scholarly journals Микровзрывная фрагментация группы неоднородных капель топлив

2020 ◽  
Vol 46 (10) ◽  
pp. 14
Author(s):  
Д.В. Антонов ◽  
П.А. Стрижак ◽  
Р.М. Федоренко
Keyword(s):  
High Temperature ◽  
Experimental Studies ◽  
Mutual Arrangement ◽  
Muffle Furnace ◽  
Delay Times ◽  
Two Component ◽  
Integral Characteristics ◽  
Explosive Fragmentation ◽  
Explosion Delay ◽  
Single Droplets

The results of experimental studies of the processes of micro-explosive fragmentation of two-component (diesel fuel – water) droplets upon heating in a high-temperature medium are presented. The experiments were carried out with a group of 10-30 falling drops in a tubular muffle furnace. Micro-explosion delay times are studied. It was shown that the mutual arrangement of the droplet group significantly affects the integral characteristics of the investigated process. Limit distances (from 8 to 10 radii) between the droplets are established at which the characteristics of the micro-explosion are similar to those recorded in experiments with single droplets.

A UNIQUE FINDING OF ZIRCON INTO BADDELEYITE TRANSFORMATION (THE ICHETJU ORE OCCURRENCE, THE MIDDLE TIMAN)

2018 ◽  
pp. 27-35
Author(s):  
S. G. Skublov ◽  
A. O. Krasotkina ◽  
A. B. Makeyev ◽  
O. L. Galankina ◽  
A. E. Melnik
Keyword(s):  
High Temperature ◽  
Experimental Studies ◽  
Middle Timan ◽  
Natural Analogues ◽  
Opposite Situation ◽  
Formation Conditions

Findings of the growth relationships between baddeleyite and zircon are rare, due to significant differences in the formation conditions of the minerals. A reaction replacement (partial to complete) of baddeleyite by zircon is possible during metamorphism accompanied by the interaction with high-Si fluids. The opposite situation, when zircon is replaced by baddeleyite, is extremely rare in the nature. Transformation of zircon from polymineral (compound) ore occurrence Ichetju (the Middle Timan) with the formation of microaggregates of baddeleyite, ratile and florencite has been found out. The size of the largest segregations of baddeleyite does not exceed 10 microns in diameter. Microaggregates are unevenly related to the rim of zircon with a thickness of 10 to 50 rfn, voids and cracks across the grain. Altered zircon rim (a mixture of newly formed minerals) is characterized by sharply increased composition of REE (especially LREE), Y, Nb, Ca, Ti. The composition of Th and U also increases. An overview of the experimental studies on the reaction between zircon and baddeleyite and single natural analogues allows to make a conclusion that the most likely mechanism of the transformation of zircon from ore occurrence Ichetju to baddeleyite (intergrowth with ratile and florencite) is due to the effect of interaction of primary zircon with high-temperature (higher than 500—600°C) alkaline fluids transporting HFSE (REE, Y, Nb, Ti). This is indirectly confirmed by the findings of zircon with anomalous high composition of Y and REE up to 100000 and 70000 ppm respectively.

scholarly journals The intimate relationship between structural relaxation and the energy landscape of monatomic liquid metals

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Franz Demmel ◽  
Louis Hennet ◽  
Noel Jakse
Keyword(s):  
High Temperature ◽  
Velocity Field ◽  
Liquid State ◽  
Liquid Metals ◽  
Energy Landscape ◽  
Experimental Studies ◽  
Transport Parameter ◽  
Arrhenius Behavior ◽  
Liquid Aluminium ◽  
Potential Energy Landscape

AbstractThe characteristic property of a liquid, discriminating it from a solid, is its fluidity, which can be expressed by a velocity field. The reaction of the velocity field on forces is enshrined in the transport parameter viscosity. In contrast, a solid reacts to forces elastically through a displacement field, the particles are trapped in their potential minimum. The flow in a liquid needs enough thermal energy to overcome the changing potential barriers, which is supported through a continuous rearrangement of surrounding particles. Cooling a liquid will decrease the fluidity of a particle and the mobility of the neighbouring particles, resulting in an increase of the viscosity until the system comes to an arrest. This process with a concomitant slowing down of collective particle rearrangements might already start deep inside the liquid state. The idea of the potential energy landscape provides an attractive picture for these dramatic changes. However, despite the appealing idea there is a scarcity of quantitative assessments, in particular, when it comes to experimental studies. Here we present results on a monatomic liquid metal through a combination of ab initio molecular dynamics, neutron spectroscopy and inelastic x-ray scattering. We investigated the collective dynamics of liquid aluminium to reveal the changes in dynamics when the high temperature liquid is cooled towards solidification. The results demonstrate the main signatures of the energy landscape picture, a reduction in the internal atomic structural energy, a transition to a stretched relaxation process and a deviation from the high-temperature Arrhenius behavior of the relaxation time. All changes occur in the same temperature range at about $$1.4 \cdot T_{melting}$$ 1.4 · T melting , which can be regarded as the temperature when the liquid aluminium enters the landscape influenced phase and enters a more viscous liquid state towards solidification. The similarity in dynamics with other monatomic liquid metals suggests a universal dynamic crossover above the melting point.

