scholarly journals A study of the effect of nano materials on the physical properties of epoxy composites

2019 ◽  
Vol 15 (32) ◽  
pp. 68-76
Author(s):  
Teba Mageed Hameed

This research studies the effect of addition of some nanoparticles(MgO, CuO) and grain size (30,40nm) on some physical properties(impact strength, hardness and thermal conductivity) for a matrixblend of epoxy resin with SBR rubber. Hand –Lay up method wasused to prepare the samples. All samples were immersed in water for9 weeks.The Results showed decreased in the values of impact strength andhardness but increased the coefficient of thermal conductivity.

2010 ◽  
Vol 123-125 ◽  
pp. 1139-1142 ◽  
Author(s):  
Sawitri Srisuwan ◽  
Pranee Chumsamrong

In this study, the effects of weave type and fiber content on the physical properties of woven sisal fiber/epoxy composites were investigated. Sisal fibers used in this work were obtained from Nakhon Ratchasima, Thailand. Both untreated and alkali-treated fibers were employed. The woven sisal fibers were manufactured by hand weaving process. The fiber content in sisal fiber/epoxy composites were 3 wt.%, 5 wt.% and 10 wt.%. The composites were cured at room temperatures. In order to determine mechanical properties of the composites, flexural and impact tests were applied. Flexural strength and flexural modulus of all composites were higher than those of pure epoxy resin and tended to increase with increasing fiber content. The impact strength of all composites was lower than that of pure epoxy resin. The composites containing 10 wt.% sisal fibers showed the highest impact strength. There was no definite influence of weave type on flexural properties of the composites. At 3 and 5 wt.% fiber, the composites containing plain weave fibers seemed to show a higher impact strength than the composites containing other weave types.


Nanomaterials ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1264 ◽  
Author(s):  
Li Zhang ◽  
Wenfeng Zhu ◽  
Ying Huang ◽  
Shuhua Qi

One-dimensional silver nanowires (AgNWs) and two-dimensional graphene oxide (GO) were combined to construct a three-dimensional network structure. The AgNWs can effectively inhibit stacking of adjacent GO sheets by occupying regions between layers of GO. Moreover, the GO sheets embedded in the gaps of the AgNWs network increase the interfacial contact area between the AgNWs and the epoxy matrix, resulting in the formation of more efficient phonon transport channels. To prepare an epoxy-based thermal conductive composite, hybrid networks were fabricated and added to epoxy resin using a solution mixing method. Significant synergistic effects were observed between the AgNWs and GO sheets. The thermal conductivity of epoxy composites filled with 10 wt.% AgNW/GO hybrids was found to be 1.2 W/mK and the impact strength was 28.85 KJ/m2, which are higher than the corresponding values of composites containing AgNWs or GO sheets alone. Thus, the thermal conductivity and impact strength of the epoxy composites were improved. The additive effects are mainly owing to the improved interfacial contact between the hybrid fillers and the epoxy resin, resulting in a more efficient phonon transport network. The use of hybrid fillers with different structures is a simple and scalable strategy for manufacturing high-performance thermally conductive materials for electronic packaging.


2017 ◽  
Vol 25 (3) ◽  
pp. 229-236 ◽  
Author(s):  
S. Sathish ◽  
K. Kumaresan ◽  
L. Prabhu ◽  
N. Vigneshkumar

The aim of this paper is to study the effect of volume fraction on mechanical and physical properties such as tensile, flexural, impact, interlaminar shear strength, void content and water absorption of flax and bamboo fibers reinforced hybrid epoxy composites. Flax and bamboo fibers reinforced epoxy resin matrix hybrid composites have been fabricated by compression molding techniques. The hybrid composites were fabricated with different volume fraction of fibers. SEM analysis on the hybrid composite materials was performed to analyze the bonding behavior of materials and internal structure of the fractured surfaces. The effect of chemical treatment of flax and bamboo fibers was verified by FTIR analysis. The results showed that the tensile, impact, flexural and ILSS are maximum for 40:0 (flax: bamboo) hybrid composites. The void content decreased for 20:20 (flax:bamboo) composites due to tightly packed flax fiber and more compatibility towards epoxy resin.


2010 ◽  
Vol 658 ◽  
pp. 460-462
Author(s):  
Hai Yun Jin ◽  
Hui Cheng Shi ◽  
Bo He ◽  
Nai Kui Gao ◽  
Zeng Ren Peng

AlN filled epoxy composites were fabricated. The microstructure of composites was observed by SEM. The thermal conductivity was also measured. The results showed that microstructure of AlN/ epoxy composites was different with monolithic epoxy, it had some crystal-like characteristics. The grain size of AlN/ epoxy composites decreased with increasing AlN contents, and the thermal conductivity of composites increased with increasing AlN content. The thermal conductivity of 40wt. % AlN/ epoxy was about 3 times of monolithic epoxy.


2020 ◽  
Vol 16 ◽  
Author(s):  
Nadia A. Ali ◽  
Alaa M. Abd-Elnaiem ◽  
Seenaa I. Hussein ◽  
Asmaa Sh. Khalil ◽  
Hatem R. Alamri ◽  
...  

