scholarly journals Kinematic Viscosity Prediction Guide: Reviewing and Evaluating Empirical Models for Diesel Fractions, and Biodiesel-Diesel Blends according to the Temperature and Feedstock

2021 ◽  
Author(s):  
Shella Santos ◽  
Maria Regina Wolf Maciel ◽  
Leonardo Vasconcelos Fregolente
Keyword(s):  
Kinematic Viscosity ◽  
Volume Fraction ◽  
Accurate Method ◽  
Estimation Accuracy ◽  
Operating Personnel ◽  
Petroleum Fractions ◽  
Different Temperatures ◽  
Design Calculations ◽  
Diesel Fractions

Abstract Experimental analysis of viscosity can be a straightforward and inexpensive analysis for few samples. However, in industrial processes that have high demands of properties measurements, the determination of viscosity and other properties involves time-consuming with sampling, analysis and availability of results. Also in refineries, the sampling routines for experimental determination of the viscosity of streams are not enough to represent variations that occur in the process, such as the shift of an oil tank in distillation units. In addition, besides requiring cost of operating personnel and laboratory analyst, all of these steps can take up to one shift until the result is available. Therefore, as an alternative, the use of predictive methods of kinematic viscosity are essential. Empirical methods have been used in simulations and design calculations of streams and mixture at industries regarding kinematic viscosity (KV) of petroleum fractions and fuels at different temperatures. However, there are uncertainties about the most accurate method to use at specific condition (temperature, feedstock, volume fraction) which might affect the KV prediction of fuels with unknown composition. Therefore, we assembled and evaluated several methods to predict KV of different diesel systems. In addition, new methods for predicting KV of diesel fractions at several temperatures were also developed for improving the estimation accuracy. As a result, we developed a guide with suggestions of the most accurate models to be applied for diesel fraction from assays, diesel fractions S500 from blend system at several temperatures, and biodiesel-diesel blends at different temperatures, volume fractions and feedstock.

scholarly journals Investigation of Physico-Chemical Properties of Simaruoba Methyl Ester and Diesel Blends

2018 ◽  
Vol 7 (4.5) ◽  
pp. 138
Author(s):  
Basavaraj R. Hosmani ◽  
Vadiraj V. Katti
Keyword(s):  
Methyl Ester ◽  
Kinematic Viscosity ◽  
Volume Fraction ◽  
Standard Procedure ◽  
Chemical Properties ◽  
Flash Point ◽  
Volume Percentage ◽  
Heating Value ◽  
Physico Chemical ◽  
Different Temperatures

This paper presents the experimental study of physico-chemical properties of Simarouba methyl ester and diesel blends at the different temperatures and with varying volume percentage of Simarouba methyl ester in the blend. Blends are prepared adding different volume fraction of Simarouba methyl ester to neat diesel. The percentage of Simarouba methyl ester added to diesel is 10% to 90%, the prepared blends are stirred well for mixing of methyl ester and diesel. The prepared blends are kept in closed container for 24 hours for observation of separation of blends. It is observed that there is no separation of Simarouba methyl ester and diesel. Experiments are carried out to find density, kinematic viscosity, flash point and heating value of blends. These properties are investigated using standard equipments with standard procedure. Viscosity is determined by using standard Red-Wood viscometer with standard procedure of methyl ester and diesel blends at different temperatures. It is observed that as volume fraction of Simarouba methyl ester increases in the blend density, kinematic viscosity, flash point increases and heating value decreases. The percentage decrease in kinematic viscosity is more at lower temperature compared to higher temperature. Correlations for estimation of viscosity and density of blends at different temperatures are proposed.  

Quantitative Assessment of Soluble Fibrin in Plasma by Affinity Chromatography – A Comparative Study with desAA-Fibrin, desAABB-Fibrin and Fibrinogen

1985 ◽  
Vol 54 (02) ◽  
pp. 533-538 ◽  
Author(s):  
Wilfried Thiel ◽  
Ulrich Delvos ◽  
Gert Müller-Berghaus
Keyword(s):  
Affinity Chromatography ◽  
Calcium Ions ◽  
Quantitative Assessment ◽  
Fluid Phase ◽  
Soluble Fibrin ◽  
Binding Characteristics ◽  
Different Temperatures ◽  
Immobilized Proteins ◽  
Sepharose 4B

