scholarly journals Quality parameters and pattern recognition methods as a tool in tracing regional origin of multifloral honey

2013 ◽  
Vol 78 (12) ◽  
pp. 1875-1892 ◽  
Author(s):  
Kristina Lazarevic ◽  
Jelena Trifkovic ◽  
Filip Andric ◽  
Zivoslav Tesic ◽  
Ivan Andjelkovic ◽  
...  

The characterization of multifloral honey regarding the mineral composition, sugar content and basic physicochemical properties has been done. The total of 164 honey samples was collected from six regions of Serbia during 2009 harvesting season. Univariate data analysis (descriptive statistics and analysis of variance), geographic information system and pattern recognition methods (principal component analysis and cluster analysis) have been performed in order to identify geographical origin of honey. The content of Mg, K, and Cu, electrical conductivity, and optical rotation were established as useful indicators in tracing regional differences between honey samples. Samples originated from Zlatibor region were clearly distinguished from those from the rest of Serbia showing higher K and Mg content, as well as higher values of optical rotation, electrical conductivity, and free acidity. The influence of the soil composition, and climate conditions, as well as the presence of particular flora on the honey composition is stressed out. The modeling of geographic origin of honey has been attempted by the means of linear discriminant analysis.

2014 ◽  
Vol 9 (11) ◽  
pp. 1934578X1400901 ◽  
Author(s):  
Cristina Truzzi ◽  
Silvia Illuminati ◽  
Anna Annibaldi ◽  
Carolina Finale ◽  
Monica Rossetti ◽  
...  

The purpose of this study was the physicochemical characterization and classification of Italian honey from Marche Region with a chemometric approach. A total of 135 honeys of different botanical origins [acacia ( Robinia pseudoacacia L.), chestnut ( Castanea sativa), coriander ( Coriandrum sativum L.), lime ( Tilia spp.), sunflower ( Helianthus annuus L.), Metcalfa honeydew and multifloral honey] were considered. The average results of electrical conductivity (0.14 – 1.45 mS cm−1), pH (3.89 – 5.42), free acidity (10.9 – 39.0 meqNaOH kg−1), lactones (2.4 – 4.5 meqNaOH kg−1), total acidity (14.5 – 40.9 meqNaOH kg−1), proline (229–665 mg kg−1) and 5-(hydroxy-methyl)-2-furaldehyde (0.6–3.9 mg kg−1) content show wide variability among the analysed honey types, with statistically significant differences between the different honey types. Pattern recognition methods such as principal component analysis and discriminant analysis were performed in order to find a relationship between variables and types of honey and to classify honey on the basis of its physicochemical properties. The variables of electrical conductivity, acidity (free, lactones), pH and proline content exhibited higher discriminant power and provided enough information for the classification and distinction of unifloral honey types, but not for the classification of multifloral honey (100% and 85% of samples correctly classified, respectively).


2011 ◽  
Vol 26 (1) ◽  
pp. 69-78 ◽  
Author(s):  
Saravanan Dharmaraj ◽  
Lay-Harn Gam ◽  
Shaida Fariza Sulaiman ◽  
Sharif Mahsufi Mansor ◽  
Zhari Ismail

FTIR spectroscopy was used together with multivariate analysis to distinguish six different species ofPhyllanthus. Among these speciesP. niruri,P. debilisandP. urinariaare morphologically similar whereasP. acidus,P. emblicaandP. myrtifoliusare different. The FTIR spectrometer was used to obtain the mid-infrared spectra of the dried powdered leaves in the region of 400–4000 cm−1. The region of 400–2000 cm−1was analyzed with four different pattern recognition methods. Initially, principal component analysis (PCA) was used to reduce the spectra to six principal components and these variables were used for linear discriminant analysis (LDA). The second technique used LDA on most discriminating wavenumber variables as searched by genetic algorithm using canonical variate approach for either 30 or 60 generations. SIMCA, which consisted of constructing an enclosure for each species using separate principal component models, was the third technique. Finally, multi-layer neural network with batch mode of backpropagation learning was used to classify the samples. The best results were obtained with GA of 60 gens. When LDA was run with the six wavenumbers chosen (1151, 1578, 1134, 609, 876 and 1227), 100% of the calibration spectra and 96.3% of the validation spectra were correctly assigned.


2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Hao Zhang ◽  
Haifeng Sun ◽  
Ling Wang ◽  
Shun Wang ◽  
Wei Zhang ◽  
...  

