Pickering Emulsion Stabilized By Hydrophobically Modified Spherical Cellulose Nanocrystals With Special Response To pH

2021 ◽  
Author(s):  
Hui Dong ◽  
Yifei Jiang ◽  
Xia Li ◽  
Wenjia Han ◽  
Qijun Ding ◽  
...  
Keyword(s):  
Cellulose Nanocrystals ◽  
High Strength ◽  
Rheological Characteristic ◽  
Low Viscosity ◽  
Hydrophobically Modified ◽  
Oil In Water ◽  
Mean Diameter ◽  
Octenyl Succinic Anhydride ◽  
The Fourier Transform ◽  
Emulsifying Ability

Abstract The aims of this study were to study the performance changes of S-CNCs (spherical cellulose nanocrystals) modified by OSA (octenyl succinic anhydride) stabilized Pickering oil-in-water (O/W) emulsions. The Fourier transform infrared (FTIR) spectroscopy and contact angle change of the MS-CNCs (modified spherical cellulose nanocrystals) prove the successful modification of OSA and the improvement of hydrophobicity. The effect of a series of MS-CNCs concentration on the volume mean diameter, emulsion ratio, stability and micro-rheological characteristic viscosity of the emulsion was studied. The results show that the emulsifying ability of the S-CNCs have been greatly improved. In addition, at a concentration of 10g/l, the volume mean diameter reaches the nanometer level (0.95 µm), and the emulsion ratio reaches 100%, while still maintaining its unique ultra-low viscosity characteristics. Furthermore, the emulsion still exhibits high-strength resistance to ionic strength, but exhibits unique responsiveness to pH (pH≤5) at special stages.

scholarly journals Influence of sodium dodecyl sulphate concentration on disperse and rheological characteristics of oil-in-water emulsions stabilized by OSA starch-SDS mixtures

2012 ◽  
Vol 77 (1) ◽  
pp. 83-94 ◽  
Author(s):  
Veljko Krstonosic ◽  
Ljubica Dokic ◽  
Ivana Nikolic ◽  
Tamara Dapcevic ◽  
Miroslav Hadnadjev
Keyword(s):  
Sodium Dodecyl Sulphate ◽  
Sodium Dodecyl ◽  
Rheological Characteristics ◽  
Sauter Mean Diameter ◽  
Oil In Water ◽  
Osa Starch ◽  
Mean Diameter ◽  
Octenyl Succinic Anhydride ◽  
Stability Of Emulsion

Stability of oil-in-water emulsions can be achieved by chemical modified starch, such as octenyl succinic anhydride (OSA) starch, as emulsifier. In order to analyse disperse and rheological characteristics of emulsions containing two kind of emulsifiers, part of the OSA starch can be substituted with adequate concentration of sodium dodecyl sulphate (SDS), which is small surfactant with same charge as OSA starch. Oil contents of examined emulsions were 5, 20 and 50%. Selected OSA starch concentration was 10% and replacements of the part of OSA starch were realized with SDS concentrations of 1, 3 and 5%. Dispersed droplets of emulsions were defined by determination of Sauter mean diameter d32 and particle size distribution. Flow curves were used to describe rheological properties of the emulsions. Also, stability of emulsion samples was observed and expressed by the creaming index. Obtained results indicated decrease in Sauter mean diameter of droplets, standard deviation and apparent viscosity of emulsions while amounts of SDS increase within emulsifiers mixture OSA starch-SDS. The emulsions with OSA starch according to creaming rate were more stable than emulsions stabilized by OSA starch and SDS combination.

scholarly journals Emulsion Formation and Stabilizing Properties of Olive Oil Cake Crude Extracts

Processes ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 633
Author(s):  
Firdaous Fainassi ◽  
Noamane Taarji ◽  
Fatiha Benkhalti ◽  
Abdellatif Hafidi ◽  
Marcos A. Neves ◽  
...  
Keyword(s):  
Olive Oil ◽  
Ethanol Extract ◽  
Active Components ◽  
Oil In Water ◽  
Surface Active ◽  
Ph Conditions ◽  
Oil Water ◽  
Surface Active Compounds ◽  
Ionizable Groups ◽  
Emulsifying Ability

The surface-active and emulsifying properties of crude aqueous ethanolic extracts from untreated olive oil cake (OOC) were investigated. OOC extracts contained important concentrations of surface-active components including proteins, saponins and polyphenols (1.2–2.8%, 7.8–9.5% and 0.7–4.5% (w/w), respectively) and reduced the interfacial tension by up to 46% (14.0 ± 0.2 mN m−1) at the oil–water interface. The emulsifying ability of OOC extracts was not correlated, however, with their interfacial activity or surface-active composition. Eighty percent aqueous ethanol extract produced the most stable oil-in-water (O/W) emulsions by high-pressure homogenization. The emulsions had average volume mean droplet diameters of approximately 0.4 µm and negative ζ-potentials of about -45 mV, and were stable for up to 1 month of storage at 5, 25 and 50 °C. They were sensitive, however, to acidic pH conditions (<5) and NaCl addition (≥25 mM), indicating that the main stabilization mechanism is electrostatic due to the presence of surface-active compounds with ionizable groups, such as saponins.