SummaryA quantitative determination of soluble fibrin in plasma was carried out by affinity chromatography. For this purpose, desAA-fibrin and fibrinogen immobilized on Sepharose 4B were used at the stationary side whereas batroxobin-induced 125I-desAA-fibrin or thrombin-induced 125I-desAABB-fibrin mixed with plasma containing 131I-fibrinogen represented the fluid phase. The binding characteristics of these mixtures to the immobilized proteins were compared at 20° C and 37° C. Complete binding of both types of fibrin to the immobilized desAA-fibrin was always seen at 20° C as well as at 37° C. However, binding of soluble fibrin was accompanied by substantial binding of fibrinogen that was more pronounced at 20° C. Striking differences depending on the temperature at which the affinity chromatography was carried out, were documented for the fibrinogen-fibrin interaction. At 20° C more than 90% of the applied desAA-fibrin was bound to the immobilized fibrinogen whereas at 37° C only a mean of 17% were retained at the fibrinogen-Sepharose column. An opposite finding with regard to the tested temperature was made with the desAABB-fibrin. Nearly complete binding to insolubilized fibrinogen was found at 37° C (95%) but only 58% of the desAABB-fibrin were bound at 20° C. The binding patterns did not change when the experiments were performed in the presence of calcium ions. The opposite behaviour of the two types of soluble fibrin to immobilized fibrinogen at the different temperatures, together with the substantial binding of fibrinogen in the presence of soluble fibrin to insolubilized fibrin in every setting tested, devaluates affinity chromatography as a tool in the quantitative assessment of soluble fibrin in patients’ plasma.

Development of an HPLC-UV Method for Quantification of Stattic

2019 ◽  
Vol 15 (6) ◽  
pp. 568-573
Author(s):  
Soheil Sedaghat ◽  
Ommoleila Molavi ◽  
Akram Faridi ◽  
Ali Shayanfar ◽  
Mohammad Reza Rashidi
Keyword(s):  
High Performance ◽  
Accurate Method ◽  
Plasma Samples ◽  
Promising Target ◽  
Relative Standard ◽  
Dimerization Inhibitor ◽  
Oncogenic Protein ◽  
First Time ◽  
Transcription 3

Background: Signal transducer and activator of transcription 3 (STAT3), an oncogenic protein found constitutively active in many types of human malignancies, is considered to be a promising target for cancer therapy. Objective: In this study for the first time, a simple and accurate method has been developed for the determination of a STAT3 dimerization inhibitor called stattic in aqueous and plasma samples. Methods: A reverse-phase high-performance liquid chromatography (RP-HPLC) composed of C18 column as stationary phase, and the mixture of acetonitrile (60%) and water (40%) as mobile phase with a UV detection at 215 nm were applied for quantification of stattic. The developed method was validated by Food and Drug Administration (FDA) guideline. Results: The method provided a linear range between 1-40 and 2.5-40 µg mL-1 for aqueous and plasma samples, respectively, with a correlation coefficient of 0.999. The accuracy (as recovery) of the developed method was found to be between 95-105% for aqueous medium and 85-115% for plasma samples. The precision (as relative standard deviation) for aqueous and plasma samples was less than 6% and 15%, respectively. The sensitivity of the developed method based on FDA guideline was 1 µg mL-1 for aqueous and 2.5 µg mL-1 for plasma samples. Conclusion: These results show that the established method is a fast and accurate quantification for stattic in aqueous and plasma samples.

Is it necessary to calculate Young’s modulus in AFM nanoindentation experiments regarding biological samples?

2020 ◽  
Vol 12 ◽  
Author(s):  
S.V. Kontomaris ◽  
A. Malamou ◽  
A. Stylianou
Keyword(s):  
Young’S Modulus ◽  
Biological Samples ◽  
Young's Modulus ◽  
Reference Sample ◽  
Nonlinear Behavior ◽  
Accurate Method ◽  
Accurate Solution ◽  
Hertz Model ◽  
Work Done

