Technology for the production of carbon nanomaterials by pyrolysis

2021 ◽  
pp. 95-108
Author(s):  
O. A. Kolenchukov ◽  
E. A. Petrovsky ◽  
N. A. Smirnov
Keyword(s):  
Carbon Nanomaterials ◽  
Raw Materials ◽  
Experimental Studies ◽  
Raw Material ◽  
Waste Oil ◽  
Hydrocarbon Gases ◽  
Associated Petroleum Gas ◽  
Associated Gas ◽  
Pyrolysis Method ◽  
Processing Petroleum

The processes of oil production and preparation involve the formation of a mixture of various hydrocarbon gases, otherwise called associated petroleum gas. Today most of associated petroleum gas produced is burned, causing damage to the natural environment, or used as an energy supply for technological equipment. At the same time, associated petroleum gas can be used as a valuable raw material to produce various chemicals. In the article, the existing methods of APG utilization are considered, and the relatively simplest and most environmentally friendly pyrolysis method is proposed. A comparative analysis of the methods of mixing raw materials was carried out, as a result of which it was revealed that the mechanical and vibration methods are considered the most rational. An experimental installation for processing petroleum associated gas by pyrolysis is presented. The results of experimental studies of the production of carbon fiber nanomaterials and hydrogen are presented. Gas (CH4) obtained by utilization of hydrocarbon-containing waste (oil sludge) was used as a feedstock. The average yield of the target products was 81 l/h for hydrogen and 325.5 g/h for nanofiber carbon.

scholarly journals Potentials of Edible Canna (Canna edulis Kerr) Starch for Bioplastic: A Review

2021 ◽  
Vol 10 (2) ◽  
pp. 182-191
Author(s):  
Azmi Alvian Gabriel ◽  
◽  
Anggita Fitri Solikhah ◽  
Alifia Yuanika Rahmawati ◽  
Yunita Sasmi Taradipa ◽  
...  
Keyword(s):  
Mineral Content ◽  
Raw Materials ◽  
Amylose Content ◽  
Experimental Studies ◽  
Raw Material ◽  
Carbohydrate Source ◽  
Polybutylene Succinate ◽  
Treatment Use ◽  
High Amylose ◽  
Short Time

Starch-based bioplastic was more economical and competitive compared to bacteria-based bioplastics (polylactic acid, polybutylene succinate, and polyhydroxyalkanoates) due to the starch variances and the availability in Indonesia, along with the simple techniques that can be applied. This review aimed to describe the potential and opportunities of edible canna starch as an alternative raw material of bioplastics production. Edible canna tuber productivity in Java, Indonesia, with a harvest age of about eight months reaches 30-49.4 tons/ha. It will produce a mature segment 70.2% of the total harvest weight. Edible canna tuber was a carbohydrate source that contains 88.10% starch with an advantage of 68% higher fiber and mineral content than other tubers. Furthermore, canna tuber starch contains amylose proportions of 35.0%. The high amylose content in canna starch is one of the properties that can position its function for developing packaging materials. The gelatinization process of canna starch requires a short time and low energy because of its large granule size (56 μm). A literature review of canna starch as an alternative of bioplastic raw materials needs to be carried out to obtain accurate data and information regarding treatment, use of additional materials, and characteristics of bioplastic products resulting from experimental studies so that they can be further implemented.

scholarly journals Optimization of the process of mixing liquid-phase heterogeneous products

2021 ◽  
Vol 83 (1) ◽  
pp. 204-210
Author(s):  
L. E. Glagoleva ◽  
N. P. Zatsepilina ◽  
M. V. Kopylov ◽  
S. O. Rodionov
Keyword(s):  
Software Package ◽  
Raw Materials ◽  
Food Additives ◽  
Whey Proteins ◽  
Experimental Studies ◽  
Good Health ◽  
The Body ◽  
Biologically Active ◽  
Raw Material ◽  
And Performance

