A preliminary study of improving the MICP effects via the extractions from seashell nacre

In microbially induced calcium carbonate precipitation (MICP) process, it is the precipitated CaCO3 that cements loose sand particles together to improve their mechanical properties. Seashell nacre composed of CaCO3 is a natural product, which is worth researching for its great hardness, strength, and toughness. However, there is no study connecting this natural nacre mineralization with MICP. Therefore, a precedent herein is established to modify the MICP process via the water-soluble matrix (WSM) extracted from nacre, where WSM contributes to the great mechanical properties of nacre. Correspondingly, this study examines the effects of WSM with different concentrations on urease activity and strength as well as microstructure of bio-cemented sand samples. The experimental results show that a small number of WSM (50mg/L) can improve the average strength of bio-cemented sand samples 1.5 times. This is because 50mg/L WSM can significantly improve the urease activity of bacteria meanwhile increasing the Ca2+ utilization rate. Thus, more CaCO3 crystals are precipitated, and the higher UCS of bio-cemented sand samples is achieved. Moreover, the XRD results indicate that the precipitated CaCO3 is almost calcite, and only a little aragonite is detected when the concentration of WSM increases to 100mg/L. Additionally, the SEM images demonstrate that WSM involvement can affect the shapes and sizes of CaCO3 crystals. Overall, this work is an unprecedented exploration imitating nacre that hopefully paves way for future studies.

Large-Scale Triaxial Tests on Dilatancy Characteristics of Lean Cemented Sand and Gravel

The dilatancy equation, which describes the plastic strain increment ratio and its dependence on the stress state, is an important component of the elastoplastic constitutive model of geotechnical materials. In order to reveal their differences of the dilatancy value determined by the total volume strain increment ratio and the real value of lean cemented sand and gravel (LCSG) materials, in this study, a series of triaxial compression tests, equiaxial loading and unloading tests, and triaxial loading and unloading tests are conducted under different cement contents and confining pressures. The results reveal that hysteretic loops appear in the stress–strain curves of equiaxial loading and unloading tests, and triaxial loading and unloading tests and that the elastic strain is an important component of the total strain. The hysteretic loop size increases with an increase in the stress level or consolidation stress, whereas the shape remains unchanged. Furthermore, with an increase in the cement content, the dilatancy value determined by the total volume strain increment ratio becomes smaller than that determined by the plastic strain increment ratio, and the influence of the elastic deformation cannot be ignored. Thus, in practical engineering scenarios, especially in the calculation of LCSG dam structures, the dilatancy equation of LCSG materials should be expressed by the plastic strain increment ratio, rather than the total volume strain increment rati.

Effect of Nutrient Solution Composition on Bio-Cemented Sand

Microbial-induced carbonate precipitation is an environmentally friendly foundation treatment technology that effectively improves soil engineering performance. The various nutrient components of liquid curing compounds significantly influence the curing effect. On the basis of penetration, dry density, water absorption, and unconfined compressive strength tests, this study showed the effect of nutrient solution composition, including urea, calcium chloride, sodium bicarbonate, ammonium chloride, and nutrient broth, on the physicomechanical properties of bio-cemented sand. The morphological differences of calcium carbonate precipitates under nutrient solution composition were compared through scanning electron microscopy (SEM). Results showed that the curing effect of compound nutrient solution was improved compared with the basic nutrient solution (urea and calcium chloride). Among the individual components added, ammonium chloride had the most remarkable effect, followed by sodium bicarbonate and nutrient broth. Among the paired components added, sodium bicarbonate + ammonium chloride had the most significant effect, followed by sodium bicarbonate + nutrient broth and ammonium chloride + nutrient broth. The strength of bio-cemented sand cured with compound nutrient solution containing five components could reach 3.43 MPa, which was 1.92 times higher than the strength of the basic nutrient solution. As shown by the SEM image, the calcium carbonate precipitation in the solidified sand was distributed in the clearance of sand particles, effectively bonding the sand particles. The calcium carbonate obtained by the composition of the compound nutrient solution precipitated the sand particles, and some of the sand particles were wrapped. Moreover, the amount of precipitation was evidently greater than that of the basic nutrient solution. Compared with the basic nutrient solution, the compound nutrient solution effectively reduced the apparent porosity and average pore size of the sand. Thus, the curing effect of the compound nutrient solution was better than that of the basic nutrient solution.

