scholarly journals Control of Chloride Ion Corrosion by MgAlO x /MgAlFeO x in the Process of Chloride Deicing

2021 ◽  
Author(s):  
Dongdong Wang ◽  
Qi Zhu ◽  
Zipeng Xing ◽  
Lei Fang
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Inhibitors ◽  
Freezing Point ◽  
Chloride Ion ◽  
Synthesis Temperature ◽  
Molar Ratio ◽  
Dsc Analysis ◽  
Deicing Salt ◽  
Deicing Salts ◽  
Chloride Salts

Abstract The corrosion inhibitor that is added to chloride deicing salt, whose anti-corrosion and low pollution is great significance. LDHs, calcined at high temperature were used as adsorbents to remove various anionic contaminants and it could reduce the solution's freezing point after adsorbing anions. Therefore, this paper reports the use of calcined LDHs as corrosion inhibitors in deicing salts. We analyzed that the removal ability of chloride ion MgAlFeOx was stronger than that of MgAlOx, reaching 85.50%, and the freezing point was lower than that of MgAlOx, the value was -12.0 °C. At the same time, we also found that CaCl2-MgAlOx and CaCl2-MgAlFeOx significantly reduce the corrosion of carbon steel and concrete compared with chloride salts, and CaCl2-MgAlFeOx has the lowest corrosion degree. Hence, we determined that MgAlFeOx was corrosion inhibitor in chloride deicing salt. The metal molar ratio, synthesis temperature and calcination temperature for preparation of MgAl/MgAlFe-LDHs were determined by XRD and TG-DSC analysis that are 9/2/1, 120 ºC and 500 ºC, respectively. The characteristics of MgAlFeOx after Fe3+ addition were studied in detail by Zeta, XRD, XPS, BET and SEM. The mechanism of corrosion inhibitor’s anticorrosion was determined, which was achieved by adsorption and neutralization.

Anti-Corrosion Properties of the Reactive Anode and Cathode Inhibitor by Electrochemical Treatment in Aqueous

2013 ◽  
Vol 284-287 ◽  
pp. 31-34
Author(s):  
Han Seung Lee ◽  
Hwa Sung Ryu
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Concrete Structure ◽  
Corrosion Inhibitors ◽  
Chloride Ion ◽  
Passive State ◽  
Molar Ratio ◽  
Ion Content ◽  
Organic Corrosion Inhibitor ◽  
Inhibition Performance

The durability of a concrete structure is most significantly influenced by the corrosion of reinforcing bars, rather than by the deterioration of concrete itself. The corrosion of reinforcement bars due to chloride serves as a main deterioration factor at the interface between the bars and the concrete in the concrete structure. Accordingly, the corrosion inhibitors are widely used to improve the resistance to chloride penetration into reinforced concrete. Corrosion inhibitors are generally divided into the anode-type inorganic inhibitors and anode-cathode-type organic inhibitors, in terms of the reaction type. It is known that when the Cl-:OH- concentration ratio exceeds 0.6%, film on passive state metal on the bar-concrete interface is damaged and local corrosion starts regardless of the chloride ion content. In this study, the performance of the corrosion inhibitor was examined using a potentiostat, with chloride ion contents of 1.2kg/m3 (as reference), 2.4kg/m3, and 4.8kg/m3. The variables were the inhibitor type, Cl-:OH- molar ratio according to the addition of anode-type inorganic corrosion inhibitor (four ratios: 0.0%, 0.3%, 0.6% and 1.2%), and ratio compared to the standard anode-cathode-type organic corrosion inhibitor liquid (four ratios: 0.0, norm 1/2, norm, norm 2 times). As a result, with the anode-type inorganic nitrite corrosion inhibitor, the corrosion inhibition performance was verified with a corrosion potential of -0.30V at a molar ratio of 0.3% or higher when the chloride ion content was 1.2kg/m3, and at a molar ratio of 0.6% or higher when the chloride ion content was 2.4kg/m3 or 4.8kg/m3. With the anode-cathode-type organic corrosion inhibitor, the corrosion inhibition performance was very good at half the standard quantity (0.42kg/m3) regardless of the chloride ion content. From the added corrosion inhibitor quantities, the anode-cathode-type organic corrosion inhibitor had a better corrosion inhibition performance than the anode-type inorganic nitrite corrosion inhibitor.