The leading direction in the field of nutrition is the creation of a range of products that contribute to improving health when they are used daily in the diet. The urgency of studying bovine colostrum-colostrum, which is an immune-modeling animal raw material, has been substantiated. Colostrum is a natural source of all the ingredients needed to build immunity. Biologically active substances contained in cow colostrum contribute to: restoration of immunity; restoration of the intestines and stomach; strengthening the nervous system; renewal of brain cells; improving emotional tone and mood; increasing vitality and performance; slowing down the aging process; protection against diseases of the intestines and stomach, cardiovascular system, respiratory tract, diabetes, allergies, osteoporosis and a number of other diseases. Colostrum contains a minimum of 37 immune factors and 8 growth factors that help the body fight disease and promote good health and longevity. The classes of immunoglobulins contained in colostrum, which represent the bulk of whey proteins, have been studied. Colostrum is a limited source of raw materials, its production period is short, there are many opportunities for industrial use, but due to the small amount of raw materials, the market remains undeveloped, with the exception of food additives. Taking into account the extensive therapeutic and medicinal properties of colostrum, its unique composition and properties, its composition and physicochemical properties were investigated, the fractionation parameters were determined using various systems. To process the experimental studies, the STATISTICA 12 software package was used. To obtain the regression equation, the matrix data were processed using the Microsoft Excel 2010 software package. The analysis of the data obtained indicates the possibility and prospects of using colostroma in food production technology.

Development of the Potential for the Cheap Explosives in Russia

2021 ◽  
pp. 7-14
Author(s):  
S.D. Viktorov ◽  
◽  
A.E. Frantov ◽  
I.N. Lapikov ◽  
◽  
...  
Keyword(s):  
Raw Materials ◽  
Liquid Waste ◽  
Oil Products ◽  
Production Costs ◽  
Raw Material ◽  
Material Base ◽  
Waste Oil ◽  
Energy Potential ◽  
Secondary Aluminum ◽  
Technical Literature

The most accessible and popular means of destruction of rocks, which are used in the extraction of ores, non-metallic minerals, mining and chemical raw materials, are the cheap explosives, in the Russian technical literature called granulites or AS-DT, in the foreign — ANFO. The article presents the research carried out to improve the formulation and explosive properties of granulites A6, Igdanit, Igdanit-P, A3. They are aimed at using the modern raw material base, increasing the efficiency of blasting, the safety of manufacturing and loading drill holes and boreholes, maintaining a balanced composition, and preserving physical stability, providing energy potential with secondary aluminum additives. Further development of granulites is aimed at creating a line of formulations using saltpeter with variable technical parameters, mixed fuels in the form of liquid (waste oil products, fuel mixtures, diesel fuel) and solid (coal powder, coke fines, rubber crumbs) phases. Based on the use of the cheap explosives in the formulation of recycling materials formed at the mining enterprises, blasting technologies are being improved, and mixing and charging equipment is being developed. The proposed approaches are aimed at maintaining high technical and economic indicators of the use of explosives, ensuring the stationarity of the explosive process and the completeness of detonation of granulites reducing the sensitivity to mechanical and thermal influences, and maintaining susceptibility to initiation by practical means of an explosive pulse. When compiling the new formulations of granulites to reduce production costs, it is proposed to use the most economical types of oxidants and fuels with ensuring quality control of mixing components with different technological properties and conditioning the temperature-viscosity properties of the waste oil products.

scholarly journals Development of the smelting technology of complex aluminum-chrome-silicon-containing ASC alloy from substandard raw materials

2018 ◽  
Vol 61 (9) ◽  
pp. 714-720
Author(s):  
A. S. Orlov ◽  
A. Z. Isagulov ◽  
O. R. Sariev ◽  
M. Zh. Tolymbekov
Keyword(s):  
Raw Materials ◽  
Experimental Studies ◽  
Coal Ash ◽  
Furnace Operation ◽  
Reducing Agent ◽  
Raw Material ◽  
Production Cycle ◽  
Resource Saving ◽  
Complex Alloy ◽  
The Rich

