scholarly journals Adsorption of anionic surfactant on surface of reservoir minerals in alkaline-surfactant-polymer system

2021 ◽  
Vol 4 (2) ◽  
pp. 124
Author(s):  
Tengku Amran Tengku Mohd ◽  
Muhammad Ikhram Abdul Wahib ◽  
Nik Khairul Irfan Nik Ab Lah ◽  
Muhammad Shafiq Mat Shayuti ◽  
Munawar Zaman Shahruddin ◽  
...  
Keyword(s):  
Sodium Dodecyl ◽  
Polymer System ◽  
Surfactant Solution ◽  
Sand Particle ◽  
Rock Surface ◽  
Surfactant Adsorption ◽  
Kaolinite Clay ◽  
Static Adsorption ◽  
Sand Particles ◽  
Alkaline Surfactant Polymer

Alkaline-surfactant-polymer (ASP) flooding is significant to the oil and gas industry due to synergistic interaction between alkaline, surfactant and polymer. However, chemical losses due to adsorptions of surfactant and polymer on the rock surface could lead to inefficiency of the process. There are also significant uncertainties on adsorption mechanism when surfactant is flooded with presence of alkaline and polymer. This study highlights the static adsorption tests using anionic sodium dodecyl sulphate (SDS), hydrolysed polyacrylamide (HPAM) and sodium carbonate (Na2CO3) as the surfactant, polymer and alkaline, respectively. Sand particles and kaolinite clay were used as the reservoir minerals. The adsorption tests were conducted at various surfactant concentrations ranging from 50 to 2000 ppm. Sodium chloride (NaCl) concentration was investigated from 0 to 2 wt.%, while the local sand and kaolinite was mixed in surfactant solution at a fixed mass to volume ratio of 1:5. The static adsorption test was conducted by shaking the mixture samples and centrifugation before analysing the supernatant liquid using UV-Visible spectrophotometer. The results showed that the surfactant adsorption was higher on kaolinite compared to sand particle. The higher the salinity, the higher the adsorption of surfactant due to higher ionic strength. The adsorption of SDS surfactant on sand particles and kaolinite was lesser in ASP system compared to the presence of surfactant solution alone. Thus, it can be concluded that the presence of polymer and alkaline in ASP solution have great potential to reduce the surfactant adsorption on both sand particle and kaolinite.

Electroacoustic Study of n-Hexadecane/Water Emulsions

2001 ◽  
Vol 54 (8) ◽  
pp. 503 ◽  
Author(s):  
Linggen Kong ◽  
James K. Beattie ◽  
Robert J. Hunter
Keyword(s):  
Particle Size ◽  
Zeta Potential ◽  
Volume Fraction ◽  
Sodium Dodecyl ◽  
Surfactant Solution ◽  
Minimum Size ◽  
Water Mixture ◽  
Concentrated Suspensions ◽  
Minimum Concentration ◽  
Median Diameter

n-Hexadecane-in-water emulsions were investigated by electroacoustics using a prototype of an AcoustoSizer-II apparatus. The emulsions were formed by passing the stirred oil/water mixture through a homogenizer in the presence of sodium dodecyl sulfate (SDS) at natural pH (6–7). With increasing oil-volume fraction, the particle size increased linearly after 5 and also after 20 passages through the homogenizer, suggesting that surface energy was determining particle size. For systems in which the surfactant concentration was limited, the particle size after 20 passages approached the value dictated by the SDS concentration. With ample surfactant present, the median diameter was a linear function of the inverse of the total energy input as measured by the number of passes. There was, however, a limit to the amount of size reduction that could be achieved in the homogenizer, and the minimum size was smaller at smaller volume fractions. Dilution of the emulsion with a surfactant solution of the same composition as the water phase had a negligible effect on the particle size and changed the zeta potential only slightly. This confirms results from previous work and validates the equations used to determine the particle size and zeta potential in concentrated suspensions. The minimum concentration of SDS that could prevent the emulsion from coalescing for the system with 6% by volume oil was 3 mM. For this dilute emulsion, the particle size decreased regularly with an increase in SDS concentration, but the magnitude of the zeta potential went through a strong maximum at intermediate surfactant concentrations.

