scholarly journals Levels of some chemical species in water of boreholes situated near dumpsites in Rumuolumeni, Port Harcourt, Rivers State, Nigeria

2021 ◽  
Vol 12 (2) ◽  
pp. 202-211
Author(s):  
Nwoke IB ◽  
Edori ES
Keyword(s):  
Heavy Metals ◽  
Health Risk ◽  
Atomic Absorption ◽  
Chemical Species ◽  
Atomic Absorption Spectrophotometer ◽  
Mean Values ◽  
Port Harcourt ◽  
The Mean ◽  
The Government ◽  
Rivers State

The concentration of six chemical species Pb, Cd, As, nitrates, fluorides and sulphates in the groundwater (borehole) samples were investigated in four boreholes sited close to a dumpsite in Rumuolumeni, Port Harcourt, Rivers State, Nigeria. Nitrates, fluorides and sulphates were analyzed using standard conventional methods while the heavy metals were determined and analyzed with Atomic Absorption Spectrophotometer. The mean values obtained for the different chemical species within the months of investigation for the stations were in the range: lead; 0.012±0.001-0.015±0.000mg/L, with an average of 0.013±0.001mg/L within the months, Cd; 0.004±0.002-0.005±0.001mg/L, with an average of 0.005±0.001mg/L within the months, As; 0.002±0.001-0.003±0.002mg/L, with an average of 0.003±0.001mg/L within the months, nitrates; 0.413±0.172-0.730±0.691mg/L, with an average of 0.511±0.139mg/L within the months, fluorides; 0.004±0.001-0.006±0.001mg/L, with an average of 0.005±0.001mg/L within the months and sulphates; 0.197±0.046-0.338±0.072mg/L, with an average of 0.290±0.055mg/L within the months. These values obtained for the different chemical species showed that the boreholes sited near the dumpsite were still at the level that will not pose any health risk to the user, for their concentrations were still within limits allowed by WHO and USEPA. Even though the government and its agencies should regulate the mode of dumping of refuse and also the siting of boreholes so that the groundwater will not be polluted.

Evaluation of heavy metals content in the canned/packed fruit juices from local and imported origin in Lahore, Pakistan

2021 ◽  
Author(s):  
Nazeefa Fatima ◽  
Munazza Khan ◽  
Muhammad Shuaib Kabeer
Keyword(s):  
Heavy Metals ◽  
Atomic Absorption ◽  
Fruit Juices ◽  
Human Consumption ◽  
Acid Digestion ◽  
Digestion Method ◽  
Mean Values ◽  
Nutritive Values ◽  
The Mean ◽  
Mean Concentration

This study was conducted to determine the mean concentration of heavy metals such as lead (Pb), copper (Cu), zinc (Zn), chromium (Cr), manganese (Mn), nickel (Ni), selenium (Se), magnesium (Mg), and iron (Fe) in canned/packed fruits juices, collected from various stores in Lahore in a period of three months. These juices were categorized into four groups; local packed and canned and also imported packed and canned products. Every group consisted of ten samples. By using the di-acid digestion method, the collected samples were digested and analyzed under Atomic Absorption Spectrophotometer (AAS). The results indicated that the mean values of 7 out of 9 tested heavy metals including Pb, Mg, Ni, Fe, Cr, Se and Mn were above permissible limits (set by WHO) in all four understudy groups. Therefore, it was concluded that commercially available fruit juices are not all safe according to their heavy metals content for the human consumption despite their nutritive values.

scholarly journals Analysis of Heavy Metals Concentrations in Food Spices from Some Markets in Port Harcourt Meteropolis, Rivers State, Nigeria

2020 ◽  
pp. 61-69
Author(s):  
Austin A. Okwelle ◽  
Tamunosisi F. Mac- Pepple
Keyword(s):  
Heavy Metals ◽  
Daily Intake ◽  
Risk Level ◽  
Human Beings ◽  
Toxic Heavy Metals ◽  
Minimum Risk ◽  
Port Harcourt ◽  
Regular Consumption ◽  
The Mean ◽  
Rivers State

