scholarly journals CHANGES IN THE STRUCTURE OF GOLD NANOPARTICLES ON THE TUNGSTEN SURFACE CAUSED BY HEATING

2020 ◽  
pp. 53-60
Author(s):  
Петр Александрович Дементьев ◽  
Михаил Николаевич Лапушкин
Keyword(s):  
Gold Nanoparticles ◽  
Room Temperature ◽  
Major Axis ◽  
Semi Major Axis ◽  
Thermal Deposition ◽  
Average Area ◽  
Tungsten Surface

Исследовано формирование наночастиц золота на поверхности вольфрама и влияние прогрева на их структуру. Найдено, что термическое напыление атомов золота на поверхность вольфрама при комнатной температуре приводит к формированию хаотично расположенных наночастиц. Средняя площадь наночастиц составляет 10210 нм. Прогрев в течение 30 минут при температуре 600 K приводит к слиянию наночастиц, что находит отражение в увеличении средней площади наночастиц до 19520 нм. Дальнейший прогрев в течение 30 минут при температуре 600 K не приводил к увеличению средней площади наночастиц. Анализ формы наночастиц показал, что они являются эллипсоидами. Непрогретые наночастицы имеют большую полуось 110 ± 30 нм и эксцентриситет 1,5 ± 0,4. Прогрев золотых наночастиц приводит к увеличению полуоси до 200 ± 120 нм и эксцентриситета до 1,8 ± 0,6. Показано, что наночастицы после прогрева приобретают форму обрезанного эллипсоида. The formation of gold nanoparticles on the tungsten surface and the effect of heating on their structure are studied. It was found that the thermal deposition of gold atoms on the tungsten surface at room temperature leads to formation of randomly located nanoparticles. The average area of nanoparticles is 10210 nm. Heating for 30 minutes at a temperature of 600 K leads to the fusion of nanoparticles, which is reflected in an increase in the average area of nanoparticles to 19520 nm. Further heating for 30 minutes at temperature 600 K did not lead to an increase in the average area of nanoparticles. An analysis of the shape of the nanoparticles showed that they are elongated ellipsoids. Unheated nanoparticles have a semi-major axis of 110±30 nm and eccentricity 1,5 ±0,4 . Heating of gold nanoparticles leads to an increase in the semi-major axis to 200 ±120 nm and an eccentricity to 1,8 ± 0,6. It is shown that the nanoparticles after heating become a cropped ellipsoid.

Detection and Characterization of earth-like Planets

1997 ◽  
Vol 161 ◽  
pp. 299-311 ◽  
Author(s):  
Jean Marie Mariotti ◽  
Alain Léger ◽  
Bertrand Mennesson ◽  
Marc Ollivier
Keyword(s):  
Direct Detection ◽  
Contrast Ratio ◽  
Angular Size ◽  
Physical Nature ◽  
Major Axis ◽  
Infrared Emission ◽  
Space Technology ◽  
Semi Major Axis ◽  
Earth Like Planets ◽  
Visible Wavelengths

AbstractIndirect methods of detection of exo-planets (by radial velocity, astrometry, occultations,...) have revealed recently the first cases of exo-planets, and will in the near future expand our knowledge of these systems. They will provide statistical informations on the dynamical parameters: semi-major axis, eccentricities, inclinations,... But the physical nature of these planets will remain mostly unknown. Only for the larger ones (exo-Jupiters), an estimate of the mass will be accessible. To characterize in more details Earth-like exo-planets, direct detection (i.e., direct observation of photons from the planet) is required. This is a much more challenging observational program. The exo-planets are extremely faint with respect to their star: the contrast ratio is about 10−10at visible wavelengths. Also the angular size of the apparent orbit is small, typically 0.1 second of arc. While the first point calls for observations in the infrared (where the contrast goes up to 10−7) and with a coronograph, the latter implies using an interferometer. Several space projects combining these techniques have been recently proposed. They aim at surveying a few hundreds of nearby single solar-like stars in search for Earth-like planets, and at performing a low resolution spectroscopic analysis of their infrared emission in order to reveal the presence in the atmosphere of the planet of CO H2O and O3. The latter is a good tracer of the presence of oxygen which could be, like on our Earth, released by biological activity. Although extremely ambitious, these projects could be realized using space technology either already available or in development for others missions. They could be built and launched during the first decades on the next century.

