scholarly journals Solid-Gas Reaction during Sintering of Si3N4 Ceramics. (Part 3). Mass Losses in a Carbon Heater Furnace.

2000 ◽  
Vol 108 (1255) ◽  
pp. 230-235 ◽  
Author(s):  
Kazushige YOKOYAMA ◽  
Shigetaka WADA
Keyword(s):  
Author(s):  
W. Braue ◽  
R.W. Carpenter ◽  
D.J. Smith

Whisker and fiber reinforcement has been established as an effective toughening concept for monolithic structural ceramics to overcome limited fracture toughness and brittleness. SiC whiskers in particular combine both high strength and elastic moduli with good thermal stability and are compatible with most oxide and nonoxide matrices. As the major toughening mechanisms - crack branching, deflection and bridging - in SiC whiskenreinforced Al2O3 and Si3N41 are critically dependent on interface properties, a detailed TEM investigation was conducted on whisker/matrix interfaces in these all-ceramic- composites.In this study we present HREM images obtained at 400 kV from β-SiC/α-Al2O3 and β-SiC/β-Si3N4 interfaces, as well as preliminary analytical data. The Al2O3- base composite was hotpressed at 1830 °C/60 MPa in vacuum and the Si3N4-base material at 1725 °C/30 MPa in argon atmosphere, respectively, adding a total of 6 vt.% (Y2O3 + Al2O3) to the latter to promote densification.


2020 ◽  
Vol 16 (1) ◽  
pp. 62-70 ◽  
Author(s):  
Narimane Rezgui ◽  
Danica Simić ◽  
Choayb Boulahbal ◽  
Dejan Micković

Background: Erosive wear causes increase in the bore diameter of firearms barrels and nozzles. Most responsible factors for this erosion are friction and heat generated during the shot. Protection from erosive wear is very important for gun tube life cycle, and various protection methods are used: adding phlegmatizers in gunpowder composition or applying protective layers on the gun bore inner surface. Objective: In this research, a possibility is examined to protect the surface of a nozzle exposed to gunpowder erosion applying a layer of tungsten disulfide fullerene-like nanoparticles, IF-WS2, known as outstanding solid lubricant of a great mechanical resistance. Methods: Nanoparticles on the nozzle surface before and after the gunfire tests were observed using scanning electron microscopy/energy dispersive X-ray spectroscopy. Gunfire tests were performed on designed erosion device. Temperatures in the defined position near the affected surface were measured with thermocouples and compared for the nozzles with and without nanoprotection, as well as the nozzle mass loss after each round. Results: For the sample with IF-WS2 lower temperatures after firing and lower mass losses were observed. Mass loss after first round was 25.6% lower for the sample with protective nanoparticles layer, and the total mass loss was about 5% lower after five rounds. After the first round the nozzle without IF-WS2 was heated up to a temperature which was for 150.8°C higher than the nozzle with IF-WS2. Conclusion: Protective function of IF-WS2 is the most pronounced for the first round. The observed results encourage its further application in firearms gun bores protection.


Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3314
Author(s):  
Kweon-Hoon Choi ◽  
Bong-Hwan Kim ◽  
Da-Bin Lee ◽  
Seung-Yoon Yang ◽  
Nam-Seok Kim ◽  
...  

In this work, the microstructure and corrosion behavior of a novel Al-6Mg alloy were investigated. The alloy was prepared by casting from pure Al and Mg+Al2Ca master alloy. The ingots were homogenized at 420 °C for 8 h, hot-extruded and cold-rolled with 20% reduction (CR20 alloy) and 50% reduction (CR50 alloy). The CR50 alloy exhibited a higher value of intergranular misorientation due to a higher cold rolling reduction ratio. The average grain sizes were 19 ± 7 μm and 17 ± 9 μm for the CR20 and CR50 alloys, respectively. An intergranular corrosion (IGC) behavior was investigated after sensitization by a nitric acid mass-loss test (ASTM G67). The mass losses of both the CR20 and CR50 alloys were similar at early periods of sensitization, however, the CR20 alloy became more susceptible to IGC as the sensitization time increased. Grain size and β phase precipitation were two critical factors influencing the IGC behavior of this alloy system.


Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 753
Author(s):  
Dmitriy Shlimas ◽  
Artem L. Kozlovskiy ◽  
Maxim Zdorovets

The interest in lithium-containing ceramics is due to their huge potential as blanket materials for thermonuclear reactors for the accumulation of tritium. However, an important factor in their use is the preservation of the stability of their strength and structural properties when under the influence of external factors that determine the time frame of their operation. This paper presents the results of a study that investigated the influence of the LiTiO2 phase on the increasing resistance to degradation and corrosion of Li2TiO3 ceramic when exposed to aggressive acidic media. Using the X-ray diffraction method, it was found that an increase in the concentration of LiClO4·3H2O during synthesis leads to the formation of a cubic LiTiO2 phase in the structure as a result of thermal sintering of the samples. During corrosion tests, it was found that the presence of the LiTiO2 phase leads to a decrease in the degradation rate in acidic media by 20–70%, depending on the concentration of the phase. At the same time, and in contrast to the samples of Li2TiO3 ceramics, for which the mechanisms of degradation during a long stay in aggressive media are accompanied by large mass losses, for the samples containing the LiTiO2 phase, the main degradation mechanism is pitting corrosion with the formation of pitting inclusions.


2019 ◽  
Vol 13 (9) ◽  
pp. 2511-2535 ◽  
Author(s):  
Wael Abdel Jaber ◽  
Helmut Rott ◽  
Dana Floricioiu ◽  
Jan Wuite ◽  
Nuno Miranda

Abstract. The northern and southern Patagonian ice fields (NPI and SPI) have been subject to accelerated retreat during the last decades, with considerable variability in magnitude and timing among individual glaciers. We derive spatially detailed maps of surface elevation change (SEC) of NPI and SPI from bistatic synthetic aperture radar (SAR) interferometry data of the Shuttle Radar Topography Mission (SRTM) and TerraSAR-X add-on for Digital Elevation Measurements (TanDEM-X) for two epochs, 2000–2012 and 2012–2016, and provide data on changes in surface elevation and ice volume for the individual glaciers and the ice fields at large. We apply advanced TanDEM-X processing techniques allowing us to cover 90 % and 95 % of the area of NPI and 97 % and 98 % of SPI for the two epochs, respectively. Particular attention is paid to precisely co-registering the digital elevation models (DEMs), accounting for possible effects of radar signal penetration through backscatter analysis and correcting for seasonality biases in case of deviations in repeat DEM coverage from full annual time spans. The results show a different temporal trend between the two ice fields and reveal a heterogeneous spatial pattern of SEC and mass balance caused by different sensitivities with respect to direct climatic forcing and ice flow dynamics of individual glaciers. The estimated volume change rates for NPI are -4.26±0.20 km3 a−1 for epoch 1 and -5.60±0.74 km3 a−1 for epoch 2, while for SPI these are -14.87±0.52 km3 a−1 for epoch 1 and -11.86±1.99 km3 a−1 for epoch 2. This corresponds for both ice fields to an eustatic sea level rise of 0.048±0.002 mm a−1 for epoch 1 and 0.043±0.005 mm a−1 for epoch 2. On SPI the spatial pattern of surface elevation change is more complex than on NPI and the temporal trend is less uniform. On terminus sections of the main calving glaciers of SPI, temporal variations in flow velocities are a main factor for differences in SEC between the two epochs. Striking differences are observed even on adjoining glaciers, such as Upsala Glacier, with decreasing mass losses associated with slowdown of flow velocity, contrasting with acceleration and increase in mass losses on Viedma Glacier.


2007 ◽  
Vol 534-536 ◽  
pp. 1089-1092
Author(s):  
Mituyoshi Nagano ◽  
Hideaki Sano ◽  
Shigeya Sakaguchi ◽  
Guo Bin Zheng ◽  
Yasuo Uchiyama

The effect of oxygen addition on oxidation behavior of the β-Si3N4 ceramics with 5 mass% Y2O3 and 2 or 4 mass% Al2O3 was investigated by performing oxidation tests in air at 1300° to 1400°C and cutting performance tests. These tests were intended to clarify their ware resistance as cutting tools. The results of mass change, SEM observation and composition analysis of the specimens before and after oxidation test showed that as the Al2O3 content in the β-Si3N4 ceramics increased, mass changes resulted higher oxidation during which process pores and cracks formed due to the release of N2 gas. The values of hardness and bending strength of the specimens with relatively small amount of 2 mass% Al2O3, which formed solid solution in the Si3N4 structure [Si6-zAlzOzN8-z (z = 0.1)], showed larger than those of the specimen with 4 mass% Al2O3 (z = 0.2). The specimens group added with Al2O3 of 2 mass% (Z = 0.1) also showed high wear resistance. From this, we could conclude that the mechanical properties of β-Si3N4 ceramics depending on oxygen introduction is much effective on cutting performance improvements of the cutting performance of β-Si3N4 ceramics.


Sign in / Sign up

Export Citation Format

Share Document