This study analysed the levels of some heavy metals like copper (Cu), cadmium (Cd), chromium(Cr), nickel (Ni) and lead (Pb) present in selected food spices widely used in Port Harcourt, Rivers State, Nigeria. The Atomic Absorption Spectroscopy (AAS) and wet digestion was used for analysis. The results revealed different concentrations of heavy metals in the food spices analysed. The mean and standard deviation of heavy metals across the samples revealed that copper had the highest concentration in tomatoes (15.45±5.09 mg/Kg), curry (10.30±2.03 mg/Kg), garlic (8.65±2.08 mg/Kg), onions (6.50±2.52 mg/Kg) and uda (6.15±3.75 mg/Kg) respectively. Chromium was only detected in curry (2.75±1.00 mg/Kg), pepper (0.65±0.02 mg/Kg) and salt (0.05±0.00 mg/kg). The detected level of nickel was high in tomatoes (6.90±4.89 mg/Kg), curry (4.09±1.90 mg/Kg), salt (6.15±3.70 mg/Kg) and onions (3.09±2.10 mg/Kg). Lead occurred more in uda (3.08±2.87 mg/Kg), tomatoes (3.80±1.28 mg/Kg), curry (2.86±1.34 mg/Kg) and salt (2.60±0.76 mg/Kg) respectively. Cadmium was not detected in any of the food spices, while in chilles spice no heavy metals was detected. The daily intake limit was calculated and compared with minimum risk level (MRL) values. The concentrations of lead in some of the food spices were much larger than those of MRL values. The regular consumption of the spices can lead to accumulation of these toxic heavy metals in human beings.

scholarly journals Assessment of Some Heavy Metal Content of Dried Crayfish Sold in Creek Road Market, Borokiri, Port Harcourt, Nigeria

2019 ◽  
pp. 1-6
Author(s):  
H. A. Waribo ◽  
E. S. Bartimaeus ◽  
I. C. Onuoha
Keyword(s):  
Heavy Metals ◽  
Atomic Emission ◽  
Mercury Content ◽  
Permissible Limit ◽  
Lead Content ◽  
Mean Values ◽  
Muscle Tissues ◽  
Standard Procedures ◽  
Port Harcourt ◽  
Rivers State

Heavy metals are elements that contaminate seafood and make them harmful to human health when present in quantities that are higher than the permissible limit. This study was conducted to determine some heavy metals such as lead and mercury contained in dried crayfish gotten from three different locations (Oron, Ataba and Nembe town in Akwa Ibom, Rivers and Bayelsa State respectively) and sold in the Creek Road Market, Borokiri, Port Harcourt, Rivers State. The dried crayfish samples were purchased randomly from marketers in the market. 5g of the dried crayfish samples with its different organs (Gills, muscle tissues) were ground into powdered form and digested with HNO3  using standard procedures   and analysed for lead and mercury using the micro plasma atomic emission spectrophotometric analyser. The results showed that Lead content in the dried crayfish from Oron, Ataba and Nembe were 0.140 ± 0.014 mg/kg, 0.040 ± 0.014 mg/kg and 0.016 ± 0.002 mg/kg respectively while for Mercury content, Oron crayfish contained 5.136 ± 0.017 mg/kg, Ataba 3.744 ± 0.017 mg/kg and Nembe 3.948 ± 0.023mg/kg. The mean values in the three different crayfish samples were significantly different (p<0.05). This result shows that the lead content present in the dried crayfish are within the permissible limit of 1 mg/kg as indicated by FAO hence safe for consumption purposes with no expected form of toxicity and health implication to consumers whereas for mercury content, the level was found to be above the permissible limit.

scholarly journals Application of pollution assessment models in soil contaminated by heavy metals in two steel rods markets, Port Harcourt, Rivers State, Nigeria

2021 ◽  
Vol 9 (2) ◽  
pp. 025-035
Author(s):  
Edori ES ◽  
Iyama WA ◽  
Edori OS
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
Risk Index ◽  
Pollution Assessment ◽  
Potential Ecological Risk ◽  
Control Site ◽  
Contamination Degree ◽  
Port Harcourt ◽  
The Mean ◽  
Rivers State