scholarly journals Synthesis, Characterization, and Visible Light Curing Capacity of Polycaprolactone Acrylate

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Jy-Jiunn Tzeng ◽  
Yi-Ting Hsiao ◽  
Yun-Ching Wu ◽  
Hsuan Chen ◽  
Shyh-Yuan Lee ◽  
...  
Keyword(s):  
Tissue Engineering ◽  
3D Printing ◽  
Visible Light ◽  
Room Temperature ◽  
Low Viscosity ◽  
Nuclear Magnetic Resonance Spectra ◽  
Light Curing ◽  
Soft Tissue Engineering ◽  
The Fourier Transform ◽  
Visible Light Curing

Polycaprolactone (PCL) is drawing increasing attention in the field of medical 3D printing and tissue engineering because of its biodegradability. This study developed polycaprolactone prepolymers that can be cured using visible light. Three PCL acrylates were synthesized: polycaprolactone-530 diacrylate (PCL530DA), glycerol-3 caprolactone triacrylate (Glycerol-3CL-TA), and glycerol-6 caprolactone triacrylate (Glycerol-6CL-TA). PCL530DA has two acrylates, whereas Glycerol-3CL-TA and Glycerol-6CL-TA have three acrylates. The Fourier transform infrared and nuclear magnetic resonance spectra suggested successful synthesis of all PCL acrylates. All are liquid at room temperature and can be photopolymerized into a transparent solid after exposure to 470 nm blue LED light using 1% camphorquinone as photoinitiator and 2% dimethylaminoethyl methacrylate as coinitiator. The degree of conversion for all PCL acrylates can reach more than 80% after 1 min of curing. The compressive modulus of PCL530DA, Glycerol-3CL-TA, and Glycerol-6CL-TA is 65.7±12.7, 80.9±6.1, and 32.1±4.1 MPa, respectively, and their compressive strength is 5.3±0.29, 8.3±0.18, and 3.0±0.53 MPa, respectively. Thus, all PCL acrylates synthesized in this study can be photopolymerized and because of their solid structure and low viscosity, they are applicable to soft tissue engineering and medical 3D printing.

Oil-in-water emulsions stabilized by hydrophobically modified hydroxyethyl cellulose: Adsorption and thickening effect

2007 ◽  
Vol 311 (1) ◽  
pp. 228-236 ◽  
Author(s):  
Wenbin Sun ◽  
Dejun Sun ◽  
Yunping Wei ◽  
Shangyin Liu ◽  
Shuiyan Zhang
Keyword(s):  
Hydroxyethyl Cellulose ◽  
Hydrophobically Modified ◽  
Oil In Water

scholarly journals Protein-Stabilized Palm-Oil-in-Water Emulsification Using Microchannel Array Devices under Controlled Temperature

Molecules ◽  
2020 ◽  
Vol 25 (20) ◽  
pp. 4805
Author(s):  
Takashi Kuroiwa ◽  
Miki Ito ◽  
Yaeko Okuyama ◽  
Kanna Yamashita ◽  
Akihiko Kanazawa
Keyword(s):  
Palm Oil ◽  
Sodium Caseinate ◽  
Droplet Generation ◽  
Basic Material ◽  
Operation Conditions ◽  
Microchannel Array ◽  
Oil In Water ◽  
Mean Diameter ◽  
Different Types ◽  
Semi Solid

Microchannel (MC) emulsification for the preparation of monodisperse oil-in-water (O/W) and water-in-oil-in-water (W/O/W) emulsions containing palm oil as the oil phase was investigated for application as basic material solid/semi-solid lipid microspheres for delivery carriers of nutrients and drugs. Emulsification was characterized by direct observation of droplet generation under various operation conditions, as such, the effects of type and concentration of emulsifiers, emulsification temperature, MC structure, and flow rate of to-be-dispersed phase on droplet generation via MC were investigated. Sodium caseinate (SC) was confirmed as the most suitable emulsifier among the examined emulsifiers, and monodisperse O/W and W/O/W emulsions stabilized by it were successfully obtained with 20 to 40 µm mean diameter (dm) using different types of MCs.

scholarly journals Preparation and Characterization of Water-Based Nano-Perfumes

Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 981 ◽  
Author(s):  
Małgorzata Miastkowska ◽  
Elwira Lasoń ◽  
Elżbieta Sikora ◽  
Katarzyna Wolińska-Kennard
Keyword(s):  
Droplet Size ◽  
Interfacial Area ◽  
High Energy ◽  
Protective Role ◽  
Food Industries ◽  
Low Viscosity ◽  
Oil In Water ◽  
Water Based

