scholarly journals Preparation of Nanoparticles in an Eco- friendly Method using Thyme Leaf Extracts

2020 ◽  
Vol 17 (2(SI)) ◽  
pp. 0670
Author(s):  
Jomana Rakaa et al.
Keyword(s):  
Spherical Shape ◽  
Average Crystallite Size ◽  
Single Step ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
Leaf Extracts ◽  
Xrd Pattern ◽  
The Face ◽  
Crystalline Nature ◽  
Face Centered

Colloidal silver nanoparticles were prepared by single step green synthesis using aqueous extracts of the leaves of thyme as a function of different molar concentration of AgNO3 (1,2,3,4 mM(. The Field Emission Scanning Electron Microscopy (FESEM), UV-Visible and X-ray diffraction (XRD) were used to characterize the resultant AgNPs. The surface Plasmon resonance was observed at wavelength of 444 nm. The four intensive peaks of XRD pattern indicate the crystalline nature and the face centered cubic structure of the AgNPs. The average crystallite size of the AgNPs ranged from 18 to 22 nm. The FESEM image illustrated the well dispersion of the AgNPs and the spherical shape of the nanoparticles with a particle size distribution between 13 to 50 nm.

Gold Nanoparticles Synthesis Using Environmentally Friendly Approach for Inhibition Human Breast Cancer

2020 ◽  
Vol 19 (05) ◽  
pp. 1950040 ◽  
Author(s):  
Neran Ali Thamer ◽  
Ban. H. Adil ◽  
A. S. Obaid
Keyword(s):  
Gold Nanoparticles ◽  
Surface Plasmon Resonance ◽  
Surface Plasmon ◽  
Plasmon Resonance ◽  
Spherical Shape ◽  
Average Crystallite Size ◽  
Single Step ◽  
Thymus Vulgaris ◽  
Face Centered Cubic ◽  
The Face

In this study, gold nanoparticles were synthesized in a single step biosynthetic method using aqueous leaves extract of thymus vulgaris L. It acts as a reducing and capping agent. The characterizations of nanoparticles were carried out using UV-Visible spectra, X-ray diffraction (XRD) and FTIR. The surface plasmon resonance of the as-prepared gold nanoparticles (GNPs) showed the surface plasmon resonance centered at 550[Formula: see text]nm. The XRD pattern showed that the strong four intense peaks indicated the crystalline nature and the face centered cubic structure of the gold nanoparticles. The average crystallite size of the AuNPs was 14.93[Formula: see text]nm. Field emission scanning electron microscope (FESEM) was used to study the morphology of the AuNPs. AuNPs exhibited a spherical shape with diameters ranging 13–53[Formula: see text]nm. The synthesized stable gold nanoparticles showed more significant anticancer activity against MCF-7 and CAL-51 cells after 48[Formula: see text]h.

scholarly journals Characterization of Cobalt Sulfide Thin Films Synthesized from Acidic Chemical Baths

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Tizazu Abza ◽  
Dereje Gelanu Dadi ◽  
Fekadu Gashaw Hone ◽  
Tesfaye Chebelew Meharu ◽  
Gebremeskel Tekle ◽  
...  
Keyword(s):  
Thin Films ◽  
Crystallite Size ◽  
Deposition Time ◽  
Average Crystallite Size ◽  
Cobalt Sulfide ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
Electron Microscopic ◽  
Face Centered

Cobalt sulfide thin films were synthesized from acidic chemical baths by varying the deposition time. The powder X-ray diffraction studies indicated that there are hexagonal CoS, face-centered cubic Co3S4, and cubic Co9S8 phases of cobalt sulfide. The crystallite size of the hexagonal CoS phase decreased from 52.8 nm to 22.5 nm and that of the cubic Co9S8 phase increased from 11 nm to 60 nm as the deposition time increased from 2 hrs to 3.5 hrs. The scanning electron microscopic images revealed crack and pinhole free thin films with uniform and smooth background and few large polygonal grains on the surface. The band gap of the cobalt sulfide thin films decreased from 1.75 eV to 1.3 eV as the deposition time increased from 2 hrs to 3.5 hrs. The photoluminescence (PL) spectra of the films confirmed the emission of ultraviolet, violet, and blue lights. The intense PL emission of violet light at 384 nm had red shifted with increasing deposition time that could be resulted from the increase in the average crystallite size. The FTIR spectra of the films indicated the presence of OH, C-O-H, C-O, double sulfide, and Co-S groups. As the deposition time increased, the electrical resistivity of the cobalt sulfide thin films decreased due to the increase in both the crystallite size and the films’ thickness.

