Silver-on-Silver versus Tin-on-Silver Electrical Connectors for High Current and High Vibration Applications

Author(s):  
Prabjit Singh ◽  
Larry Palmer ◽  
James Demarest ◽  
Larry Fischer ◽  
George Hutt ◽  
...  

Abstract Contrary to known art, we have discovered that lubricated tin-silver connectors have better electrical performance and are more reliable than lubricated silver-silver connectors under high-current and high-vibration conditions. The antifretting lubricant, that enhances the performance and reliability of the tin-silver connectors, is a grease consisting of a hydrocarbon oil in a nano-sized silica-particle base. Focused ion beam and scanning electron microscopy were used to understand the contact degradation mechanism. The superior electrical performance and reliability of the lubricated tin-silver connectors is due to a mechanism that replaces the tin plating from the contact surface with a coating of silver. The removal of the tin plating may be due to wear and the replacement by the silver coating may be due to an electrochemical displacement reaction.

2012 ◽  
Vol 1433 ◽  
Author(s):  
Andrew A. Woodworth ◽  
Ali Sayir ◽  
Philip G. Neudeck ◽  
Balaji Raghothamachar ◽  
Michael Dudley

ABSTRACTCommercially available bulk silicon carbide (SiC) has a high number (>2000/cm2) of screw dislocations (SD) that have been linked to degradation of high-field power device electrical performance properties. Researchers at the NASA Glenn Research Center have proposed a method to mass-produce significantly higher quality bulk SiC. In order for this bulk growth method to become reality, growth of long single crystal SiC fibers must first be achieved. Therefore, a new growth method, Solvent-Laser Heated Floating Zone (Solvent-LHFZ), has been implemented. While some of the initial Solvent-LHFZ results have recently been reported, this paper focuses on further characterization of grown crystals and their growth fronts. To this end, secondary ion mass spectroscopy (SIMS) depth profiles, cross section analysis by focused ion beam (FIB) milling and mechanical polishing, and orientation and structural characterization by X-ray transmission Laue diffraction patterns and X-ray topography were used. Results paint a picture of a chaotic growth front, with Fe incorporation dependant on C concentration.


2012 ◽  
Vol 706-709 ◽  
pp. 671-676
Author(s):  
Kohei Morishita ◽  
S. Ochiai ◽  
H. Okuda ◽  
Toshihiro Ishikawa ◽  
M. Sato

For description of the mechanical performance of SiC/SiC composites and for safety design for practical use, it is needed to reveal the degradation mechanism especially of fiber under the oxygen atmosphere. In the present work, the fracture behavior and microstructure of the polycrystalline silicon carbide fiber exposed in air at 1173-1873 K for 20 and 3.6 ks were studied with monofilament tensile test, microstructure observation and fracture toughness determination test using newly developed FIB(focused-ion-beam)-method.


2012 ◽  
Vol 1478 ◽  
Author(s):  
A.H. Khan ◽  
A.V. Sumant

AbstractDespite the many superior attributes of diamond, electronic device performance to date has fallen well behind theoretical expectation. The potential realization of highly efficient electronic polycrystalline diamond devices has been more than limited by certain technological challenges such as maintaining efficient/shallow n-type doping without higher density of defects or incorporation of sp2 bonded carbon as a result of doping(during ion implantation process). Specific n-type diamond reports demonstrating phosphorus doping (with activation energy reported in the range of 485 meV to 600 meV in (100) oriented systems have been particularly problematic as a lower solubility is found as compared to (111) oriented synthesis efforts, in addition to the reported self-compensating nature. Amongst the previous reports of Phosphorus-doped diamond nearly all experimental reports to date show visual crystallographic dislocation/pitting on the (100) facet with even moderate doping where dislocations have been observed to be incorporated into the bulk volume during growth. These dislocations, which are known carrier scattering sites, subsequently lower mobility rendering poor conductance and high resistivity. Due to this well-known sensitivity of phosphorus incorporation to the crystal quality, typically lower in polycrystalline than homoepitaxial films, polycrystalline-based experimental reports have been largely absent. With respect to Phosphorus in-situ doping based efforts, rendered films demonstrate both the visually identifiable pitting and electronically identifiable poor conduction characteristic, and with respect to ion beam doping efforts, complete graphitic flaking at even moderate doses (i.e. greater than 3x1017cm−3). Motivated by these shortcomings and the success of recent experimentation, we present the methodology and data from our recent successful fabrication of polycrystalline diamond P+-i-N junction (diode) with high crystal quality, high power handling capability, high current density, low threshold voltage, and ohmic contact, under room temperature operation, previously undemonstrated across all diamond material types. The superior electrical performance of the device was obtained by novel ion beam methodology designed to resolve previously unaddressed issues relating to n-type doping of diamond materials. A high current density of approximately 104 A/cm2 is attained at 20V forward bias.


