scholarly journals Hydrazine-nitrate combustion synthesis of BaCeO3 preceramic powders: structure, morphology and thermophysical properties

2021 ◽  
Author(s):  
Maksim Tenevich ◽  
Andrey Pavlovich Shevchik ◽  
Vadim Igorevich Popkov
Keyword(s):  
Thermophysical Properties ◽  
Simultaneous Thermal Analysis ◽  
Combustion Method ◽  
Sintered Sample ◽  
Combustion Products ◽  
Laser Flash ◽  
Barium Cerate ◽  
Hydrazine Nitrate ◽  
Average Size ◽  
The Impact

Abstract In the present work, preceramic nanocrystallite barium cerate (BaCeO3) was successfully synthesized using the hydrazine-nitrate combustion method. Using carbon-free hydrazine (N2H4) as fuel significantly reduced the formation of carbon by-products. Characterization of the as-received powders was performed by XRD, energy-dispersive X-ray spectroscopy (EDXS), scanning electron microscopy (SEM), simultaneous thermal analysis (DTA-TGA) and adsorption-structural analysis (N2, 77 K). Thermophysical properties of the sample annealed at 1000 °С were investigated using laser flash analysis (LFA) in the temperature interval of 1000 °С. As a result of a comprehensive study, the sequence of chemical and phase transformations that lead to the formation of BaCeO3 with a rhombic structure (Pnma, a = 6.2145 Å, b = 8.7776 Å, c = 6.2337 Å) during the thermal processing of combustion products was investigated. It was established that the average size of the obtained nanocrystals is 38 ± 3 nm and that they form micron-sized agglomerates with a specific surface area of the powder of 4.8 m2/g. It was shown that the sintered sample of BaCeO3 is characterized by thermal diffusivity values of 0.28 to 0.20 mm2/s and thermal conductivity values of 0.41 to 0.35 W/mK, depending on temperature. These results, given the impact of porosity on the sample (~ 40%), show very good agreement with the thermophysical characteristics of densely sintered ceramics based on BaCeO3 – a solid oxide electrolyte SOFC. Consequently, the proposed method of hydrazine-nitrate synthesis of BaCeO3 presents itself as a promising approach to obtaining preceramic powders and ceramics in the area of SOFC.

scholarly journals Microwave-Assisted Combustion Synthesis of ZnO Nanoparticles

2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
M. Kooti ◽  
A. Naghdi Sedeh
Keyword(s):  
Electron Microscopy ◽  
Zno Nanoparticles ◽  
Combustion Method ◽  
Zinc Nitrate ◽  
High Yield ◽  
Fast Method ◽  
Simple Method ◽  
X Ray ◽  
Microwave Assisted ◽  
Average Size

A new and simple method was applied for the synthesis of ZnO nanoparticles with an average size of 20 nm. In this microwave-assisted combustion method, glycine as a fuel and zinc nitrate as precursor were used. The final product was obtained very fast with high yield and purity. The synthesized nanoscale ZnO was characterized by X-ray Diffraction (XRD), Energy Dispersive X-ray spectroscopy (EDX), and Fourier transform infrared spectroscopy (FT-IR). The size and morphology of the ZnO nanoparticles have been determined by field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) techniques. This is a simple and fast method for the preparation of ZnO nanoparticles with no need for expensive materials or complicated treatments.

scholarly journals POROSITY PARAMETERS OF CEMENT STONE CONTAINING CHEMICAL ADMIXTURES OF DIFFERENT PURPOSE / CEMENTINIO AKMENS SU SKIRTINGOS PASKIRTIES CHEMINIAIS PRIEDAIS PORINGUMO RODIKLIAI

2013 ◽  
Vol 5 (5) ◽  
pp. 530-535
Author(s):  
Lukas Venčkauskas ◽  
Mindaugas Daukšys
Keyword(s):  
Cement Paste ◽  
Cement Stone ◽  
Hardened Cement ◽  
Closed Porosity ◽  
Hardened Cement Paste ◽  
Chemical Admixtures ◽  
Average Size ◽  
The Impact ◽  
Plasticizing Admixture

