scholarly journals Transformation of oil dispersed systems during operation

Author(s):  
V. D. Cherepanov ◽  
S. G. D’yachkova ◽  
I. I. Kuzora ◽  
D. A. Dubrovskii ◽  
V. I. Lukina

Abstract: Using the example of oil road bitumen grades BND 100/130, BND 130/200 and BND 70/100, this article studies the transformation of oil dispersed systems under various logistic schemes of operation. This research focuses on the influence of the conditions for storing road bitumens of different grades on their physical and mechanical properties and group hydrocarbon composition during transportation from the manufacturer to the consumer. The results show that a change in the physical and mechanical properties of road bitumens during high-temperature storage is related to the changes in the group hydrocarbon composition due to the hydrocarbons autooxidation and destabilization of the colloidal structure of dispersal systems. The conditions for storing bitumen with a minimum change in its quality indicators have been determined. It has been established that storage of bitumen under atmospheric conditions allows preserving its original properties without significant changes. There is evidence that nitrogen purging significantly reduces the effect of homolytic processes leading to the transformation of oil dispersed systems during further transportation from the manufacturer to the consumer. Experimental data confirm that of all basic physical and mechanical properties of bitumen, “the depth of penetration of needle” is the most sensitive index, while the “softening temperature” index, frequently used for quality control of bitumen, is inertial. Determining the change in penetration, depending on the duration of storing bitumen, has required formulating a special equation. It has been established that when storing road bitumen at a temperature of 180 ºС, for each hour the index of the penetration depth of the needle at 25 º decreases by 0.8 units. Organizational and technical measures have been determined to ensure the stability of the road bitumen quality during manufacture, storage and transportation to consumers.

2021 ◽  
Vol 2124 (1) ◽  
pp. 012019
Author(s):  
A O Belyaev ◽  
V E Danilov ◽  
M V Morozova

Abstract The percentage of wooden buildings damaged or even lost due to the lack or insufficient technical measures for their preservation is growing every year. This fact makes it mandatory to treat the surface of wood building materials with protective and decorative agents. Within the framework of this study, a multifunctional protective composition for wood was developed that can increase its physical and mechanical properties. Modification of the wood surface with organomineral compositions leads to an increase in its density, hardness and strength. The hardness of the treated wood is 24% higher and the compressive strength along the fiber is 20% higher than that of untreated wood. After treatment, the surface of the wood darkened and slightly yellowed, which does not prevent its use in the construction and reconstruction of buildings. The results of measuring the color coordinates of the surface of the modified samples indicate the stability and durability of the developed protective coating even after 4 months of exposure to atmospheric conditions. Judging by the slight return of the color coordinates of the treated wood back to values of the original wood, it can be concluded that the composition is partially washed out.


Author(s):  
K. Z. Tilloev ◽  
S. V. Kondakov

The construction and method of calculating the stability of a crawler excavator equipped with a new working body (cone roller) are considered. The calculation is made on two working positions (longitudinal and transverse) of the excavator, provided that the excavator must apply the maximum force on the working body at an angle of 90°. The force applied by the excavator boom to the cone roller during the introduction depends on the physical and mechanical properties of the compacted soil. The calculation method differs in that during the compaction of the roadbed, the cone sinks into the ground, and the excavator tends to roll in the direction of the rear track support roller, in contrast to the traditional danger of tipping over the front support roller when working with a bucket.


2019 ◽  
Vol 945 ◽  
pp. 433-437
Author(s):  
M.D. Sokolova ◽  
A.F. Fedorova ◽  
M.L. Davydova

