scholarly journals Evaluation of Groundwater Quality for Heavy Metals by Using Chemical Indices Approach in Karachi, Pakistan

2021 ◽  
Vol 22 (2) ◽  
pp. 358-366
Author(s):  
Aziz Ur Rahman ◽  
Haq Nawaz Abbasi ◽  
Muhammad Owais

Freshwater consumption has been increased because of population growth and economic development. At the same time, depletion and contamination of groundwater is subject of great concern. Karachi is the industrial hub and serves as the economic backbone of Pakistan. The research aims to investigate the heavy metal pollution in the groundwater of Korangi Industrial Area, one of the largest industrial estates in Karachi. Eighteen representative locations were selected to collect groundwater samples and study the concentrations of heavy metals Cr, Fe, Ni, Cu, Zn, and Pb. Pollution load index, Nemerow's pollution index, and geo accumulation index approaches were used to interpret the basic data. The average concentrations of the measured heavy metals were 354.67 µg.L-1 , 694.33 µg.L-1 , 39.2 µg.L-1 , 12.89 µg.L-1 , 9.5 µg.L-1 , and 6.17 µg.L-1 for Fe, Zn, Cu, Pb, Cr, and Ni, respectively. The results showed that groundwater quality in the study area is poor and mainly contaminated by Pb and Fe.

Author(s):  
Defri Yona ◽  
Syarifah Hikmah Julinda Sari ◽  
Anedathama Kretarta ◽  
Citra Ravena Putri Effendy ◽  
Misba Nur Aini ◽  
...  

This study attempted to analyze the distribution and contamination status of heavy metals (Cu, Fe and Zn) along western coast of Bali Strait in Banyuwangi, East Java. Bali Strait is one of the many straits in Indonesia with high fisheries activities that could potentially contributed to high heavy metal pollution. There were five sampling areas from the north to south: Pantai Watu Dodol, Pantai Kalipuro, Ketapang Port, Pantai Boom and Muncar as the fish landing area. Heavy metal pollution in these locations comes from many different activities such as tourism, fish capture and fish industry and also domestic activities. Contamination factor (CF), geo-accumulation index (Igeo) and enrichment factor (EF) of each heavy metal were calculated to obtain contamination status of the research area. The concentrations of Fe were observed the highest (1.5-129.9 mg/kg) followed by Zn (13.2-23.5 mg/kg) and Cu (2.2-7.8 mg/kg). The distribution of Cu, Fe and Zn showed variability among the sampling locations in which high concentrations of Cu and Zn were higher in Ketapang Port, whereas high concentration of Fe was high in almost all sampling locations. According to the pollution index, contamination factors of Cu, Fe and Zn were low (CF < 1 and Igeo < 1). However, high index of EF (> 50) showed high influence of the anthropogenic activities to the contribution of the metals to the environment. This could also because of the high background value used in the calculation of the index due to the difficulties in finding background value from the sampling areas.Keywords: heavy metals, pollution index, contamination factor, geo-accumulation index, Bali Strait


Author(s):  
Abinotami Williams Ebuete ◽  
Andy Etta Bisong ◽  
Okereke Chukuma ◽  
Lucky E. Ndiwari ◽  
Ibim Yarwamara Ebuete

The Kolo Creek is an inland water body in the Niger Delta receiving organic and chemical wastes arising from anthropogenic activities within the catchment area. This study was therefore carried out to investigate the spatial variabilities of heavy metals in surface and sediment and their geochemical factors that influence their presence along the Kolo Creek in 2018 using Geo-accumulation index and pollution load index to extrapolate the level of heavy metal contraction in the two medium. Sediment and Water samples were collected for five (5) months and assessed from eight sampling points (A-h) for seven (7) heavy metals such as  Copper (Cu), Lead (Pb), Iron(Fe), Camium (Cd), Manganese (Mn), Nickel (Ni) and Mercury (Hg). All the heavy metals had geo-accumulation indices below zero which indicates no pollution except Fe which had geo-accumulation index in the range 3.327 in surface water and 7.751 in sediment, furthermore, the pollution load index revealed a toxicity of 0.664 times in surface water as against 1.501 times in sediment exceeding the background concentration in the Kolo Creek. Hence, poor ecological ethics and culture should be discouraged to keep the Kolo Creek water under check for safe domestic water use.