The aim of this work is to identify the adulteration of edible gelatin using near-infrared (NIR) spectroscopy combined with supervised pattern recognition methods. The spectral data obtained from a total of 144 samples consisting of six kinds of adulterated gelatin gels with different mixture ratios were processed with multiplicative scatter correction (MSC), Savitzky–Golay (SG) smoothing, and min-max normalization. Principal component analysis (PCA) was first carried out for spectral analysis, while the six gelatin categories could not be clearly distinguished. Further, linear discriminant analysis (LDA), soft independent modelling of class analogy (SIMCA), backpropagation neural network (BPNN), and support vector machine (SVM) were introduced to establish discrimination models for identifying the adulterated gelatin gels, which gave a total correct recognition rate of 97.44%, 100%, 97.44%, and 100%, respectively. For the SIMCA model with significant level α = 0.05, sample overlapping clustering appeared; thus, the SVM model presents the best recognition ability among these four discrimination models for the classification of edible gelatin adulteration. The results demonstrate that NIR spectroscopy combined with unsupervised pattern recognition methods can quickly and accurately identify edible gelatin with different adulteration levels, providing a new possibility for the detection of industrial gelatin illegally added into food products.


2017 ◽  
Vol 60 (4) ◽  
pp. 1037-1044
Author(s):  
Zhenbo Wei ◽  
Yu Zhao ◽  
Jun Wang

Abstract. In this study, a potentiometric E-tongue was employed for comprehensive evaluation of water quality and goldfish population with the help of pattern recognition methods. Four water quality parameters, i.e., pH and concentrations of dissolved oxygen (DO), nitrite (NO2-N), and ammonium (NH3-N), were tested by conventional analysis methods. The differences in water quality parameters between samples were revealed by two-way analysis of variance (ANOVA). The cultivation days and goldfish population were classified well by principal component analysis (PCA) and canonical discriminant analysis (CDA), and the distribution of each sample was clearer in CDA score plots than in PCA score plots. The cultivation days, goldfish population, and water parameters were predicted by a T-S fuzzy neural network (TSFNN) and back-propagation artificial neural network (BPANN). BPANN performed better than TSFNN in the prediction, and all fitting correlation coefficients were >0.90. The results indicated that the potentiometric E-tongue coupled with pattern recognition methods could be applied as a rapid method for the determination and evaluation of water quality and goldfish population. Keywords: Classify, E-tongue, Goldfish water, Prediction.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Mihaela Emanuela Crăciun ◽  
Oana Cristina Pârvulescu ◽  
Andreea Cristina Donise ◽  
Tănase Dobre ◽  
Dumitru Radu Stanciu

AbstractThree groups of Romanian acacia honey, i.e., pure, directly adulterated (by mixing the pure honey with three sugar syrups), and indirectly adulterated (by feeding the bees with the same syrups), were characterized and discriminated based on their physicochemical parameters. Moisture, ash, 5-hydroxymethylfurfural (HMF), reducing sugars (fructose and glucose), and sucrose contents, free acidity, diastase activity, ratio between stable carbon isotopes of honey and its proteins (δ13CH and δ13CP) were evaluated. Adulteration led to a significant increase in sucrose content, HMF level, and Δδ13C = δ13CH‒δ13CP as well a decrease in reducing sugar content and diastase activity. Principal component analysis (PCA) and linear discriminant analysis (LDA) were applied to experimental data in order to distinguish between pure and adulterated honey. The most relevant discriminative parameters were diastase activity, HMF, sucrose, and reducing sugar contents. Posterior classification probabilities and classification functions obtained by LDA revealed that 100% of honey samples were correctly assigned to their original group.


1982 ◽  
Vol 4 (4) ◽  
pp. 378-396 ◽  
Author(s):  
Morris S. Good ◽  
Joseph L. Rose ◽  
Barry B. Goldberg

Ultrasonic pulse-echo rf waveform analysis and selected pattern recognition methods were applied to classification of breast tissue. Emphasis was placed on the classification of solid tissue areas since fluid areas are easily identified by present B-scan techniques. Pattern recognition techniques such as the Fisher Linear Discriminant (FLD), Probability Density Function (PDF) curves, jackknife estimate and committee vote were used to construct and evaluate a two class algorithm, malignant versus benign tissue areas. A data base consisting of frequency domain features from 100 pathologically confirmed tissue areas from 87 patients were used to train the algorithm. Algorithm performance was acquired via the generalized jackknife procedure to significantly reduce the bias frequently encountered in algorithm evaluation. Estimated values of algorithm performance are sensitivity and specificity values of 96 percent and 68 percent, respectively.