1991 ◽  
Vol 30 (Part 1, No. 11B) ◽  
pp. 3233-3237 ◽  
Author(s):  
Yoshio Takahashi ◽  
Yuuichi Madokoro ◽  
Tohru Ishitani

Author(s):  
J. M. Mackenzie ◽  
D. P. Griffis ◽  
P. E. Russell

Many biological events occur at a small number of specific sites within a very large volume. It has recently been shown that focused ion beam (FIB) technology is useful for exposing biological structures for examination. In addition, it has been shown that biological material can be removed using FIB without detectable collateral damage beyond 100Å in fixed, dehydrated, critically point dried tissue.The next step in determining the practical utility of FIB for removal of material from a representative tissue block is to demonstrate that relevant biological structure can be exposed at a selected site. A cross sectioning technique, commonly used for analysis of semiconductor devices, was employed to demonstrate this capability on a block of rat liver prepared as above for SEM. A contiguous-series of successively deeper rectangles are cut into the material using a relatively large, high current beam (0.18μm diameter, 1nA), removing a wedge of material and leaving a large exposed face perpendicular to the surface. The exposed face can then be examined by tilting the sample and viewing with either the FIB or by SEM.


Author(s):  
L. Bischoff ◽  
J. Teichert ◽  
E. Hesse ◽  
D. Panknin ◽  
W. Skorupa

Author(s):  
Kyle M. Winter ◽  
Steven B. Herschbein ◽  
Carmelo F. Scrudato ◽  
Brian L. Yates

Abstract Focused Ion Beam (FIB) circuit edit allows for rapid prototyping of potential semiconductor design changes without the need to run a full manufacturing cycle in a semiconductor Fab. By FIB editing a completed module, thorough testing on the bench or in a full system can be achieved. Logic can be toggled, validation of speed enhancements performed, and constructive and destructive failure analysis can be enabled. In order to fulfill all the needs of clients in a rapidly evolving SOC driven market, simply modifying existing devices by “rewiring” circuits is becoming insufficient. Often the team is tasked with making very repeatable structures to aid the circuit analysis group. These include relatively precise resistors for tuning RF circuits (part of an RC network), adding known loads or delays, et cetera. Naturally resistive FIB deposited metal lines connected to the existing circuitry can be used in this capacity. FIB chip edit is considered to be a “Direct Write” process. The beam pattern in conjunction with process gases defines the regions of milling and deposition. Unfortunately, FIB edit is rarely an exact science. In many cases, a number of characteristics seem to be outside the realm of precise repeatable control. This is evident not only in individual tool operational logs but also in FIB tool matching, where maintaining identical system performance within the lab is difficult or nearly impossible. These characteristics are highly dependent on precursor reservoir composition and flow, surface adsorption conditions, beam patterning integrity, and the total interaction space of competing back sputtering during the new material structure formation. Due to these factors, the shape, composition and electrical performance of metal and insulator depositions vary over an often unacceptable range. As a result, we were not meeting the needs of some critical customer applications. Direct written precision resistive structures displayed several issues for which iterative edits were required to compensate for variability. When attempting to create an exact resistance, this process was not reliable, nor was it repeatable enough for accurate circuit performance trimming. Space-constrained serpentine resistors or multiple discrete resistors side-by-side showed the greatest process variability. Metal deposition processes tend to be somewhat self-limiting, so thick boxprofile lines are difficult to form. Conductive material deposited outside of the pattern definition (overspray) results in line-to-line leakages. Attempts to remove the overspray thru ion beam assisted etch-back tends to damage the deposited conductors and underlying insulators. The low-k region between lines can become cross-linked, experience gallium doping, and become tungsten impregnated. This lowered the resistivity of the insulator, increased the resistivity of the conductor, and produced variability in the device which was especially an issue when dealing with varying initial substrates. GLOBALFOUNDRIES began a project to create a more robust repeatable resistive structure by removing several variables. Rather than direct writing lines onto a top surface layer, a confined deposition based on the concepts of dual damascene processing used with copper layers in modern semiconductor fabrication will be employed. The damascene process begins with the definition of a box to be filled with a conductive material. The process of ion beam gas assisted anisotropic etching/milling has a far more predictable outcome than ion beam induced deposition. It is possible to create a surface box mill or even a deep drilled via of desired dimensions with a more consistent repeatability. Deposition of tungsten into a confined region using, for example, a W(CO)6 precursor and a Ga+ ion beam results in an excellent via fill. Using this behavior, precision resistors can be created with metal deposition within the trenches which are created by the gas assisted mill. An enclosed space can be filled nearly void-free, and has repeatable electrical parameters. The self-limiting factors with tungsten deposition go away as sputtered material becomes trapped within the well resulting in a near limitless Zheight potential. The constant dielectric with a uniform and contained tungsten fill can allow for a well-defined resistivity for the FIB deposited tungsten material. Having a known resistivity, calculation of dimensions for resistive and inductive structures during the design process becomes feasible. With process variability under control, structures can be formed reliably enough to offer this as a service to customers.


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