electron Microscope (SEM) and Energy Dispersive X-Ray (EDX) were used to verify the growth of ZnO nanowire structures. Further characterization using Source Meter was used to measure its resistance and resistivity based on the I-V graph. The sensor substrate wire set-up is connected to the Source Meter for resistance measurements as exposed to the different gas concentration of aldehydes. Gas sensing measurements were done at the static headspace gas concentration of the identified aldehydes. The sensor response of nanostructured ZnO-based gas sensor towards different gas concentrations ranges from 5.84% to 38.08%. Response time varies but it was observed that octanal gas has the longest response while pentanal has the fastest response.


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