Effect of New Corrosion Inhibitor on Electrochemical Behavior of Prestressed Steel Wire in Simulated Concrete Pore Solution

2014 ◽  
Vol 941-944 ◽  
pp. 1390-1393
Author(s):  
Qi Lei Sun ◽  
Ze Rui Liu ◽  
Yun Zhu Guo ◽  
Feng Liu
Keyword(s):  
Corrosion Inhibitor ◽  
Passive Film ◽  
Corrosion Inhibitors ◽  
Pore Solution ◽  
Steel Wire ◽  
Chloride Ion ◽  
Ammonium Molybdate ◽  
Surface Coat ◽  
Protective Oxide ◽  
Protective Oxide Film

The polarization curve and AC impedance are used to study the impacts of new corrosion inhibitor on the prestressed steel wire electrochemistry action in the simulated concrete pore solution. The result shows that, the ammonium molybdate, DETA, propylene thiourea, 1,4-butynediol and other compound corrosion inhibitors are positive inhibitory corrosion inhibitors, with the components of passivator and healant of protective oxide film, which can contribute to the formation of a passive film of oxide on the rebar surface, repair the defects of rebar surface, coat the entire rebar with a passive film of oxide with good compactness and stability, prevent the chloride ion from penetration, reduce the free rate of iron ions, and thus achieve the anti-corrosion purpose.

A Highly Effective Corrosion Inhibitor by Use of Gemini Imidazoline

SPE Journal ◽  
2016 ◽  
Vol 21 (05) ◽  
pp. 1743-1746 ◽  
Author(s):  
Jiang Yang ◽  
Liyang Gao ◽  
Xuan Liu ◽  
Wenlong Qin ◽  
Chengxian Yin ◽  
...  
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Inhibition ◽  
Corrosion Inhibitors ◽  
Oil And Gas ◽  
Oil And Gas Industry ◽  
Molar Ratio ◽  
Co2 Corrosion ◽  
Highly Effective ◽  
Carbon Dioxide Co2 ◽  
Triethylene Tetramine

Summary Corrosion inhibitors are widely used to control corrosion under the sweet and sour environments in the oil and gas industry. More effective and environmentally friendly corrosion inhibitors need to be developed. This paper studies a new gemini imidazoline (GIM) corrosion inhibitor, in which two hydrocarbon chains and two head groups are linked by a rigid spacer. The GIM was synthesized through the reaction of oleic acid with triethylene tetramine at 2:1 molar ratio. The performance of the GIM on inhibition of carbon dioxide (CO2) corrosion was evaluated by linear polarization resistance in sparged-beaker testing. Rotating-wheel testing was performed to evaluate the film persistency of the test inhibitors. The results showed that corrosion inhibition of the GIM was more effective at lower concentration than that of conventional imidazoline. The mixture of GIM and fatty acid also showed better film persistency than conventional imidazoline. The emulsion tendency of the GIM was less than that of conventional imidazoline. The mechanism of the highly effective GIM was studied. It showed that GIM has much-higher surface activity than conventional imidazoline. The critical micelle concentration (CMC) of GIM is several times lower than that of conventional imidazoline. Hence, the new GIM corrosion inhibitor and its mixture give more-effective corrosion inhibition at low concentration; there is also a lesser environmental effect.

