Photocatalytic oxidation of chlorophenols in the presence of manganese ions

1999 ◽  
Vol 39 (10-11) ◽  
pp. 225-230 ◽  
Author(s):  
Jong-Nan Chen ◽  
Yi-Chin Chan ◽  
Ming-Chun Lu
Keyword(s):  
Aqueous Solution ◽  
Ionic Strength ◽  
Photocatalytic Oxidation ◽  
Reaction Rate ◽  
Removal Rate ◽  
Adsorption Rate ◽  
Manganese Ions ◽  
Manganese Ion ◽  
Cp Decomposition ◽  
The Relationship

The decomposition of chlorophenols in aqueous solution with UV-illuminated TiO2 suspensions in the presence of manganese ions was studied. It was found that the removal rate of chlorophenols would be the highest at pH 3 in the presence of 1.18×10−4 M manganese ion. The effect of ionic strength on the 2-CP decomposition can be ignored in the range from 0.1 to 0.005 M for NaClO4. This study is also to explore the relationship between the adsorption rate and reaction rate. Results showed that the more the adsorption rate the more the decomposition rate for the three chlorophenols. Manganese ions can increase the photocatalytic oxidation of 2-chlorophenol in terms of DOC. The relationship between temperature and reaction rate for 2-CP is k = 0.0043T - 1.2146.

scholarly journals Photoreduction of Cr(VI) Ions in Aqueous Solutions by UV/ Photocatalytic Processes

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Chih Ming Ma ◽  
Yung Shuen Shen ◽  
Po Hsiang Lin
Keyword(s):  
Aqueous Solutions ◽  
Reaction Rate ◽  
Removal Rate ◽  
Experimental Results ◽  
Order Kinetic ◽  
Solution Ph ◽  
Relationship Of ◽  
The Relationship ◽  
Photocatalytic Processes ◽  
Order Kinetic Equation

This study discussed the photoreduction of Cr(VI) ions in aqueous solutions by UV/TiO2photocatalytic processes under various operational factors. Experimental results showed that the removal rate of Cr(VI) increased with decreasing solution pH values and with increasing dosages of organic compounds, indicating that the recombination rate of electrons and h+can be retarded in the reaction systems by the addition of the scavenger, thus raising the reaction rate of Cr(VI). The relationship of the chemical reaction rate of Cr(VI), TiO2dosage, and changes of Cr(VI) concentration was expressed by the pseudo-first-order kinetic equation. Comparing the experimental results of two different doping metals in modified TiO2photoreduction systems, the removal rate of Cr(VI) by the Ag/TiO2process is larger, possibly because the electron transferring ability of Ag is superior to that of Cu. However, the photoreduction rates of Cr(VI) by modified UV/TiO2processes are worse than those by a nonmodified commercial UV/TiO2process.

Enhancement of decomposition of 2-chlorophenol with ultrasound/H2O2 process

1996 ◽  
Vol 34 (9) ◽  
pp. 41-48 ◽  
Author(s):  
Jih-Gaw Lin ◽  
Cheng-Nan Chang ◽  
Jer-Ren Wu ◽  
Ying-Shih Ma
Keyword(s):  
Ionic Strength ◽  
Reaction Rate ◽  
Order Reaction ◽  
Pseudo First Order Reaction ◽  
Initial Concentration ◽  
First Order ◽  
Toc Removal ◽  
Cp Decomposition ◽  
Effects Of Ph ◽  
Pseudo First Order

We investigated the effects of pH, ionic strength, catalyst, and initial concentration on both decomposition of 2-chlorophenol (2-cp) and removal of total organic carbon (TOC) in aqueous solution with ultrasonic amplitude 120 μm and H2O2 (200 mg/l). When the initial concentrations of 2-cp was 100 mg/l and the pH was controlled at 3, the rate of 2-cp decomposition was enhanced up to 6.6-fold and TOC removal up to 9.8-fold over pH controlled at 11. At pH 3, the efficiency of decomposition of 2-cp was 99% but the removal of TOC was only 63%; a similar situation applied at pH 7 and 11. Hence intermediate compounds were produced and 2-cp was not completely mineralized. When the concentration of ionic strength was increased from 0.001 to 0.1 M, the rate of 2-cp decomposition was enhanced only 0.3-fold, whereas the TOC removal was not enhanced. In comparison of the effects of pH and ionic strength, pH had greater influence on both 2-cp decomposition and TOC removal than ionic strength. The effect of a catalyst (FeSO4) on decomposition of 2-cp was insignificant comparing with direct addition of H2O2. The reaction rate at a smaller initial concentration of 2-cp (10 mg/l) was more rapid than at a greater one (100 mg/l). The rate of 2-cp decomposition and TOC removal appeared to follow pseudo-first-order reaction kinetics.