CERIA NANOPARTICLES SYNTHESIZED BY A POLYMER PRECURSOR METHOD

2013 ◽  
Vol 22 ◽  
pp. 169-172
Author(s):  
B. SONI ◽  
S. BISWAS
Keyword(s):  
Sol Gel ◽  
Average Crystallite Size ◽  
Xrd Analysis ◽  
Poly Vinyl Alcohol ◽  
Face Centered Cubic ◽  
Ceria Nanoparticles ◽  
X Ray Diffraction ◽  
Precursor Method ◽  
Fluorite Type ◽  
Face Centered

We report a novel synthesis technique of ceria nanoparticles by a sol-gel type chemical process using poly-vinyl alcohol (PVA) as a capping as well as a reducing agent. The as-synthesized CeO 2 nanoparticles were characterized by X-ray diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM). The XRD analysis reveals the fluorite type face centered cubic structure in the ceria nanoparticles with an average crystallite size of 6 nm and 9 nm for the samples calcined at 350°C and 400°C, respectively.

Controlling Aspect Ratio of Copper Group Nanowire Arrays by Electrochemical Deposition in the Nanopores of AAO

2011 ◽  
Vol 335-336 ◽  
pp. 429-432 ◽  
Author(s):  
Xiu Yu Sun ◽  
Fa Qiang Xu
Keyword(s):  
Aspect Ratio ◽  
Nanowire Arrays ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
X Ray ◽  
Anodic Aluminum ◽  
Au Nanowire ◽  
The Face ◽  
Face Centered ◽  
Xrd Patterns

Highly ordered Cu, Ag and Au nanowire arrays with high aspect ratio and highly dense self-supporting nanowire patterns of copper group were successfully prepared using cyclic voltammetry with the assistance of anodic aluminum oxide (AAO) template. The X-ray diffraction (XRD) patterns of the metal nanowries were indexed to the face-centered cubic structure. The field emission scanning electron microscope (FE-SEM) results demonstrated that the length of nanowire could be controlled by changing the electrodepositon conditions. The aspect ratio of nanowire arrays can be tuned.

scholarly journals Preparation and Characterization of porous Carbon/Nickel Nanofibers for Supercapacitor

2013 ◽  
Vol 8 (4) ◽  
pp. 155892501300800 ◽  
Author(s):  
Dawei Gao ◽  
Lili Wang ◽  
Xin Xia ◽  
Hui Qiao ◽  
Yibing Cai ◽  
...  
Keyword(s):  
Carbon Nanofibers ◽  
Porous Carbon ◽  
Composite Nanofibers ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
Nickel Particles ◽  
The Face ◽  
Embedded Particles ◽  
Face Centered

Two polymer solutions of polyacrylonitrile, polyvinyl pyrrolidone, and Ni(CH3COOH)2 in dimethylformamide were electrospun into ternary composite nanofibers, followed by stabilization and carbonization processes to obtain porous carbon/nickel composite nanofibers with diameters of 100–200 nm. The study revealed that carbon/nickel composite nanofibers were successfully prepared, which allowed nickel particles with diameters of 20–70 nm to be uniformly distributed in the carbon nanofibers. It was also observed that the fibrous structures with particles embedded formed and the fibers broke into shorter fibers after sintering. X-ray diffraction indicated that embedded particles crystallized with the face centered cubic structure. The Brunauer-Emmett-Teller analysis revealed that carbon/nickel composite nanofibers with meso-pores possessed larger specific surface area than that of carbon nanofibers. The specific capacitance of the composite nanofiber electrode was as high as 103.8 F/g and showed stable cyclicity (73.8%).

Formation of face-centered cubic titanium on a Ni single crystal and in Ni/Ti multilayers

1994 ◽  
Vol 9 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Alan F. Jankowski ◽  
Mark A. Wall
Keyword(s):  
Structural Characteristics ◽  
Single Layer ◽  
High Resolution Electron Microscopy ◽  
Cubic Phase ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
X Ray ◽  
Resolution Electron ◽  
The Face ◽  
Face Centered

The artificial layering of metals can change both physical and structural characteristics from the bulk. The stabilization of polymorphic metallic phases can occur on a dimensional scale that ranges from single overgrowth layers to repetitive layering at the nanoscale. The sputter deposition of crystalline titanium on nickel, as both a single layer and in multilayer form, has produced a face-centered cubic phase of titanium. The atomic structure of the face-centered cubic titanium phase is examined using high resolution electron microscopy in combination with electron and x-ray diffraction.

Preparation and Characterization of the Ordered SiO2 Colloidal Crystallization Films

2008 ◽  
Vol 368-372 ◽  
pp. 1389-1391 ◽  
Author(s):  
Shuan Gui Qing ◽  
Bo Liu ◽  
Xun Liang ◽  
Hai Yang Li ◽  
Wei Zhong Lv ◽  
...  
Keyword(s):  
Self Assembly ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
Assembly Method ◽  
Colloidal Crystallization ◽  
The Face ◽  
Infrared Spectrometer ◽  
Face Centered ◽  
Sio2 Spheres

Multilayer SiO2 crystals modified by alkoxysilanes were fabricated by the vertical deposition technique combined with self-assembly method. The SiO2 colloidal crystallization was prepared by the traditional Stöber-Fink-Bohn method, and modified by different alkoxysilanes to investigate the properties of the films. The films fabricated by the ordering of SiO2 spheres were investigated by infrared spectrometer, X-ray diffraction, scanning electron microscope, UV-visible spectrophotometer. The results showed that thin film is the face-centered cubic structures and the spheres are [111]-oriented.

