Failure Analysis and Elimination of Galvanic Corrosion on Bondpads During Wafer Sawing

2000 ◽  
Author(s):  
Y. N. Hua ◽  
E. C. Low ◽  
L. H. An ◽  
Shailesh Redkar
Keyword(s):  
Failure Analysis ◽  
Feed Rate ◽  
Galvanic Corrosion ◽  
Experimental Results ◽  
Metal Corrosion ◽  
Wafer Fabrication ◽  
Al Alloy ◽  
Assembly Process ◽  
Water Problem ◽  
Sawing Process

Abstract In our previous paper [1], discolored bondpads due to galvanic corrosion were studied. The results showed that the galvanic corrosion occurred in 0.8 ìm wafer fabrication (fab) process with cold Al alloy (Al-Si, 0.8 wt%-Cu, 0.5 wt%) metallization. Galvanic corrosion is also known as a two-metal corrosion and it could be due to either wafer fab process or assembly process. Our initial suspicion was that it was due to a DI water problem during wafer sawing at assembly process. After that, we did further failure analysis and investigation work on galvanic corrosion of bondpads and further found that galvanic corrosion might be due to longer rinsing time of DI water during wafer sawing. The rinsing time of DI water is related to the cutting time of wafer sawing. Therefore, some experiments of wafer sawing process were done by using different sizes of wafer (1/8 of wafer, a quadrant of wafer and whole of wafer) and different sawing speed (feed-rate). The results showed that if the cutting time was longer than 25 minutes, galvanic corrosion occurred on bondpads. However, if the cutting time was shorter than 25 minutes, galvanic corrosion was eliminated. Based on the experimental results, it is concluded that in order to prevent galvanic corrosion of bondpads, it is necessary to select higher feed-rate during wafer sawing process at assembly houses. In this paper, we will report the details of failure analysis and simulation experimental results, including the solution to eliminate galvanic corrosion of bondpads during wafer sawing at assembly houses.

Studies on a Failure Analysis Flow of Surface Contamination, Corrosion, and Underetch on Microchip Al Bondpads in Wafer Fabrication

2005 ◽  
Author(s):  
Hua Younan
Keyword(s):  
Failure Analysis ◽  
Galvanic Corrosion ◽  
Surface Contamination ◽  
Wafer Fabrication ◽  
Tof Sims ◽  
Corrosion Passivation

Abstract A failure analysis flow is developed for surface contamination, corrosion and underetch on microchip Al bondpads and it is applied in wafer fabrication. SEM, EDX, Auger, FTIR, XPS and TOF-SIMS are used to identify the root causes. The results from carbon related contamination, galvanic corrosion, fluorine-induced corrosion, passivation underetch and Auger bondpad monitoring will be presented. The failure analysis flow will definitely help us to select suitable methods and tools for failure analysis of Al bondpad-related issues, identify rapidly possible root causes of the failures and find the eliminating solutions at both wafer fabrication and assembly houses.

Analysis of Al-over-Cu Bond Pad Hillock and Pit Hole Defects

2005 ◽  
Author(s):  
Daniel Cavasin ◽  
Abdullah Yassine
Keyword(s):  
Focused Ion Beam ◽  
Galvanic Corrosion ◽  
Process Analysis ◽  
Ion Beam ◽  
Metal Corrosion ◽  
Process Characterization ◽  
Nucleation Sites ◽  
Hole Defects ◽  
Bond Pads ◽  
Sawing Process

Abstract Bond pad metal corrosion was observed during assembly process characterization of a 0.13um Cu microprocessor device. The bond pad consisted of 12kÅ of Al-0.5%Cu atop 9kÅ of Cu, separated by a thin Ta diffusion barrier. The corrosion was first noted after the wafer dicing process. Analysis of the pad surface revealed pitting-type corrosion, consistent with published reports of classic galvanic cell reactions between Al2Cu (theta phase) particles and the surrounding Al pad metal. Analysis of the bond pads on samelot wafers which had not been diced showed higher-thanexpected incidence of hillock and pit hole defects on the Al surface. Statistically designed experiments were formulated to investigate the possibility that the observed pre-saw pad metal defects act as nucleation sites for galvanic corrosion during the sawing process. Analyses of the experimental samples were conducted using optical and scanning electron microscopy, along with focused ion beam deprocessing and energy dispersive X-ray. This paper explores the relationship between the presence of these pre-existing defects and the propensity for the bond pads to corrode during the dicing process, and reviews the conditions under which pit hole defects are formed during the final stages of the Cu-metallized wafer fabrication process. Indications are that strict control of wafer fab backend processes can reduce or eliminate the incidence of such defects, resulting in elimination of bond pad corrosion in the wafer dicing process.