The conducted research has established a complex influenceand the impact of separate chemical admixtures of differentpurpose on the parameters of the porosity of hardened cementpaste such as open and closed porosity, the average size of poresand the rates of pore inequality. According to the parametersof the porosity of hardened cement paste, on the basis of A. E.Sheikin’s methodology, the number of freezing-thawing cycleswas predicted. This research used plasticizing, viscosity modifyingand antifoaming admixtures. It has been found that, when theamount of plasticizing admixture in cement paste (W/C–0.45) isconstant and makes 1.1% of the cement mass, and the amountof viscosity modifying and antifoaming the admixture increasesfrom 0.1 to 0.6% and from 0.05 to 0.3% respectively, the openporosity of hardened cement paste varies between 30.21% and31.06%, while closed porosity varies between 5.39% and 6.22%.When the amount of the plasticizing admixture in cement paste(W/C–0.45) exceeds 1.1% of the cement mass, the open porosityof hardened cement paste increases by 1.4 times and closedporosity decreases by 2.5 times. While adding 0.1% of the viscositymodifying admixture to cement paste, the open porosityof hardened cement paste is increased by 1.5 times and closedporosity decreases by 2.4 times. The amount of 0.05% of thecement mass of the antifoaming admixture results in the increasedopen porosity of hardened cement paste by 1.5 times and reducedclosed porosity by 3.5 times. Santrauka Tyrimo metu nustatyta kompleksinė bei atskirų skirtingos paskirties cheminių priedų įtaka cementinio akmens poringumo rodikliams – atvirajam ir uždarajam poringumui, vidutinio porų dydžio ir porų vienodumo rodikliams. Tyrimuose naudoti cheminiai priedai: plastifikuojantis, klampą modifikuojantis ir mišinyje susiformavusias oro poras suardantis priedas. Nustatyta, kad cemento tešloje (V/C – 0,45) esant pastoviam plastifikuojančio priedo kiekiui – 1,0 % cemento masės, klampą modifikuojančio priedo kiekiui kintant nuo 0,1 iki 0,6 %, o mišinyje susiformavusias oro poras suardančio priedo kiekiui kintant nuo 0,05 iki 0,3 %, cementinio akmens atvirasis poringumas svyruoja nuo 30,21 iki 31,06 %, o uždarasis – nuo 5,39 iki 6,22 %. Cemento tešloje viršijus plastifikuojančio priedo 1,1 % cemento masės, cementinio akmens atvirasis poringumas padidėja apie 1,4 karto, o uždarasis poringumas sumažėja apie 2,5 karto. Pridėjus į tešlą 0,1 % cemento masės klampą modifikuojančio priedo, cementinio akmens atvirasis poringumas padidėja apie 1,5 karto, uždarasis poringumas sumažėja apie 2,4 karto. Oro poras suardančio priedo kiekis 0,05 % cemento masės cementinio akmens atvirąjį poringumą padidina apie 1,5 karto, uždarąjį poringumą sumažina apie 3,5 karto.

A Convenient Method for Preparing Well-Dispersed Er2Zr2O7 Nanocrystals

2010 ◽  
Vol 123-125 ◽  
pp. 611-614 ◽  
Author(s):  
Yu Ping Tong ◽  
Rui Zhu Zhang ◽  
Shun Bo Zhao ◽  
Chang Yong Li
Keyword(s):  
Particle Size ◽  
Combustion Synthesis ◽  
Crystal Size ◽  
Lattice Distortion ◽  
Combustion Method ◽  
Treatment Temperature ◽  
Synthesis Process ◽  
Thermal Treatment Temperature ◽  
Average Size ◽  
Xrd And Tem

Well-dispersed fluorite Er2Zr2O7 nanocrystals have been successfully prepared by a convenient salt-assistant combustion method. The effects of calcinations temperature and salt category on the characteristics of the products were investigated by XRD and TEM. The thermal treatment temperature has an important effect on crystal size and lattice distortion of the nanocrystals. The experiment showed that the introduction of salt in the combustion synthesis process resulted in the formation of well-dispersed Er2Zr2O7 nanocrystals. The average size was 30 nm and was in agreement with the XRD result, which indicated that the nanocrystals were uniform in particle size distribution. Moreover, the possible formation process in the salt-assisted combustion synthesis was also analyzed.

scholarly journals Australian agricultural scale and corporate agroholdings: environmental and climatic impacts