Highly Oriented Co Soft Magnetic Films on Si Substrates

1999 ◽  
Vol 562 ◽  
Author(s):  
Heng Gong ◽  
Wei Yang ◽  
Maithri Rao ◽  
David E. Laughlin ◽  
David N. Lambeth
Keyword(s):  
Magnetic Properties ◽  
Magnetic Films ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
Orientation Relationships ◽  
Soft Magnetic ◽  
X Ray ◽  
Si Substrates ◽  
The Face ◽  
Face Centered

ABSTRACTThin Co and Co based alloy films with the face centered cubic (FCC) structure have been epitaxially grown on single crystal Si wafers by sputter deposition. Epitaxial orientation relationships have been determined by x-ray diffraction, x-ray pole figure scans and TEM. Magnetic properties have been characterized using vibrating sampling magnetometer (VSM), torque magnetometer and BH loop tracer. Soft magnetic properties have been observed for the pure Co films.

A partly disordered 2 × 2 × 2 – superstructure of γ-brass related phase in Mn–Ni–Zn system

2021 ◽  
Vol 236 (3-4) ◽  
pp. 71-80
Author(s):  
Sivaprasad Ghanta ◽  
Anustoop Das ◽  
Rajat Kamboj ◽  
Partha P. Jana
Keyword(s):  
Crystal Structure ◽  
High Symmetry ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
X Ray ◽  
Lattice Constants ◽  
Cubic Lattice ◽  
The Face ◽  
Face Centered ◽  
Related Phase

Abstract The T phase in the Mn–Ni–Zn system was obtained as a product of high-temperature solid-state syntheses from the loaded composition of MnxNi2−xZn11 (x = 0.2–1.5)/MnxNi15.38−xZn84.62 (x = 1.54–11.54). The crystal structure of the T phase has been explored by means of X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopy (EDS). The structures were solved in the face-centered cubic space group F 4 ‾ 3 m $F‾{4}3m$ (216) and contain 409–410 atoms/unit cell. The lattice constants were found to be a = 18.1727(2) and 18.1954(1) Å for crystals C1 and C2, respectively. The crystal structure denoted the T phase is a (2aγ)3-superstructure of the ordinary cubic γ-brass-type phase. The phase is isostructural to (Fe, Ni)Zn6.5. A “cluster” description has been used to visualize the crystal structure of the title phase. The structures have been constructed by the five distinct clusters and they are situated about the high symmetry sites of the face-centered cubic lattice. The T phase is stabilized at a valance electron concentration of 1.78, which is slightly higher than those expected for typical γ-brass Hume‐Rothery compounds.

Bandgap Anomaly, Atomic Ordering, and Their Applications

MRS Bulletin ◽  
1997 ◽  
Vol 22 (7) ◽  
pp. 33-37 ◽  
Author(s):  
Tohru Suzuki
Keyword(s):  
Physical Metallurgy ◽  
Face Centered Cubic ◽  
X Ray Diffraction ◽  
Ordered Structures ◽  
Practical Applications ◽  
Resistivity Measurements ◽  
Electrical Resistivities ◽  
The Face ◽  
Face Centered ◽  
Made In

In 1916 a group of Russian chemists—Kurnakov and his colleagues—discovered that slowly cooled CuxAu1 − xmetal alloys had anomalously low electrical resistivities at simple compositions of CuAu and Cu3Au. Nine years later in 1925, Swedish physicists Johansson and Linde found by x-ray-diffraction experiments that the alloys had ordered structures on the face-centered-cubic lattice, now called CuAu I-type and AuCu3-type. Two years later, Johansson and Linde discovered CuPt-type ordering in Cu0.5Pt0.5 alloy by noticing a similar anomaly in their electrical-resistivity measurements for CuxPt1 − x. These were among the events at the dawn of physical metallurgy and study on order-disorder transformations. Many years later in 1985, the first observation of ordering in semiconductor alloys was made in AlGaAs grown on GaAs(110); the type was CuAu I. CuPt-type ordering was observed in SiGe grown on Si(001). Since the (110) orientation of the substrate for AlGaAs was clumsy for practical purposes and the degree of ordering in SiGe was extremely low, these phenomena seemed to have little relevance in practical applications. Other observations were made such as famatinite-type ordering in GalnAs and chalcopyrite-type ordering in GaAsSb. These observations however were quite rare, with only isolated cases reported.

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