scholarly journals Effect of the coexistence of SO32− and PO43− on the adsorption performance of zeolite-loaded FeOOH@ZnO for S2−

2021 ◽  
Author(s):  
Fen Li ◽  
Youjing Li ◽  
Baocai Ge ◽  
Jinguang Hu ◽  
Cailian Yu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydrothermal Method ◽  
Significant Influence ◽  
Removal Rate ◽  
Adsorption Properties ◽  
Adsorption Rate ◽  
Modified Zeolite ◽  
Adsorption Performance ◽  
Modified Zeolites

Abstract The present study deals with the synthesis of zeolite-loaded FeOOH@ZnO by hydrothermal method and investigates the effects of coexisting SO32− and PO43− ions in the aqueous solution on the adsorption performance for S2−. The results showed that the HNO3-modified zeolite loaded with FeOOH@ZnO (FeOOH@ZnO/HZ) resulted in a maximum S2− removal rate of ≈98%. The adsorbent's performance on removing S2− was significantly enhanced, compared with NaOH and ZnCl2-modified zeolites loaded with FeOOH@ZnO, and the adsorption was proved to be a heat-absorbing process. When SO32− and PO43− coexisted with S2−, SO32− and PO43− had a significant influence on the adsorption properties of FeOOH@ZnO/HZ. When three ions of S2−, SO32− and PO43− were present simultaneously, the adsorption performance of FeOOH@ZnO/HZ on S2− was further, and the removal rate dropped to about 80%. Moreover, FeOOH@ZnO/HZ also adsorbed PO43− and SO32− in the system containing multiple ions, but the adsorption rate of PO43− and SO32− were much lower than S2−. This indicated that the adsorption of S2− in the presence of FeOOH@ZnO/HZ dominates under competitive conditions.

Application of a membrane bioreactor immobilized with Bacillus subtilis HHT-1 for removing manganese ions in water

2001 ◽  
Vol 1 (2) ◽  
pp. 183-189
Author(s):  
K. Takamizawa ◽  
Y.C. Chang ◽  
J. Hattori ◽  
M. Kani ◽  
K. Mori ◽  
...  
Keyword(s):  
Bacillus Subtilis ◽  
Manganese Oxides ◽  
Membrane Bioreactor ◽  
Removal Rate ◽  
Cell Mass ◽  
Ion Concentration ◽  
Manganese Sulfate ◽  
Raw Water ◽  
Manganese Ions ◽  
Manganese Ion

A newly isolated Bacillus subtilis HHT-1 has the ability to oxidize manganese ions. We attempted to immobilize the cells on the microfiltration membrane and remove manganese ions from the raw water as manganese oxides. After subculturing, the broth was filtered with NTF-5200 (pore size 0.2 μm), Nitto, Japan. The filter was set in Nitto Membrane Master RUM-2, Nitto, Japan and used as the bioreactor. Manganese sulfate was dissolved in distilled water to become 1 mg/l or 0.2 mg/l of the final manganese ion concentration, and used as the raw water. The volume of the bioreactor was 10 ml. The flow rate, pressure, retention time of the bioreactor, and circulation frequency were, 0.08 l/min, 0.4 kgf/cm2, 7.5 sec, and 0.04 time/min, respectively. Removal rate of manganese ions rose with increasing cell mass immobilized. The bioreactor was active even at low concentration of initial manganese (0.2 mg/l) and 0.04 mg/l or less of manganese ion concentration in the treated water was obtained.