Study on the Anti- Corrosion Properties of Organic and Inorganic Inhibitor by Electrochemical Treatment in Aqueous Solution

2011 ◽  
Vol 415-417 ◽  
pp. 2070-2073 ◽  
Author(s):  
Hwa Sung Ryu ◽  
Han Seung Lee
Keyword(s):  
Corrosion Inhibitor ◽  
Nitrous Acid ◽  
Acid Corrosion ◽  
Chloride Ion ◽  
Electrochemical Treatment ◽  
Molar Ratio ◽  
Ion Content ◽  
Corrosion Properties ◽  
Acid Corrosion Inhibitor ◽  
Organic Corrosion Inhibitor

The various methods for improving chloride penetration resistance in the reinforced concrete have been developed. Among the related general ways, using of corrosion inhibitor became very common. Therefore, in this study, in order to comprehend performance of corrosion inhibitor, the experiment study was conducted about corrosion characteristic of 3 steps(0.0, norm 1/2, norm) compared to organic corrosion inhibitor standard use of liquid and molar 3 steps(0.0, 0.3, 0.6%) of Chloride by added amount of inorganic corrosion inhibitor by the corrosion inhibitor types about 2.4kg/m3, 4.8kg/m3based on Chloride ion content 1.2kg/m3for service life prediction of concrete structure by using Poteniostat. As results, in the case of inorganic nitrous acid corrosion inhibitor, it was confirmed that anti-corrosive performance of Chloride ion content 1.2kg/m3by corrosion Ecorr -0.30V in more than molar ratio 0.3%, and it also was confirmed that anti-corrosive performance of 2.4kg/m3, 4.8kg/m3in more than molar ratio 0.6%. In addition, the excellent anti-corrosive performance of organic corrosion inhibitor was shown in 1/2(0.42kg/m3) of norm regardless of Chloride ion content, and it can be seen that absorption types organic corrosion inhibitor has excellent anti-corrosive performance compared to the inorganic nitrous acid corrosion inhibitor by the added amount of corrosion inhibitor.

A novel additive-free oxides–hydrothermal approach for monazite-type LaPO4nanomaterials with controllable morphologies

2010 ◽  
Vol 43 (5) ◽  
pp. 990-997 ◽  
Author(s):  
Jie Ma ◽  
Qingsheng Wu
Keyword(s):  
Electron Microscopy ◽  
Treatment Time ◽  
Synthesis Temperature ◽  
Molar Ratio ◽  
Hydrothermal Conditions ◽  
Typical Sample ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron ◽  
High Resolution Tem ◽  
Hydrothermal Approach

A facile oxides–hydrothermal (O–HT) method is demonstrated to prepare high-purity monazite-type LaPO4nanomaterials. In this approach, La2O3and P2O5powder are first directly used as precursors under additive-free hydrothermal conditions. The as-prepared samples are characterized with X-ray diffraction, Fourier transform IR spectroscopy, thermogravimetry, scanning electron microscopy, transmission electron microscopy (high-resolution TEM, energy dispersive spectroscopy) and selected-area electron diffraction. The typical sample obtained at 433 K in 24 h comprises uniform single-crystal nanofibres with a diameter of ∼15–28 nm and an aspect ratio of 30–50. The influences of treatment time, synthesis temperature and P/La molar ratio are investigated. The phase transition from hexagonal hydrate to monoclinic anhydrous lanthanum phosphate and the growth process of nanofibres are revealed by the experimental results. The formation mechanism of the monoclinic LaPO4is discussed. The result indicates that the P/La ratio does not influence the composition and crystal phase but changes the morphology of the product in the O–HT system.

scholarly journals Foaming of industrial lean methyldiethanolamine solution in the presence of hydrocarbon and fatty acid based corrosion inhibitors

2018 ◽  
Vol 73 ◽  
pp. 76 ◽  
Author(s):  
Mohammad Keewan ◽  
Fawzi Banat ◽  
Priyabrata Pal ◽  
Jerina Zain ◽  
Emad Alhseinat
Keyword(s):  
Fatty Acid ◽  
Pore Size ◽  
Corrosion Inhibitor ◽  
Flow Rate ◽  
Gas Flow ◽  
Corrosion Inhibitors ◽  
Liquid Volume ◽  
Operating Parameters ◽  
Time Flow ◽  
Foaming Time

