scholarly journals Defluoridation of synthetic and natural waters by polyaluminum chloride-chitosan (PACl-Ch) composite coagulant

2017 ◽  
Vol 18 (1) ◽  
pp. 259-269 ◽  
Author(s):  
Mehrnoosh Abtahi ◽  
Ali Koolivand ◽  
Sina Dobaradaran ◽  
Kamyar Yaghmaeian ◽  
Anoushiravan Mohseni-Bandpei ◽  
...  

Abstract Removal of fluoride from drinking water by polyaluminum chloride-chitosan (PACl-Ch) composite coagulant was studied in a batch system. Two types of PACl-Ch coagulant were synthetized as PACl-Ch I and PACl-Ch II with chitosan to aluminum (Ch:Al) weight ratios of 0.5 and 1.0, respectively, and were used for defluoridation under different operating conditions. The composite coagulants were found to be more efficient than both PACl and chitosan. By an increase in the Ch:Al ratio from 0.5 to 1.0, the composite coagulant provided a little more efficiency of fluoride removal and lower residual level of Al. The optimum conditions of pH for fluoride removal by PACl-Ch I and PACl-Ch II were 8.0 and 7.5, respectively. Fluoride removal by the coagulants was not significantly affected by natural organic matter and turbidity, but was declined by high concentrations of common ions. To achieve desirable fluoride levels (lower than 1.0 mg/L) for natural water samples with fluoride levels of 2.0–2.9 mg/L, the required dosage of the composite coagulants were determined to be as low as 3–5 mgAl/L. The PACl-Ch coagulants demonstrated high efficiency for fluoride removal as well as low Al residual level (mainly lower than 0.2 mg/L) in a wide range of operating conditions.

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 607
Author(s):  
Tommy R. Powell ◽  
James P. Szybist ◽  
Flavio Dal Forno Chuahy ◽  
Scott J. Curran ◽  
John Mengwasser ◽  
...  

Modern boosted spark-ignition (SI) engines and emerging advanced compression ignition (ACI) engines operate under conditions that deviate substantially from the conditions of conventional autoignition metrics, namely the research and motor octane numbers (RON and MON). The octane index (OI) is an emerging autoignition metric based on RON and MON which was developed to better describe fuel knock resistance over a broader range of engine conditions. Prior research at Oak Ridge National Laboratory (ORNL) identified that OI performs reasonably well under stoichiometric boosted conditions, but inconsistencies exist in the ability of OI to predict autoignition behavior under ACI strategies. Instead, the autoignition behavior under ACI operation was found to correlate more closely to fuel composition, suggesting fuel chemistry differences that are insensitive to the conditions of the RON and MON tests may become the dominant factor under these high efficiency operating conditions. This investigation builds on earlier work to study autoignition behavior over six pressure-temperature (PT) trajectories that correspond to a wide range of operating conditions, including boosted SI operation, partial fuel stratification (PFS), and spark-assisted compression ignition (SACI). A total of 12 different fuels were investigated, including the Co-Optima core fuels and five fuels that represent refinery-relevant blending streams. It was found that, for the ACI operating modes investigated here, the low temperature reactions dominate reactivity, similar to boosted SI operating conditions because their PT trajectories lay close to the RON trajectory. Additionally, the OI metric was found to adequately predict autoignition resistance over the PT domain, for the ACI conditions investigated here, and for fuels from different chemical families. This finding is in contrast with the prior study using a different type of ACI operation with different thermodynamic conditions, specifically a significantly higher temperature at the start of compression, illustrating that fuel response depends highly on the ACI strategy being used.