Author(s):  
Yebpella G.G ◽  
Magomya A.M ◽  
Hikon B.N ◽  
Joshua Y ◽  
Gani J

Heavy metals accumulation in biological system are by inhalation of contaminated air, intake of contaminated food or drinking water has been considered to be an ecological menace to man and other organisms. This study was carried out to ascertain the pollution status of Cr, Pb, Zn, Cu and Cd in sediment of Akata Lake, Katsina- Ala Benue State, Nigeria. Sediment samples were collected, digested using 30% H2O2 followed by 0.5M HCl and the metal concentrations were determined with Varian AA240 Atomic absorption spectrophotometer equipped with Zeeman’s background correction (Varian, New Jersey, USA). The mean level of the heavy metals, Pb, Zn, Cu, Cd and Cr are 31.05, 2.72, 19.22 and 0.88 mg/kg while the concentration of Cr was below the detection limit of the instrument. The values obtained were compared with the established soil and sediment standard by World Health Organization (WHO). The contamination factors value for Zn, Cu and Cd are <1 while that of Pb is >1, hence it shows that the sediment is polluted by lead. The pollution load index (PLI) and Geo-accumulation index (Igeo) levels for Cr, Zn, Cu, Cd heavy metals in sample A - E were less than 1 except for Pb which is >1, this show that, the sediment were polluted with Pb.


2018 ◽  
Vol 34 ◽  
pp. 02018
Author(s):  
A.A. Ahmad Zubir ◽  
F.N. Mohd Saad ◽  
F.A. Dahalan

The contamination of heavy metals gives bad implications to the aquatic environment. Thus, a study was conducted to assess the sediment quality by using different contamination indices such as Enrichment Factor (EF), Geo-accumulation Index (Igeo), and Pollution Load Index (PLI). Each sediment sample was collected at the surface (0-15cm) at 5 locations based on the land use activity; jetty port (A), seaside restaurant (B), roadside area (C), power plant (D) and residential area (E). All samples were undergoes acid digestion and analyzed with AAS. Four elements identified from the sediment samples which are Cr, Cu, Pb and Zn were used to calculate the respective indices. Results show that, the highest EF value of Pb which categorized as very severe enrichment was at point E. Meanwhile minor enrichment was detected at point B for Cu while Cr and Zn at point A. Based on Igeo value the sediment quality along Kuala Perlis was in the unpolluted-moderately polluted condition (class 1). As for PLI it shows that the sediment of the coastal area is unpolluted (PLI<1). Therefore, this study revealed that, the main contributor of heavy metals in this area is Pb while the sediment quality of Kuala Perlis was in minor pollution condition.


2016 ◽  
Vol 10 (3) ◽  
pp. 41-46
Author(s):  
Soheil Sobhanardakani ◽  
◽  
Mehrnaz Ghoochian ◽  

Background: Soil and sediment serve as major reservoir for contaminants as they possess ability to bind various chemicals together. In this study the concentrations of heavy metals Cd, Cr and Cu were analyzed in surface sediments of Agh Gel Wetland in west of Iran. Methods: The sediment samples were taken from 10 stations. The samples were subjected to bulk digestion and chemical partitioning and Cd, Cr and Cu concentrations of the sediments were determined by ICP-OES. Geo-accumulation index (I-geo), Contamination factor (CF) and Pollution load index (PLI) were used to evaluate the magnitude of contaminants in the sediment profile. Results: The mean sediment concentrations (mg kg-1 dry weight) ranged within 0.20-0.29 (Cd), 58-71 (Cr) and 23-36 (Cu). According to the I-geo values, the sediments' qualities are classified as unpolluted to moderately polluted category. According to the CF values, the sediments' qualities are classified as low to moderate contamination. Furthermore, the PLI values indicated that there were no metal pollution exists for all sampling stations. Conclusion: The Agh Gel Wetland is potential to be threatened by chemical pollutants such as agricultural effluent. So to preserve the environment of the Agh Gel Wetland from deterioration, periodically monitoring of the water and sediment qualities is recommended.