In natural gas sweetening alkanolamine processes one of the regularly used chemical is the corrosion inhibitor. For better operation of the plant it is essential to understand the effect of their presence on foaming of industrial lean Methyldiethanolamine (MDEA) used as solvents at different temperatures. This study aimed at investigating the effect of HydroCarbon Based (HCB) and fatty acid based corrosion inhibitor having chemical name Bis(2-Hydroxyethyl)Cocoalkylamine (BHCL) on the foaming tendency of industrial real lean MDEA solutions. Experiments were conducted with different operating parameters, including liquid volume of the solution, foaming time, flow rate of nitrogen gas, concentration of the corrosion inhibitors, temperature of the solution, and gas diffuser pore size using the Foam Scan instrument. With the increase in solution volume and foaming time foaming happens to be more. The foaming tendency of lean MDEA solutions decreased with increasing temperature in absence of corrosion inhibitors but showed different behavior in their presence. At small diffuser pore size and high gas flow rate, the final foam volume increased in the presence of HCB but decreased with the BHCL inhibitor. Optimizing the operating parameters to minimize foaming was verified to be a function of the type of inhibitor used.

scholarly journals Newly Synthesized N-Substituted Thiosemicarbazone as a Potential Corrosion Inhibitor for Mild Steel in 1 M HCl

2019 ◽  
Vol 7 (4.14) ◽  
pp. 168
Author(s):  
N Z. Nor Hashim ◽  
K Kassim ◽  
F H. Zaidon
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Potentiodynamic Polarization ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Langmuir Adsorption ◽  
Before And After ◽  
Ft Ir ◽  
L1 And L2

Two N-substituted thiosemicarbazone derivatives namely as 2-(4-chlorobenzylidene)-N-phenylhydrazinecarbothioamide and 2-benzylidene-N-phenylhydrazinecarbothioamide (L1 and L2, respectively) have been tested as corrosion inhibitors on mild steel in 1 M HCl. The ligands were synthesized and investigated using potentiodynamic polarization (PD) and electrochemical impedance spectroscopy (EIS).  The obtained results indicated that inhibition efficiency, (IE, %) L1 increased with increasing inhibitor concentrations which behaved as a good corrosion inhibitor compared to L2. The synthesized ligands were successfully characterized by melting point, elemental analysis (C, H, N, and S), Fourier-transform infrared spectroscopy (FT-IR) and NMR (1H and 13C) spectroscopy. The excellent inhibition effectiveness for both compounds on mild steel before and after immersion in 1 M HCl solution containing 40 ppm of L1 and L2 were also verified by scanning electron microscope (SEM). Based on potentiodynamic polarization results, it can be concluded that all investigated compounds are mixed-type inhibitors and obey the Langmuir adsorption isotherm. 

Cl−, SO42−, and PO43− distribution in concrete slabs ponded by corrosion-inhibitor-added deicing salts

1998 ◽  
Vol 8 (3-4) ◽  
pp. 101-107 ◽  
Author(s):  
Ji-Won Jang ◽  
Mark G. Hagen ◽  
Glenn M. Engstrom ◽  
Iwao Iwasaki
Keyword(s):  
Corrosion Inhibitor ◽  
Concrete Slabs ◽  
Deicing Salts

Study on fine lines and undercut suppression of printed circuit board prepared by electrolytic etching

Circuit World ◽  
2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Denglin Fu ◽  
Yanan Wen ◽  
Jida Chen ◽  
Lansi Lu ◽  
Ting Yan ◽  
...  
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Inhibitors ◽  
Printed Circuit Board ◽  
Copper Surface ◽  
Etching Process ◽  
Circuit Board ◽  
Content Type ◽  
Printed Circuit ◽  
Etching Method ◽  
Electrolytic Etching