Catalytic ozonation of 2-dichlorophenol by metallic ions

2003 ◽  
Vol 47 (1) ◽  
pp. 77-82 ◽  
Author(s):  
C.-H. Ni ◽  
J.-N. Chen ◽  
P.-Y. Yang
Keyword(s):  
Reaction Rate ◽  
Removal Rate ◽  
Reaction Rate Constant ◽  
Manganese Concentration ◽  
Functional Improvement ◽  
Metallic Ions ◽  
Manganese Ions ◽  
Toc Removal ◽  
Mechanism Of Reaction ◽  
Initial Ph

This research is mainly to explore functional improvement by adding various kinds of metallic ions in the ozonation of 2-chlorophenol solution. During the experiment, various kinds of metallic ions (Pb+, Cu2+, Zn2+, Fe2+, Ti2+, and Mn2+) were added; it was found that the reaction rate increased in all cases. The best result was obtained by using manganese ions, followed by iron and titanium ions. At pH = 3 and 1 ppm Mn2+ concentration, the reaction rate was increased by three times. TOC removal rate was also increased from 12.6% to 38% at 60 min reaction time. Ozone self-decomposition with various kinds of metallic ions alone was tested. It was found the ozone self-decomposition coefficient is highly dependent on the reaction rate constant for ozonation of 2-chlorophenol. The improvement of reaction was relevant to the mechanism of reaction between ozone and metallic ions. Furthermore, the effect of adding manganese ions was studied. With the initial manganese concentration at 0-2 ppm, after gas exposure for 20 min the removal rate can be increased from 38% to 93%. TOC removal rate was increased from 11% to 38%. The reaction rate was improved more greatly at the initial pH = 3.

scholarly journals Application of Poly-γ-Glutamic Acid Flocculant to Flocculation–Sedimentation Treatment of Ultrafine Cement Suspension

Water ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1748
Author(s):  
Tomokazu Yanagibashi ◽  
Motoyoshi Kobayashi ◽  
Keisuke Omori
Keyword(s):  
Ionic Strength ◽  
Glutamic Acid ◽  
Removal Efficiency ◽  
Control Charts ◽  
Removal Rate ◽  
Rapid Mixing ◽  
Mixing Intensity ◽  
The Relationship ◽  
Addition Amount ◽  
Ultrafine Cement

We examined the effect of poly-γ-glutamic acid flocculant (PGAF) on the removal of ultrafine cement (UFC) particles stabilized by a poly-carboxylate co-polymer, which is a superplasticizer (SP). The flocculation–sedimentation treatment with PGAF successfully removed the SP-stabilized cement particles through the gravitational settling of the formed flocs. The removal efficiency reduced with the increase in the ionic strength, probably because of the shrunk form of poly-γ-glutamic acid (γ-PGA) at high ionic strengths. Increasing the mixing intensity during rapid mixing improved the removal efficiency. A series of flocculation–sedimentation experiments provided a diagram showing the relationship between ionic strengths and the addition amount of PGAF. Our results suggest that PGAF is a good candidate for the purification of cement suspension by flocculation–sedimentation, and a better removal performance can be obtained at lower ionic strengths with intense rapid mixing. From the diagram of the control charts presented in this study, we can determine the optimal addition amount of PGAF for achieving the target removal rate for cement suspension under any ionic strength.

Photo-catalytic activity of cationic zinc(II) complexes of phthalocyanine and porphyrazine derivatives loaded on the surface of silica gel

2011 ◽  
Vol 15 (09n10) ◽  
pp. 1078-1084
Author(s):  
Kuninobu Kasuga ◽  
Hiroyuki Irie ◽  
Hidekazu Tanaka ◽  
Takahisa Ikeue ◽  
Tamotsu Sugimori ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Catalytic Activity ◽  
Silica Gel ◽  
Electrostatic Interaction ◽  
Visible Light Irradiation ◽  
Reaction Rate ◽  
Initial Reaction Rate ◽  
Initial Reaction ◽  
Photo Catalytic Activity ◽  
The Relationship

Cationic 2,9,16,23-tetra(3-N,N,N-trimethylaminoethyloxy)phthalocyaninatozinc(II) (complex 1) and 22,23-di(4-N,N,N-trimethylaminophenyl)benzo[b]-7,8,12,13,17,18-hexa(4-t-butylphenyl) porphyrazinatozinc(II) (complex 2) were loaded on the surface of silica gel by use of an electrostatic interaction with deprotonated silanol groups of silica gel. While complex 1 formed its dimer with increase in the amount of the complex in the composite, complex 2 hardly formed the dimer in the composite due to the steric hindrance of its peripheral substituents. 1,3-diphenylisobenzofuran was photo-oxidized using the composites as the sensitizer in aerated methanol. The reaction proceeded with singlet dioxygen generated by the visible-light irradiation upon the sensitizer. While the initial reaction rate with the composite of complex 2 steadily increased in accordance with increase in the amount of the complex, that with the composite of complex 1 at first increased, but subsequently decreased due to the formation of the photo-inactive dimer. Bilirubinditaurate was also photo-oxidized using the composites as the sensitizer in an aerated aqueous solution. The reaction proceeded with superoxide instead of singlet dioxygen. The relationship between the initial reaction rate and the amount of the complex was similar to that in methanol.