Studies of Silicon Dust Corrosion on Microchip Al Bondpads and Elimination of Silicon Dust During Wafer Sawing Process

2006 ◽  
Author(s):  
Hua Younan ◽  
Zhao Siping ◽  
Mo Zhiqiang ◽  
Cho Jie Ying
Keyword(s):  
Theoretical Model ◽  
Galvanic Corrosion ◽  
Complex Compounds ◽  
Assembly Process ◽  
Corrosion Problem ◽  
Sawing Process

Abstract After wafer-die sawing process, sometimes silicon (Si) dust on microchip Al bondpads is difficult to be cleaned away by DI water, especially at pinhole/corrosive areas caused by galvanic corrosion, thus resulting in non-stick on pads (NSOP) problem in assembly process. To eliminate NSOP problem due to Si dust contamination, in this paper, we will study the mechanism of Si dust contamination and propose a concept of Si dust corrosion. A theoretical model will be introduced so as to explain Si dust contamination and corrosion problem during wafer die sawing process. Based on the mechanism proposed, Si dust contamination and corrosion is related to galvanic corrosion as OH- ions generated from galvanic corrosion will not only react with Al to cause Al corrosion, but also react with Si dust to cause Si dust corrosion. During Si dust corrosion, poly-H2SiO3 and Si-Al-O complex compounds will be formed on Al bondpads, especially at the pinholes/corrosive areas. Poly-H2SiO3 and Si-Al-O complex compounds are “gel-like” material and stick onto the surface of bondpads. It is insoluble in water and difficult to be cleaned away by DI water during or after wafer die sawing process and will cause bondpad discoloration or/and NSOP problem. Some eliminating methods of Si dust contamination and corrosion on Al bondpads during wafer die sawing process are also discussed.

Failure Mechanism Studies and Root Cause Identification of Nonstick on Pad on Microchip Al Bondpads

2014 ◽  
Author(s):  
Hua Younan ◽  
Zhou Yongkai ◽  
Chen Yixin ◽  
Fu Chao ◽  
Li Xiaomin
Keyword(s):  
Failure Analysis ◽  
Failure Mechanism ◽  
Wafer Fabrication ◽  
Assembly Process ◽  
Root Cause ◽  
Barrier Metal ◽  
Root Cause Identification ◽  
Induced Defects

Abstract It is well-known that underetch material, contamination, particle, pinholes and corrosion-induced defects on microchip Al bondpads will cause non-stick on pads (NSOP) issues. In this paper, the authors will further study NSOP problem and introduce one more NSOP failure mechanism due to Cu diffusion caused by poor Ta barrier metal. Based on our failure analysis results, the NSOP issue was not due to the assembly process, but due to the wafer fabrication. The failure mechanism might be that the barrier metal Ta was with pinholes, which caused Cu diffused out to the top Al layer, and then formed the “Bump-like” Cu defects and resulted in NSOP on Al bondpads during assembly process.

Failure Analysis of Discolored Bondpads in Wafer Fabrication

1999 ◽  
Author(s):  
Younan N. Hua
Keyword(s):  
Failure Analysis ◽  
Surface Analysis ◽  
Trace Amount ◽  
Wafer Fabrication ◽  
Al Alloy ◽  
Wafer Fab ◽  
Analysis Technique ◽  
Pull Testing ◽  
Etch Time

Abstract Discolored bondpads & non-stick failure in 0.6 μm wafer fab process with the hot Al alloy metallization was investigated. SEM, EDX & AES techniques were used to identify the root causes. Failure analysis results showed that discolored bondpads & non-stick failure were caused by TiN residue introduced during L95 bondpad opening wafer fab process. TiN residue on bondpad might have led to non-stick bondpad issue. The results also showed that it was difficult to determine the trace amount of TiN residue on bondpad using EDX technique due to its limitations. In this work, Auger surface analysis technique was used to determine TiN residue on bondpads with Al/TiW/Ti metallization. Auger results showed that Ti & N peaks were detected on discolored bondpads. It has resulted in non-stick bondpad failure. The solution to eliminate TiN residue on bondpads was to increase etch time at L95 bondpad opening wafer fab process. After using the new recipe with longer etch time, Auger results on the bondpads showed that no Ti & N peaks were detected and the bond-pull testing also passed.

A New Failure Analysis Flow of Gate Oxide Integrity Failure in Wafer Fabrication

2009 ◽  
Author(s):  
Hua Younan ◽  
Chu Susan ◽  
Gui Dong ◽  
Mo Zhiqiang ◽  
Xing Zhenxiang ◽  
...  
Keyword(s):  
Failure Analysis ◽  
Gate Dielectric ◽  
Dielectric Breakdown ◽  
Defect Density ◽  
Gate Oxide ◽  
Oxide Thickness ◽  
Fault Isolation ◽  
Wafer Fabrication ◽  
Root Cause ◽  
Gate Oxide Integrity