Seed-mediated synthesis and PEG coating of gold nanoparticles for controlling morphology and sizes

MRS Advances ◽  
2020 ◽  
Vol 5 (63) ◽  
pp. 3353-3360
Author(s):  
Susana Helena Arellano Ramírez ◽  
Perla García Casillas ◽  
Christian Chapa González
Keyword(s):  
Gold Nanoparticles ◽  
Polyethylene Glycol ◽  
Room Temperature ◽  
Colloidal Stability ◽  
Infrared Spectrometry ◽  
Ammonium Bromide ◽  
Chloroauric Acid ◽  
Vis Spectroscopy ◽  
Seed Mediated ◽  
Peg Coating

AbstractA significant area of research is biomedical applications of nanoparticles which involves efforts to control the physicochemical properties through simple and scalable processes. Gold nanoparticles have received considerable attention due to their unique properties that they exhibit based on their morphology. Gold nanospheres (AuNSs) and nanorods (AuNRs) were prepared with a seed-mediated method followed of polyethylene glycol (PEG)-coating. The seeds were prepared with 0.1 M cetyltrimethyl-ammonium bromide (CTAB), 0.005 M chloroauric acid (HAuCl4), and 0.01 M sodium borohydride (NaBH4) solution. Gold nanoparticles with spherical morphology was achieved by growth by aggregation at room temperature, while to achieve the rod morphology 0.1 M silver nitrate (AgNO3) and 0.1 M ascorbic acid solution were added. The gold nanoparticles obtained by the seed-mediated synthesis have spherical or rod shapes, depending on the experimental conditions, and a uniform particle size. Surface functionalization was developed using polyethylene glycol. Morphology, and size distribution of AuNPs were evaluated by Field Emission Scanning Electron Microscopy. The average size of AuNSs, and AuNRs was 7.85nm and 7.96 x 31.47nm respectively. Fourier transform infrared spectrometry was performed to corroborate the presence of PEG in the AuNPs surface. Additionally, suspensions of AuNSs and AuNRs were evaluated by UV-Vis spectroscopy. Gold nanoparticles were stored for several days at room temperature and it was observed that the colloidal stability increased once gold nanoparticles were coated with PEG due to the shield formed in the surface of the NPs and the increase in size which were 9.65±1.90 nm of diameter for AuNSs and for AuNRs were 29.03±5.88 and 8.39±1.02 nm for length and transverse axis, respectively.

scholarly journals Some Special Types of Orbits around Jupiter

Aerospace ◽  
2021 ◽  
Vol 8 (7) ◽  
pp. 183
Author(s):  
Yongjie Liu ◽  
Yu Jiang ◽  
Hengnian Li ◽  
Hui Zhang
Keyword(s):  
Gravity Model ◽  
Small Perturbation ◽  
Equilibrium Points ◽  
Major Axis ◽  
Semi Major Axis ◽  
Ground Track ◽  
The Earth ◽  
Degenerate Equilibrium ◽  
The Mean ◽  
Element Theory

This paper intends to show some special types of orbits around Jupiter based on the mean element theory, including stationary orbits, sun-synchronous orbits, orbits at the critical inclination, and repeating ground track orbits. A gravity model concerning only the perturbations of J2 and J4 terms is used here. Compared with special orbits around the Earth, the orbit dynamics differ greatly: (1) There do not exist longitude drifts on stationary orbits due to non-spherical gravity since only J2 and J4 terms are taken into account in the gravity model. All points on stationary orbits are degenerate equilibrium points. Moreover, the satellite will oscillate in the radial and North-South directions after a sufficiently small perturbation of stationary orbits. (2) The inclinations of sun-synchronous orbits are always bigger than 90 degrees, but smaller than those for satellites around the Earth. (3) The critical inclinations are no-longer independent of the semi-major axis and eccentricity of the orbits. The results show that if the eccentricity is small, the critical inclinations will decrease as the altitudes of orbits increase; if the eccentricity is larger, the critical inclinations will increase as the altitudes of orbits increase. (4) The inclinations of repeating ground track orbits are monotonically increasing rapidly with respect to the altitudes of orbits.

scholarly journals Dynamical properties of the Molniya satellite constellation: long-term evolution of the semi-major axis

2021 ◽  
Author(s):  
Jérôme Daquin ◽  
Elisa Maria Alessi ◽  
Joseph O’Leary ◽  
Anne Lemaitre ◽  
Alberto Buzzoni
Keyword(s):  
Major Axis ◽  
Long Term Evolution ◽  
Semi Major Axis ◽  
Satellite Constellation ◽  
Term Evolution ◽  
Dynamical Properties

scholarly journals Creation/destruction of ultra-wide binaries in tidal streams

2020 ◽  
Author(s):  
Jorge Peñarrubia
Keyword(s):  
Globular Clusters ◽  
Galactic Halo ◽  
Local Density ◽  
Formation Rate ◽  
Semimajor Axis ◽  
Major Axis ◽  
Binding Energies ◽  
Semi Major Axis ◽  
The Mean ◽  
Tidal Streams