Soil samples were collected at a depth of 0-30cm within two steel markets and a control site in Port Harcourt, Rivers State Nigeria to assess the level of heavy metals (Fe, Pb, Cu, Cd, Cr, Ni and As) in the environment. Atomic Adsorption Spectrophotometer was used to analyze the samples for heavy metals. The concentrations of all the heavy metals in the steel rods markets exceeded that of the control. The results indicated that heavy metals concentrations in the sites were in the order; Mile III > Kala > RSU. The average levels of contamination of heavy metals recorded followed the order Fe > Cr > Cu > Pb > Ni > As > Cd in Mile III, Fe > Pb > Cu > Cr > Ni > As > Cd in Kala and Fe > Cu > Pb > Cr > Ni > As > Cd in RSU (control). Mean concentrations obtained for heavy metals within the months of investigation were; 1420.931±9.155, 7.753±0.184, 8.730±0.050, 2.843±0.124, 9.428±0.122, 7.433±0.047 and 3.732±0.047 mg/Kg for Fe, Pb, Cu, Cd, Cr, Ni and As respectively at the mile III station, while the mean concentrations of heavy metals observed at the Kala station were; 1161.173±1.823, 9.425±0.054, 7.596±0.027, 1.425±0.020, 6.507±0.006, 5.455±0.033 and 1.901±0.010 mg/Kg for Fe, Pb, Cu, Cd, Cr, Ni and As respectively. The mean values of heavy metals concentrations observed at the RSU station within the period were; 892.064±1.025,5.603±0.007, 5.841±0.051, 0.173±0.005, 3.389±0.009, 2.309±0.010 and 0.706±0.006 mg/Kg for Fe, Pb, Cu, Cd, Cr, Ni and As respectively. Pollution assessment models used for assessing the anthropogenic input on the quality of the soil in the area using the control site as the basis of judgment were: contamination factor (CF), pollution load index (PLI), contamination degree (CD), modified contamination degree (mCD), potential ecological risk coefficient (Eir), potential ecological risk index (RI), Geo-accumulation index (Igeo) and anthropogenicity. These indices revealed that the steel markets were contaminated and polluted and poses ecological risks by heavy metals, even though the values obtained were still below the WHO acceptable limits. The steel rods markets need to be adequately monitored and regulated to avoid further soil contamination by heavy metals to a degree that will be dangerous to human health.

scholarly journals COMPARATIVE ANALYSIS OF SOME HEAVY METALS LEVELS IN LEAVES, PEELS AND TUBERS OF CASSAVA PLANTED ALONG EAST-WEST ROAD RIVERS STATE

2021 ◽  
Vol 9 (8) ◽  
pp. 1-13
Author(s):  
Isaac Eguarkhide Ogah ◽  
Ekpete A. Ozioma
Keyword(s):  
Heavy Metals ◽  
Comparative Analysis ◽  
Mean Values ◽  
Cassava Leaves ◽  
Safe Limit ◽  
The Mean ◽  
Rivers State ◽  
The Impact ◽  
Mean Concentration ◽  
East West

Introduction: Pollution of the environment by heavy metals has caused serious environmental problems, which threatens the existence of various ecological system, agriculture and human health. This study assessed the comparative analysis of some heavy metals levels in leaves, peels and tubers of cassava planted along East-West Road Rivers State. Materials/Methods: Cassava leaves and tubers samples were collected from farmlands along East-West road (SX, SY and SZ communities, in Emohua, Tai, and Ahoada West LGA respectively), Rivers state, Nigeria. The samples were monitored for heavy metals levels to assess the impact of automobiles on cassava peels, leaves and tubers using Solar Thermo Elementary Atomic Absorption Spectrometer, ModelSG 71906. Metals studied were Lead (Pb), Nickel (Ni), Chromium (Cr), Cadmium (Cd), and Arsenic (As). Results: The mean concentration of Ni present in leaf was 2.81±0.104 mg/kg, tubers recorded 2.23±0.073 mg/kg and peels 3.20±0.06 mg/kg. The highest concentration (4.064±0.035 mg/kg) of Ni was observed in peels while the least concentration (1.80±1.023 mg/kg) was recorded in the tubers. The mean values of Pb in leaves, tubers and peels were 2.22±1.023 mg/kg, 1.80±1.023 mg/kg and 2.64±0.32, highest concentration was recorded in tubers. Arsenic values were 0.16±0.020 mg/kg > 0.51±0.021 mg/kg > 0.38±0.203 mg/kg in peels, tubers and leaves respectively. The values of As were above WHO safe limit of 0.1mg/kg. Also, the mean values of cadmium in leaves, tubers and peels were 0.054±0.570 mg/kg, 0.046±0.057 mg/kg and 0.16±0.609 mg/kg respectively. The highest concentration (0.138±0.109 mg/kg) was in the tubers. Finally, chromium was found to be present in all the cassava samples (leaves, peels and tubers). The mean concentration of chromium (Cr) was 3.58±0.023 mg/kg, 2.76±0.005 mg/kg and 3.83±0.203 mg/kg in leaves, tubers and peels respectively. Conclusion: From the findings, heavy metals were found in the samples and thus, crops should be cultivated far away from major roads.

