scholarly journals Itaconic acid-modified layered double hydroxide as a ‎novel adsorbent for effective removal of Congo red from aqueous solutions

2021 ◽  
Author(s):  
Mohammad Dinari ◽  
Shirin Shabani
Keyword(s):  
Layered Double Hydroxide ◽  
Itaconic Acid ◽  
Congo Red ◽  
Aqueous Media ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Order Kinetic ◽  
Solution Ph ◽  
Pseudo Second Order ◽  
Double Hydroxide

Abstract Herein, we report the synthesis of Cu-Ca-Al/NO3-based layered double hydroxide through co-precipitation methodology. The prepared layered double hydroxide was then modified with itaconic acid. The physicochemical properties of the prepared materials were studied using Fourier transform-infrared spectroscopy, scanning electron microscopy, X-ray diffraction analysis, thermogravimetric analysis, and nitrogen adsorption/desorption technique. The prepared materials were then applied as novel adsorbents for the removal of Congo red as a model of an anionic dye from aqueous media. To reach maximum adsorption, the effect of parameters including sample solution pH, adsorbent amount, contact time, and initial concentration of Congo red on the adsorption process was investigated. Kinetic studies were also conducted to study the mechanism of adsorption. In this regard, the kinetic models of pseudo-first-order, pseudo-second-order, Elovich, and intra-particle diffusion were studied. The results showed that the adsorption of Congo red onto Cu-Ca-Al-LDH and LDH-ITA adsorbents followed the pseudo-second-order kinetic model. To evaluate the equilibrium adsorption data, different isotherms including Langmuir, Freundlich, and Dubinin-Radushkevich were also applied. The data revealed that the Freundlich isotherm provided the best fit with the equilibrium data of both adsorbents. Maximum adsorption capacities of 81 and 84 mg g− 1 were obtained using Cu-Ca-Al-LDH and LDH-ITA adsorbents, respectively.

Adsorption of Congo Red Dye from Aqueous Solutions by Montmorillonite as a Low-cost Adsorbent

2017 ◽  
Vol 16 (1) ◽  
Author(s):  
Yusef Omidi Khaniabadi ◽  
Hassan Basiri ◽  
Heshmatollah Nourmoradi ◽  
Mohammad Javad Mohammadi ◽  
Ahmad Reza Yari ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Congo Red ◽  
Low Cost ◽  
Aqueous Media ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Effective Option ◽  
Pseudo Second Order

AbstractIn this study, the sorption of Congo red (CR), as a toxic dye, from aqueous media was investigated using montmorillonite (MMT) as a low-cost adsorbent. The influence of several factors such as contact time, pH, adsorbent dosage, dye content, and ionic strength was investigated on the dye removal. MMT was characterized by Fourier transformed infrared (FTIR) spectroscopy and X-ray diffractometer (XRD). Different kinetic and isotherm models including pseudo-first and pseudo-second order kinetic and Langmuir and Freundlich were applied to analyze experimental data, respectively. The results showed that the data were well fitted by pseudo-second-order kinetic and Freundlich isotherm models. The optimum conditions for the sorption of CR were achieved over 40 min and at pH=2. According to the results of the present study, MMT can be used as a low-cost, eco-friendly and effective option for the adsorption of CR from aqueous solutions.

scholarly journals Banana Fibers as Sorbent for Removal of Acid Green Dye from Water

2016 ◽  
Vol 2016 ◽  
pp. 1-11 ◽  
Author(s):  
Siti Kartina Abdul Karim ◽  
Soh Fong Lim ◽  
S. N. David Chua ◽  
Shanti Faridah Salleh ◽  
Puong Ling Law
Keyword(s):  
Freundlich Isotherm ◽  
Sorption Process ◽  
Agitation Speed ◽  
Second Order ◽  
Order Kinetic ◽  
Solution Ph ◽  
Banana Fiber ◽  
Banana Fibers ◽  
Pseudo Second Order ◽  
Banana Leaves

