Spring Waters as an Indicator for Non-Point-Source Nitrate Pollution of Rural Watercourses – Findings from Two Decades of Spring Monitoring in the Low Mountain Landscape of Saarland
Abstract Background:Interflow-dominated spring waters provide a comprehensive picture of emissions with nitrate and other pollutants caused by the type and intensity of land use in the topographic catchment area. One aim of this study was to develop a model for predicting the share of nitrate pollution from non-point sources based on the type of agricultural use in the catchment areas of small and medium-sized watercourses. Methods:Fifty-five springs in Saarland and the adjacent Rhineland-Palatinate were monitored for pollutants during three monitoring periods of at least twelve months duration between 2000 and 2019. The catchment areas are representative of the natural regions in the study area and are outside the influence of settlements and other developments. In addition to nitrate and other physicochemical parameters, 25 agriculturally impacted springs were screened for pesticides and their metabolites.Results:Since the first measurements were taken in 2000, the vast majority of agriculturally impacted springs have consistently exhibited high nitrate concentrations of between 20 and 40 mg/L NO3-. Springs not influenced by agriculture contain an average of 3.6 mg/L of nitrate. The extreme values observed in the early 2000s decreased to the limit value of 50 mg/L, but most of the springs with moderate levels exhibited an increase to approximately 30 mg/L. The number of pesticidal agents detected in the spring waters demonstrates a clear correlation with the intensity of agricultural usage and the nitrate content detected. A regression model derived from the highly significant correlation between nitrate content and the share of cropland in the catchment area can be used to quantify the share of nitrate pollution attributable to non-point-source inputs for larger catchments in the region under investigation.Conclusion:Nitrate discharged from farmland has not decreased since the EC WFD entered into force. At the extremely heavily polluted sites of the past, measures have been implemented in the meantime that have led to compliance with the limit value of the Nitrate Directive. As below this limit, nitrate levels are increasing significantly, we suggest to incorporate the marine ecology target as a binding mark for official water pollution control in the future.