scholarly journals An Analysis of Relations for Determining the Thermal Conductivity of Rigid Polymer Foams

2018 ◽  
Vol 23 (4) ◽  
pp. 1015-1023 ◽  
Author(s):  
A. Alsabry ◽  
V.I. Nikitsin ◽  
V.A. Kofanov ◽  
B. Backiel-Brzozowska

Abstract In the paper the authors present the effectiveness of the generalized thermal conductivity method for polymer foams, including modelling their geometrical structure. Calculations of the effective thermal conductivity coefficient λ are based on the generally accepted assumption of the additivity of different thermal exchange mechanisms in porous media and this coefficient is presented as a sum the coefficients of conductive λq, radiative λp, and convective λk thermal conductivity. However, in literature not enough attention is given to relations determined by means of the theory of generalized conductivity, including modelling the geometrical structure. This paper presents an analysis of these relations and verifies their ability to predict experimental data in comparison with the best formulae included in the paper [2].

Entropy ◽  
2019 ◽  
Vol 22 (1) ◽  
pp. 13
Author(s):  
Ivan Anashkin ◽  
Sergey Dyakonov ◽  
German Dyakonov

An expression is proposed that relates the transport properties of polar substances (diffusion coefficient, viscosity coefficient, and thermal conductivity coefficient) with entropy. To calculate the entropy, an equation of state with a good description of the properties in a wide region of the state is used. Comparison of calculations based on the proposed expressions with experimental data showed good agreement. A deviation exceeding 20% is observed only in the region near the critical point as well as at high pressures.


2010 ◽  
Vol 297-301 ◽  
pp. 1400-1407
Author(s):  
Giovano de Oliveira Cardozo ◽  
José Pedro Rino

Equilibrium and non-equilibrium molecular dynamics calculations of thermal conductivity coefficient are presented for bulk systems of InSb, using an effective two- and three-body inter atomic potential which demonstrated to be very transferable. In the calculations, the obtained coefficients were comparable to the experimental data. In the case of equilibrium simulations a Green-Kubo approach was used and the thermal conductivity was calculated for five temperatures between 300 K and 900 K. For the non equilibrium, or direct method, which is based on the Fourier’s law, the thermal conductivity coefficient was determined at a mean temperature of 300K. In this case it was used a pair of reservoirs, placed at a distance L from each other, and with internal temperatures fixed in 250 K, for the cold reservoir, and 350 K for the hot one. In order to obtain an approach to an infinite system coefficient, four different values of L were used, and the data was extrapolated to L→∞.


2020 ◽  
Vol 24 (4) ◽  
pp. 2385-2391
Author(s):  
Ya-Ping Li ◽  
Li-Li Wang ◽  
Jie Fan

Fluids in porous media driven by the capillary force are greatly affected by capillary?s geometrical structure. The steady flow in a non-uniform capillary is numerically analyzed by the finite element method. With the given initial and boundary conditions, the flow velocity distribution with different geometrical parameters is obtained, and the result is in a good agreement with the experimental data.


Author(s):  
K. K. Abgaryan ◽  
I. S. Kolbin

In this work, we calculate the effective thermal conductivity coefficient for a binary semiconductor heterostructure using the GaAs/AlAs superlattice as an example. Different periods of layers and different ambient temperatures are considered. At the scale under consideration, the use of models based on the Fourier law is very limited, since they do not take into account the quantum-mechanical properties of materials, which gives a strong discrepancy with experimental data. On the other hand, the use of molecular dynamics methods allows us to obtain accurate solutions, but they are significantly more demanding on computing resources and also require solving a non-trivial problem of potential selection. When considering nanostructures, good results were shown by methods based on the solution of the Boltzmann transport equation for phonons; they allow one to obtain a fairly accurate solution, while having less computational complexity than molecular dynamics methods. To calculate the thermal conductivity coefficient, a modal suppression model is used that approximates the solution of the Boltzmann transport equation for phonons. The dispersion parameters and phonon scattering parameters are obtained from first-principle calculations. The work takes into account 2-phonon (associated with isotopic disorder and barriers) and 3-phonon scattering processes. To increase the accuracy of calculations, the non-digital profile of the distribution of materials among the layers of the superlattice is taken into account. The obtained results are compared with experimental data showing good agreement.


Sensors ◽  
2019 ◽  
Vol 19 (9) ◽  
pp. 1968 ◽  
Author(s):  
Sylvie Bilent ◽  
Thi Hong Nhung Dinh ◽  
Emile Martincic ◽  
Pierre-Yves Joubert

This paper reports on the study of microporous polydimethylsiloxane (PDMS) foams as a highly deformable dielectric material used in the composition of flexible capacitive pressure sensors dedicated to wearable use. A fabrication process allowing the porosity of the foams to be adjusted was proposed and the fabricated foams were characterized. Then, elementary capacitive pressure sensors (15 × 15 mm2 square shaped electrodes) were elaborated with fabricated foams (5 mm or 10 mm thick) and were electromechanically characterized. Since the sensor responses under load are strongly non-linear, a behavioral non-linear model (first order exponential) was proposed, adjusted to the experimental data, and used to objectively estimate the sensor performances in terms of sensitivity and measurement range. The main conclusions of this study are that the porosity of the PDMS foams can be adjusted through the sugar:PDMS volume ratio and the size of sugar crystals used to fabricate the foams. Additionally, the porosity of the foams significantly modified the sensor performances. Indeed, compared to bulk PDMS sensors of the same size, the sensitivity of porous PDMS sensors could be multiplied by a factor up to 100 (the sensitivity is 0.14 %.kPa−1 for a bulk PDMS sensor and up to 13.7 %.kPa−1 for a porous PDMS sensor of the same dimensions), while the measurement range was reduced from a factor of 2 to 3 (from 594 kPa for a bulk PDMS sensor down to between 255 and 177 kPa for a PDMS foam sensor of the same dimensions, according to the porosity). This study opens the way to the design and fabrication of wearable flexible pressure sensors with adjustable performances through the control of the porosity of the fabricated PDMS foams.


Author(s):  
Ahmed E Aboueregal ◽  
Hamid M Sedighi

The present contribution aims to address a problem of thermoviscoelasticity for the analysis of the transition temperature and thermal stresses in an infinitely circular annular cylinder. The inner surface is traction-free and subjected to thermal shock heating, while the outer surface is thermally insulated and free of traction. In this work, in contrast to the various problems in which the thermal conductivity coefficient is considered to be fixed, this parameter is assumed to be variable depending on the temperature change. The problem is studied by presenting a new generalized thermoelastic model of thermal conductivity described by the Moore–Gibson–Thompson equation. The new model can be constructed by incorporating the relaxation time thermal model with the Green–Naghdi type III model. The Laplace transformation technique is used to obtain the exact expressions for the radial displacement, temperature and the distributions of thermal stresses. The effects of angular velocity, viscous parameter, and variance in thermal properties are also displayed to explain the comparisons of the physical fields.


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