Nanoparticles Aid Oil Recovery During Alternating Injection

2021 ◽  
Vol 73 (09) ◽  
pp. 62-63
Author(s):  
Chris Carpenter
Keyword(s):  
Oil Recovery ◽  
Sodium Dodecyl ◽  
Surfactant Solution ◽  
Volatile Oil ◽  
Technical Conference ◽  
Reservoir Rock ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Custom Made ◽  
Salinity Water

This article, written by JPT Technology Editor Chris Carpenter, contains highlights of paper SPE 201586, “Effect of Silica Nanoparticles on Oil Recovery During Alternating Injection With Low-Salinity Water and Surfactant Into Carbonate Reservoirs,” by Saheed Olawale Olayiwola, SPE, and Morteza Dejam, SPE, University of Wyoming, prepared for the 2020 SPE Annual Technical Conference and Exhibition, originally scheduled to be held in Denver, Colorado, 5–7 October. The paper has not been peer reviewed. Although the potential of nanoparticles (NPs) to improve oil recovery is promising, their effect during alternating injection is still uncertain. The main objective of the authors’ study is to investigate the best recovery mechanisms during alternating injection of NPs, low-salinity water (LSW), and surfactant and transform the results into field-scale technology. The outcome of these experiments revealed that tertiary injection of NPs results in additional oil recovery beyond the limits of LSW. Introduction A series of coreflooding experiments was conducted using several cores with an effective permeability of approximately 1 md to the brine at a temperature and pressure of 70°C and 3,000 psi. The study performs four different alternating injections of NPs with LSW and surfactant to determine optimal oil recovery. The wettability of the rock and fluid and the interfacial tension (IFT) of oil and water are measured to understand the mechanisms of interactions between the fluids and the reservoir rock. Materials A 12×12×12-in. block taken from an outcrop of Indiana limestone reservoir was purchased for this study. Four core plugs with a diameter of 1.5 in., used for the coreflooding experiments, were selected from this block. A synthetic 100,000-ppm (10 wt%) brine was prepared in the laboratory by dissolving sodium chloride (NaCl) and calcium chloride with a ratio of 4:1 in deionized water. The crude oil used in this study was a volatile oil (properties are described in Table 2 of the complete paper) obtained from the Permian Basin in Texas. Injected Fluids. A 10,000-ppm (1 wt%) LSW was prepared by diluting the synthetic brine 10 times. The surfactant solutions were prepared from an anionic sodium dodecyl sulfate (SDS) surfactant. A 1,000-ppm (0.1 wt%) surfactant solution used throughout the experiments was selected on the basis of the estimated critical micelle concentration of 600 to 2,240 ppm for SDS and nanofluid/NaCl. The concentration of silica NPs used in this study was 500 ppm (0.05 wt%). The nanofluids were pre-pared either as a simple solution or as a mixture with other chemicals to make a concentration of 500-ppm silica NPs. Coreflooding System. The established coreflooding system used for this experimental study was custom-made to determine the oil recovery and the relative permeabilities at steady-state and unsteady-state flows. However, the focus of this study is to investigate the effect of silica NPs on oil recovery. The schematic diagram of the coreflooding system is shown in Fig. 1.

Influence of Pipeline Inclination on Hydraulic Conveying of Sand Particles

2012 ◽  
Author(s):  
Ahmed Mohamed Nossair ◽  
Peter Rodgers ◽  
Afshin Goharzadeh
Keyword(s):  
Particle Transport ◽  
High Speed ◽  
Sand Dune ◽  
Sand Particle ◽  
Hydrocarbon Production ◽  
Production Wells ◽  
Load Transport ◽  
Bed Load Transport ◽  
Sand Particles ◽  
Dune Dynamics

The understanding of sand particle transport by fluids in pipelines is of importance for the drilling of horizontal and inclined hydrocarbon production wells, topside process facilities, infield pipelines, and trunk lines. Previous studies on hydraulic conveying of sand particles in pipelines have made significant contributions to the understanding of multiphase flow patterns, pressure drop and particle transport rate in horizontal pipelines. However, due to the complexity of the flow structure resulting from liquid-sand interactions, the mechanisms responsible for bed-load transport flow for hydraulic conveying of sand particles have not been extensively studied in inclined pipelines. This paper presents an experimental investigation of hydraulic conveying of sand particles resulting from a stationary flat bed in both horizontal and +3.6 degree upward inclined pipelines. The characteristics of sand transportation by saltation from an initial sand bed are experimentally visualized using a transparent Plexiglas pipeline and high-speed digital photography. The dune formation process is assessed as a function of pipeline orientation. Based on the visualized dune morphology, pipeline inclination is found to have a significant influence on hydraulic conveying of sand dune dynamics (i.e., dune velocity), as well as sand dune geometry (i.e., dune pitch and characteristic dune angles).