Abstract As device feature size continues to shrink, the reducing gate oxide thickness puts more stringent requirements on gate dielectric quality in terms of defect density and contamination concentration. As a result, analyzing gate oxide integrity and dielectric breakdown failures during wafer fabrication becomes more difficult. Using a traditional FA flow and methods some defects were observed after electrical fault isolation using emission microscopic tools such as EMMI and TIVA. Even with some success with conventional FA the root cause was unclear. In this paper, we will propose an analysis flow for GOI failures to improve FA’s success rate. In this new proposed flow both a chemical method, Wright Etch, and SIMS analysis techniques are employed to identify root cause of the GOI failures after EFA fault isolation. In general, the shape of the defect might provide information as to the root cause of the GOI failure, whether related to PID or contamination. However, Wright Etch results are inadequate to answer the questions of whether the failure is caused by contamination or not. If there is a contaminate another technique is required to determine what the contaminant is and where it comes from. If the failure is confirmed to be due to contamination, SIMS is used to further determine the contamination source at the ppm-ppb level. In this paper, a real case of GOI failure will be discussed and presented. Using the new failure analysis flow, the root cause was identified to be iron contamination introduced from a worn out part made of stainless steel.

Intermittent Failures in High Pin Count Packaging

2006 ◽  
Author(s):  
Ramesh Varma ◽  
Richard Brooks ◽  
Ronald Twist ◽  
James Arnold ◽  
Cleston Messick
Keyword(s):  
Failure Analysis ◽  
Shape Analysis ◽  
State Of The Art ◽  
Process Variation ◽  
High Reliability ◽  
Temperature Cycling ◽  
Assembly Process ◽  
System Failures ◽  
Industrial Grade ◽  
Corrective Actions

Abstract In a prequalification effort to evaluate the assembly process for the industrial grade high pin count devices for use in a high reliability application, one device exhibited characteristics that, without corrective actions and/or extensive screening, may lead to intermittent system failures and unacceptable reliability. Five methodologies confirmed this conclusion: (1) low post-decapsulation wire pull results; (2) bond shape analysis showed process variation; (3) Failure Analysis (FA) using state of the art equipment determined the root causes and verified the low wire pull results; (4) temperature cycling parts while monitoring, showed intermittent failures, and (5) parts tested from other vendors using the same techniques passed all limits.

Failure Analysis of Killer Defects and Yield Enhancement of Flat ROM Devices in Wafer Fabrication

2000 ◽  
Author(s):  
Y. N. Hua ◽  
Z. R. Guo ◽  
L. H. An ◽  
Shailesh Redkar
Keyword(s):  
Electron Microscope ◽  
Failure Analysis ◽  
Fault Isolation ◽  
Yield Enhancement ◽  
Wafer Fabrication ◽  
X Ray ◽  
Particle Contamination ◽  
Emission Microscopy ◽  
Microscopy Techniques ◽  
Scanning Electron

Abstract In this paper, some low yield cases in Flat ROM device (0.45 and 0.6 µm) were investigated. To find killer defects and particle contamination, KLA, bitmap and emission microscopy techniques were used in fault isolation. Reactive ion etching (RIE) and chemical delayering, 155 Wright Etch, BN+ Etch and scanning electron microscope (SEM) were used for identification and inspection of defects. In addition, energy-dispersive X-ray microanalysis (EDX) was used to determine the composition of the particle or contamination. During failure analysis, seven kinds of killer defects and three killer particles were found in Flat ROM devices. The possible root causes, mechanisms and elimination solutions of these killer defects/particles were also discussed.

Unique Autoclave Stress Induced Failure Mechanism

2005 ◽  
Author(s):  
John Butchko ◽  
Bruce T. Gillette
Keyword(s):  
Corrosion Rate ◽  
Grain Boundary ◽  
Failure Analysis ◽  
Failure Mechanism ◽  
Metal Corrosion ◽  
Corrosion Mechanism ◽  
Reliability Testing ◽  
Process Change ◽  
Transistor Reliability ◽  
Pass Through

Abstract Autoclave Stress failures were encountered at the 96 hour read during transistor reliability testing. A unique metal corrosion mechanism was found during the failure analysis, which was creating a contamination path to the drain source junction, resulting in high Idss and Igss leakage. The Al(Si) top metal was oxidizing along the grain boundaries at a faster rate than at the surface. There was subsurface blistering of the Al(Si), along with the grain boundary corrosion. This blistering was creating a contamination path from the package to the Si surface. Several variations in the metal stack were evaluated to better understand the cause of the failures and to provide a process solution. The prevention of intergranular metal corrosion and subsurface blistering during autoclave testing required a materials change from Al(Si) to Al(Si)(Cu). This change resulted in a reduced corrosion rate and consequently prevented Si contamination due to blistering. The process change resulted in a successful pass through the autoclave testing.

Failure analysis of H13 steel die for high pressure die casting Al alloy

2021 ◽  
pp. 105330
Author(s):  
Rengen Ding ◽  
Haibo Yang ◽  
Shuzhi Li ◽  
Guodong Wu ◽  
Jiahao Mo ◽  
...  
Keyword(s):  
High Pressure ◽  
Failure Analysis ◽  
Die Casting ◽  
Al Alloy ◽  
H13 Steel ◽  
High Pressure Die Casting ◽  
Pressure Die Casting
Sign in / Sign up

Export Citation Format

Share Document