scholarly journals Studies of Surface Area and Pore Structure on Portland Cement Produced in Bajil and Amran, Yemen

2008 ◽  
Vol 13 ◽  
pp. 13
Author(s):  
A.M. Saad ◽  
Abdul-Basit A. Saleh ◽  
Fatima A. Al-Kadri ◽  
Abdulla S. Babaqi ◽  
Abdulla A. Basissa ◽  
...  
Keyword(s):  
Portland Cement ◽  
Pore Structure ◽  
Hysteresis Loops ◽  
Hardened Cement ◽  
Pore System ◽  
Nitrogen Gas ◽  
Time Intervals ◽  
Cement Pastes ◽  
Adsorption Desorption ◽  
Hardened Cement Pastes

Portland cement pastes of various porosities were prepared using water/cement ratios of 0.30, 0.35, 0.40, 0.45, 0.50 and 0.55; and were hydrated for various time intervals ranging from 0.021 to 28 days.  Pore structure and VL–t plots (plots of volume vs. thickness) of the hardened cement pastes were measured using nitrogen gas as the adsorbate. The results were found to be related to the mechanism of hydration as controlled by the pore system of the hardened pastes. Type ІІ adsorption isotherms of nitrogen were obtained for all hardened cement pastes. The adsorption-desorption isotherms indicated the existence of closed hysteresis loops for most of the investigated samples and in some other cases, these isotherms were fully reversible.  

scholarly journals Effect of Some Acrylate—Poly(Ethylene Glycol) Copolymers as Superplasticizers on the Mechanical and Surface Properties of Portland Cement Pastes

2005 ◽  
Vol 23 (3) ◽  
pp. 245-254 ◽  
Author(s):  
S.A. Abo-El-Enein ◽  
S. Hanafi ◽  
F.I. El-Hosiny ◽  
El-Said H.M. El-Mosallamy ◽  
M.S. Amin
Keyword(s):  
Ethylene Glycol ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Mechanical Characteristics ◽  
Hardened Cement ◽  
Poly Ethylene Glycol ◽  
Cement Pastes ◽  
Surface Areas ◽  
Poly Ethylene ◽  
Hardened Cement Pastes

Ordinary Portland cement (OPC) pastes with added superplasticizer were made using water/cement weight ratios of standard consistency. Three types of superplasticizer based on acrylate—poly(ethylene glycol) copolymers were used. The pastes were hydrated for various time lengths and the mechanical characteristics of the hardened cement pastes were studied and related to their pore structures. It was found that the addition of the superplasticizers to OPC improved the mechanical properties of the hardened pastes for all hydration lengths. The addition of such superplasticizers to OPC resulted in a decrease in the specific surface areas and total pore volumes of the hardened superplasticized cement pastes relative to the corresponding hardened neat cement pastes.

Composites of Portland Cement and Natural Polymers

2005 ◽  
Vol 498-499 ◽  
pp. 407-412 ◽  
Author(s):  
Ulisses Targino Bezerra ◽  
Antonio Eduardo Martinelli ◽  
D.M.A. Melo ◽  
D.M. Henrique ◽  
E.M. Rodrigues ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Portland Cement ◽  
Environmentally Friendly ◽  
Hardened Cement ◽  
Oil Well ◽  
Natural Polymer ◽  
Natural Polymers ◽  
Cement Pastes ◽  
Preliminary Results ◽  
Hardened Cement Pastes

The tensile strength of Portland cement may be increased by additional reinforcement. This is usually accomplished by means of steel rods, fibers or particles, which are mixed to the slurry. In an attempt of increasing toughness and tensile strength of hardened cement pastes, the present work describes the behavior of composites consisting of Portland reinforced by natural polymer particles for oil well cementing. The main purpose of the study was to select plastic and environmentally friendly powdered materials capable of filling the typical porosity developed on hardened Portland cement. Preliminary results suggested that the tensile strength of plain Portland hardened slurries could be increased by as much as 40% by adding 10% of reinforcement.

Matlab Image Processing Technique and Application in Pore Structure Characterization of Hardened Cement Pastes

2013 ◽  
Vol 785-786 ◽  
pp. 1374-1379 ◽  
Author(s):  
An Qun Lu ◽  
Shou Zhi Zhang ◽  
Qian Tian
Keyword(s):  
Image Processing ◽  
Pore Structure ◽  
Processing Technique ◽  
Image Processing Technique ◽  
Hardened Cement ◽  
Analysis Method ◽  
Image Analysis Method ◽  
Cement Pastes ◽  
Backscattered Electron ◽  
Hardened Cement Pastes

Based on Matlab image processing technique and backscattered electron image analysis method, a characterization method is set up to make quantitative analysis on pore structure of hardened cement pastes. Adopt Matlab to acquire images, and carry out gradation and binarization processing for them; use the combination method of local threshold segmentation and histogram segmentation to obtain pore structure characteristics. The results showed that evolution law of pore structure of fly ash cement pastes via Matlab image analysis method is similar to the conclusion obtained through BET and DVS. Selecting different angle of backscattered electron images in the same sample, its statistic results are more representative.

