A record of the Jurassic/Cretaceous boundary climatic variation on the southern margin of the Tethys : clay minerals and palynofacies of the early Cretaceous Jebel Meloussi section (Central Tunisia, Sidi Kralif Formation)

2005 ◽  
Vol 176 (2) ◽  
pp. 171-182 ◽  
Author(s):  
Johann Schnyder ◽  
Georges Gorin ◽  
Mohamed Soussi ◽  
François Baudin ◽  
Jean-François Deconinck

Abstract In order to precise the paleogeographic extension of the climatic variation known at the Jurassic/Cretaceous boundary, the sedimentary organic matter (palynofacies and Rock-Eval) and the clay minerals content of Berriasian sediments of the Sidi Kralif Formation are studied on the Jebel Meloussi section, central Tunisia. Standard sedimentological and palynofacies analysis allow to reconstruct the bathymetric curve and the sequence stratigraphic scheme. Using existing biostratigraphy based on calpionellids and ammonite zonation, the sequence stratigraphic interpretation can be correlated with the established eustatic chart. Clay mineral assemblages are characterized by a shift in the kaolinite content, recorded at the end of the calpionellid zone B, at the early/middle Berriasian boundary, at a time of high long-term sea-level (MFS Be2, second order eustatic peak). A contemporary change in the clay mineral assemblages, interpreted as a climatic change, is known from the boreal area, and from the northern margin of the Tethys Sea. That change is also documented southerly in southern Morocco (Agadir area), on the Atlantic domain. A late Tithonian to early Berriasian dry and cooler phase is replaced by a middle to late Berriasian more humid phase, indicated by a general increase in kaolinite in the clay mineral assemblages. The trend from a dry climatic phase to a more humid one, recorded on the boreal domain and along the northern margin of the Tethys is also recorded in lower paleolatitudes of Tunisia, on the southern margin of the Tethys, in better dated outcrops than the ones of Morocco. The results obtained in Tunisia show that the beginning of the climatic change was precisely synchronous on both margins, and occurred within the same long-term high sea-level context.

Clay Minerals ◽  
1993 ◽  
Vol 28 (1) ◽  
pp. 61-84 ◽  
Author(s):  
M. Thiry ◽  
T. Jacquin

AbstractThe distribution of clay minerals from the N and S Atlantic Cretaceous deep-sea sediments is related to rifting, sea-floor spreading, sea-level variations and paleoceanography. Four main clay mineral suites were identified: two are inherited and indicative of ocean geodynamics, whereas the others result from transformation and authigenesis and are diagnostic of Cretaceous oceanic depositional environments. Illite and chlorite, together with interstratified illite-smectite and smectite occur above the sea-floor basalts and illustrate the contribution of volcanoclastic materials of basaltic origin to the sediments. Kaolinite, with variable amounts of illite, chlorite, smectite and interstratified minerals, indicates detrital inputs from continents near the platform margins. Kaolinite decreases upward in the series due to open marine environments and basin deepening. It may increase in volume during specific time intervals corresponding to periods of falling sea-level during which overall facies regression and erosion of the surrounding platforms occurred. Smectite is the most abundant clay mineral in the Cretaceous deep-sea sediments. Smectite-rich deposits correlate with periods of relatively low sedimentation rates. As paleoweathering profiles and basal deposits at the bottom of Cretaceous transgressive formations are mostly kaolinitic, smectite cannot have been inherited from the continents. Smectite is therefore believed to have formed in the ocean by transformation and recrystallization of detrital materials during early diagenesis. Because of the slow rate of silicate reactions, transformation of clay minerals requires a long residence time of the particles at the water/sediment interface; this explains the relationships between the observed increases in smectite with long-term sea-level rises that tend to starve the basinal settings of sedimentation. Palygorskite, along with dolomite, is relatively common in the N and S Atlantic Cretaceous sediments. It is not detrital because correlative shelf deposits are devoid of palygorskite. Palygorskite is diagnostic of Mg-rich environments and is indicative of the warm and hypersaline bottom waters of the Cretaceous Atlantic ocean.