Purpose The purpose of this paper is to study an electrolytic etching method to prepare fine lines on printed circuit board (PCB). And the influence of organics on the side corrosion protection of PCB fine lines during electrolytic etching is studied in detail. Design/methodology/approach In this paper, the etching factor of PCB fine lines produced by new method and the traditional method was analyzed by the metallographic microscope. In addition, field emission scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used to study the inhibition of undercut of the four organometallic corrosion inhibitors with 2,5-dimercapto-1,3,4-thiadiazole, benzotriazole, l-phenylalanine and l-tryptophan in the electrolytic etching process. Findings The SEM results show that corrosion inhibitors can greatly inhibit undercut of PCB fine lines during electrolytic etching process. XPS results indicate that N and S atoms on corrosion inhibitors can form covalent bonds with copper during electrolytic etching process, which can be adsorbed on sidewall of PCB fine lines to form a dense protective film, thereby inhibiting undercut of PCB fine lines. Quantum chemical calculations show that four corrosion inhibitor molecules tend to be parallel to copper surface and adsorb on copper surface in an optimal form. COMSOL Multiphysics simulation revealed that there is a significant difference in the amount of corrosion inhibitor adsorbed on sidewall of the fine line and the etching area. Originality/value As a clean production technology, electrolytic etching method has a good development indicator for the production of high-quality fine lines in PCB industry in the future. And it is of great significance in saving resources and reducing environmental pollution.

Inhibiting Calcium Chloride Heavy Brines to be Used as Drilling Fluids: Hurdles Encountered in Treatment, Application, Corrosion Mitigation, Solubility, and Foaming Tendencies for Drilling Sites in Canada

2021 ◽  
Author(s):  
Thenuka M. Ariyaratna ◽  
Nihal U. Obeyesekere ◽  
Tharindu S. Jayaneththi ◽  
Jonathan J. Wylde
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Inhibitors ◽  
Drilling Fluid ◽  
Solvent System ◽  
Test Fluid ◽  
Drilling Fluids ◽  
Drilling Process ◽  
Drill Cuttings ◽  
Well Completion ◽  
Completion Fluids

Abstract A need for more economic drilling fluids has been addressed by repurposing heavy brines typically used as completion fluids. Heavy brine corrosion inhibitors have been designed for stagnant systems. Drilling fluids are subjected to both heavy agitation and aeration through recirculation systems and atmospheric exposure during the various stages of the drilling process. This paper documents the development of heavy brine corrosion inhibitors to meet these additional drilling fluid requirements. Multiple system scenarios were presented requiring a methodical evaluation of corrosion inhibitor specifications while still maintaining performance. Due to the high density of heavy brine, traditional methods of controlling foaming were not feasible or effective. Additional product characteristics had to be modified to allow for the open mud pits where employees would be working, higher temperatures, contamination from drill cuttings, and product efficacy reduction due to absorption from solids. The product should not have any odor, should have a high flash point, and mitigate corrosion in the presence of drill cuttings, oxygen, and sour gases. Significant laboratory development and testing were done in order to develop corrosion inhibitors for use in heavy brines based on system conditions associated with completion fluids. The application of heavy brine as a drilling fluid posed new challenges involving foam control, solubility, product stability, odor control, and efficacy when mixed with drill cuttings. The key to heavy brine corrosion inhibitor efficacy is solubility in a supersaturated system. The solvent packages developed to be utilized in such environments were highly sensitive and optimized for stagnant and sealed systems. Laboratory testing was conducted utilizing rotating cylinder electrode tests with drill cuttings added to the test fluid. Product components that were found to have strong odors or low flash points were removed or replaced. Extensive foaming evaluations of multiple components helped identify problematic chemistries. Standard defoamers failed to control foaming but the combination of a unique solvent system helped to minimize foaming. The evaluations were able to minimize foaming and yield a low odor product that was suitable for open mud pits and high temperatures without compromising product efficacy. The methodology developed to transition heavy brine corrosion inhibitors from well completion applications to drilling fluid applications proved to be more complex than initially considered. This paper documents the philosophy of this transitioning and the hurdles that were overcome to ensure the final product met the unique system guidelines. The novel use of heavy brines as drilling fluids has created a need for novel chemistries to inhibit corrosion in a new application.

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