High-Entropy Ultra-High-Temperature Borides and Carbides: A New Class of Materials for Extreme Environments

2021 ◽  
Vol 51 (1) ◽  
Author(s):  
Lun Feng ◽  
William G. Fahrenholtz ◽  
Donald W. Brenner
Keyword(s):  
High Temperature ◽  
Extreme Environments ◽  
Experimental Studies ◽  
Heat Fluxes ◽  
Annual Review ◽  
Publication Date ◽  
Structure Property ◽  
High Entropy ◽  
Ultra High Temperature Ceramics ◽  
Ultra High Temperature

Herein, we critically evaluate computational and experimental studies in the emerging field of high-entropy ultra-high-temperature ceramics. High-entropy ultra-high-temperature ceramics are candidates for use in extreme environments that include temperatures over 2,000°C, heat fluxes of hundreds of watts per square centimeter, or irradiation from neutrons with energies of several megaelectron volts. Computational studies have been used to predict the ability to synthesize stable high-entropy materials as well as the resulting properties but face challenges such asthe number and complexity of unique bonding environments that are possible for these compositionally complex compounds. Experimental studies have synthesized and densified a large number of different high-entropy borides and carbides, but no systematic studies of composition-structure-property relationships have been completed. Overall, this emerging field presents a number of exciting research challenges and numerous opportunities for future studies. Expected final online publication date for the Annual Review of Materials Science, Volume 51 is July 2021. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.

Expanding Polymer Injectivity Tests on a Second Giant Carbonate UAE Oil Reservoir at High Salinity & High Temperature Conditions.

2021 ◽  
Author(s):  
S.A. Baloch ◽  
J.M. Leon ◽  
S.K. Masalmeh ◽  
D. Chappell ◽  
J. Brodie ◽  
...  
Keyword(s):  
High Temperature ◽  
Polymer Solution ◽  
High Salinity ◽  
Laboratory Data ◽  
Experimental Studies ◽  
Carbonate Reservoirs ◽  
Field Conditions ◽  
Sweep Efficiency ◽  
Tertiary Butyl ◽  
Solution Preparation

Abstract Over the last few years, ADNOC has systematically investigated a new polymer-based EOR scheme to improve sweep efficiency in high temperature and high salinity (HTHS) carbonate reservoirs in Abu Dhabi (Masalmeh et al., 2014). Consequently, ADNOC has developed a thorough de-risking program for the new EOR concept in these carbonate reservoirs. The de-risking program includes extensive laboratory experimental studies and field injectivity tests to ensure that the selected polymer can be propagated in the target reservoirs. A new polymer with high 2-acrylamido-tertiary-butyl sulfonic acid (ATBS) content was identified, based on extensive laboratory studies (Masalmeh, et al., 2019, Dupuis, et al., 2017, Jouenne 2020), and an initial polymer injectivity test (PIT) was conducted in 2019 at 250°F and salinity >200,000 ppm, with low H2S content (Rachapudi, et al., 2020, Leon and Masalmeh, 2021). The next step for ADNOC was to extend polymer application to harsher field conditions, including higher H2S content. Accordingly, a PIT was designed in preparation for a multi-well pilot This paper presents ADNOC's follow-up PIT, which expands the envelope of polymer flooding to dissolve H2S concentrations of 20 - 40 ppm to confirm injectivity at representative field conditions and in situ polymer performance. The PIT was executed over five months, from February 2021 to July 2021, followed by a chase water flood that will run until December 2021. A total of 108,392 barrels of polymer solution were successfully injected during the PIT. The extensive dataset acquired was used to assess injectivity and in-depth mobility reduction associated with the new polymer. Preliminary results from the PIT suggest that all key performance indicators have been achieved, with a predictable viscosity yield and good injectivity at target rates, consistent with the laboratory data. The use of a down-hole shut-in tool (DHSIT) to acquire pressure fall-off (PFO) data clarified the near-wellbore behaviour of the polymer and allowed optimisation of the PIT programme. This paper assesses the importance of water quality on polymer solution preparation and injection performance and reviews operational data acquired during the testing period. Polymer properties determined during the PIT will be used to optimise field and sector models and will facilitate the evaluation of polymer EOR in other giant, heterogeneous carbonate reservoirs, leading to improved recovery in ADNOC and Middle East reservoirs.