1987 ◽  
Vol 124 (3) ◽  
pp. 261-271 ◽  
Author(s):  
Julian E. Andrews

AbstractClay minerals from Middle Jurassic lagoonal mudrocks, siltstones and silty fine-grained sandstones of the upper Great Estuarine Group (Bathonian) are divided into four assemblages. Assemblage 1, the most common assemblage, is rich in mixed-layer illite–smectite with attendant illite and kaolinite. Assemblage 2 is dominated by smectitic clay. These assemblages are indicative of primary Jurassic deposition. Illite and kaolinite were probably derived from the weathering of older rocks and soils in the basin hinterland and were deposited in the lagoons as river-borne detritus. The majority of smectite and mixed-layer illite–smectite is interpreted as the argillization product of Jurassic volcanic dust, also deposited in the lagoons by rivers. Near major Tertiary igneous intrusions these depositional clay mineral assemblages have been altered. Assemblage 3 contains smectite-poor mixed-layer illite–smectite, whilst Assemblage 4 contains no smectitic clay at all. Destruction of smectite interlayers occurred at relatively shallow burial depths (< 2500 m) due to enhanced geothermal gradients and local convective hot-water circulation cells associated with the major Tertiary igneous intrusions.


Clay Minerals ◽  
2002 ◽  
Vol 37 (4) ◽  
pp. 699-707 ◽  
Author(s):  
A. Mirabella ◽  
M. Egli ◽  
S. Carnicelli ◽  
G. Sartori

AbstractThe formation of clay minerals was investigated in Spodosols developed in the subalpine belt, with similar exposure, climate and age, but deriving from different parent materials. All the soils were classified as Haplic Podzols and showed the characteristic eluviation and illuviation features of Fe, Al and organic carbon. However, varying parent material lithology led to different clay mineral assemblages in the soil. Smectite could be found in the E horizons of soils developed from granodiorite and tonalite materials. Its formation was strongly dependent on the presence of chlorite in the parent material. If nearly no other 2:1 mineral components, such as chlorite, are present in the lower soil horizons, then a residual micaceous mineral becomes the dominant clay mineral. The latter derives from a mica-vermiculite interstratified mineral.


Geologos ◽  
2009 ◽  
Vol 15 (3-4) ◽  
pp. 169-180 ◽  
Author(s):  
Ahmed Khidir ◽  
Octavian Catuneanu

Predictive diagenetic clay-mineral distribution in siliciclastic rocks as a tool for identifying sequence boundaries in non-marine successions: the Coalspur Formation, west-central AlbertaThe study of upper Cretaceous-lower Tertiary fluvial deposits of the Coalspur Formation in the Foothills region of west-central Alberta reveals that the distribution of early authigenic kaolinite has a well-defined relation to the sequence stratigraphic framework. In this context, it has been observed that the kaolin mineral content increases in sandstones lying below subaerial unconformities, which mark the most significant stratigraphic hiatuses and hence the sequence boundaries in fully fluvial successions. The increased abundance of authigenic kaolinite immediately below sequence boundaries may have been caused by the infiltration of meteoric water during times of subaerial erosion, resulting in the dissolution of unstable minerals (e.g., micas and feldspar) and the formation of kaolinite and secondary porosity. It is therefore suggested that the change in clay mineral assemblages in the stratigraphic section depends in part on the position of the analyzed sandstone samples relative to the sequence boundaries. In a larger context, the method of using authigenic clays to delineate depositional sequences in non-marine successions needs to be evaluated on a case-by-case basis, as the diagnostic early diagenetic minerals underlying the sequence boundary may change as a function of palaeoclimate and also as a function of late diagenetic processes.


Clay Minerals ◽  
2009 ◽  
Vol 44 (3) ◽  
pp. 389-404 ◽  
Author(s):  
M. Setti ◽  
L. Marinoni ◽  
A. Lopez-Galindo