Studying dispersed and rheological properties of hydrocarbon-containing acid emulsions and their efficiency in removing asphalt-resin-paraffin deposits

2020 ◽  
pp. 128-139
Author(s):  
M. Yu. Shumakher ◽  
V. V. Konovalov ◽  
A. P. Melnikov
Keyword(s):  
Aqueous Solution ◽  
Hydrochloric Acid ◽  
Rheological Properties ◽  
Reaction Rate ◽  
Experimental Studies ◽  
Efficient Removal ◽  
Reservoir Properties ◽  
Hydrocarbon Solvents ◽  
Formation Zone ◽  
Effect Of The Composition

Currently, the treatment of the bottomhole formation zone with acidic compositions is one of the most common methods to intensify the oil inflow. The use of various modified acid compositions increases the efficiency of acid treatments on the bottomhole formation zone. Acid compositions, including those containing hydrocarbon solvents, which contribute to more efficient removal of organic colmatants, affect the reaction rate of the reagent with the rock and processing equipment, change the reservoir properties, etc.The article presents the results of experimental studies, which are aimed at establishing the effect of the composition of hydrocarbon-containing acidic emulsions consisting of an aqueous solution of hydrochloric acid, toluene and Neonol AF 9-10 on their dispersed and rheological properties, as well as their efficiency in removing paraffin deposits.

Heterogeneous Fenton Catalytic Removal of Organic Pollutant in Aqueous Solution by using Coal Gangue as a Catalyst

2019 ◽  
Vol 12 (4) ◽  
pp. 312-325
Author(s):  
Jiwei Zhang ◽  
Jingjing Xu ◽  
Shuaixia Liu ◽  
Baoxiang Gu ◽  
Feng Chen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Hydroxyl Radical ◽  
Removal Rate ◽  
Organic Pollutant ◽  
Coal Gangue ◽  
Ion Leakage ◽  
Heterogeneous Fenton ◽  
Solution Ph ◽  
X Ray

Background: Coal gangue was used as a catalyst in heterogeneous Fenton process for the degradation of azo dye and phenol. The influencing factors, such as solution pH gangue concentration and hydrogen peroxide dosage were investigated, and the reaction mechanism between coal gangue and hydrogen peroxide was also discussed. Methods: Experimental results showed that coal gangue has the ability to activate hydrogen peroxide to degrade environmental pollutants in aqueous solution. Under optimal conditions, after 60 minutes of treatment, more than 90.57% of reactive red dye was removed, and the removal efficiency of Chemical Oxygen Demand (COD) up to 72.83%. Results: Both hydroxyl radical and superoxide radical anion participated in the degradation of organic pollutant but hydroxyl radical predominated. Stability tests for coal gangue were also carried out via the continuous degradation experiment and ion leakage analysis. After five times continuous degradation, dye removal rate decreased slightly and the leached Fe was still at very low level (2.24-3.02 mg L-1). The results of Scanning Electron Microscope (SEM), energy dispersive X-Ray Spectrometer (EDS) and X-Ray Powder Diffraction (XRD) indicated that coal gangue catalyst is stable after five times continuous reuse. Conclusion: The progress in this research suggested that coal gangue is a potential nature catalyst for the efficient degradation of organic pollutant in water and wastewater via the Fenton reaction.

scholarly journals Are rate and selectivity correlated in iridium-catalysed hydrogen isotope exchange reactions?

2021 ◽  
Author(s):  
Daria S. Timofeeva ◽  
David M Lindsay ◽  
W. J. Kerr ◽  
David James Nelson
Keyword(s):  
Functional Groups ◽  
Hydrogen Isotope ◽  
Isotope Exchange ◽  
Reaction Rate ◽  
Exchange Reactions ◽  
Reaction Selectivity ◽  
Hydrogen Isotope Exchange ◽  
The Relationship

Herein we examine the relationship between reaction rate and reaction selectivity in iridium-catalysed hydrogen isotope exchange (HIE) reactions directed by Lewis basic functional groups. We have recently develped a directing...

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