Experimental and Numerical Analysis of Mixing Process of Two Component Gases in a Vertical Fluid Layer in a VHTR

2019 ◽  
Vol 5 (2) ◽  
Author(s):  
Tetsuaki Takeda
Keyword(s):  
High Temperature ◽  
Natural Convection ◽  
Numerical Analysis ◽  
Pressure Vessel ◽  
Storage Tank ◽  
Molecular Diffusion ◽  
Flow Characteristics ◽  
Mixing Process ◽  
Two Component ◽  
Air Ingress

When a depressurization accident of a very-high-temperature reactor (VHTR) occurs, air is expected to enter into the reactor pressure vessel from the breach and oxidize in-core graphite structures. Therefore, in order to predict or analyze the air ingress phenomena during a depressurization accident, it is important to develop a method for the prevention of air ingress during an accident. In particular, it is also important to examine the influence of localized natural convection and molecular diffusion on the mixing process from a safety viewpoint. Experiment and numerical analysis using a three-dimensional (3D) computational fluid dynamics code have been carried out to obtain the mixing process of two-component gases and the flow characteristics of localized natural convection. The numerical model consists of a storage tank and a reverse U-shaped vertical rectangular passage. One sidewall of the high-temperature side vertical passage is heated, and the other sidewall is cooled. The low-temperature vertical passage is cooled by ambient air. The storage tank is filled with heavy gas and the reverse U-shaped vertical passage is filled with a light gas. The result obtained from the 3D numerical analysis was in agreement with the experimental result quantitatively. The two component gases were mixed via molecular diffusion and natural convection. After some time elapsed, natural circulation occurred through the reverse U-shaped vertical passage. These flow characteristics are the same as those of phenomena generated in the passage between a permanent reflector and a pressure vessel wall of the VHTR.

Formation of coagulated colloidal silica in high-temperature mineralizing fluids

2002 ◽  
Vol 66 (4) ◽  
pp. 547-553 ◽  
Author(s):  
B. J. Williamson ◽  
J. J. Wilkinson ◽  
P. F. Luckham ◽  
C. J. Stanley
Keyword(s):  
High Temperature ◽  
Hydrothermal Fluid ◽  
Colloidal Silica ◽  
Fluid Transport ◽  
Experimental Studies ◽  
Hydrothermal Fluids ◽  
Ore Formation ◽  
Colloidal Gel ◽  
Material Forming ◽  
Mineralizing Fluids

AbstractRecent experimental studies have suggested that colloidal silica can form in high-T (300 to >700°C) hydrothermal fluids (Wilkinson et al., 1996). Natural evidence in support of this was found by Williamson et al. (1997) who proposed a colloidal (gel) silica origin for <50 μm irregularly-shaped inclusions of quartz contained in greisen topaz from southwest England. Confocal and microprobe studies, presented here, strengthen this argument although rather than forming a gel in the hydrothermal fluid, it is suggested that the colloidal silica aggregated as a viscous coagulated colloid, with much of its volume (<10 to 30 vol.%) consisting of metal (mainly Fe) -rich particles. This is evident from the largely solid nature of metal-rich shrinkage bubbles contained at the margins of the inclusions of quartz which shows that the material forming the inclusions contained much less liquid than would be expected in a silica gel. These findings may have important implications for models of ore formation since the precipitation of a coagulated colloid could inhibit hydrothermal fluid transport and cause co-deposition of silica and entrained ore-forming elements. The mode of formation of the colloidal silica and further implications of the study are discussed.

scholarly journals Equilibrium modeling of mono and binary sorption of Cu(II) and Zn(II) onto chitosan gel beads

2016 ◽  
Vol 37 (4) ◽  
pp. 485-501 ◽  
Author(s):  
Józef Nastaj ◽  
Małgorzata Tuligłowicz ◽  
Konrad Witkiewicz
Keyword(s):  
Metal Ion ◽  
Ph Value ◽  
Experimental Studies ◽  
Process Conditions ◽  
Optimal Process ◽  
Sorption Data ◽  
Gel Beads ◽  
Two Component ◽  
Equilibrium Data ◽  
Chitosan Gel