Author(s):  
E. Benvenuti ◽  
B. Innocenti ◽  
R. Modi

This paper outlines parameter selection criteria and major procedures used in the PGT 25 gas turbine power spool aerodynamic design; significant results of the shop full-load tests are also illustrated with reference to both overall performance and internal flow-field measurements. A major aero-design objective was established as that of achieving the highest overall performance levels possible with the matching to latest generation aero-derivative gas generators; therefore, high efficiencies were set as a target both for the design point and for a wide range of operating conditions, to optimize the turbine’s uses in mechanical drive applications. Furthermore, the design was developed to reach the performance targets in conjunction with the availability of a nominal shaft speed optimized for the direct drive of pipeline booster centrifugal compressors. The results of the full-load performance testing of the first unit, equipped with a General Electric LM 2500/30 gas generator, showed full attainment of the design objectives; a maximum overall thermal efficiency exceeding 37% at nominal rating and a wide operating flexibility with regard to both efficiency and power were demonstrated.


2021 ◽  
Author(s):  
Stefan D. Cich ◽  
J. Jeffrey Moore ◽  
Chris Kulhanek ◽  
Meera Day Towler ◽  
Jason Mortzheim

Abstract An enabling technology for a successful deployment of the sCO2 close-loop recompression Brayton cycle is the development of a compressor that can maintain high efficiency for a wide range of inlet conditions due to large variation in properties of CO2 operating near its dome. One solution is to develop an internal actuated variable Inlet Guide Vane (IGV) system that can maintain high efficiency in the main and re-compressor with varying inlet temperature. A compressor for this system has recently been manufactured and tested at various operating conditions to determine its compression efficiency. This compressor was developed with funding from the US DOE Apollo program and industry partners. This paper will focus on the design and testing of the main compressor operating near the CO2 dome. It will look at design challenges that went into some of the decisions for rotor and case construction and how that can affect the mechanical and aerodynamic performance of the compressor. This paper will also go into results from testing at the various operating conditions and how the change in density of CO2 affected rotordynamics and overall performance of the machine. Results will be compared to expected performance and how design changes were implanted to properly counter challenges during testing.


Author(s):  
Jia Mi ◽  
Lin Xu ◽  
Sijing Guo ◽  
Mohamed A. A. Abdelkareem ◽  
Lingshuai Meng ◽  
...  

Hydraulic-electromagnetic Energy-regenerative Shock Absorber (HESA) has been proposed recently, with the purpose of mitigating vibration in vehicle suspensions and recovering vibration energy traditionally dissipated by oil dampers simultaneously. The HESA is composed of hydraulic cylinder, check valves, accumulators, hydraulic motor, generator, pipelines and so on. The energy conversion from hydraulic energy to mechanical energy mainly depends on the hydraulic motor between two accumulators. Hence, the dimension match and parameter settings of hydraulic motor for the HESA are extremely important for efficiency of the whole system. This paper studies the methods and steps for dimension matching and parameter settings of the hydraulic motor in a case of a typical commercial vehicle. To evaluate suspension’s vibration characteristics, experiments on the target tour bus have been done. Simulations are conducted to investigate the effects of the hydraulic motor in different working conditions. The simulation results verify that the methods and steps adopted are accurate over a wide range of operating conditions and also show that appropriate matching and parameter settings of the hydraulic motor attached in the HESA can work with high efficiency and then effectively improving energy conversion efficiency for the whole system. Therefore, the theory of the matching progress can guide the future design of an HESA.


Author(s):  
Dirk Anding ◽  
Henning Ressing ◽  
Klaus Hörmeyer ◽  
Roland Pisch ◽  
Kai Ziegler

