scholarly journals Hydrogen Embrittlement of High Strength Steels in High Pressure Hydrogen Gas at Ambient Temperature

1978 ◽  
Vol 64 (7) ◽  
pp. 899-905 ◽  
Author(s):  
Shigeharu HINOTANI ◽  
Fukunaga TERASAKI ◽  
Keizo TAKAHASHI
Keyword(s):  
High Pressure ◽  
Hydrogen Embrittlement ◽  
Ambient Temperature ◽  
High Strength Steels ◽  
High Strength ◽  
Hydrogen Gas ◽  
Pressure Hydrogen

Evaluation of Hydrogen Embrittlement of Cr-Mo Low Alloy Steel by Slow Strain Rate Technique With Cathodically Charged Specimen

2017 ◽  
Author(s):  
Daichi Tsurumi ◽  
Hiroyuki Saito ◽  
Hirokazu Tsuji
Keyword(s):  
High Pressure ◽  
Hydrogen Embrittlement ◽  
Fracture Surface ◽  
Strain Rate ◽  
Current Density ◽  
Cleavage Fracture ◽  
Hydrogen Gas ◽  
Low Alloy Steel ◽  
Slow Strain Rate Technique ◽  
Pressure Hydrogen

As an alternative method to slow strain rate technique (SSRT) under high-pressure hydrogen gas evaluation, SSRT was performed with a cathodically charged specimen. Cr-Mo low alloy steel with a tensile strength of 1000 MPa grade was selected as a test material. Cathodic charging was performed in 3% NaCl solution and at a current density in the range of 50–600 A/m2. The effect of specimen size on the hydrogen embrittlement properties was evaluated. Relative reduction of area (RRA) values obtained by tests at a cathode current density of 400 A/m2 were equivalent to those performed in hydrogen gas at pressures of 10 to 35 MPa. Fracture surface observations were also performed using scanning electron microscopy (SEM). The quasi-cleavage fracture surface was observed only after rupture of small specimens that were subjected to hydrogen charged tests. It was also necessary for the diameter of the specimen to be small to form the quasi-cleavage fracture surface. The results indicated that to simulate the high-pressure hydrogen gas test, a specimen with a smaller parallel section diameter that is continuously charged until rupture is preferable.

Hydrogen Compatibility and Suitability of (Ni)-Cr-Mo High-Strength Low-Alloy Seamless Line Pipe Steels for Pressure Vessels for Hydrogen Storage

2018 ◽  
Author(s):  
Akihide Nagao ◽  
Nobuyuki Ishikawa ◽  
Toshio Takano
Keyword(s):  
Mechanical Properties ◽  
High Pressure ◽  
High Strength ◽  
Pressure Vessels ◽  
Hydrogen Gas ◽  
Low Alloy Steels ◽  
Pipe Steels ◽  
Line Pipe ◽  
Alloy Steels ◽  
Pressure Hydrogen

Cr-Mo and Ni-Cr-Mo high-strength low-alloy steels are candidate materials for the storage of high-pressure hydrogen gas. Forging materials of these steels have been used for such an environment, while there has been a strong demand for a higher performance material with high resistance to hydrogen embrittlement at lower cost. Thus, mechanical properties of Cr-Mo and Ni-Cr-Mo steels made of quenched and tempered seamless pipes in high-pressure hydrogen gas up to 105 MPa were examined in this study. The mechanical properties were deteriorated in the presence of hydrogen that appeared in reduction in local elongation, decrease in fracture toughness and accelerated fatigue-crack growth rate, although the presence of hydrogen did not affect yield and ultimate tensile strengths and made little difference to the fatigue endurance limit. It is proposed that pressure vessels for the storage of gaseous hydrogen made of these seamless line pipe steels can be designed.

Mechanical Properties of a New Nitrogen-Strengthened Stainless Steel With Reduced Amount of Ni and Mo in High Pressure Gaseous Hydrogen

2013 ◽  
Author(s):  
Kazuhisa Matsumoto ◽  
Shinichi Ohmiya ◽  
Hideki Fujii ◽  
Masaharu Hatano
Keyword(s):  
High Pressure ◽  
Stainless Steel ◽  
Fatigue Crack ◽  
Fatigue Crack Growth ◽  
Crack Growth ◽  
High Strength ◽  
Hydrogen Gas ◽  
Fracture Surfaces ◽  
Growth Properties ◽  
Pressure Hydrogen