2020 ◽  
Author(s):  
Madri Pramod Kumar ◽  
Tella Lakshmi Prasad ◽  
Kothapalli Nagalakshmi ◽  
Nadimikeri Jayaraju ◽  
Ballari Lakshmanna

Bottom sediment samples from six stations were sampled in pre monsoon 2016, from the Govindampalli – Durgarajupatnam (GP-DP) coast. Heavy metals viz., Fe, Mn, Cr, Cu, Ni, Pb, Zn and Cd analysis was carried out by using ICP-OES, and the average concentrations are as follows Fe > Mn > Zn > Cr > Pb > Ni > Cu > Cd. Various environmental indices like Factor Analysis (FA), Geo-accumulation Index (Igeo), Enrichment Factor (EF) and Pollution Load Index (PLI) were applied to the chemical data in order to know the levels of contamination and factors contributing to the pollution. Correlation coefficient results exhibits significant positive and negative relationships among Fe, Mn, Pb, Zn, Cd. All the environmental indices suggest that heavy metals were present at higher concentrations and the impacts of anthropogenic activities are crucial that serves as source of heavy metals in the zone. Relatively, maximum number of heavy metals viz., Fe, Ni and Pb were accumulated at the brackish environment i.e., at confluence of Swarnamukhi river (GP-S Station).


DEPIK ◽  
2020 ◽  
Vol 9 (3) ◽  
pp. 403-410
Author(s):  
Edward Edward

Contamination and pollution of heavy metals in the bottom sediment can pose serious issues to marine organisms and human health. Jakarta Bay which is located adjacent to the capital city of Indonesia is notorious for its pollution problems. The purpose of this research was to assest the contamination levels of heavy metals Hg, Pb, and Cd in sea-bottom sediments based on an index analysis approach (contamination factors, geo accumulation index, pollution load index). Sediment samples were collected from 31 stations in Jakarta Bay. Heavy metal concentration was measured using Atomic Absorption Spectrophotometer (AAS). The results showed that an average mercury (Hg) concentration ranged from 0.150 to 0.530 µg.g-1 with an total average of 0.362 µg.g-1, Lead (Pb) from 14.870 to 35.650 µg.g-1 with an total average of 21.774 µg.g-1, Cadmium (Cd) 0.110-0.280 µg.g-1 with an total average of 0.190 µg.g-1.The average concentration of Hg, Pb, and Cd is still lower than the sediment quality threshold values set by the Office of the State Minister of Environment of Indonesia  2010. The results of the index analysis showed that the average value of contamination factor (CF) are Hg 0.685, Pb 0.558, and Cd 0.380 respectively (low contamination) and geo accumulation index values are Hg 0.237, Pb -1.655, and Cd 0.069 respectively (unpolluted to moderate polluted). Overall, based on the pollution load index value is -0,511 (PLI 1), sediments in these waters are categorized as not yet polluted by Hg, Pb and Cd. This situation  is so necessary to be maintained, that in order for the preservation of marine resources will remain.Keywords: Jakarta Bay, sediment, pollution, heavy metals, assessmentABSTRAKKontaminasi dan pencemaran logam berat pada sedimen dasar dapat menimbulkan masalah yang serius bagi biota laut dan kesehatan manusia. Teluk Jakarta yang terletak berdekatan dengan ibu kota Indonesia terkenal karena masalah pencemarannya yang parah. Tujuan penelitian ini adalah untuk menilai tingkat kontaminasi logam berat Hg, Pb dan Cd dalam sedimen dasar laut berdasarkan pendekatan analisis indeks. Contoh sedimen diambil dari 31 stasiun penelitian di Teluk Jakarta. Kadar logam berat diukur dengan alat Spektrofometer Penyerapan Atom. Hasil penelitian menunjukkan kadar Hg rerata berkisar 0,150-0,530 µg. g-1 dengan rerata total 0,362 µg. g-1, Timbal (Pb) 14,870-35,650 µg. g-1 dengan rerata total 21,774 µg. g-1, Kadmium (Cd) 0,110-0,280 µg. g-1 dengan rerata total 0,190 µg.g-1. Kadar rerata Hg, Pb dan Cd masih lebih rendah dari nilai ambang batas kualitas sedimen yang ditetapkan oleh Kantor Menteri Negara Lingkungan Hidup Indonesia 2010. Hasil analisis indeks menunjukkan nilai rerata faktor kontaminasi (CF) berturut-turut adalah Hg 0,685, Pb 0,352 dan Cd 0,380 (kontaminasi rendah) dan nilai indeks geo akumulasi berturut-turut adalah Hg 0,227, Pb 1,098 dan Cd 0,633 (tidak tercemar sampai tercemar sedang). Secara keseluruhan, berdasarkan nilai indeks beban pencemaran yakni -3.772 (PLI 1), sedimen di perairan ini termasuk kategori belum tercemar oleh Hg, Pb dan Cd. Keadaan ini perlu dipertahankan, agar kelestarian sumberdaya laut tetap terjaga.Kata kunci: Teluk Jakarta, sedimen, pencemaran, logam berat, penilaian