In this study, banana fibers extracted from banana leaves, stem, and stalk were used to remove acid green dye from aqueous solution. Three initial concentrations (750, 1000, and 1500 ppm) were chosen to determine the kinetic characteristics of the banana fiber sorbents at 25°C, agitation speed of 200 rpm, and total contact time of 3 hours. The pseudo-first-order, pseudo-second-order, and Dunwald-Wagner kinetic models were applied to the experimental kinetic data. For isotherm study, the batch experiments were performed at 25°C, initial pH 2, agitation speed of 200 rpm, and initial concentrations between 100 and 2000 ppm. The experimental data was fitted to the Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin isotherms. The equilibrium was achieved in less than 90 minutes. The removal of the acid green dye was found to be following closely the pseudo-second-order kinetic model. For equilibrium study, the Freundlich isotherm was found to fit well with adsorption of acid green dye on the banana leaves, stem, and stalk sorbents. The calculated mean free energy of 4–11 J/mol indicated that the sorption process was mostly physical in nature. Experimental results also showed the adsorption performance is greatly affected by the initial solution pH.

Congo Red Dye Removal Using Ca-Al Layered Double Hydroxide: Kinetics and Equilibrium

2019 ◽  
Vol 814 ◽  
pp. 463-468 ◽  
Author(s):  
Hong Tham Nguyen Thi ◽  
Duy Chinh Nguyen ◽  
Thi Thuong Nguyen ◽  
Van Thuan Tran ◽  
Huu Vinh Nguyen ◽  
...  
Keyword(s):  
Layered Double Hydroxide ◽  
Congo Red ◽  
Removal Rate ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Initial Concentration ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Red Dye ◽  
Double Hydroxide

This In this study, the Ca-Al layered double hydroxide was used as a potential adsorbent for the removal of Congo red from aqueous solutions. The effects of Initial concentration and contact time on the adsorption properties of Congo red by Ca-Al LDHs were studied. The removal rate of Conge red reached to 59.416 mg/g under room temperature with 0.2g of adsorbent, initial concentration of 50 ppm, adsorption time of 210 min, shaking speed of 90r/min. The experimental equilibrium data for the removal of Congo red were evaluated by various isotherm models. The pseudo-second-order kinetic models were found to fit the adsorption kinetics, and the equilibrium data were appropriately fitted to Langmuir and Freundlich model adsorption isotherm.

Study of the kinetics and the adsorption isotherm of cadmium(II) from aqueous solution using green algae (Ulva lactuca) biomass

2015 ◽  
Vol 72 (9) ◽  
pp. 1505-1515 ◽  
Author(s):  
H. Asnaoui ◽  
A. Laaziri ◽  
M. Khalis
Keyword(s):  
Aqueous Solution ◽  
Metal Ions ◽  
Low Cost ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Ulva Lactuca ◽  
Order Kinetic ◽  
Solution Ph ◽  
Algae Biomass ◽  
Pseudo Second Order

Batch experiments were conducted to study the adsorption of hazardous cadmium onto low-cost algae biomass in aqueous solution with respect to concentration of adsorbate, adsorbent dosage, contact time, solution pH and temperature. Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms and the isotherm constants were determined. The activation energy of adsorption was also evaluated for the adsorption of cadmium onto Ulva lactuca biomass. Experimental data were tested in terms of biosorption kinetics using pseudo-first-order and pseudo-second-order kinetic models. The results showed that the biosorption processes of Cd(II) followed well pseudo-second-order kinetics. Langmuir and Freundlich models were applied to describe the biosorption isotherm of the metal ions by Ulva lactuca biomass. Langmuir model fitted the equilibrium data better than the Freundlich isotherm. The biosorption capacity of Ulva lactuca biomass for cadmium was found to be 3.02 mg/g at pH 5.60 min equilibrium time and 20 °C. The mean free energy which was calculated was 6.24 kJ/mol for Cd(II) biosorption, which shows that the adsorption is physical. The calculated thermodynamic parameters (ΔG0, ΔH0 and ΔS0) showed that the biosorption of Cd(II) onto Ulva lactuca biomass was feasible, spontaneous and exothermic under examined conditions. The results indicate that algae Ulva lactuca could be employed as a low-cost material for the removal of metal ions from aqueous solution.

