scholarly journals Taguchi Optimization of Carboxymethylation Process and Effect Reaction Efficiency on Swelling Capacity

2019 ◽  
Vol 7 (5) ◽  
Author(s):  
Ernest C. Agwamba ◽  
Lawal G. Hassan ◽  
Achor Muhammad ◽  
Abdullahi M. Sokoto

The aim of this research paper was to ascertain the optimum conditions required to economical synthesis carboxymethylated starch using experimental design technique by Taguchi for Larger-is-better and smaller-is better of reaction efficiency (RE). Orthogonal Array method was utilized in the design of the experiment which consisted of eighteen (18) runs based on three (3) independent Factors which are; Sodium hydroxide (NaOH) with three concentration levels (1, 1.5, and 2.0M), Sodium monochloroacetate (SMCA) with three concentration levels (1, 1.5, and 2.0M) and Reaction Time (T) with two (2) levels (2 and 4 hours) respectively and the response is reaction efficiency (R.E). The result obtained from the experiment was interpreted using the Taguchi method of larger-is-better and smaller-is-better was apply to estimate the Response for Signal-to-Noise Ratios. The analysis showed that for larger-is-better, the optimal condition to obtain high reaction efficiency (R.E.) of 9.97%, will require NaOH at 2.0 M, SMCA at 1.0 M, at reaction period of, while for smaller-is-better, the optimal condition to obtain low reaction efficiency (RE) of 1.93 %, will required the concentration of NaOH (aq) and SMCA (aq) to be 1.5 M and 1.5 M with a reaction period (T) of 4 hours respectively. The result was also study the influence of variable SMCA (aq) and NaOH (aq) concentrations on swelling capacity (SC) at reaction time of 2 hours. The result shows that 2M NaOH is the optimum concentration for carboxymethyl starch (CMS) synthesis. .Significant difference was ascertained using Tukey method, and at 95% Confidence level.

Author(s):  
K.A. Nugroho ◽  
M.C.D. Kurnianingtyas

Concentration is the ability needed to solve a problem.  Students in learning also need concentration (DePorter et al., 2010). Unfortunately students have difficulty concentrating on doing a job. To help concentrate, students play pen, spin coins, play cellphones and other fun activities. To meet this goal, an agitated repellent device such as fidget spinner and fidget cube was made (Plafke, 2016). The benefits of spinner fidget for increasing concentration are still questionable (Schecter et al., 2017). Therefore, quantitative research is needed to prove the claim that fidget spinner can increase concentration. Unfortunately there is currently no quantitative research that tests the effectiveness of these tools to increase short-term memory. The concentration level of a person can be measured using the Stroop test. Stroop tests utilize primitive cognitive operations, offering clues to the basic process of attention. The variable studied is Reaction Time for Correct Answer (RTCA), which is the amount of reaction time in answering correctly divided by the number of correct answers. The results of this study are: the use of fidget spinner does not have a significant effect on differences in the results of measurement of RTCA. The use of fidget spinner does not provide a significant difference in average error between not using fidget spinner and using fidget spinner.


Agriculture ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 377
Author(s):  
Moo-Joon Shim ◽  
Seung-Mok Lee

Cu and Zn are known to be abundant in swine feces; hence, concentrations of these metals need to be lowered before swine feces are applied to land in order to prevent potential environmental problems. The main objective of this study was to develop an appropriate chemical process to remove Cu and Zn from swine feces using acid extractions. The removal efficiencies of Cu and Zn decreased in the order of H2SO4 > HNO3 > organic acids (citric and oxalic acids). Owing to the highest removal efficiencies of Cu and Zn by using H2SO4, it was selected for further elimination of Cu and Zn from swine feces. By using H2SO4, the optimal concentration, solid-to-liquid ratio, and reaction time were 2%, 1:50, and 8 h, respectively. At the optimum conditions, Cu concentration was decreased from 198 mg/kg to 40.1 mg/kg and Zn concentration from 474 mg/kg to 80.0 mg/kg, with removal rates of 79.7% and 83.1%, respectively. The low Cu removal efficiency, resulting from the strong complexation between Cu and organic matter of swine feces, was improved by the increase in the reaction time and H2SO4 solution concentrations. However, about half of the total nitrogen (TN) was also removed by using H2SO4, indicating that the swine feces treated with H2SO4 may have poor value as fertilizer. Additional studies are required to find an optimal method to maintain TN concentrations while simultaneously removing Cu and Zn.