To confirm a compatibility of a newly developed high strength stainless steel “NSSC STH®2” for hydrogen related applications, tensile and fatigue crack growth properties were evaluated in high pressure hydrogen gas up to 90MPa. At temperatures between −40 and 85°C, no conspicuous deterioration of tensile properties including ductility was observed even in 90 MPa hydrogen gas at −40°C while strength of STH®2 was higher than SUS316L. Although a slight drop of reduction of area was recognized in one specimen tested in 90 MPa hydrogen gas at −40°C, caused by the segregation of Mn, Ni and Cu in the laboratory manufactured 15mm-thick plate, it was considerably improved in the large mill products having less segregation. Fatigue crack growth rates of STH®2 in high pressure hydrogen gas were almost the same as that of SUS316L in air. Although fatigue crack growth rate in air was considerably decelerated and lower than that in hydrogen gas at lower ΔK region, this was probably caused by crack closure brought by oxide debris formed on the fracture surfaces near the crack tip by the strong contact of the fracture surfaces after the fatigue crack was propagated. By taking the obtained results into account, it is concluded that NSSC STH®2 has excellent properties in high pressure hydrogen gas in addition to high strength compared with standard JIS SUS316L.

Effect of δ-ferrite on susceptibility to hydrogen embrittlement of 304 austenitic stainless steel in high-pressure hydrogen atmosphere

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Fan Bao ◽  
Kaiyu Zhang ◽  
Zhengrong Zhou ◽  
Wenli Zhang ◽  
Xiao Cai ◽  
...  
Keyword(s):  
High Pressure ◽  
Stainless Steel ◽  
Fatigue Crack ◽  
Hydrogen Embrittlement ◽  
Hydrogen Gas ◽  
304 Stainless Steel ◽  
Content Type ◽  
Gas Environment ◽  
Type 304 ◽  
Pressure Hydrogen

Purpose The purpose of this paper is to demonstrate the effect of δ-ferrite on the susceptibility to hydrogen embrittlement of type 304 stainless steel in hydrogen gas environment. Design/methodology/approach The mechanical properties of as-received and solution-treated specimens were investigated by the test of tensile and fatigue crack growth (FCG) in 5 MPa argon and hydrogen. Findings The presence of δ-ferrite reduced the relative elongation and the relative reduction area (H2/Ar) of 304 stainless steel, indicating that δ-ferrite increased the susceptibility of hydrogen embrittlement in 304 stainless steel. Moreover, δ-ferrite promoted the fatigue crack initiation and propagation at the interface between δ-ferrite and austenite. The FCG tests were used to investigate the effect of δ-ferrite on the FCG rate in hydrogen gas environment, and it was found that δ-ferrite accelerated the FCG rate, which was attributed to rapid diffusion and accumulation of hydrogen around the fatigue crack tip through δ-ferrite in high-pressure hydrogen gas environment. Originality/value The dependence of the susceptibility to hydrogen embrittlement on δ-ferrite was first investigated in type 304 steel in hydrogen environment with high pressures, which provided the basis for the design and development of a high strength, hydrogen embrittle-resistant austenitic stainless steel.

scholarly journals Susceptibility of SUS304 Steel to Hydrogen Embrittlement in High-pressure Hydrogen Gas at 250°C

2014 ◽  
Vol 63 (10) ◽  
pp. 523-527 ◽  
Author(s):  
Kenichi Koide ◽  
Takao Minami ◽  
Toshirou Anraku ◽  
Akihiro Iwase ◽  
Hiroyuki Inoue
Keyword(s):  
High Pressure ◽  
Hydrogen Embrittlement ◽  
Hydrogen Gas ◽  
Pressure Hydrogen

Mechanical Properties of High Nitrogen - High Strength Stainless Steels in High Pressure Gaseous Hydrogen Environment

2013 ◽  
Author(s):  
Jun Nakamura ◽  
Tomohiko Omura ◽  
Yusaku Tomio ◽  
Hiroyuki Hirata ◽  
Masaaki Terunuma ◽  
...  
Keyword(s):  
High Pressure ◽  
Hydrogen Embrittlement ◽  
Stainless Steels ◽  
High Strength ◽  
Hydrogen Gas ◽  
Gaseous Hydrogen ◽  
Fatigue Properties ◽  
Slow Strain Rate Test ◽  
Chemical Compositions ◽  
High Nitrogen

The susceptibility to hydrogen embrittlement and the fatigue properties of several high nitrogen stainless steels were evaluated by SSRT (Slow Strain Rate Test) and external fatigue test. The tensile properties were evaluated by SSRT in gaseous hydrogen pressurized up to 90MPa in the temperature range from −40 degree C to room temperature. Despite the increase of nitrogen content, high nitrogen stainless steels showed no degradation by hydrogen. The susceptibility to hydrogen embrittlement depended on the chemical compositions. Fatigue properties in high pressure gaseous hydrogen were evaluated by the external cyclic pressurization test using tubular specimens. In this test the tubular specimen was filled with high pressure hydrogen gas filled with hydrogen pressurized up to 90MPa, and the outside of the specimen was cyclically pressurized with water pressurized up to 90MPa. The difference of fatigue life between hydrogen and inert gas was extremely small. Susceptibility to hydrogen embrittlement was discussed based on stability of an austenitic structure.

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