scholarly journals Synthesis of silicon quantum dots using chitosan as a novel reductor agent

2021 ◽  
Vol 67 (2 Mar-Apr) ◽  
pp. 249
Author(s):  
P. A. Hernández-Abril ◽  
J. L. Iriqui-Razcón ◽  
E. León-Sarabia ◽  
S. D. Leal-Soto ◽  
M. E. Álvarez-Ramos ◽  
...  

In the present paper we report a novel synthesis method of silicon quantum dots (SiQDs) using 3-Aminopropyltriethoxysilane (APTES) as silicon precursor and low molecular weight chitosan (CS) as reducing agent. The obtained SiQDs have a hydrodynamic diameter of 2.3 nm, water dispersible, presents blue emission band at 434.5 nm (2.85 eV) with a Commission Internationale de l’Eclairage 1931 (CIE1931) chromaticity coordinates (x = 0.1665, y = 0.1222), the experimental absorbance of the SiQDS was measured and the band gap (Eg) was estimated through PerkinElmer’s method, the obtained value was 3.1 eV and a positive ζ-potential of + 35 mV, resulting in photonics, microelectronics, and biotechnological potential applications.

2021 ◽  
Author(s):  
Congjie Pan ◽  
Qiaoqiao Wen ◽  
Longfei Ma ◽  
Xuezhen Qin ◽  
Suxiang Feng

Curcumin, an active ingredient of Curcuma longa, which possesses good biological and pharmacological activities, is effective in treating of many diseases. Developing simple and sensitive methods for detection of curcumin...


2019 ◽  
Vol 5 (2) ◽  
pp. 24 ◽  
Author(s):  
Ganeshlenin Kandasamy

Carbon quantum dots (CQDs)/carbon nanodots are a new class of fluorescent carbon nanomaterials having an approximate size in the range of 2–10 nm. The majority of the reported review articles have discussed about the development of the CQDs (via simple and cost-effective synthesis methods) for use in bio-imaging and chemical-/biological-sensing applications. However, there is a severe lack of consolidated studies on the recently developed CQDs (especially doped/co-doped) that are utilized in different areas of application. Hence, in this review, we have extensively discussed about the recent development in doped and co-doped CQDs (using elements/heteroatoms—e.g., boron (B), fluorine (F), nitrogen (N), sulphur (S), and phosphorous (P)), along with their synthesis method, reaction conditions, and/or quantum yield (QY), and their emerging multi-potential applications including electrical/electronics (such as light emitting diode (LED) and solar cells), fluorescent ink for anti-counterfeiting, optical sensors (for detection of metal ions, drugs, and pesticides/fungicides), gene delivery, and temperature probing.


2015 ◽  
Vol 10 (1) ◽  
Author(s):  
Yun Wang ◽  
Hao Wang ◽  
Jun Guo ◽  
Jiang Wu ◽  
Li J. Gao ◽  
...  

2011 ◽  
Vol 133 (36) ◽  
pp. 14192-14195 ◽  
Author(s):  
Yao He ◽  
Yiling Zhong ◽  
Fei Peng ◽  
Xinpan Wei ◽  
Yuanyuan Su ◽  
...  

2017 ◽  
Vol 727 ◽  
pp. 623-627 ◽  
Author(s):  
Zai Fa Yang ◽  
Deng Hui Xu ◽  
Xue Dong Gao ◽  
Jiang Nan Du ◽  
Jia Yue Sun

A novel blue-emitting Sr3NaLu (PO4)3F:Eu2+ phosphor for white light-emitting diodes (w-LEDs) have been successfully prepared via the solid-state reaction. The crystal structure and phase of the prepared phosphors were investigated using X-ray diffraction (XRD). The band gap of Sr3NaLu (PO4)3F was estimated to be about 5.79 eV from the diffuse reflection spectrum. The Sr3NaLu (PO4)3F:0.05Eu2+ phosphor exhibits an intense and broad excitation band ranging from 200 to 450 nm in the near ultraviolet region and produces a bright blue emission band with the CIE chromaticity coordinates of x = 0.133 and y = 0.148 under the excitation of 365 nm, which were ascribed to the 4f-5d transitions of Eu2+. Moreover, the fluorescence decay curves were also investigated in detail. All the results suggest that Sr3NaLu (PO4)3F:Eu2+ might be a promising blue-emitting phosphor used in w-LEDs.


2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Jieqiong Zeng ◽  
Hong Yu

Doping of silicon quantum dots (Si QDs) is important for realizing the potential applications of Si QDs in the fields of Si QDs-based all-Si tandem solar cells, thin-film transistors, and optoelectronic devices. Based on the first-principle calculations, structural and electronic properties of hydrogen terminated Si QDs doped with single Boron (B) or phosphorus (P) are investigated. It is found out that the structural distortion induced by impurity doping is related to the impurity characteristic, impurity position, and the QD size according to the structural analysis. The relative energetic stability of Si QDs with a single impurity in different locations has been discussed, too Furthermore, our calculations of the band structure and electronic densities of state (DOS) associated with the considered Si QDs show that impurity doping will introduce impurity states within the energy gap, and spin split occurs for some configurations. A detailed analysis of the influences of impurity position and QD size on the impurity levels has been made, too.


2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
C. Torres-Torres ◽  
J. Bornacelli ◽  
R. Rangel-Rojo ◽  
J. A. García-Merino ◽  
B. Can-Uc ◽  
...  

The third-order nonlinear infrared and ultraviolet properties exhibited by silicon quantum dots irradiated by ultrashort pulses were studied. The samples were prepared by 1.5 MeV Si+2ion implantation processes in high-purity silica substrates. Femtosecondz-scan measurements conducted at 830 nm wavelength revealed strong self-focusing effects together with two-photon absorption that can be switched to saturable absorption as a function of the input irradiance. Changes in the main physical mechanism responsible for the picosecond absorptive nonlinearity in the sample were also observed at 355 nm, made possible by the assistance of photothermal phenomena. Ultraviolet self-diffraction explorations allowed us to estimate the Kerr effect of the nanostructures. Potential applications for developing all-optical filtering functions performed by silicon-based nanosystems can be considered.


2014 ◽  
Vol 67 (4) ◽  
pp. 663 ◽  
Author(s):  
Melissa R. Dewi ◽  
William M. Skinner ◽  
Thomas Nann

Cube-shaped magnetic iron oxide nanoparticles were synthesised and studied with the aim to achieve superior magnetic properties. This study describes a straightforward and simple synthesis method for preparing monodisperse 11–14-nm superparamagnetic iron oxide nanocubes via an ‘effective monomer’ growth mechanism. The as-synthesised nanoparticles are insoluble in water. However, substitution of the non-polar ligands of the particles using a new method that involved an ionic compound generated colloidally stable and water dispersible cube-shaped particles with a very small hydrodynamic diameter. The cubes displayed superior magnetic properties over spherical particles.


RSC Advances ◽  
2015 ◽  
Vol 5 (44) ◽  
pp. 35291-35296 ◽  
Author(s):  
Jiechao Ge ◽  
Pengpeng Chen ◽  
Qingyan Jia ◽  
Weimin Liu ◽  
Hangyue Zhou ◽  
...  

A facile HSVM method has been developed for mass production of water-dispersible SiQDs for long-term cell imaging.


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