OPTIMAL CRITERIA OF ALGERIAN BLENDED CEMENT USING LIMESTONE FINES/ALŽYRIETIŠKAS MIŠRUSIS CEMENTAS SU MALTU KALKAKMENIU

2008 ◽  
Vol 14 (4) ◽  
pp. 269-275 ◽  
Author(s):  
Z’hor Guemmadi ◽  
Musa Resheidat ◽  
Hacéne Houari ◽  
Belkacem Toumi
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Blended Cement ◽  
Total Porosity ◽  
Hardened Cement ◽  
Compact Structure ◽  
Limestone Filler ◽  
Cement Pastes ◽  
Limestone Fines ◽  
Hardened Cement Pastes

The effect of substitution of Portland cement by limestone up to 40% as well as its fineness on the physico‐mechanical properties of fresh and hardened cement pastes is studied. The binder was prepared by substitution of cement by limestone filler. Fillers were chosen of various particle sizes and with percentages from 5 to 40. Test results revealed that the replacement of Portland cement by the finest filler of limestone slightly decreases the consistency and the setting times (initial and final). The total porosity decreases and accordingly the compressive strength is improved with the content and fines of limestone. Although limestone has a little accelerating effect on the hydration process of Portland cement, but acts only as a filler reducing the porosity due to its compact structure, in which the compressive strength of the hardened cement paste is enhanced. The XRD and DTA analyses of samples cured up to 28 days showed that this amelioration is due to formation of new hydrated compounds. It is concluded that an addition of finely ground limestone filler only up to 15% gives a better strength. Santrauka Tirtos šviežios ir sukietėjusios cementinės tešlos, kurioje iki 40 % cemento pakeista įvairaus smulkumo maltu kalkakmeniu, savybės. Rišiklis buvo paruoštas dalį cemento pakeitus maltu kalkakmenio užpildu. Užpildo dalelės buvo įvairaus dydžio, o jų kiekis buvo keičiamas nuo 5 % iki 40 %. Tyrimai parodė, kad priedas leidžia sumažinti vandens kiekį, reikalingą tos pačios konsistencijos mišiniui gauti, taip pat cemento rišimosi pradžiai ir pabaigai paankstinti. Sumažėja cementinio akmens suminis poringumas ir atitinkamai padidėja stipris gniuždant cementinio akmens, kuriame yra kalkakmenio priedų. Nors kalkakmenio priedas nedaug pagreitina portlandcemenčio hidratacijos procesą, tačiau veikia kaip užpildas, sutankinantis struktūrą, dėl to labai padidėja sukietėjusio cementinio akmens stipris gniuždant. Bandinių, išlaikytų 28 dienas, rentgenostruktūrinė ir diferencinė terminė analizė parodė, kad pagerėjimas yra dėl susidariusių naujadarų. Apibendrinant galima teigti, kad 15 % malto kalkakmenio priedas turi didžiausią įtaką stiprumo rezultatams.

Pore Structure and Chloride Ion Transport Mechanisms in Concrete

2006 ◽  
Vol 302-303 ◽  
pp. 528-535
Author(s):  
Cai Jun Shi ◽  
De Hua Deng ◽  
You Jun Xie
Keyword(s):  
Pore Structure ◽  
Chloride Ion ◽  
Engineering Properties ◽  
Hardened Cement ◽  
Transport Mechanisms ◽  
Reinforced Concrete Structure ◽  
Cement Pastes ◽  
Capillary Suction ◽  
Structure Characteristics ◽  
Hardened Cement Pastes

Hardened cement paste and concrete are porous materials. Most engineering properties of hardened cement pastes and concrete, such as strength, shrinkage, permeability, etc., are influenced or controlled by their pore structure characteristics. The ingress of chloride ion into concrete can cause steel corrosion and damage of steel reinforced concrete structure. This paper reviews the pore structure characteristics and transport mechanisms of chloride ion, such as hydrostatic advection, capillary suction, diffusion, thermal migration and electrical migration, in hardened cement pastes and concrete.

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