scholarly journals Treatment of textile effluents by chloride-intercalated Zn-, Mg- and Ni-Al layered double hydroxides

2016 ◽  
Vol 7 (3) ◽  
pp. 307-318 ◽  
Author(s):  
F. Z. Mahjoubi ◽  
A. Khalidi ◽  
O. Cherkaoui ◽  
R. Elmoubarki ◽  
M. Abdennouri ◽  
...  
Keyword(s):  
Oxygen Demand ◽  
Freundlich Isotherm ◽  
Chloride Ions ◽  
Second Order ◽  
Cod Removal ◽  
Precipitation Method ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Solution Ph ◽  
Pseudo Second Order

This work involved the preparation, characterization and dyes removal ability of Zn-Al, Mg-Al and Ni-Al layered double hydroxide (LDH) minerals intercalated by chloride ions. The materials were synthetized by the co-precipitation method. X-ray diffraction, Fourier transform infrared, thermogravimetric-differential thermal analysis and transmission electron microscopy characterization exhibited a typical hydrotalcite structure for all the samples. Adsorption experiments for methyl orange were performed in terms of solution pH, contact time and initial dye concentration. Experimental results indicate that the capacity of dye uptake augmented rapidly within the first 60 min and then stayed practically the same regardless of the concentration. Maximum adsorption occurred with acidic pH medium. Kinetic data were studied using pseudo-first-order and pseudo-second-order kinetic models. Suitable correlation was acquired with the pseudo-second-order kinetic model. Equilibrium data were fitted to Langmuir and Freundlich isotherm models. The maximum Langmuir monolayer adsorption capacities were 2,758, 1,622 and 800 mg/g, respectively, for Zn-Al-Cl, Mg-Al-Cl and Ni-Al-Cl. The materials were later examined for the elimination of color and chemical oxygen demand (COD) from a real textile effluent wastewater. The results indicated that the suitable conditions for color and COD removal were acquired at pH of 5. The maximum COD removal efficiency from the effluent was noted as 92.84% for Zn-Al-Cl LDH.

scholarly journals Adsorptive removal of direct red 80 and methylene blue from aqueous solution by potato peels: a comparison of anionic and cationic dyes

2021 ◽  
Author(s):  
Khawla Ben Jeddou ◽  
Fatma Bouaziz ◽  
Fadia Ben Taheur ◽  
Oumèma Nouri-Ellouz ◽  
Raoudha Ellouz-Ghorbel ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Adsorption Process ◽  
Fourier Transforms ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Order Kinetic ◽  
Solution Ph ◽  
Model Calculations ◽  
Pseudo Second Order ◽  
Potato Peels