scholarly journals Elucidation of Antimicrobial Activity of Non-Covalently Dispersed Carbon Nanotubes

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1676 ◽  
Author(s):  
Mansab Ali Saleemi ◽  
Mohammad Hosseini Fouladi ◽  
Phelim Voon Chen Yong ◽  
Eng Hwa Wong
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Antimicrobial Activity ◽  
Growth Inhibition ◽  
Microbial Growth ◽  
Sodium Dodecyl ◽  
Surfactant Solution ◽  
Microbial Growth Inhibition ◽  
The Impact ◽  
Walled Cnts

Microorganisms have begun to develop resistance because of inappropriate and extensive use of antibiotics in the hospital setting. Therefore, it seems to be necessary to find a way to tackle these pathogens by developing new and effective antimicrobial agents. Carbon nanotubes (CNTs) have attracted growing attention because of their remarkable mechanical strength, electrical properties, and chemical and thermal stability for their potential applications in the field of biomedical as therapeutic and diagnostic nanotools. However, the impact of carbon nanotubes on microbial growth has not been fully investigated. The primary purpose of this research study is to investigate the antimicrobial activity of CNTs, particularly double-walled and multi-walled nanotubes on representative pathogenic strains such as Gram-positive bacteria Staphylococcus aureus, Gram-negative bacteria Pseudomonas aeruginosa, Klebsiella pneumoniae, and fungal strain Candida albicans. The dispersion ability of CNT types (double-walled and multi-walled) treated with a surfactant such as sodium dodecyl-benzenesulfonate (SDBS) and their impact on the microbial growth inhibition were also examined. A stock concentration 0.2 mg/mL of both double-walled and multi-walled CNTs was prepared homogenized by dispersing in surfactant solution by using probe sonication. UV-vis absorbance, Fourier transform infrared spectroscopy (FTIR), and transmission electron microscopy (TEM) were used for the characterization of CNTs dispersed in the surfactant solution to study the interaction between molecules of surfactant and CNTs. Later, scanning electron microscopy (SEM) was used to investigate how CNTs interact with the microbial cells. The antimicrobial activity was determined by analyzing optical density growth curves and viable cell count. This study revealed that microbial growth inhibited by non-covalently dispersed CNTs was both depend on the concentration and treatment time. In conclusion, the binding of surfactant molecules to the surface of CNTs increases its ability to disperse in aqueous solution. Non-covalent method of CNTs dispersion preserved their structure and increased microbial growth inhibition as a result. Multi-walled CNTs exhibited higher antimicrobial activity compared to double-walled CNTs against selected pathogens.

scholarly journals Foam Formation and Interaction with Porous Media

Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 143 ◽  
Author(s):  
Phillip Johnson ◽  
Mauro Vaccaro ◽  
Victor Starov ◽  
Anna Trybala
Keyword(s):  
Porous Media ◽  
Critical Micelle Concentration ◽  
Sodium Dodecyl ◽  
Surfactant Solution ◽  
Foam Formation ◽  
Compression Device ◽  
Time Interaction ◽  
The Media ◽  
Soft Porous Media ◽  
First Time

Foams are a common occurrence in many industries and many of these applications require the foam to interact with porous materials. For the first time interaction of foams with porous media has been investigated both experimentally and theoretically by O. Arjmandi-Tash et al. It was found that there are three different regimes of the drainage process for foams in contact with porous media: rapid, intermediate and slow imbibition. Foam formation using soft porous media has only been investigated recently, the foam was made using a compression device with soft porous media containing surfactant solution. During the investigation, it was found that the maximum amount of foam is produced when the concentration of the foaming agent (dishwashing surfactant) is in the range of 60–80% m/m. The amount of foam produced was independent of the pore size of the media in the investigated range of pore sizes. This study is expanded using sodium dodecyl sulphate (SDS), which has the same critical micelle concentration as the commercial dishwashing surfactant, where the foam is formed using the same porous media and compression device. During the investigation, it was found that 10 times the critical micelle concentration (CMC) is the optimum concentration for a pure SDS surfactant solution to create foam. Any further increase in concentration after that point resulted in no further mass of foam being generated.

scholarly journals Association of neutral red with micelles and its effect on the pKa