The present paper outlines the results of full-scale tests of climatic stability and the study of resistance to the action of hydrocarbon media of rubbers based on BNKS-18-18 (butadiene-nitrile rubber) and Hydrin T6000 epichlorohydrin rubber containing one of 6PPDstabilizerwith an aromatic amine moiety widely used in synthetic rubbers. Samples are exposed in an open ground under natural conditions of exposure to climatic external factors of Yakutsk in the Republic of Sakha (Yakutia), as well as in the oil environment of Talakanskoye field and I-50A hydraulic fluid in an unheated room. Such indexes of the samples as conditional tensile strength, elongation at rupture, hardness and degree of swelling are measured to determine the resistance of rubbers to aging after the first, third, and sixth months of exposing. The results of the study reveal the contribution of 6PPD stabilizer in maintaining the stability of the physical and mechanical properties of BNKS-18: rubber containing 6PPD has less property changes both in the open air and in hydrocarbon media compared to rubber without a stabilizer. It should be noted that the oil environment is the most aggressive environment, the swelling of rubbers in oil leads to a significant reduction in strength due to a decrease in intermolecular interaction.6PPD stabilizer occurred less effective for the rubber based on Hydrin T6000: changes in properties of the samples containing the stabilizer are larger than those of the samples without the stabilizer. However, unlike BNKS-18-18-based rubber, the swelling of rubber based on Hydrin T6000 led to the greatest stability of the physical and mechanical properties in the oil environment compared to the open air and hydraulic fluids.


2011 ◽  
Vol 331 ◽  
pp. 270-274 ◽  
Author(s):  
Yan Yan Chu ◽  
Qing Wang ◽  
Shi Zhong Cui

Abstract:Pure TiO2 water sol, pure ZnO water sol and three compound TiO2/ZnO water sols are prepared under low temperature. Then the padding and baking process is used to put the functional sol liquid on the fabric. SEM is use to analyzed the change of surface feature and the result show that all of the water sol except pure ZnO water sol liquid formed a thin film on the fiber The stability of pure ZnO water sol is the best one and the pure TiO2 water sol is the worst one at temperature of 15°C. The compound water sols stabilities are between these two water sols and with the more amount of ZnO, the stability last longer. Both mole of TiO2 and ZnO with the rate of 5 to 5 and 7 to 3 display the best antistatic behavior, but the washing fastnesses are not good. After treatment, the moisture regain displays most dramatically changes; the next one is whiteness of fabric, but the other physical and mechanical properties have a little change.


2018 ◽  
Vol 2018 ◽  
pp. 1-14 ◽  
Author(s):  
Yanbo Feng ◽  
Chao Yang

Red mud is the tailings generated from the production process of aluminum industry and is mainly stacked in open-air at present, so how to ensure the stability of red mud stockpile is very important. Regarding mud stockpile of Guizhou Aluminum Factory as the research object, this paper studies the physical and mechanical properties of Bayer red mud from wetting process, Bayer red mud from drying process, and sintering red mud through laboratory test and finally analyzes its stability under extreme rainfall condition in this region by the Geo-Studio software. The research results show that the red muds in different processes have big difference in physical and mechanical properties. The strength of sintering red mud is about 4.2 times of that of Bayer red mud from wetting process on average, and the strength of Bayer red mud from drying process is about 1.5 times of that of Bayer red mud from wetting process on average. So, the sintering red mud can be used as the subdam of red mud stockpile, to reduce the risk of collapse and dam break. The stability coefficients of the mixed stocking method under three rainfall conditions are 2.611, 2.597, and 2.631, respectively, all of which are above 1.0. It reveals that the dilatation scheme of using the sintering red mud with good engineering properties to stockpile the Bayer red mud is feasible. It can not only guarantee the safety and stability of red mud stockpiles, but also reduce the risk of red mud dam break and the capital investment of red mud yard.