Objective: In this work, graphene (Gr) or/and Cu particles are used to improve the thermal and mechanical properties of epoxy resin. Methods: Various contents of Gr powder (0.1, 0.3, and 0.5 wt%), Cu powder (10, 30, and 50 wt%) were loaded to epoxy to form Gr/epoxy and Cu/epoxy composites, respectively. In addition, hybrids epoxy/Cu/Gr samples were prepared with a selection of lowest (0.1 and 10) and highest (0.5 and 50) ratios of Gr, and Cu, respectively. Results: The thermal conductivity increases with the increasing weight ratio of Gr and Cu as compared to the pure epoxy. The Thermogravimetric analysis (TGA) of epoxy composites and hybrid composites reveals an improvement in the thermal stability. In addition, the mechanical properties such as hardness shore D and the wear resistance are enhanced for both the epoxy composites and hybrids composites. However, the Ep+0.5wt%Gr+50wt%Cu hybrid composite has the maximum hardness 84, thermal conductivity of 3.84 W/m.K, it shows the lowest wear resistance 2.7×10-6 mm3/Nm at loading 10 N. Conclusion: The hybrid composite containing 0.5wt%Gr and 50wt%Cu shows the maximum hardness and thermal conductivity, as well as the lowest wear resistance when compared to other composites. The physical properties of the hybrid composite can be controlled by the host blend, and hence the morphology, and interfacial characteristics.


1973 ◽  
Vol 13 (05) ◽  
pp. 267-273 ◽  
Author(s):  
J. Anand ◽  
W.H. Somerton ◽  
E. Gomaa

Abstract Measuring the thermal properties of rocks and rock-fluid systems is difficult and time consuming and the results from such measurements are of limited value unless complete descriptions of the rock and fluids are given. A need exists for a method of predicting thermal behavior from other more easily measurable properties. Presented here are correlations developed for predicting the thermal conductivity of consolidated sandstones from a knowledge of density, porosity, permeability, and formation resistivity factor. Values for all these properties are available from well logs or core properties are available from well logs or core analysis data. Also obtained were correlations for estimating the thermal conductivity of liquid-saturated sandstones from a knowledge of the conductivities of dry sandstone. The thermal conductivity of most rocks decreases with increasing temperature and a method of estimating this effect is presented. The effect of pressure on conductivities is generally small, but may be predicted from a knowledge of the bulk predicted from a knowledge of the bulk compressibility of the rock. Introduction Although thermal recovery processes have been applied in the petroleum industry for many years, there is still a lack of basic thermal data with which predict the performance of these processes. Much of the thermal conductivity work reported in the literature lacks a complete description of the physical properties of the rocks used, and in physical properties of the rocks used, and in addition, most of the thermal conductivity measurements have been made at room temperature and at atmospheric pressure. The work reported in this paper deals with the thermal conductivity of typical porous rocks at simulated subsurface conditions of temperature, pressure, and saturation. Because thermal conductivity is difficult to measure, emphasis has been placed here on methods of predicting thermal conductivity from other more easily measured properties as well as on methods of predicting the effects of temperature, pressure, and liquid saturation on thermal properties. pressure, and liquid saturation on thermal properties. RELATIONSHIP OF THERMAL CONDUCTIVITY TO OTHER PHYSICAL PROPERTIES The thermal conductivities of dry rocks have been shown to be functions of density, porosity, grain size and shape, cementation, and mineral composition. The first two properties are easy to measure and precise values may, be assigned for correlation purposes. Grain size and shape and cementation are difficult to quantify. There are, however, other related properties that can be used to characterize these properties for use in correlations. Permeability and formation resistivity factors are probably most closely related to these properties and are readily measurable as unique properties and are readily measurable as unique values. Precise mineral composition values are generally not available, and even A they were, it would be difficult to introduce them into correlations. The high thermal conductivity of quartz seems to have a predominating influence, and thus for most sandstones containing quartz in moderate amounts, the effects of other minerals can be ignored. Many efforts have been made to relate thermal conductivity to the physical properties of porous rocks. These efforts have been reviewed in rather complete detail by Scorer and Anand. Unfortunately, most of the correlations developed require a knowledge of the thermal conductivity of the rock matrix or the dry rock at some known porosity. Although some simple correlations have porosity. Although some simple correlations have been obtained, these are for specific systems and are not applicable generally. Probably the most useful work in this area is that reported by Zierfuss and Van der Vliet. Basing their analysis on 36 sandstones having a wide range in measured properties, they obtained a correlation between properties, they obtained a correlation between effective porosity and the product of thermal conductivity and formation resistivity factor. A fourth-order polynomial fit of thermal conductivity and fractional porosity was obtained by regression analysis. Their data also seemed to indicate that thermal conducting increases with permeability, this being attributed to conduction with permeability. SPEJ P. 267


2019 ◽  
Vol 58 (4) ◽  
pp. 98-101
Author(s):  
Vladimir Yu. Chukhlanov ◽  
◽  
Kirill V. Smirnov ◽  
Natalia V. Chukhlanova ◽  
◽  
...  

