A Novel Mycelial Pellet Enhanced by Activated Carbon for Eriochrome Black T-containing Wastewater Treatment

Author(s):  
Jianghong Liu ◽  
Jingwei Ren ◽  
Ruidan Xu ◽  
Jian Xue ◽  
Xiaohang Wei ◽  
...  
1999 ◽  
Vol 40 (4-5) ◽  
pp. 137-144 ◽  
Author(s):  
K. Miserez ◽  
S. Philips ◽  
W. Verstraete

A number of new technologies for the advanced treatment of wastewater have recently been developed. The oxidative cometabolic transformation by methanotrophs and by nitrifiers represent new approaches in relation to organic carbon. The Biological Activated Carbon Oxidative Filters characterized by thin biofilms are also promising in that respect. Moreover, implementing genetically modified organisms with improved catabolic potential in advanced water treatment comes into perspective. For very refractory effluents chemical support techniques, like e.g. strong chemical oxidation, can be lined up with advanced biology.


Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 337
Author(s):  
Sara Mesa Medina ◽  
Ana Rey ◽  
Carlos Durán-Valle ◽  
Ana Bahamonde ◽  
Marisol Faraldos

Two commercial activated carbon were functionalized with nitric acid, sulfuric acid, and ethylenediamine to induce the modification of their surface functional groups and facilitate the stability of corresponding AC-supported iron catalysts (Fe/AC-f). Synthetized Fe/AC-f catalysts were characterized to determine bulk and surface composition (elemental analysis, emission spectroscopy, XPS), textural (N2 isotherms), and structural characteristics (XRD). All the Fe/AC-f catalysts were evaluated in the degradation of phenol in ultrapure water matrix by catalytic wet peroxide oxidation (CWPO). Complete pollutant removal at short reaction times (30–60 min) and high TOC reduction (XTOC = 80 % at ≤ 120 min) were always achieved at the conditions tested (500 mg·L−1 catalyst loading, 100 mg·L−1 phenol concentration, stoichiometric H2O2 dose, pH 3, 50 °C and 200 rpm), improving the results found with bare activated carbon supports. The lability of the interactions of iron with functionalized carbon support jeopardizes the stability of some catalysts. This fact could be associated to modifications of the induced surface chemistry after functionalization as a consequence of the iron immobilization procedure. The reusability was demonstrated by four consecutive CWPO cycles where the activity decreased from 1st to 3rd, to become recovered in the 4th run. Fe/AC-f catalysts were applied to treat two real water matrices: the effluent of a wastewater treatment plant with a membrane biological reactor (WWTP-MBR) and a landfill leachate, opening the opportunity to extend the use of these Fe/AC-f catalysts for complex wastewater matrices remediation. The degradation of phenol spiked WWTP-MBR effluent by CWPO using Fe/AC-f catalysts revealed pH of the reaction medium as a critical parameter to obtain complete elimination of the pollutant, only reached at pH 3. On the contrary, significant TOC removal, naturally found in complex landfill leachate, was obtained at natural pH 9 and half stoichiometric H2O2 dose. This highlights the importance of the water matrix in the optimization of the CWPO operating conditions.


2003 ◽  
Vol 47 (1) ◽  
pp. 113-120 ◽  
Author(s):  
D.S. Chaudhary ◽  
S. Vigneswaran ◽  
V. Jegatheesan ◽  
H.H. Ngo ◽  
H. Moon ◽  
...  

Wastewater treatment has always been a major concern in the developed countries. Over the last few decades, activated carbon adsorption has gained importance as an alternative tertiary wastewater treatment and purification process. In this study, granular activated carbon (GAC) adsorption was evaluated in terms of total organic carbon (TOC) removal from low strength synthetic wastewater. This paper provides details on adsorption experiments conducted on synthetic wastewater to develop suitable adsorption isotherms. Although the inorganics used in the synthetic wastewater solution had an overall unfavourable effect on adsorption of organics, the GAC adsorption system was found to be effective in removing TOC from the wastewater. This study showed that equation of state (EOS) theory was able to fit the adsorption isotherm results more precisely than the most commonly used Freundlich isotherm. Biodegradation of the organics with time was the most crucial and important aspect of the system and it was taken into account in determining the isotherm parameters. Initial organic concentration of the wastewater was the determining factor of the model parameters, and hence the isotherm parameters were determined covering a wide range of initial organic concentrations of the wastewater. As such, the isotherm parameters derived using the EOS theory could predict the batch adsorption and fixed bed adsorption results of the multi-component system successfully. The isotherm parameters showed a significant effect on the determination of the mass transfer coefficients in batch and fixed bed systems.


Author(s):  
S. Kaviya ◽  
R. M. Jayabalakrishnan ◽  
M. Maheswari ◽  
S. Selvakumar

The present study investigates the characterization of different coconut based low cost adsorbents like coconut shell biochar, zinc chloride impregnated coconut shell activated carbon, coir fibre and coir geotextile and their suitability characteristics as a filter bed in different wastewater treatment process. The characterization study helps to investigate their physical, chemical and morphological properties like proximate and ultimate analysis, iodine number, decolorizing power, SEM, Surface area using BET, Particle size and Zeta potential. The experiment results showed that among the different adsorbents activated carbon has high fixed carbon content (82.99 percent), more surface area (590.8 m2 g-1), low ash content (1.31 percent) with a decolorizing power of 240-300 mg g-1. The coir fibre and coir geotextile having neutral pH with negative surface charge easily adsorbs the positive cations from aqueous solutions at highest apparent density. The experimental findings suggest that the activated adsorbent which shows better results as an effective filter media for adsorption of organic compounds and pollutants from wastewater.


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