A New Type of Cemented Sand-Gravel (CSG) Mixtures for Water-Tightening of Hardfill Dams

This paper aims to achieve a specific type of cemented sand-gravel mixtures with low permeability to implement in the impervious zone of hardfill dams. To this end, various mixtures are prepared by blending two native soils of sand and gravel with different amounts of kaolinite or bentonite additives in presence of various cement content. The compaction properties, uniaxial compressive strength, permeability and scanning electron microscope (SEM) images of mixtures are measured. According to the results, the cemented mixture containing 10% of kaolinite additive regardless of native soil type exhibits the maximum strength. However, the bentonite disturbs the cement hydration in the mixture, and the strength of mixtures especially with high cement content decreases with increasing the bentonite content. The permeability of mixtures is related to the amount of cement and fine additive in the mixture. The permeability of both cemented sand and gravel mixtures decreases with increasing the bentonite additive. However, the kaolinite additive has a limited influence on the permeability of cemented gravel mixtures. The lowest permeability is achieved in the mixture involving the higher amount of bentonite (with a weight ratio of 30%) in presence of adequate cement.

Influence of Zeolite on the Compaction Characteristics and Shear Strength Parameters of Cemented Sand

It is well known that in geotechnical engineering, soil stabilization using cement is one of the appropriate approaches for enhancing soil characteristics. With respect to zeolite, its impact on the characteristics of cemented soil has not been fully evaluated. Thus, in the current research, a set of laboratory tests including standard Proctor compaction and direct shear tests (DSTs) considering four cement contents (2, 4, 6, and 8% of sand dry weight) and four zeolite contents (0%, 30%, 60%, and 90% of cement percentage as a replacement material) was carried out. The results indicated that the zeolite reduced Maximum Dry Density (MDD) while it increased value of Optimum Moisture Content (OMC) of cemented sand. Through the DSTs, it has been found that the replacement of cement by zeolite up to 30%, leads to the highest values of shear strength parameters due to the occurrence of pozzolanic and chemical reactions, particularly the production of higher amounts of calcium aluminate and calcium silicate hydrates in comparison with zeolite-free samples.

The Influence of Fly Ash Content on the Compressive Strength of Cemented Sand and Gravel Material

Cemented sand and gravel (CSG) material is a new type of dam material developed on the basis of roller compacted concrete, hardfill, and ultra-poor cementing materials. Its main feature is a wide range of sources of aggregate (aggregate is not screened but by simply removing the large particles it can be fully graded on the dam filling) and low amounts of cementitious materials per unit volume. This dam construction material is not only economical and practical, but also green and environmentally friendly. There are many factors affecting the mechanical properties of CSG materials, such as aggregate gradation, sand ratio, water content, water–binder ratio, fly ash content, admixture content, etc. Based on the existing research results of the team, this paper focuses on the influence of fly ash content on the compressive strength of CSG materials. Through a large number of laboratory measured data, we found: (1) The compressive strength law of materials at different ages; the compressive strength of CSG material at age 90 d is generally 10~30% higher than that at 28 d, and it is proposed that 90 d or 180 d strength should be used as the design strength in the design of CSG material dam; (2) There is an optimal value of fly ash content in CSG materials: when the fly ash content is 50% of the total amount of cementitious materials (cement + fly ash), the fly ash content is defined as the optimal content, and the test data are verified by regression analysis. The discovery of an 'optimal dosage' of fly ash provides an important reference for the design and construction of CSG dams.