2017 ◽  
Vol 20 (2) ◽  
pp. 187-190 ◽  
Author(s):  
Bradley Plunkett ◽  
Andrew Duff ◽  
Ross Kingwell ◽  
David Feldman
Keyword(s):  
Large Scale ◽  
Climatic Variability ◽  
Institutional Setting ◽  
Corporate Ownership ◽  
Family Structures ◽  
Climatic Impacts ◽  
The Stability ◽  
Average Size ◽  
The Impact ◽  
Concentrate Production

The average size of Australian farms in scale and revenue are the globe’s largest. This scale is a result, in part, of low average rural population densities; development patterns in broadacre production; low levels of effective public policy transfers; a stable and suitable institutional setting suitable for corporate and other large scale investment; and low yields. It is also a factor of the natural variability of the country’s climatic systems which have contributed to the scale of extensive northern cattle production; this variability has implications for the pattern of ownership of broadacre and extensive production. Corporate ownership, tends to concentrate production aggregations at sufficient scale to offset its additional overheads in areas of relative climatic stability and to replicate these agroholding aggregations spatially to protect the stability of revenue flows. Family structures are more dominant in areas of greater climatic variability. Of interest is the impact that any increasing climatic variability (versus rapid changes in technology) may have upon this pattern.

scholarly journals Applications of nanotechnology with hybrid Photovoltaic/Thermal systems

2020 ◽  
pp. 1-15
Author(s):  
Mohammed Alktranee
Keyword(s):  
Thermophysical Properties ◽  
Base Fluid ◽  
Volume Fraction ◽  
Working Fluid ◽  
Spectral Filter ◽  
Thermal Systems ◽  
Cooling Fluid ◽  
Numerical Studies ◽  
The Impact ◽  
T System

This paper appears potential of use nanofluids as a working fluid with the photovoltaic/thermal (PV/T) systems as an alternative of the conventional liquids in improves the efficiency of the hybrid PV/T system. The review highlights the impact of some parameters (base fluid, volume fraction, the concentration of nanoparticles, surfactants, shape, and size of nanoparticles) on nanofluids' thermophysical properties and their effect on the PV/T system's efficiencies. Hence, it discusses the PV/T behavior, which uses different nanofluids based on previous experimental, analytical, and numerical studies. The review concluded that using nanofluid as a cooling fluid or spectral filter contributes by enhancing the performance and increasing the PV/T system's efficiency. Thus, each type of nanofluids has certain features that contribute to removing the PV cells' excess heat by cooling it, contributing to its work's stability, and increasing its productivity. Nanofluids thermophysical properties play an intrinsic role by enhancing nanofluids' performance, thus positively reflecting on the PV/T system's performance. Despite the variation in the values of thermal and electrical efficiency, Most of the studies that used nanofluids have achieved encouraging results that appeared by improving the performance of PV/T systems.

scholarly journals METHOD OF CONTROLLING PRESENCE OF FOREIGN SUBSTANCES AND OBJECTS IN THE BORE OF THE BARREL USING MONOCHROME LIGHT

2021 ◽  
pp. 53-57
Author(s):  
V. Kozachuk ◽  
M. Sliusarenko
Keyword(s):  
Combustion Products ◽  
The Other ◽  
Light Sources ◽  
Current Value ◽  
Precision And Accuracy ◽  
Shell Particles ◽  
The Military ◽  
Parameter Values ◽  
The Impact ◽  
Powder Combustion

In the article, the authors propose a method for controlling the presence of foreign substances and objects inside the barrel. The problem of surface cleanliness control remains relevant in many areas, ranging from sanitary cleaning to nanoelectronics. In the military sphere, this becomes particularly important during the cleaning of cannon barrels. Both powder combustion products and cartridge cap and bullet shell particles are deposited in the barrel during firing from guns. Under the impact of high temperatures, the bullet particles are partially oxidized and cover the barrel channel with a thin layer of deposit of oxides, which are difficult to dissolve. As a result, the density of the bullet abuting the walls changes. This affects the characteristics of its motion inside the barrel. The accuracy of the shot is reduced, and subsequently the precision and accuracy of shooting in general decreases. The essence of the proposed method consists in the fact that a light source is placed in the bore of the barrel on one side, and an optical device is placed on the other side, with the help of which the presence of foreign substances and objects is monitored. Unlike the known methods, this method is characterized in that several monochrome light sources in addition are placed in turn in the bore of the barrel from the breech part, and in the bore of the barrel from the muzzle part there is equipment for receiving (detecting) monochrome light. Then, obtained monochrome light is analyzed, current value of its defined parameters is determined. At the next stage, parameter values of monochrome light fixed during control are compared with parameter values of reference signatures, which had been obtained before the barrel was put in service. These values are stored in equipment memory. If the values of at least one of the parameters from at least one of the monochrome light sources are found to be inconsistent with the parameters of the reference signatures, the equipment for receiving and analyzing monochrome light gives a signal about the presence of foreign substances and objects in the bore of the barrel.