Author(s):  
A. B. Petrovsky ◽  
V. Ya. Prushak ◽  
E. A. Lutovich

The geological structure and the physical-mechanical properties of rocks composing and overlapping the Third potash formation in the areas of the mine field mine No. 4 JSC Belaruskali, which are scheduled to practice, are studied. The geological sections of the Third potash layer and its roof were built, the thickness of sylvinite and halite layers was measured, the roof falling of the rocks of the layer with a height of up to 20 m was assessed, and the type of immediate roof was determined by the composition and structure of its constituent rocks. It was established that the strength under uniaxial compression of both sylvinite and halite layers for the areas under consideration differs slightly. Therefore, to solve engineering problems of ensuring the stability of mine workings and to calculate fastening parameters, strength values averaged over the groups of layers can be used that correlate well with the percentage of weak and clay interlayers. The same applies to Poisson’s ratio, the values of which for various layers of formation are slightly different and can be taken by their averaging. It is shown that the main factor that negatively affects the strength of rocks occurring in the roof of the Third potash seam is the presence of weak and clay interlayers, which increases with depth. The introduction of the obtained results allows us to improve the calculation accuracy of securing mining parameters, to reduce the costs of their maintenance, and to improve the safety of mining operations in developing the Third potash formation in complex geological and mining conditions.


Author(s):  
Safura Satayeva ◽  
Aibarsha Аbdrakhmanova ◽  
Anar Kurmangaliyeva

The quality of road bitumen is one of the most important factors determining the service life and quality of road asphalt concrete pavements. Current trends in oil refining and, in particular, increasingly deeper processing of crude oil, require consideration of the characteristics of its chemical composition and structure for the production of road bitumen, and, accordingly, the physical and mechanical properties of the bitumen produced. In this study the BOR 70/100 oil asphalt from the Aktau Bitumen Factory LLP “CaspiBitum” was considered. An asphalt was modified with polymer waste to upgrade operating properties. The I-40 industrial oil was used as a softener. Indicators like penetration, extensibility (ductility), brittleness temperature and softening temperature of bitumen were explored in this study. It was shown, that physical-mechanical properties of bitumen increased after modification: needle penetration depth decreased, extensibility decreased, softening temperature increased. Also, the influence of polymers on the structure of bitumen and the effect of their action in the composition were examined. Structure of polymer waste in Republic of Kazakhstan was analyzed. It was proved, that the usage of the recycled polyethylene as a modifier is a rational approach, and it lets to recycle stocks of secondary polymeric materials. Also problems of improving the properties of polymer-bitumen binder and ecology solved.


2021 ◽  
Vol 1043 ◽  
pp. 101-107
Author(s):  
Natalia Yatsenko ◽  
Alexandr Evforitsky ◽  
Natalya Kotenko

The possibility of using waste porcelain stoneware - a high-strength non-porous, dense material as a finely crushed mineral part of asphalt concrete with 0-5 mm fraction has been established. The adhesive additive Bitaden content was revealed, that intensifies porcelain stoneware interaction with bitumen due to the additional hydrogen bonds formation, the particles’ contact plane activation with the action of van der Waals forces. The conditions for obtaining asphalt concrete mixtures of type B, grade 1 and G, grade 2 of the optimal grain composition with a reduced content of BND 60/90 bitumen have been developed. Physical and mechanical properties are characterized by an increase in the water resistance of asphalt concrete samples based on porcelain stoneware, compressive strength and shear resistance.


Author(s):  
Xudong Hu ◽  
Jiazhen Gao ◽  
Mingtao Zhou ◽  
Songtao Peng ◽  
Wennian Xu ◽  
...  

The physical and mechanical properties of the ecological slope protection substrate will be affected by long-term variation of the meteorological condition, resulting in the stability of the substrate being reduced. So an artificial substrate of vegetation cement-soil was selected as the research object to prepare specimens with the different initial moisture content of 13%, 19%, 25%, 31%, 37%, and 43%. And a series of tests are conducted to investigate the evolution of the physical and mechanical properties under drying-wetting cycling conditions. Typical results of the vegetation cement-soil evolution can be divided into three stages: cement hydration stage, shrinkage stage, and stabilization stage. In terms of different initial moisture content, the shrinkage cracks number, cracks length, crack width, and cracks surface area are increased first and then stabilize with the increase of the number of drying-wetting cycles. In contrast, the cohesion and internal friction angle of the vegetation cement-soil is reduced with the increase of the number of cycles. Comprehensive analysis shows that the initial moisture content of vegetation cement soil ranges from 25% to 31% is the optimal choice to ensure substrate stability in production practice.


Sign in / Sign up

Export Citation Format

Share Document