AbstractThe CRP-3 drilling project collected sediments from 3 to 939 mbsf (metres below sea floor) in the Victoria Land Basin in Antarctica. The upper sequence (down to ~790 m bsf) is of Cenozoic age and made up of detrital glaciogenic sediments; the characteristics of clay minerals in this part have been reported elsewhere. Here, the compositional features of clay minerals in the lower sequence such as conglomerates, Devonian sandstones and dolerites are described and genetic processes clarified. Clay minerals in the deepest part of the sequence derive from the alteration of different lithologies that mostly make up the sedimentary basin.Two clay mineral assemblages were characterized through analysis by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). From 790 to 823 mbsf, samples consist of authigenic smectite of variable chemical composition forming imbricated texture of plates or flakes. The smectites probably result from hydrothermal/diagenetic transformation of earlier minerals. The primary smectite cement underwent reorganization during shearing and cataclasis. The lowest part of the sequence (below 823 mbsf) is characterized by an assemblage of kaolinite, mixed-layer illite-smectite, Fe oxyhydroxide, sporadic smectite and poorly crystallized illite. It reflects a stronger alteration process than that recorded in the upper units of core CRP-3, related to hydrothermalism connected with the intrusion of an igneous body. Both assemblages show clear differences in particle morphology, texture and smectite composition to the clay assemblages found in the Cenozoic glaciomarine sediments in the upper sequence. The different phases of alteration appear related to the processes of rifting, exhumation and faulting that characterized this region since the Mesozoic.


Clay Minerals ◽  
2008 ◽  
Vol 43 (4) ◽  
pp. 615-630 ◽  
Author(s):  
L. Daoudi ◽  
F. Rocha ◽  
B. Ouajhain ◽  
J. L. Dinis ◽  
D. Chafiki ◽  
...  

AbstractUpper Cenomanian–Turonian clay mineral assemblages of sediments cropping out in the Western High Atlas basin are studied in four sections. Smectite and mixed-layer illite-smectite (I-S) have been identified as major constituents of the deposits. The composition of clay associations in black shales and associated sediments varies considerably according to age, but usually depends either on the general lithology, the abundance of organic matter, or the depth of burial. A distinct correlation is evident between clay mineral distribution and sea-level. Smectite and mixed-layer I-S with greater percentages of smectite layers increase in sediments deposited during transgressive periods, whereas they decrease progressively in the shallower facies deposited during regression in favour of illite and mixed-layer I-S with a greater percentage of illite. The vertical evolution and lateral distribution of clay assemblages and their relationships with sea-level as well as the palaeogeographic conditions prevailing during the Late Cenomanian–Turonian period (flattened topography and arid climate), indicate a detrital origin of the smectite minerals and a distribution pattern controlled by differential settling processes.


Clay Minerals ◽  
2006 ◽  
Vol 41 (1) ◽  
pp. 473-512 ◽  
Author(s):  
R. J. Merriman

AbstractLower Palaeozoic rocks crop out extensively in Wales, the Lake District of northern England and the Southern Uplands of Scotland; they also form the subcrop concealed beneath the English Midlands and East Anglia. These mainly marine sedimentary rocks were deposited in basins created during plate tectonic assembly of the various terranes that amalgamated to form the British Isles, 400-600 Ma ago. Final amalgamation occurred during the late Lower Devonian Acadian Orogeny when the basins were uplifted and deformed, producing belts of cleaved, low-grade metasediments, so-called slate belts, with a predominantly Caledonian (NE-SW) trend. The clay mineralogy of mudrock lithologies - including mudstone, shale and slate - found in these belts is reviewed. Using X-ray diffraction data from the <2 μm fractions of ~4500 mudrocks samples, clay mineral assemblages are summarized and discussed in terms of diagenetic and low-grade metamorphic reactions, and the metapelitic grade indicated by the Kübler index of illite crystallinity.Two sequences of clay mineral assemblages, or regional assemblages, are recognized. Regional Assemblage A is characterized by a greater diversity of clay minerals in assemblages from all metapelitic grades. It includes K-rich, intermediate Na/K and Na-rich white micas, chlorite and minor amounts of pyrophyllite. Corrensite, rectorite and pyrophyllite are found in the clay assemblages of contact or hydrothermally altered mudstones. K-white micas are aluminous and phengite-poor, with b cell dimensions in the range 8.98-9.02 Å. Regional Assemblage B has fewer clay minerals in assemblages from a range of metapelitic grades. Phengite-rich K-mica is characteristic whereas Na- micas are rare, and absent in most assemblages; chlorite is present and minor corrensite occurs in mudrocks with mafic-rich detritus. Minor amounts of kaolinite are sporadically present, but dickite and nacrite are rare; pyrophyllite and rectorite are generally absent. The b cell dimensions of K-white mica in Regional Assemblage B are in the range 9.02-9.06 Å. The two regional assemblages are found in contrasting geotectonic settings. Regional Assemblage A is characteristic of the extensional basin settings of Wales, the northern Lake District and the Isle of Man. These basins have a history of early burial metamorphism associated with extension, and syn-burial or post-burial intrusive and extrusive volcanic activity. Intermediate Na/K mica probably developed from hydrothermal fluids generated around submarine volcanic centres. Deep diagenetic and low anchizonal clay mineral in these basins may develop a bedding-parallel microfabric. Chlorite-mica stacks also occur in the extensional basins and the stacking planes represent another type of bedding-parallel microfabric. Both types of microfabric are non-tectonic and developed by burial during the extensional phase of basin evolution. Regional Assemblage B is developed in the plate-convergent settings of the Southern Uplands and the southern Lake District. In the accretionary complex of the Southern Uplands the processes of burial diagenesis, metamorphism and tectonism were synchronous events. In both plate- convergent basins, low temperatures and tectonic fabric-formation had an important role in clay mineral reactions, whereas hydrothermal fluids played no part in clay genesis.