Blade vibrations resulting in alternating stresses are often the critical factor in determining blade life. Indeed, many of the failures experienced by turbomachinery blades occur due to high-cycle fatigue caused by blade vibrations. These vibrations can arise either through self-excited oscillations known as flutter or through aerodynamic forcing of the blades from factors such as periodic wakes from up and/or downstream vanes or unsteady flow phenomena such as compressor surge. The current paper deals with the design and the analytical and experimental verification of the axial blading for a new generation of industrial compressors, a hybrid axial compressor that combines the advantages of conventional industrial compressors — broad operating range and high efficiency — with the advantages of gas turbine compressors — high power-density and high stage pressure ratios. Additionally, the surge robustness of this novel compressor blading has been greatly improved. During the development phase extensive efforts were made to ensure safe operation for future service life. This was achieved by designing blades that will not flutter, do not have high resonance amplitudes throughout their entire operating range and are extremely robust against surge. This strongly increased robustness of the new compressor blading was achieved by the implementation of a “wide-chord” blade design in all rotor blade rows in combination with a proper tuning of resonance frequencies throughout the entire operating range. For the verification of the new blading well-established methods accepted by industry were used such as CFD and FEA. Furthermore, coupling of the two into a method referred to as Fluid Structure Interaction (FSI) was used to more closely investigate the interaction of flow and structural dynamics phenomena. These analytical techniques have been used in conjunction with extensive testing of a scaled test compressor, which was operated at conditions of dynamic similitude (matching of scaled blade vibration frequencies, flow conditions, and Mach number) with full-scale operational conditions. Strain gauges placed on the blades and a state of the art technique known as “tip timing” were used to verify blade vibrations over a wide range of combinations of guide vane positions and rotational speeds. No propensity was found of any of the blades to develop high vibration amplitudes at any of the operating conditions investigated in the rig tests. The comparison of non-linear forced response analyses and the rig test results from strain gauges and tip timing showed close agreement, verifying the analysis techniques used. In conclusion it can be stated that the blade design exhibits a very high level of safety against vibrations within the entire operating range and during surge.


Author(s):  
Yan Jin ◽  
Chao Liu ◽  
Jiren Zhou ◽  
Fangping Tang

Submersible tubular pump is particularly suitable for ultra-low head (net head less than 2 m) pumping station which can reduce the excavation depth, lower engine room height, simplify hydraulic structure, and save civil engineering costs. Submersible tubular pump with smaller motor unit can reduce the flow resistance. The flow field inside the submersible tubular pump is simulated in a commercial computation fluid dynamics (CFD) code FLUENT. The RNG k-ε turbulent model and SIMPLE algorithm are applied to analyze the full passage of a submersible tubular pump, the performance of pump such as head, shaft power and efficiency are predicted based on the calculation of different operating conditions. The simulations are carried out over a wide range of operating points, from 0.8 of the reference mass flow rate at the best efficiency point (BEP) to the 1.28 of the BEP flow rate at the same rotating speed. For verifying the accuracy and reliability of the calculation results, a model test is conducted. The comparison of simulation results and the experiment data show that the calculation performances are agree with the experiment results in the high efficiency area and large discharge condition, but in the condition of low discharge, it exists deviations between the two results. Compare with the numerical simulation and experiment, which can provide more evidences for the hydraulic performance prediction and optimization design of submersible tubular pump pumping system.


2013 ◽  
Vol 135 (3) ◽  
Author(s):  
Ivan Ermanoski ◽  
Nathan P. Siegel ◽  
Ellen B. Stechel

We describe and analyze the efficiency of a new solar-thermochemical reactor concept, which employs a moving packed bed of reactive particles produce of H2 or CO from solar energy and H2O or CO2. The packed bed reactor incorporates several features essential to achieving high efficiency: spatial separation of pressures, temperature, and reaction products in the reactor; solid–solid sensible heat recovery between reaction steps; continuous on-sun operation; and direct solar illumination of the working material. Our efficiency analysis includes material thermodynamics and a detailed accounting of energy losses, and demonstrates that vacuum pumping, made possible by the innovative pressure separation approach in our reactor, has a decisive efficiency advantage over inert gas sweeping. We show that in a fully developed system, using CeO2 as a reactive material, the conversion efficiency of solar energy into H2 and CO at the design point can exceed 30%. The reactor operational flexibility makes it suitable for a wide range of operating conditions, allowing for high efficiency on an annual average basis. The mixture of H2 and CO, known as synthesis gas, is not only usable as a fuel but is also a universal starting point for the production of synthetic fuels compatible with the existing energy infrastructure. This would make it possible to replace petroleum derivatives used in transportation in the U.S., by using less than 0.7% of the U.S. land area, a roughly two orders of magnitude improvement over mature biofuel approaches. In addition, the packed bed reactor design is flexible and can be adapted to new, better performing reactive materials.