Foods ◽  
2021 ◽  
Vol 10 (10) ◽  
pp. 2270
Author(s):  
Linxia Wu ◽  
Ling Li ◽  
Guoguang Zhang ◽  
Nan Jiang ◽  
Xihui Ouyang ◽  
...  

Chinese jujube fruits are known for their high nutritional and functional values. To protect advantageous regional jujube fruits, it is important to monitor quality indicators and trace the origin and variety. In this study, 31 quality indicators of Chinese jujubes collected from 6 main producing areas were determined. According to different origins and varieties, Chinese jujube fruits were divided into five and six categories, respectively. To simplify the parameters, eight of the main characteristics, namely, soluble sugar content, fresh mass, edible rate, Na, Mg, K, Zn, and cyclic adenosine monophosphate (cAMP), were screened based on multiple comparison, correlation analysis, and principal component analysis (PCA). According to the eight main parameters, it was found that that both the categorical and cross-validated classification accuracy of linear discriminant analysis (LDA) were 100%. The discrimination accuracy of the testing set samples based on the orthogonal partial least squares-discriminant analysis (OPLS-DA) model were 90 and 93% for geographical and varietal classification, respectively. This indicated that the eight main parameters could be used as the characteristic parameters for the origin and variety traceability of Chinese jujubes.


Author(s):  
Wenshen Jia ◽  
Gang Liang ◽  
Hui Tian ◽  
Jing Sun ◽  
Cihui Wan

In this paper, PEN3 electronic nose was used to detect and recognize fresh and moldy apples (inoculated with Penicillium expansum and Aspergillusniger) taken Golden Delicious apples as model subject. Firstly, the apples were divided into two groups: apples only inoculated with different molds (Group A) and mixed apples of inoculated apples with fresh apples (Group B). Then the characteristic gas sensors of the PEN3 electronic nose that were most closely correlated with the flavor information of the moldy apples were optimized and determined, which can simplify the analysis process and improve the accuracy of results. Four pattern recognition methods, including linear discriminant analysis (LDA), backpropagation neural network (BPNN), support vector machines (SVM) and radial basis function neural network (RBFNN), were then applied to analyze the data obtained from the characteristic sensors, respectively, aiming at establishing the prediction model of flavor information and fresh/moldy apples. The results showed that only the gas sensors of W1S, W2S, W5S, W1W and W2W in the PEN3 electronic nose exhibited strong signal response to the flavor information, indicating were most closely correlated with the characteristic flavor of apples and thus the data obtained from these characteristic sensors was used for modeling. The results of the four pattern recognition methods showed that BPNN presented the best prediction performance for the training and validation sets for both the Group A and Group B, with prediction accuracies of 96.29% and 90.00% (Group A), 77.70% and 72.00% (Group B), respectively. Therefore, it first demonstrated that PEN3 electronic nose can not only effectively detect and recognize the fresh and moldy apples, but also can distinguish apples inoculated with different molds.


2014 ◽  
pp. 61-67
Author(s):  
A. Amari ◽  
N. El Bari ◽  
B. Bouchikhi

An electronic nose based system, which employs an array of six inexpensive commercial gas sensors based on tin dioxide (Figaro Engineering Inc., Japan), has been used to analyse the freshness states of anchovies. Fresh anchovies were stored in a refrigerator at 4 ± 1°C over a period of 15 days. Electronic nose measurements need no sample preparation and the results indicated that the spoilage process of anchovies could be followed by using this technique. Conductance responses of volatile compounds produced during storage of anchovy were monitored and the result were analysed by multivariate analysis methods. In this paper principal component analysis (PCA) and linear discriminant analysis (LDA) were used to investigate whether the electronic nose was able to distinguishing among different freshness states (fresh, moderated and non-fresh samples). The loadings analysis was used to identify the sensors responsible for discrimination in the current pattern file. Therefore, the support vector machines (SVM) method was applied to the new subset, with only the selected sensors, to confirm that a subset of a few sensors can be chosen to explain all the variance. The results obtained prove that the electronic nose can discriminate successfully different freshness state using LDA analysis. Some sensors have the highest influence in the current pattern file for electronic nose. Support vector machine (SVM) model, applied to the new subset of sensors show the good performance.


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