Abstract This paper uses statistical and N-body methods to explore a new mechanism to form binary stars with extremely large separations (≳ 0.1 pc), whose origin is poorly understood. Here, ultra-wide binaries arise via chance entrapment of unrelated stars in tidal streams of disrupting clusters. It is shown that (i) the formation of ultra-wide binaries is not limited to the lifetime of a cluster, but continues after the progenitor is fully disrupted, (ii) the formation rate is proportional to the local phase-space density of the tidal tails, (iii) the semimajor axis distribution scales as p(a)da ∼ a1/2da at a ≪ D, where D is the mean interstellar distance, and (vi) the eccentricity distribution is close to thermal, p(e)de = 2ede. Owing to their low binding energies, ultra-wide binaries can be disrupted by both the smooth tidal field and passing substructures. The time-scale on which tidal fluctuations dominate over the mean field is inversely proportional to the local density of compact substructures. Monte-Carlo experiments show that binaries subject to tidal evaporation follow p(a)da ∼ a−1da at a ≳ apeak, known as Öpik’s law, with a peak semi-major axis that contracts with time as apeak ∼ t−3/4. In contrast, a smooth Galactic potential introduces a sharp truncation at the tidal radius, p(a) ∼ 0 at a ≳ rt. The scaling relations of young clusters suggest that most ultra-wide binaries arise from the disruption of low-mass systems. Streams of globular clusters may be the birthplace of hundreds of ultra-wide binaries, making them ideal laboratories to probe clumpiness in the Galactic halo.

scholarly journals Facile Green, Room-Temperature Synthesis of Gold Nanoparticles Using Combretum erythrophyllum Leaf Extract: Antibacterial and Cell Viability Studies against Normal and Cancerous Cells

Antibiotics ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 893
Author(s):  
Olufunto T. Fanoro ◽  
Sundararajan Parani ◽  
Rodney Maluleke ◽  
Thabang C. Lebepe ◽  
Jose R. Varghese ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Cell Viability ◽  
Leaf Extract ◽  
Room Temperature ◽  
Klebsiella Oxytoca ◽  
Cost Effective ◽  
Average Diameter ◽  
Antibacterial Activities ◽  
Inhibition Concentration ◽  
First Time

We herein report a facile, green, cost-effective, plant-mediated synthesis of gold nanoparticles (AuNPs) for the first time using Combretum erythrophyllum (CE) plant leaves. The synthesis was conducted at room temperature using CE leaf extract serving as a reducing and capping agent. The as-synthesized AuNPs were found to be crystalline, well dispersed, and spherical in shape with an average diameter of 13.20 nm and an excellent stability of over 60 days. The AuNPs showed broad-spectrum antibacterial activities against both pathogenic Gram-positive (Staphylococcus epidermidis (ATCC14990), Staphylococcus aureus (ATCC 25923), Mycobacterium smegmatis (MC 215)) and Gram-negative bacteria (Proteus mirabilis (ATCC 7002), Escherichia coli (ATCC 25922), Klebsiella pneumoniae (ATCC 13822), Klebsiella oxytoca (ATCC 8724)), with a minimum inhibition concentration of 62.5 µg/mL. In addition, the as-synthesized AuNPs were highly stable with exceptional cell viability towards normal cells (BHK- 21) and cancerous cancer cell lines (cervical and lung cancer).

EFFECTS OF INITIAL INHOMOGENEOUS DENSITY DISTRIBUTION AND VOID SHAPE ON POWDER FORGING OF POROUS METAL

2013 ◽  
Vol 27 (19) ◽  
pp. 1341008
Author(s):  
TAIQING DENG ◽  
LIANXI HU ◽  
YU SUN ◽  
XIAOYA LIU
Keyword(s):  
Density Distribution ◽  
Initial Density ◽  
Porous Metal ◽  
Major Axis ◽  
Average Density ◽  
Semi Major Axis ◽  
Punch Force ◽  
Inhomogeneous Density ◽  
Void Shape ◽  
Initial Density Distribution

The deformation behavior during axisymmetric upsetting of sintered metals has been studied based on the finite-element method. The investigation on the effects of the initial density distribution, void shape and die friction on the density distribution and punch force during deformation have been conducted. It was found that under low-friction conditions, the initial density distribution affects the deformation geometry and the density distribution. However, the effect of the initial density distribution was found to be negligible under high-friction conditions. The initial density distribution did not affect the punch force or the average density, regardless of the friction conditions. When the force is perpendicular to semi-major axis of elliptical void, it is not only good for densification but also decrease the punch force in forging of porous metal.

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