Abstract Adsorption of direct red 80 (DR 80) and methylene blue (MB) from aqueous solutions on potato peels (PP) has been compared. The use of peels in decontamination technology is very promising given the near zero-cost for the synthesis of those adsorbents. The selected potato peels were first analyzed by scanning using electron microscopy (SEM) and Fourier transforms infra red spectroscopy (FTIR). Then the adsorption behavior was studied in a batch system. The adsorption process is affected by various parameters such as the solution pH (2–11), the initial concentration of the dye (20, 50, 100, 150 and 200 mg L−1), the adsorbent dose (0.1%–3%), the temperature (303.16 K, 313.16 K, and 323.16 K), agitation (up to 250 rpm), as well as the contact time. Adsorption isotherms of the studied dye on the adsorbent were determined and compared with the Langmiur, Freundlich and Temkin adsorption models. The results show that the data was most similar to the Freundlich isotherm (R2 = 0.99). The maximum adsorption capacities (Qmax) of MB and DR 80 by the PP at temperatures 303.16 K, 313.16 K and 323.16 K were found to be approximately 97.08 mg g−1; 45.87 mg g−1; 61.35 mg g−1 and 27.778 mg g−1; 45.45 mg g−1; and 32.258 mg g−1. The kinetic data was compared to the pseudo-first-order, pseudo-second-order, and intraparticle diffusion models. This revealed that adsorption of methylene blue onto PP abided mostly to the pseudo-second-order kinetic model. Calculations of various thermodynamic parameters such as enthalpy change (ΔH), entropy change (ΔS), and free energy change (ΔG) display the endothermic and spontaneous nature of the adsorption process.

scholarly journals Adsorption of Chromium Ions on Activated Carbon Produced from Cow Bones

2019 ◽  
Vol 20 (2) ◽  
pp. 23-32
Author(s):  
Marah Waleed Khalid ◽  
Sami D. Salman
Keyword(s):  
Surface Area ◽  
Kinetic Equations ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Raw Material ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Solution Ph ◽  
Chromium Ions ◽  
Pseudo Second Order

Due to the broad range uses of chromium for industrial purposes, besides its carcinogenic effect, an efficient, cost effective removal method should be obtained. In this study, cow bones as a cheap raw material were utilized to produce active carbon (CBAC) by physiochemical activation, which was characterized using: SEM to investigate surface morphology and BET to estimate the specific surface area. The best surface area of CBAC was 595.9 m2/gm which was prepared at 600 ᵒC activation temperature and impregnation ratio of 1:1.5. CBAC was used in aqueous chromium ions adsorption. The investigated factors and their ranges are: initial concentration (10-50 mg/L), adsorption time (30-300 min), temperature (20-50 ᵒC) and solution pH (2-11). Isotherm of adsorption and its kinetics were studied. The adsorption process was modeled statistically and was represented by an empirical model. Equilibrium data were fitted to the Langmuir and Freundlich isotherm models and the data best represented by Freundlich isotherm. Pseudo- first order and pseudo- second order kinetic equations were utilized to study adsorption kinetics, where chromium adsorption on CBAC fitted pseudo- second order fitted the data more adequately. The best removal efficiency was found to be 94.32%.

scholarly journals Study on novel modified large mesoporous silica FDU-12/polymer matrix nanocomposites for adsorption of Pb(II)

PLoS ONE ◽  
2021 ◽  
Vol 16 (1) ◽  
pp. e0245583
Author(s):  
Hamed Ghaforinejad ◽  
Hossein Mazaheri ◽  
Ali Hassani Joshaghani ◽  
Azam Marjani
Keyword(s):  
Electron Microscopy ◽  
Methyl Methacrylate ◽  
Aqueous Media ◽  
Nitrogen Adsorption ◽  
Nylon 6 ◽  
Second Order ◽  
Order Kinetic ◽  
Solution Ph ◽  
Poly Methyl Methacrylate ◽  
Pseudo Second Order

In this study, porous methacrylate-modified FDU-12/poly(methyl methacrylate) and amine-modified FDU-12/Nylon 6 nanocomposites were synthesized via a facile solution casting protocol. The physicochemical properties of the prepared materials were studied using various characterization techniques including Fourier transform-infrared spectroscopy, field emission-scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption/desorption. After characterization of the materials, the prepared nanocomposites were applied as novel adsorbents for the removal of Pb(II) from aqueous media. In this regard, the effect of various parameters including solution pH, adsorbent amount, contact time, and initial concentration of Pb(II) on the adsorption process was investigated. To study the mechanism of adsorption, kinetic studies were conducted. The kinetic models of pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion were employed. The results revealed that the adsorption of Pb(II) onto methacrylate-modified FDU-12/poly(methyl methacrylate) and amine-modified FDU-12/Nylon 6 adsorbents followed the pseudo-second-order kinetic model. Also, different isotherms including Langmuir, Freundlich, and Dubinin-Radushkevich were applied to evaluate the equilibrium adsorption data. Langmuir isotherm provided the best fit with the equilibrium data of both adsorbents with maximum adsorption capacities of 99.0 and 94.3 mg g-1 for methacrylate-modified FDU-12/poly(methyl methacrylate) and amine-modified FDU-12/Nylon 6, respectively, for the removal of Pb(II).