Abstract The objective of the work are in-depth experimental studies of Cu(II) and Zn(II) ion removal on chitosan gel beads from both one- and two-component water solutions at the temperature of 303 K. The optimal process conditions such as: pH value, dose of sorbent and contact time were determined. Based on the optimal process conditions, equilibrium and kinetic studies were carried out. The maximum sorption capacities equaled: 191.25 mg/g and 142.88 mg/g for Cu(II) and Zn(II) ions respectively, when the sorbent dose was 10 g/L and the pH of a solution was 5.0 for both heavy metal ions. One-component sorption equilibrium data were successfully presented for six of the most useful three-parameter equilibrium models: Langmuir-Freundlich, Redlich-Peterson, Sips, Koble-Corrigan, Hill and Toth. Extended forms of Langmuir-Freundlich, Koble-Corrigan and Sips models were also well fitted to the two-component equilibrium data obtained for different ratios of concentrations of Cu(II) and Zn(II) ions (1:1, 1:2, 2:1). Experimental sorption data were described by two kinetic models of the pseudo-first and pseudo-second order. Furthermore, an attempt to explain the mechanisms of the divalent metal ion sorption process on chitosan gel beads was undertaken.

scholarly journals Near-Wake Observations behind Azimuthally Perforated Disks With Varying Hole Layout and Porosity in Smooth Airstreams at High Reynolds Numbers

2018 ◽  
Vol 141 (5) ◽  
Author(s):  
Raf Theunissen ◽  
Robert Worboys
Keyword(s):  
Drag Coefficient ◽  
Experimental Studies ◽  
Reynolds Numbers ◽  
Wake Flow ◽  
Mean Flow ◽  
Flow Topology ◽  
Near Wake ◽  
Two Component ◽  
High Reynolds ◽  
Component Particle

Porous disks are commonly encountered in experimental studies dealing with flow through objects such as wind turbines, parachutes, and fluidic devices to regulate pressure and/or downstream turbulence. Perforations are typically staggered and only porosity is altered to attain the required disk drag coefficient, despite a documented influence of topology. Few works have reported, however, to which extent the spatial distribution of the circular perforations affect the mean flow pertaining freestanding disks, and for this reason, this work presents a first, more systematic study focused on the effect of azimuthally varying hole topology and porosity on disk drag and near-wake characteristics. An experimental study performed in airflows of negligible freestream turbulence at Reynolds numbers in the order of 105 is reported and related to the existing literature to ensure reliability. Complementary to drag measurements, near-wake surveys have been performed on a variety of perforation layouts using two-component laser Doppler velocimetry and two-component particle image velocimetry. It is shown that minor changes in perforations can cause drastic changes in near-wake flow topology and no perforation layout can be consistently associated with highest drag. Explicit empirical expressions for drag coefficient linked with the simplified topologies considered have been derived.

scholarly journals High-temperature multilevel sterilization of canned goods with heat recovery and its constructive and technological support

2021 ◽  
Vol 247 ◽  
pp. 01030
Author(s):  
Mafiiat Rakhmanova ◽  
Amiiat Demirova ◽  
Magomed Akhmedov ◽  
Faina Azimova ◽  
Irada Gadzhibekova ◽  
...  
Keyword(s):  
Heat Treatment ◽  
High Temperature ◽  
Heat Recovery ◽  
Experimental Studies ◽  
Cooling Water ◽  
Practical Implementation ◽  
Canned Food ◽  
Significant Saving ◽  
Technological Support ◽  
Thermal Sterilization

New technical solutions improving the process of thermal sterilization of canned products through the use of multilevel high-temperature modes and heat recovery have been considered and proposed. The essence of the developed method lies in the fact that the heat released by cooling cans with the product that has undergone thermal sterilization is used to heat other cans with the product queued for sterilization. In this mode of heat treatment, except in the last stage, the heat emitted by cooled cans that have already undergone heat treatment is used to heat up the canned food. Hence, the use of the principle of heat recovery by cooling canned products in the baths where others are simultaneously heated provides a significant saving of heat energy and water. Depending on the temperature parameters at different stages of the heat treatment, the heat recovery rate can reach up to 90%. The method also provides savings on cooling water. For the practical implementation of the developed method, the design of the device for multilevel high-temperature thermal sterilization of canned food with heat recovery has been developed. On the basis of experimental studies, new, multilevel high-temperature modes of apple compote sterilization have been developed.

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