The application of nanoemulsions as a novel delivery system for lipophilic materials, such as essential oils, flavors, and fragrances is one of the growing technologies used in cosmetic, pharmaceutical, and food industries. Their characteristic properties, like small droplet size with high interfacial area, transparent or semi-transparent appearance, low viscosity, and high kinetic stability, make them a perfect vehicle for fragrances, in the perfume industry. They could be a great alternative to water-based perfumes, without alcohol, and solve problems related to the oxidation and low bioavailability of fragrances with other non-alcoholic vehicles of perfumes like pomades or gels. The aim of our study was to develop stable Oil-in-Water (O/W) nanoemulsions that are compatible with selected fragrance compositions, without ethanol, polyols, and ionic surfactants, and to study their physicochemical, microbiological, and dermatological properties. The nano-perfume systems were obtained with a low-energy (Phase Inversion Composition; PIC) and with a high-energy (ultrasound, US) method, taking into account the possibility of moving from the laboratory scale to an industrial scale. The optimized nano-perfume formulations, prepared with different methods, yielded the same physicochemical properties (stability, medium droplet size of the inner phase, polydispersity, viscosity, surface tension, pH, density). Stable systems were obtained with a fragrance composition concentration within 6–15% range. These formulations had a low viscosity and a pH suitable for the skin. Moreover, the obtained results confirmed the protective role of nanoemulsions. The peroxide number measurement (POV) showed that the tested fragrance compositions had a high chemical stability. The results of the microbiological tests confirmed that the obtained products were free of microbiological contamination and were appropriately preserved. The dermatological test results confirmed the safety of the developed preparations.

Characterization of Curaua Fibers by Infrared Spectroscopy

2014 ◽  
Vol 775-776 ◽  
pp. 325-329 ◽  
Author(s):  
Sergio Neves Monteiro ◽  
Frederico Muylaert Margem ◽  
Noan Tonini Simonassi ◽  
Rômulo Leite Loiola ◽  
Michel Picanço Oliveira
Keyword(s):  
Infrared Spectroscopy ◽  
Natural Fibers ◽  
High Strength ◽  
Relevant Information ◽  
Lignocellulosic Fibers ◽  
The Fourier Transform ◽  
Curaua Fibers ◽  
Physical And Chemical ◽  
Curauá Fiber

Natural fibers obtained from plants are being investigated as possible engineering materials with application in polymer composite reinforcement. For instance, the lignocellulosic fibers extracted from the leaves of the curaua plant (Ananas erectifolius) display a reinforcement potential owing to their relatively high strength. However, the curaua fiber has a poor adhesion with the polymeric matrix. In order to understand the curaua fiber interaction with a polymer matrix, the physical and chemical characteristics need to be evaluated. Among these characteristics, the Fourier transform infrared spectroscopy (FTIR) provides relevant information about the functional molecular groups and their possible interaction. Therefore, the objective of the present work was to analyze the FTIR of curaua fibers by means of transmittance spectrum obtained in the FTIR method with a 60o angle. The results showed peaks corresponding to specific molecular interaction that are discussed and compared to other results.

scholarly journals Improving the Physical and Oxidative Stability of Emulsions Using Mixed Emulsifiers: Casein-Octenyl Succinic Anhydride Modified Starch Combinations

Nanomaterials ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 1018 ◽  
Author(s):  
Yang ◽  
Qin ◽  
Kan ◽  
Liu ◽  
Zhong
Keyword(s):  
Oxidative Stability ◽  
Food Industry ◽  
Succinic Anhydride ◽  
Droplet Growth ◽  
Modified Starch ◽  
Hydrogen Bonding Interaction ◽  
Bonding Interaction ◽  
Oil In Water ◽  
Octenyl Succinic Anhydride ◽  
Droplet Aggregation

This study aims to investigate the influence of casein and octenyl succinic anhydride modified starch (OSAS) combinations on the physical and oxidative stability of fish oil-in-water emulsions. The interaction between casein and OSAS was manifested in changes in protein structure and hydrogen-bonding interaction. Casein–OSAS combinations could effectively inhibit droplet aggregation at pH 4 and attenuate droplet growth at a high CaCl2 concentration of 0.2 mol/L, compared with casein as an emulsifier. Nanoemulsions stabilized by casein–OSAS combinations or casein showed better oxidative stability compared with OSAS-stabilized emulsions. Therefore, casein–OSAS combinations can improve some physical properties of protein-based emulsions and oxidative stability of modified starch-based emulsions, suggesting protein-modified starch combinations are more promising in the emulsion-based food industry compared to each of the two emulsifiers alone.

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