scholarly journals Adsorption Kinetics for the Removal of Hazardous Dye Congo Red by Biowaste Materials as Adsorbents

2013 ◽  
Vol 2013 ◽  
pp. 1-12 ◽  
Author(s):  
Sumanjit Kaur ◽  
Seema Rani ◽  
Rakesh Kumar Mahajan
Keyword(s):  
Congo Red ◽  
Low Cost ◽  
Correlation Coefficients ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Experimental Conditions ◽  
Order Kinetic Model ◽  
Pseudo Second Order

The present work aims to investigate the removal of dye congo red from aqueous solutions by two low-cost biowaste adsorbents such as ground nut shells charcoal (GNC) and eichhornia charcoal (EC) under various experimental conditions. The effect of contact time, ionic strength, temperature, pH, dye concentration, and adsorbent dose on the removal of dye was studied. The kinetic experimental data were fitted to pseudo-first order, pseudo-second order, intraparticle diffusion, Elovich model, and Bangham’s model. Results imply that adsorption of congo red on these adsorbents nicely followed the second order kinetic model and maximum adsorption capacity was found to be 117.6 and 56.8 mg g−1for GNC and EC at 318 K, however it increases with increase in temperature for both adsorbents. Equilibrium isotherms were analyzed by Langmuir, Freundlich, Temkin, Dubinin and Radushkevich, and Generalized Isotherms. Freundlich isotherm described the isotherm data with high-correlation coefficients. The results of the present study substantiate that biowaste material GNC and EC are promising adsorbents for the removal of the dye congo red.

scholarly journals Photodegradation of Rhodamine B using Cd-Al/C double layered hydroxide catalyst

2020 ◽  
Vol 12 (1) ◽  
pp. 24-30
Author(s):  
A.S. Muhammad ◽  
F.A. Garzali
Keyword(s):  
Visible Light ◽  
Layered Double Hydroxide ◽  
Rhodamine B ◽  
Second Order ◽  
Aluminium Chloride ◽  
Order Kinetic ◽  
Pseudo Second Order ◽  
Good Catalytic Activity ◽  
Double Hydroxide ◽  
Double Layered Hydroxide

This paper presents the degradation of Rhodamine B using cadmium aluminium carbon (Cd-Al/C) catalyst under visible light. The layered double hydroxide was successfully prepared from cadmium fluoride (CdF2), aluminium chloride (AlCl3), and rice husks activated carbon, and then characterized by X-ray Diffaraction (XRD) Scaning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) methods. The peaks at 2Ө 23.4 and 35.5 in the XRD result confirmed the presences of LDH. The effect of contact time, catalyst dosage, pH and initial concentration, on the photo degradiation of Rhodamine B were investigated. The experimental results showed that after 100min visible light irradiation, the percentage degradation using 200mg Cd-Al/C, pH 7 and 3ppm Rhodamine B concentration reached to 76.22%.  For kinetics studies the data obtained were analysed using pseudo first order and pseudo second order kinetic models. From the linear regression coefficient values the data were found to be best fitted to pseudo second order kinetics. The results revealed that the Cd-Al/C show good catalytic activity. Key words: Layered Double Hydroxide (LDH) Cadnium fluoride, Aluminium Chloride and Rhodamine B.

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