Author(s):  
Jun Wu ◽  
Zuhua Deng ◽  
Yongfeng Deng ◽  
Annan Zhou ◽  
Yunsheng Zhang

The strength of cement stabilized clay is less than that of concrete and mortar and shows a distinct variability owing to the existence of various clay minerals. To better understand the cement-clay reactions and the strength generation, two artificial clays with the unique clay mineral and major strength-producing constituents of cement clinker were investigated via mechanical, compositional, and microstructural analyses. Results show that C3A-stabilized clay gains strength rapidly in the first three days, but this favourable tendency vanishes over time. After 90 days of curing, the strength of C3S-stabilized clay is about four times that of the corresponding C3A-stabilized clay, indicating the remarkable long-term stabilization efficiency of C3S. Furthermore, clay minerals primarily draw into strength evolution in the reaction process. Despite that bentonite is more reactive than kaolin as long as the highly alkaline conditions persist, it has a higher probability to flocculate into large aggregates during the mixing process, which may impair the reaction efficiency and even brings adverse stabilization effects, suggesting the importance of uniformity control.


2020 ◽  
Author(s):  
Shengfa Liu ◽  
Xuefa Shi ◽  
Xisheng Fang ◽  
Yanguang Dou ◽  
Yanguang Liu ◽  
...  

&lt;p&gt;We present a paleoclimatic reconstruction for the Holocene by clay mineral analyses of sediments from core MZ02 retrieved from the mud area of the inner continental shelf of the East China Sea (ECS). The clay minerals mainly consist of illite (66%-79%) and chlorite (12%-19%), with minor kaolinite (7%-13%) and smectite (0-6%). Provenance analysis suggests that the illite-dominated clay minerals were derived mainly from the detrital outputs of the Changjiang, Minjiang, and small rivers from Taiwan Island. Our study indicates that the sea level rise since the last glacial, the strength of the Taiwan Warm Current (TWC) and Chinese Coastal Current (CCC) have controlled the dispersal and deposition of clay minerals on the ECS, that in turn determined the clay mineral compositions in the core sediments. During 13,000-9500 BP, due to the lower sea level and shorter distance between these three estuaries and core MZ02, fine sediments on the inner shelf of the ECS were primarily supplied by mixed provenances from the Changjiang, Taiwanese, and Minjiang rivers. During the early Holocene (9500-6200 BP), stronger sediment reworking and erosion at the shelf edge was responsible for the increased lateral transport of fine sediments in the ECS, which lead to a dominance of the sediment source from the Changjiang, while the Taiwanese and Minjiang rivers only provided minor components of detrital sediment to the shelf. Increased strength of TWC might have played an important role in the sediment dispersal and deposition on the inner shelf of the ECS during 6200-2400 BP, with a dominance of more than 60% sediments transported from Taiwanese rivers. Furthermore, our study implies that the Asian monsoon and the weakening of TWC were linked to the abrupt increase of Changjiang and Minjiang derived terrigenous detritus materials since 2400 BP.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;Acknowledgments&lt;/p&gt;&lt;p&gt;This work was supported by National Nature Science Foundation of China (No.41106063), Science and Technology Basic Special Program of China (No.2008FY220300), Marine Public Welfare Research Project of China (No.200805063), China Postdoctoral Science Foundation (No.20100481304) and Coastal Investigation and Research Project of China (No. 908-01-CJ12).&lt;/p&gt;


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