scholarly journals Analysis of environmental impacts of combustion products of some pyrotechnic compositions

2019 ◽  
pp. 123-132
Author(s):  
Bożena Kukfisz ◽  
Jakub Rakus ◽  
Robert Piec
Keyword(s):  
Life Cycle ◽  
Combustion Products ◽  
Rocket Engines ◽  
Product Categories ◽  
Gas Products ◽  
Potential Impact ◽  
Pyrotechnic Mixtures ◽  
Quality Of Products ◽  
The Impact

The study examined mixtures obtained from ready pyrotechnic articles available on the market in Poland. Samples were taken from various products with different performance characteristics, i.e. pyrotechnic batteries, firecrackers, volcanoes, as well as smoke candles, rockets (including rocket engines), and cold fires. These are the product categories most frequently used by users. The research allowed to determine gaseous combustion products and showed their life cycle in the environment. A comparative analysis of selected pyrotechnic mixtures was carried out in terms of their impact on the climate change of gas products. Using the ICT-Thermodynamic Code program, gaseous combustion products were estimated and the life cycle was analysed using the SimaPro program. Determining the impact on the environment (upon the basis of Ecoindicator 99) allowed to know the scale of the problem and set the direction of development of the pyrotechnic industry, so that importers could compete not only with the price and quality of products offered, but also tried to reduce the potential impact on the environment.

Materials for Safety and Security

2020 ◽  
pp. 288-320
Author(s):  
Jozef Martinka ◽  
Janka Dibdiakova
Keyword(s):  
Hydrogen Cyanide ◽  
Ignition Temperature ◽  
Fire Risk ◽  
Combustion Products ◽  
Security Engineering ◽  
Insulating Materials ◽  
Properties Of Materials ◽  
Materials Used ◽  
Carbon Monoxide Yield ◽  
The Impact

This chapter deals with materials used in safety and security engineering. The most commonly used materials in this field include shielding materials, materials for protective suits, electrically insulating materials and materials for fire protection. The first part of the chapter describes the properties of materials used in the above applications. The second part of the chapter focuses on characteristics of materials that accurately describe their fire risk. The fire risk of a material is quantified by its resistance to ignition (determined generally by critical heat flux and ignition temperature) and by the impact of the fire on the environment. The impact of fire is usually determined by the heat release rate, toxicity of combustion products (primarily determined by carbon monoxide yield and for materials that contain nitrogen, also through the hydrogen cyanide yield) and the decrease of visibility in the area (depending on the geometry of the area and the smoke production rate).

scholarly journals Scientific experiment focused at pigment degradation by polyvinyl chloride combustion in Science education

2019 ◽  
Vol 9 (3) ◽  
pp. 458
Author(s):  
Zita Jenisová ◽  
Jana Braniša
Keyword(s):  
Environmental Education ◽  
Cross Section ◽  
Chemistry Education ◽  
Combustion Products ◽  
Teaching Profession ◽  
Chemistry Teaching ◽  
Scientific Experiment ◽  
Science Classes ◽  
The Impact

The Environmental education navigates students towards environmentally friendly life style and securing a quality of life. The implementation of cross-section topics, including the Environmental education, into science classes, is possible through a variety of techniques. One of the least used methods is a real school experiment. The following paper presents the experiment, by which we simulate the combustion of PVC and observe the impact of combustion products on plants via UV-Vis spectrophotometry optical method. This method is suitable for qualification and analysis of vegetable pigments, i.e. chlorophylls, carotenoids, and anthocyanins. The experiment is integrated into the Techniques and Didactics of School Chemistry Experiments as a part of master degree course, which prepares students for the Chemistry teaching profession. The introduced experiment enables pedagogues to integrate the environmental education into teaching process and develop mathematical and science literacy of students in the Chemistry education.

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