In this article the physical-mechanical, thermal and electrical properties of spheroplastic based on epoxy resin ED-20 and hollow phenol-formaldehyde microspheres were studied. The samples were obtained by mixing an epoxy resin, cured with polyethylene polyamine, with hollow phenol-formaldehyde microspheres, poured into a mold and then cured at room temperature. The influence of the filler on the kinetics of the interaction of epoxy oligomer and aliphatic polyamine was studied. The effect of reducing the time of gel formation may occur due to the possible presence of reactive groups on the surface of microspheres. The experiments showed that the introduction of hollow phenol-formaldehyde microspheres in General leads to a slight decrease in the gel formation time. It is established that the introduction of hollow microspheres into the composition leads to a decrease in the density of the finished composition. The impact strength of spheroplastic was determined in accordance with GOST 4647-2015 "Method of Charpy impact strength determination" (ISO 179-1: 2010, NEQ). The introduction of hollow microspheres into the composition leads to a change in the impact strength of the composition in the direction of its decrease. A similar trend is observed in the study of the strength in the separation from the substrate of different materials. The coefficient of thermal conductivity was determined in a stationary mode on the device ITP-MG4"100" GOST 7076-99 "Method for determining the thermal conductivity and thermal resistance in a stationary thermal regime." Studies have shown that an increase in the content of hollow microspheres in the composition to 15% leads to a gradual decrease in the thermal conductivity coefficient to 0.74 W/m∙K. The studied materials can be used as thermal insulation materials and for the manufacture of products used in various fields of science and technology.


Author(s):  
A. S. Mostovoi ◽  
A. S. Nurtazina ◽  
Yu. A. Kadykova

The aim of this work is to increase the physicochemical, deformation and strength properties and to reduce the combustibility of composites on the base of epoxy resin by introducing a oligo(resorcinophenyl phosphate) with terminal phenyl groups Fyrolflex - modifier of polyfunctional action, and disperse mineral fillers – diorite and chromite. Result of the studies established that the optimum amount of modifier in the composition of the epoxy resin is 40 mass parts, which provides an increase in the operational properties of the composites: the breaking stress at bending increases by 2 times, the breaking stress at compression increases by 28%, the impact strength increases twice, while the modulus of elasticity and hardness of composites slightly decrease. The addition of modifier into the epoxy polymer provides an increase in heat resistance from 86 to 132–156 °C, also it improves the thermal stability of the composite, which manifests itself in a shift from the initial temperature to higher temperatures (from 200 to 230 °C), while it is noticed furthermore that yield of carbonized Structures was risen from 40 to 54%, providing less release of volatile pyrolysis products into the gas phase, which leads to the decrease in flammability of the epoxy composite and it can be shown in the reduction of its loss in mass while cauterizing in air from 78 to about 4.7% and an increase in the oxygen index from 19 to 28% by volume what transfers the material into class with low flammability. The rational content of diorite and chromite (100 parts by weight of chromite and 50 parts by mass of diorite) is chosen as a filler, which ensures an increase in physical and mechanical characteristics and a reduction in the cost of production: the breaking stress increases by 15–30% and the elastic modulus at bending increases 3.5–4.5 times, the breaking stress increases by 35%, and the tensile modulus by 50–240%, the hardness increases by 68–95%, while the impact strength remains at the level of the unfilled plasticized composite. In addition, it is proved that the addition of both diorite and chromite provides an increase in the thermal and heat resistance of epoxy composites, also lowers combustibility of the epoxy composite: the weight loss at ignition in air is reduced to 1.2–2.2% and the oxygen index rises from 28 to 30–35% by volume, thus the material does not support combustion in air and belongs to the class of hardly flammable. The study was carried out with the financial support of a grant for young scientists of the SSTU named after Gagarin Yu.A. (project SGTU-287).


Alloy Digest ◽  
1958 ◽  
Vol 7 (2) ◽  

Abstract BERYLCO-10CR is a heat treatable, beryllium-copper casting alloy having high elastic and endurance strength, high ductility and impact strength, and high electrical and thermal conductivity. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on casting, heat treating, machining, joining, and surface treatment. Filing Code: Cu-59. Producer or source: Beryllium Corporation.


2019 ◽  
Vol 11 (01) ◽  
pp. 1950001
Author(s):  
Alexander Kalamkarov ◽  
Igor Andrianov ◽  
Galina Starushenko

The effective properties of the fiber-reinforced composite materials with fibers of square cross-section are investigated. The novel formula for the effective coefficient of thermal conductivity refining the classical Maxwell formula (MF) is derived. The methods of asymptotic homogenization, boundary shape perturbation and Schwarz alternating process are applied. It is shown that the principal term of the asymptotic expansion of the refined formula in powers of small size of inclusions coincides with the classical MF. The corrections to the MF are obtained for different values of geometrical and physical properties of the constituents of the composite material. The analytical and numerical analyses are carried out and illustrated graphically. In particular, the derived refined formula and the MF are compared for the limiting values of the geometric dimensions and physical properties of the composite. It is shown that the refined formula is applicable for the inclusions with any conductivity in the entire range of the geometric sizes of inclusions, including the limiting cases of inclusions with zero thermal conductivity and maximally large inclusions.


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