1970 ◽  
Vol 31 (2) ◽  
pp. 343-348 ◽  
Author(s):  
Jerry W. Thornton ◽  
Paul D. Jacobs

Two tasks (simple and choice reaction time) were examined while varying three types of stressors (shock, threat of shock, and noise) and the stressor task relationship (i.e., task-related stress, task-unrelated stress, and no-stress). Four specific hypotheses were tested and 3 were supported in the simple reaction-time task. There were no significant differences among stressors for either task, although greater differences were reported in the simple than in the choice reaction-time task. A significant difference between the “task-relatedness” of stress levels in the simple task was interpreted as possibly due to a “coping” or “protective adaptive mechanism” in which increases in performance serve to reduce stress. Practical applications were examined.


2010 ◽  
Vol 10 (1) ◽  
pp. 1-6 ◽  
Author(s):  
R. Murillo ◽  
J. Sarasa ◽  
M. Lanao ◽  
J. L. Ovelleiro

The degradation of chlorpyriphos by different advanced oxidation processes such as photo-Fenton, TiO2, TiO2/H2O2, O3 and O3/H2O2 was investigated. The photo-Fenton and TiO2 processes were optimized using a solar chamber as light source. The optimum dosages of the photo-Fenton treatment were: [H2O2]=0.01 M; [Fe3 + ]=10 mg l−1; initial pH = 3.5. With these optimum conditions total degradation was observed after 15 minutes of reaction time. The application of sunlight was also efficient as total degradation was achieved after 60 minutes. The optimum dosage using only TiO2 as catalyst was 1,000 mg l−1, obtaining the maximum degradation at 20 minutes of reaction time. On the other hand, the addition of 0.02 M of H2O2 to a lower dosage of TiO2 (10 mg l−1) provides the same degradation. The ozonation treatment achieved complete degradation at 30 minutes of reaction time. On the other hand, it was observed that the degradation was faster by adding H2O2 (H2O2/O3 molar ratio = 0.5). In this case, total degradation was observed after 20 minutes.


2018 ◽  
Vol 6 (3) ◽  
pp. 232596711876103 ◽  
Author(s):  
Eleni Diakogeorgiou ◽  
Theresa L. Miyashita

Background: Gaining a better understanding of head impact exposures may lead to better comprehension of the possible effects of repeated impact exposures not associated with clinical concussion. Purpose: To assess the correlation between head impacts and any differences associated with cognitive testing measurements pre- and postseason. Study Design: Case-control study; Level of evidence, 3. Methods: A total of 34 National Collegiate Athletic Association Division I men’s lacrosse players wore lacrosse helmets instrumented with an accelerometer during the 2014 competitive season and were tested pre- and postseason with the Sport Concussion Assessment Tool (SCAT 3) and Concussion Vital Signs (CVS) computer-based neurocognitive tests. The number of head impacts >20 g and results from the 2 cognitive tests were analyzed for differences and correlation. Results: There was no significant difference between pre- and postseason SCAT 3 scores, although a significant correlation between pre- and postseason cognitive scores on the SCAT 3 and total number of impacts sustained was noted ( r = –0.362, P = .035). Statistically significant improvements on half of the CVS testing components included visual reaction time ( P = .037, d = 0.37), reaction time ( P = .001, d = 0.65), and simple reaction time ( P = .043, d = 0.37), but no correlation with head impacts was noted. Conclusion: This study did not find declines in SCAT 3 or CVS scores over the course of a season among athletes who sustained multiple head impacts but no clinical concussion. Thus, it could not be determined whether there was no cognitive decline among these athletes or whether there may have been subtle declines that could not be measured by the SCAT 3 or CVS.


2021 ◽  
Vol 20 (1) ◽  
pp. 31-39
Author(s):  
Oluyemisi Adebowale Bamiro ◽  
Aishat Oyinkansola Salisu ◽  
Ese Mary Iyere ◽  
Olatundun Atoyegbe ◽  
Olutayo Ademola Adeleye ◽  
...  

The aim of the work was to characterize chitosan extracted from snail shell and evaluate its use as a disintegrant and binder in metronidazole tablet formulation in comparison with standard chitosan (SC). The mechanical properties were assessed using crushing strength and friability, while the release properties were assessed using disintegration and dissolution times. The extracted chitosan (EC) was crystalline in nature and the scanning electron microscopy (SEM) showed polygonal particles with rough surface. The moisture and swelling capacity was 1.80% and 15.00%, respectively. The densities and flow properties were significantly (p<0.05) higher than those of the SC. As a binder, the crushing strength of formulations containing EC was higher than SC, but both formulation failed friability test. There was significant difference between the disintegration times of the metronidazole formulations containing EC and SC as a disintegrant. The result showed that EC is more effective as a binder in tablet formulations. Dhaka Univ. J. Pharm. Sci. 20(1): 31-39, 2021 (June)


Author(s):  
Cosmin Miha Moca ◽  
Dan Mihai Gherţoiu

ABSTRACT. Introduction. Reaction is a purposeful voluntary response to an external stimulus. There is certain time period between application of external stimulus and appropriate motor response to the stimulus called the reaction time. Objectives. The aim of this paper was to determine if different colour contrasts affects the reaction time of young tennis players. Materials and Methods. The participants in this study were young tennis players (N = 10), 3 females and 7 males, with the ages between 12 to 13 years old. Results. There was a significant difference in the scores for white background (M=7.5, SD=1.51) and orange background (M=6, SD=0.81) conditions; t(9)=3.30, p = 0.009. Conclusion. Our study managed to show that a different kind of background colour can affect the reaction accuracy in identifying an object of different shape and colour than the background.