Author(s):  
Matthias Strauch ◽  
Wolfgang Beer ◽  
Ingo Stephan

Flexible operation at a wide range of operating conditions combined with very high efficiency is a fundamental customer requirement for industrial steam turbines today. The blading of turbines has to be designed with those objectives in mind. Especially for intermediate pressure (IP) blades operating at fixed and variable speed there is high potential for improvement with respect to efficiency. Nonetheless these blades have to satisfy rules of reliability and mechanical integrity, in many cases American Petroleum Institute (API) Standard 612 requirements. In this paper the dynamic behavior of IP blades with an improved and efficient 3D design is investigated numerically and verified by experiments. Shrouded blades are common for IP blade design to ensure a low dynamic stress level. These blades are supposed to form a closed coupling contact between adjacent blades to grant higher stiffness of the blade row and additional contact damping. Natural frequencies and mode shapes mainly remain on stiffness and mass distribution. Contact pressure at assembly state is generated by geometric interferences of the blades. Operational centrifugal forces and untwisting of blades tend to reduce the shroud contact pressure. One focus of this study is the research of different blade shroud contact conditions after the assembly process and the influence on closed shroud conditions during operation. A highly sophisticated numerical 3D model was set up to simulate and predict contact status and dynamic behavior of the blade row. Forced vibrations were imposed on the blade rows in a spin bunker to measure speed dependent frequencies and the effect of reduced shroud forces. Three-dimensional blades as well as cylindrical blades were tested on the same rotor to compare efficiency improved blades with long term industrial proven design. Results of the experiment were in good agreement with results of numerical calculations. A 10 MW steam turbine with one controlled extraction was used for validation. The turbine was operated within and beyond standard operational limits. Amongst others, the predicted contact and dynamic behavior were verified based on centrifugal forces, steam forces and real temperature distributions. Results confirmed that closed shroud contact was maintained at all operating points for properly assembled blade rows.


2018 ◽  
pp. 157-165
Author(s):  
Anja Slavič ◽  
Gabriela Kalčikova ◽  
Anita Jemec Kokalj ◽  
Andreja Žgajnar Gotvajn

The aim of this study was to evaluate the biodegradability of the artificial sweetener saccharin in surface waters and groundwater. Artificial sweeteners are generally persistent under environmental conditions and have been recently classified as emerging pollutants. Biodegradability in three surface waters and one groundwater was tested: the rivers Ljubljanica, Pivka, and Unica, and the groundwater Planina Cave (river Pivka). Under environmentally relevant conditions, saccharin degraded well in hypertrophic water (98%, 14 days) due to high concentrations of phosphorus and nitrogen. There was a longer lag phase and biodegradation time compared to the optimum conditions achieved in the standardized laboratory test. It has been concluded that saccharin is biodegradable in natural waters if said waters contain enough microorganisms and nutrients.


Author(s):  
Jacqueline O’Connor ◽  
Mark Musculus

The use of close-coupled post injections is an in-cylinder soot-reduction technique that has much promise for high efficiency heavy-duty diesel engines. Close-coupled post injections, short injections of fuel that occur soon after the end of the main fuel injection, have been known to reduce engine-out soot at a wide range of engine operating conditions, including variations in injection timing, exhaust gas recirculation (EGR) level, load, boost, and speed. While many studies have investigated the performance of post injections, the details of the mechanism by which soot is reduced remains unclear. In this study, we have measured the efficacy of post injections over a range of load conditions, at constant speed, boost, and rail pressure, in a heavy-duty optically-accessible research diesel engine. Here, the base load is varied by changing the main-injection duration. Measurements of engine-out soot indicate that not only does the efficacy of a post injection decrease at higher engine loads, but that the range of post-injection durations over which soot reduction is achievable is limited at higher loads. Optical measurements, including the natural luminescence of soot and planar laser-induced incandescence of soot, provide information about the spatiotemporal development of in-cylinder soot through the cycle in cases with and without post-injections. The optical results indicate that the post injection behaves similarly at different loads, but that its relative efficacy decreases due to the increase in soot resulting from longer main-injection durations.


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