2021 ◽  
Vol 9 (8) ◽  
pp. 899
Author(s):  
Ammar A. Mannaa ◽  
Athar Ali Khan ◽  
Rabea Haredy ◽  
Aaid G. Al-Zubieri

The Al-Salam Lagoon is one of the recreational sites along the Jeddah coast, showing the environmental impacts of urbanization along the coast. A sediment core (220 cm) was collected from the intertidal zone to evaluate the heavy metals (Fe, Mn, Cr, Ni, Cu, Zn, and Pb) and geochemical indices (contamination factor, geo-accumulation index, and pollution load index). In the organ-ic-rich muddy sediments (0–100 cm), there is a high metals content and a pollution load index of ~3, indicting anthropogenic impacts with high Cu contamination (CF:12) and moderate Fe, Mn, Cr, Ni, Zn, and Pb contamination (CF: <3). The organic matter and heavy metals washed through surface run-off from the land and deposited as urban waste. Down the core, consistent metals concentration, CF, and Igeo trends indicate a common pollutant source and pollution load variations over time. In the sediment section (70–40 cm), a high organic matter, metal concentration, CF, Igeo, and PLI value (≥5) suggest an uncontrolled pollution load. The decreased and stable trends of environmental indicators toward surface sediments suggest measures taken to control the pollution along the Jeddah coast. Below 110 cm, the carbonate-rich sediments have low organic matter and metals, showing an unpolluted depositional environment. The negative geo-accumulation index implies a geogenic source and indicates no anthropogenic impacts as inferred from low (~1.0) CF and PLI.


2021 ◽  
Vol 8 (4) ◽  
pp. 319-327
Author(s):  
Amir Javid ◽  
Alireza Nasiri ◽  
Hakimeh Mahdizadeh ◽  
Seyed Mojtaba Momtaz ◽  
Mahdieh Azizian ◽  
...  

Background: Urban and industrial development has increased the concentration of heavy metals in various environments, and also, increased their amount in dust fall particles. The aim of this study was to determine and assess the risk of heavy metals in air dust fall particles. Methods: Sampling of air dust fall particles was performed using the British model Dust Fall Jar devices. Heavy metals concentrations in the samples were determined using an atomic absorption spectrometer device. Then, the risk assessment of heavy metals in air dust fall was calculated by three indicators including enrichment factor (EF), geo-accumulation index (Igeo), and integrated pollution index (IPI). Data were analyzed using descriptive statistics and Excel 2016 software. Results: Zn was the most abundant heavy metal. The results of EF index showed that the highest degree of enrichment of dust fall particles with heavy metals is related to Ag and the lowest one is related to Cr. Also, the changes of Mean of both Igeo and IP indicators were as Ag > Pb > Zn > Cd > Cu > Co > Cr. Conclusion: According to the results, it can be concluded that Cr metal is originated from the earth and other metals are of man-made origin and are mainly due to the emissions of vehicles and industries. Also, on average, the samples had very low pollution in relation to all metals. Although the amount of pollution caused by heavy metals has not exceeded the allowable limits, but considering industrial development programs in the region, continuous measures to control air pollution caused by industries, are absolutely necessary.


2021 ◽  
Vol 15 (3) ◽  
pp. 1249-1263
Author(s):  
O.B.M. Lucinde Bocodaho ◽  
Waris Kéwouyèmi Chouti ◽  
R. Arthur Cakpo ◽  
Daouda Mama

The uncontrollable population growth is reaching Benin's rivers, especially the coastal lagoon, raising then the thorny problem of pollution, which is considerably accentuated by the malevolent behavior of the populations. The aim of this paper is to characterize the degree of contamination of the water and sediments of the lagoon in heavy metals (Cd, Cr, Zn, Cu, Pb and Fe) through the dosage with the molecular absorption spectrophotometer type DR 3900. At the same time, a cytotoxicity test with Allium cepa will be carried out in order to evaluate the toxic potential of the pollutants responsible for the degradation of the lagoon. The Cd, Cu and Zn contents in the water and sediments far exceed the accepted standards at almost all the stations. The Pollution Index (PI) and geo-accumulation index (Igeo) indicate the existence of polymetallic pollution in the sediments, which is extremely strong and dominated in order to decrease abundance by: Cd>Zn>Cu>Pb. The results of the cytotoxicity test highlight acute toxicity on 82% of the stations surveyed. The poor states of the coastal lagoon indexed by this study, impose the application of urgent measures of participative management, preservation and sanitation of the coastal zone


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