scholarly journals Heavy Metals (Cd, Pb, and Zn) Residue in Selected Tissue and Organs of Slaughtered Goat-Meat randomly selected from Markets in Ayegbaju-Ekiti, Akure, and Owena

2020 ◽  
Vol 10 (1) ◽  
pp. 1896-1903
Keyword(s):  
Heavy Metals ◽  
Atomic Absorption ◽  
General Trend ◽  
Atomic Absorption Spectrophotometer ◽  
Goat Meat ◽  
Health Implications ◽  
Permissible Limits ◽  
Zn Content ◽  
The Mean ◽  
Mean Concentration

This study investigated Cadmium (Cd), Lead (Pb), and Zinc (Zn) content of some selected organs (liver, kidney, heart, and intestine) and tissue (blood) of slaughtered goats randomly sampled from central markets in Ayegbaju-Ekiti, Akure and Owena, South-western Nigeria. Atomic Absorption Spectrophotometer (AAS) was used to determine the level of heavy metals based on comparison with standards. The mean concentrations obtained Zn were detected in all samples investigated, but Cd was undetected in some samples, especially the liver and blood of goat from Owena. The general trend in the mean concentration of metals was Zn>Pb>Cd, in tissue and organs was kidney > liver > intestine > heart > blood, and in-market, with respect to metals, was Akure > Ayegbaju-Ekiti=Owena for Cd, Ayegbaju-Ekiti > Akure > Owena for Pb and Owena > Akure > Ayegbaju-Ekiti for Zn. All the metals in some samples of goat, especially Cd in the kidney (2.50±2.18) from Akure, Pb in the kidney (19.00±9.17 mg/kg) from Ayegbaju-Ekiti and intestine (15.00±17.35 mg/kg) from Akure as well as Zn in the heart (71.50±95.90 mg/kg) from Ayegbaju-Ekiti, had a mean concentration in excess of the permissible limits set by FAO/WHO. Some of the tissue and organs of goats sampled from the studied area were therefore polluted with all the metals investigated, and their consumption may have health implications.

scholarly journals Heavy metal levels in spent engine oils and fingernails of auto-mechanics

2021 ◽  
Vol 32 (1) ◽  
pp. 28-32
Author(s):  
Chris Oche Ikese ◽  
Peter Agorye Adie ◽  
Christie Adah ◽  
Raphael Amokaha ◽  
Grace Abu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Atomic Absorption ◽  
Atomic Absorption Spectrophotometer ◽  
Exposure Limits ◽  
Engine Oils ◽  
Metal Levels ◽  
Study Population ◽  
Permissible Exposure Limits ◽  
The Mean

Abstract The levels of some heavy metals in spent engine oils and in the fingernails of auto-mechanics were studied. Engine oils and fingernails were collected from auto-mechanics who had practiced between ≤ 5 years, ≤ 10 years and ≤ 15 years in 3 auto-mechanic workshop clusters. Pb, Ni, V, Cd, and As levels were determined using Atomic Absorption Spectrophotometer. The mean levels of Pb, Ni, V and Cd in spent engine oils were 14.31, 2.25, 0.38 and 2.07 ppm respectively, and these far exceeded their permissible exposure limits. The mean levels of heavy metals in the fingernails of auto-mechanics who had practiced for ≤ 5 years, ≤ 10 years and ≤ 15 years were all considerably below their pathological thresholds. Thus, auto-mechanics in the study area are exposed to unsafe levels of Pb, Ni, V, and Cd, but no immediate threat of their toxicities in the study population exist. However, a progressive bioaccumulation of the heavy metals was observed with increase in years of practice.

scholarly journals The Effects of Processing On Heavy Metals Concentrations and Health Risk Assessment in African Palm Weevil (Rhynchophorus Phoenicis) Larvae

2020 ◽  
Vol 3 (1) ◽  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Health Risk ◽  
Atomic Absorption ◽  
Health Risk Assessment ◽  
Dry Weight ◽  
Atomic Absorption Spectrophotometer ◽  
Health Concern ◽  
Palm Weevil ◽  
The Moment