Background: The determination of the mechanical properties of biological samples using Atomic Force Microscopy (AFM) at the nanoscale is usually performed using basic models arising from the contact mechanics theory. In particular, the Hertz model is the most frequently used theoretical tool for data processing. However, the Hertz model requires several assumptions such as homogeneous and isotropic samples and indenters with perfectly spherical or conical shapes. As it is widely known, none of these requirements are 100 % fulfilled for the case of indentation experiments at the nanoscale. As a result, significant errors arise in the Young’s modulus calculation. At the same time, an analytical model that could account complexities of soft biomaterials, such as nonlinear behavior, anisotropy, and heterogeneity, may be far-reaching. In addition, this hypothetical model would be ‘too difficult’ to be applied in real clinical activities since it would require very heavy workload and highly specialized personnel. Objective: In this paper a simple solution is provided to the aforementioned dead-end. A new approach is introduced in order to provide a simple and accurate method for the mechanical characterization at the nanoscale. Method: The ratio of the work done by the indenter on the sample of interest to the work done by the indenter on a reference sample is introduced as a new physical quantity that does not require homogeneous, isotropic samples or perfect indenters. Results: The proposed approach, not only provides an accurate solution from a physical perspective but also a simpler solution which does not require activities such as the determination of the cantilever’s spring constant and the dimensions of the AFM tip. Conclusion: The proposed, by this opinion paper, solution aims to provide a significant opportunity to overcome the existing limitations provided by Hertzian mechanics and apply AFM techniques in real clinical activities.

The flow of liquid in a stream from the standard turbine impeller

1979 ◽  
Vol 44 (3) ◽  
pp. 700-710 ◽  
Author(s):  
Ivan Fořt ◽  
Hans-Otto Möckel ◽  
Jan Drbohlav ◽  
Miroslav Hrach
Keyword(s):  
Reynolds Number ◽  
Kinematic Viscosity ◽  
Momentum Flux ◽  
Relative Size ◽  
Mean Velocity ◽  
Axial Profile ◽  
The Mean ◽  
Hot Film ◽  
Turbine Impeller

Profiles of the mean velocity have been analyzed in the stream streaking from the region of rotating standard six-blade disc turbine impeller. The profiles were obtained experimentally using a hot film thermoanemometer probe. The results of the analysis is the determination of the effect of relative size of the impeller and vessel and the kinematic viscosity of the charge on three parameters of the axial profile of the mean velocity in the examined stream. No significant change of the parameter of width of the examined stream and the momentum flux in the stream has been found in the range of parameters d/D ##m <0.25; 0.50> and the Reynolds number for mixing ReM ##m <2.90 . 101; 1 . 105>. However, a significant influence has been found of ReM (at negligible effect of d/D) on the size of the hypothetical source of motion - the radius of the tangential cylindrical jet - a. The proposed phenomenological model of the turbulent stream in region of turbine impeller has been found adequate for values of ReM exceeding 1.0 . 103.

scholarly journals Low-carbon cast microalloyed steel intercritically heat-treated at different temperatures: microstructure and mechanical properties

2021 ◽  
Vol 21 (2) ◽  
Author(s):  
Hadi Torkamani ◽  
Shahram Raygan ◽  
Carlos Garcia Mateo ◽  
Yahya Palizdar ◽  
Jafar Rassizadehghani ◽  
...  
Keyword(s):  
Carbon Content ◽  
Volume Fraction ◽  
Block Size ◽  
Tensile Tests ◽  
Total Elongation ◽  
Martensite Phase ◽  
Low Carbon ◽  
Steel Increase ◽  
Different Temperatures ◽  
The Impact

AbstractIn this study, dual-phase (DP, ferrite + martensite) microstructures were obtained by performing intercritical heat treatments (IHT) at 750 and 800 °C followed by quenching. Decreasing the IHT temperature from 800 to 750 °C leads to: (i) a decrease in the volume fraction of austenite (martensite after quenching) from 0.68 to 0.36; (ii) ~ 100 °C decrease in martensite start temperature (Ms), mainly due to the higher carbon content of austenite and its smaller grains at 750 °C; (iii) a reduction in the block size of martensite from 1.9 to 1.2 μm as measured by EBSD. Having a higher carbon content and a finer block size, the localized microhardness of martensite islands increases from 380 HV (800 °C) to 504 HV (750 °C). Moreover, despite the different volume fractions of martensite obtained in DP microstructures, the hardness of the steels remained unchanged by changing the IHT temperature (~ 234 to 238 HV). Applying lower IHT temperature (lower fraction of martensite), the impact energy even decreased from 12 to 9 J due to the brittleness of the martensite phase. The results of the tensile tests indicate that by increasing the IHT temperature, the yield and ultimate tensile strengths of the DP steel increase from 493 to 770 MPa, and from 908 to 1080 MPa, respectively, while the total elongation decreases from 9.8 to 4.5%. In contrast to the normalized sample, formation of martensite in the DP steels could eliminate the yield point phenomenon in the tensile curves, as it generates free dislocations in adjacent ferrite.

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