2018 ◽  
Vol 8 (1) ◽  
pp. 121-127 ◽  
Author(s):  
Tanzer Eryilmaz

In this study, the methyl ester production process from neutralized waste cooking oils is optimized by using alkali-catalyzed (KOH) single-phase reaction. The optimization process is performed depending on the parameters, such as catalyst concentration, methanol/oil ratio, reaction temperature and reaction time. The optimum methyl ester conversion efficiency was 90.1% at the optimum conditions of 0.7 wt% of potassium hydroxide, 25 wt% methanol/oil ratio, 90 min reaction time and 60°C reaction temperature. After the fuel characteristics of the methyl ester obtained under optimum conditions were determined, the effect on engine performance, CO and NOx emissions of methyl ester was investigated in a diesel engine with a single cylinder and direct injection. When compared to diesel fuel, engine power and torque decreased when using methyl ester, and specific fuel consumption increased. NOx emission increases at a rate of 18.4% on average through use of methyl ester.


2017 ◽  
Vol 76 (12) ◽  
pp. 3278-3288 ◽  
Author(s):  
Zhenchao Zhang

Abstract In this study, a combined process was developed that included micro-electrolysis, Fenton oxidation and coagulation to treat oilfield fracturing wastewater. Micro-electrolysis and Fenton oxidation were applied to reduce chemical oxygen demand (COD) organic load and to enhance organic components gradability, respectively. Orthogonal experiment were employed to investigate the influence factors of micro-electrolysis and Fenton oxidation on COD removal efficiency. For micro-electrolysis, the optimum conditions were: pH, 3; iron-carbon dosage, 50 mg/L; mass ratio of iron-carbon, 2:3; reaction time, 60 min. For Fenton oxidation, a total reaction time of 90 min, a H2O2 dosage of 12 mg/L, with a H2O2/Fe2+ mole ratio of 30, pH of 3 were selected to achieve optimum oxidation. The optimum conditions in coagulation process: pH, cationic polyacrylamide dosage, mixing speed and time is 4.3, 2 mg/L, 150 rpm and 30 s, respectively. In the continuous treatment process under optimized conditions, the COD of oily wastewater fell 56.95%, 46.23%, 30.67%, respectively, from last stage and the total COD removal efficiency reached 83.94% (from 4,314 to 693 mg/L). In the overall treatment process under optimized conditions, the COD of oily wastewater was reduced from 4,314 to 637 mg/L, and the COD removal efficiency reached 85.23%. The contribution of each stage is 68.45% (micro-electrolysis), 24.07% (Fenton oxidation), 7.48% (coagulation), respectively. Micro-electrolysis is the uppermost influencing process on COD removal. Compared with the COD removal efficiency of three processes on raw wastewater under optimized conditions: the COD removal efficiency of single micro-electrolysis, single Fenton oxidation, single coagulation is 58.34%, 44.88% and 39.72%, respectively. Experiments proved the effect of combined process is marvelous and the overall water quality of the final effluent could meet the class III national wastewater discharge standard of petrochemical industry of China (GB8978-1996).


2015 ◽  
Vol 1 (2) ◽  
pp. 67
Author(s):  
Haq Nawaz ◽  
Muhammad Aslam Shad ◽  
Rabia Mehmood ◽  
Tanzila Rehman ◽  
Hira Munir

<p>Functional properties such as protein solubility, swelling capacity, water holding capacity, gelling ability, bulk density and foaming capacity of flours of some commonly used cereals and legume (wheat, refined wheat, maize and chickpea) and their blends were studied. Blends of flours were prepared by mixing equal proportions of selected floors. Statistically significant difference  in studied functional properties except bulk density was observed among cereal flours and their blends. Chickpea flour was found to possess comparatively high water holding capacity, protein solubility index and swelling capacity. The functional properties of maize and wheat flours were found to be improved when blended with chickpea. Chickpea flour and its blends with cereal flours were found to possess good functional score and suggested as favorable candidates for use in the preparation of viscous foods and bakery products. The data provide guidelines regarding the improvement in functional properties of economically favorable cereal flours.<strong></strong></p>


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