This study investigated the concentrations of the heavy metals, Fe, Zn, Cu, Mn and Co in a raw and processed (boiled and fried) Rhynchophorus phoenicis larvae. The concentrations of the metals were measured using Thermal-Elemental Atomic Absorption Spectrophotometer (FAAS) S4-710-a6 model. The concentrations (mg/kg dry weight bases) of Fe, Zn, Cu, Mn and Co in raw, boiled and fried samples were; raw (10.23+0.08), (15.06+0.09), (5.19+0.01), (2.75+0.05) (1.75+0.12), boiled (7.24+0.19), (9.50+0.07), (4.11+0.09), (1.85+0.07), (2.00+0.00), and fried (6.25+0.06) (5.36+0.11), (3.31+0.04), (1.47+0.09), (2.88+0.07); respectively. The results showed a decreased order of Zn>Fe>Cu>Mn>Co in the raw sample, while the boiled and fried samples were in the order of Zn>Fe>Cu>Co>Mn. Generally, the observed trends were that the processing (boiling and frying) reduces the concentration of the metals except for Co where the highest concentration was found in the fried sample. The results of the non-carcinogenetic risk assessment were less than 1, which signifies no health concern at the moment. However, considering the toxicity and bioaccumulative nature of these metals, the frying practice is advocated, since it caused a significant decreased in most of the metals studied.

scholarly journals Determination of Heavy Metals in Crab and Prawn in Ojo Rivers Lagos, Nigeria

2010 ◽  
Vol 7 (2) ◽  
pp. 526-530 ◽  
Author(s):  
R. A. Olowu ◽  
O. O. Ayejuyo ◽  
A. Adejoroi ◽  
G. O. Adewuyi ◽  
M. O. Osundiya ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Atomic Absorption ◽  
Atomic Absorption Spectrophotometer ◽  
The Mean ◽  
Mean Concentration

The level of heavy metals in crabs and prawns was investigated using Atomic Absorption Spectrophotometer. The mean concentration of copper in the crab was 1.56±0.87 µg/g; the mean concentration of zinc in the crab was also 0.64±1.96 ܖg/g. Chromium had the highest mean concentration of 8.936±35.4 µg/g while cadmium had the lowest mean of 1.66±1.82 µg/g lead was not detected. The mean concentration of heavy metals in prawn samples were follows: copper: 1.04±0.6 µg/g, cadmium: 0.07±0.08 µg/g, chromium: 4.06±7.00 µg/g and Zn 0.64±0.45 µg/g. Lead was not detected in prawn. The mean concentration of copper, cadmium and zinc in prawn was observed to be within the range NAFDAC standard for water and aquatic foods while crabs have higher mean concentration of heavy metals with the exception of zinc and copper are within the limit.

Evaluation of chemical contamination of surface water and groundwater in the landfill city of Ardabil

2015 ◽  
Vol 16 (SE) ◽  
pp. 631-637
Author(s):  
Maliheh Shahmorad Moghanlou ◽  
Ebrahim Fataei
Keyword(s):  
Heavy Metals ◽  
Surface Water ◽  
International Standards ◽  
Chemical Contamination ◽  
Mean Values ◽  
Surface Water And Groundwater ◽  
Turbidity Level ◽  
The Mean ◽  
Spss Software ◽  
Hydrodynamic Thickness

Todays in our country the problem of waste disposal and the effects of entry alluvial aquifer their leachate and pollution of aquifers by hydrodynamic thickness in the direction of groundwater flow is highly regarded analytical descriptive study was conducted. To this purpose, the concentration of heavy metals plumb and cadmium and some physicochemical and biological parameters of surface water and groundwater around the landfill city of Ardabil in two time periods in spring 2015 and summer seasons were measured. Sampling, preparation and analysis of samples in accordance with the standard method of station 10 to within 5.5 km of landfill were Ardabil. Measurement of heavy metals, plumb and cadmium by atomic absorption were performed. The Results were analyzed by SPSS software, for the comparison of each parameter with drinking water standards and Agriculture tests comparing the average (T-TEST) was used. The results showed that groundwater and surface water of heavy metals, non-contaminated area and their results are below international standards. The mean values ??of microbiological and physicochemical parameters other than normal turbidity level and at the level of 1% were significantly lower than international standards.

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