1993 ◽  
Vol 71 (11) ◽  
pp. 1785-1791 ◽  
Author(s):  
Robin K. Dutta ◽  
Subray N. Bhat
Keyword(s):  
Equilibrium Constants ◽  
Sodium Dodecyl ◽  
Surfactant Solution ◽  
Neutral Red ◽  
Association Constants ◽  
Alkyltrimethylammonium Bromides ◽  
Surfactant Solutions ◽  
Constant Ph ◽  
Apparent Association Constants ◽  
Apparent Association

The interactions of neutral red with cationic surfactants, viz., N-hexadecylpyridinium chloride and alkyltrimethylammonium bromides; a nonionic surfactant, viz., Triton X100; and an anionic surfactant, viz., sodium dodecyl sulfate, were investigated spectroscopically. The equilibrium constants for the association of the indicator with the micelles were determined from the apparent association constants at constant pH at 298 K. The effects of the indicator-micelle association on the apparent pKa of the indicator in aqueous surfactant solutions are discussed. It was shown that the apparent pKa of the indicator in cationic surfactant solution can be predicted from knowledge of the indicator-micelle association constant.

scholarly journals Mechanism of Sand Cementation with an Efficient Method of Microbial-Induced Calcite Precipitation

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5631
Author(s):  
Lu Wang ◽  
Shuhua Liu
Keyword(s):  
Compressive Strength ◽  
Calcium Carbonate ◽  
Efficient Method ◽  
Sand Particle ◽  
Carbonate Content ◽  
Calcite Precipitation ◽  
Sand Column ◽  
Cemented Sand ◽  
Initial Ph ◽  
Sand Particles

This paper presents an efficient method of microbial-induced calcite precipitation (MICP) for cementation of sand particles. First, the influence of initial pH value of the culture medium on the growth of bacteria was discussed. Then, the compressive strength and calcium carbonate content of cemented sand columns with different sand particle sizes were measured to indicate the cementation effectiveness. The microstructure of cemented sand columns as well as the mineral composition and distribution of calcium carbonate were characterised by means of scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) and X-ray diffraction (XRD). The results showed that the urease-producing bacteria S. pasteurii can be cultured at the initial pH values of 7–10, while a higher pH (e.g., 11) would hinder its growth and decrease its urease activity. The injection method of MICP with high standing time can cement sand columns effectively. Small average sand particle size of sand columns and high injection cycles can facilitate the gain of compressive strength, while calcium carbonate content of sand column higher than 8% can promote the increase of compressive strength. XRD results indicate that the fine grains generated on the surface of sand particles are calcite. The distribution of calcite on sand particles’ surface is broad and uniform. First, calcite was precipitated on the surface of sand particles, and then a precipitation layer was formed, which would connect sand particles through its high enough thickness and contribute to the development of compressive strength of the whole sand column.

Numerical Study of an Inlet Particle Separator

2004 ◽  
Author(s):  
A. Ghenaiet ◽  
S. C. Tan
Keyword(s):  
Separation Efficiency ◽  
Numerical Study ◽  
Turbine Engines ◽  
Sand Particle ◽  
Field Calculation ◽  
Particle Trajectories ◽  
Viscous Forces ◽  
Mass Flow Rates ◽  
Sand Particles ◽  
Particle Separator

Helicopters operating in a desert region are often subjected to the environmental effects of sand ingestion that can erode gas turbine engines and block the cooling passages. Traditional method of removing sand particles include barrier filters that employed vortex tube and impact filter designs, and inertial particle separator (IPS). Barrier filters are normally quite heavy and require constant servicing or replacement. IPS relies on contoured surfaces to direct particulates to a scavenge area through the actions of the viscous forces and bounce characteristics of the sand particles. The geometrical design of an IPS plays an important role in determining the sand separation efficiency. This paper presents a numerical study of the RTM322 IPS, which includes the effects of changing the hub, splitter and scavenge duct geometries on the sand separation efficiency. The flow field calculation in the IPS was performed with the commercial CFD software package called TASCflow. The particle trajectories were computed using an in-house developed trajectory code, which was based on the lagrangian method. The effects of flow turbulence on the trajectory were simulated using the eddy lifetime concept. Several design geometrical modifications were investigated such as the shape of the hub and splitter and their relative locations. Particle trajectories and separation efficiency were performed for a range of sand particle sizes, inlet mass flow rates and scavenge ratios.

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