Scientists of the Chemical-Metallurgical Institute named after Zh.  Abishev develop new types of highly effective alloys based on resource-saving technologies that allow the complex processing of natural and technogenic raw materials, such as carbonaceous waste, chrome ore fines, etc. Therefore, it has led to the creation of a onestage, slag-free and non-waste technology with the maximum use of all useful charge components. With disappearance of rich ore reserves, as well as the expansion of demand for raw materials and the development of technology, the rich ores are replaced by poorer and substandard ones that require new methods of processing. The maximum use of raw materials and industrial waste, if this is economically justified, is one of the basic requirements for the technology. This task is closely intertwined, and in many cases coincides with another task – the development of integrated methods of raw materials processing, which, in the general production cycle, allows using, if possible, all useful elements of raw materials. The main objective of the study is to find ways to improve the use of sub-standard chrome ore. As a reducing agent in the electrothermal smelting of the ACS alloy, instead of expensive coke, without which no process of carbothermic smelting is required, a cheap high-ash Borly coal was used. The coal ash, which mainly consists of silica and alumina, is an additional source of silicon and aluminum in the alloy. This technology will be simple and allows regarding substandard chromium ore as a complex metallurgical raw material, since not only chrome is used, but also the components of the waste rock – silicon and aluminum. As a result of the complete reduction of all charge oxides, this technology will make it possible to obtain a complex alloy of ACS with an approximate chemical composition: 39  –  43  % of chromium, 23  –  27  % of silicon, 7  –  10  % of aluminum. The transition of the main components of the charge to the alloy will be: 82  –  85  % of chromium, 68  –  70  % of silicon, 59  –  60  % of aluminum. In this paper, the results of experimental studies on the production of a complex alloy of ACS (aluminum-chromium-silicon) from high-ash coals of the Borly deposit and chrome ore minerals of the Donskoi GOK are presented. The course of furnace operation is described with a lack, excess, and also the calculated amount of the reducing agent. The ways of eliminating the upset in furnace operation are shown.

scholarly journals PERSPECTIVES OF VEGETABLE PRESSED SKINS PROCESSING AND USE IN FOOD INDUSTRY

2021 ◽  
pp. 37-43
Author(s):  
Aleksandr Cherevko ◽  
Valeriy Mykhaylov ◽  
Оlga Mayak ◽  
Andrey Shevchenko ◽  
Svitlana Prasol ◽  
...  
Keyword(s):  
Food Industry ◽  
Raw Materials ◽  
Experimental Studies ◽  
Raw Material ◽  
Vacuum Drying ◽  
Swelling Degree ◽  
Technological Production ◽  
Material Separation ◽  
Vegetable Raw Materials ◽  
Drying Regime

Vegetable concentrates contain in their composition dietary fibers, microelements, color-forming substances, allowing to use them as a replacer of a main substance in food products rather successfully. The authors propose a way of vegetables processing into vegetable semi-products. Vacuum drying of vegetable pressed skins using vibration is provided. The method of vegetables processing into vegetable concentrates on an example of carrot provides raw material separation in juice and pressed skin with further separate processing of each component. For realizing the proposed method, a technological production line of concentrates of vegetable raw materials, including developed and studied equipment: vacuum evaporating apparatus with a device for heating and mixing, vacuum vibration dryer has been developed. Experimental studies of a swelling degree, solubility and reproduction of vegetable pressed skins have proved an advantage of drying raw materials under the influence of vibration that confirmed the choice of process parameters. Vegetable pressed skins at using vibration and vacuum have a swelling degree by 120…170 % more than at the convection drying regime

scholarly journals Experimental Studies on Compressive Strength of Aerated Concrete with Varying Percentage of Aluminium Powder

2021 ◽  
Vol 309 ◽  
pp. 01197
Author(s):  
G.V.V. Satyanarayana ◽  
A. Ranjith
Keyword(s):  
Compressive Strength ◽  
Building Materials ◽  
Raw Materials ◽  
Experimental Studies ◽  
Raw Material ◽  
Industrial Growth ◽  
Aluminium Powder ◽  
Aerated Concrete ◽  
Lime Powder ◽  
By Products

Today the disposal of various by-product materials is a concern against the environment, these are producing due to rapid industrial growth in our country. Most of the researchers are focused on the utilization of these by-products in the civil engineering construction industry. By using these by-products, on one hand, will protect the environment and other hands the disposal problem will be solved. Day by day the requirement of building materials increased due to urbanization, due to this more raw materials are required and depleted the natural resources. In this contest, environmental protection is need to protect incremental temperature in nature. To avoid these problems of the modern era, aggregation of these by-products can be used as one of building material and to overcome this situation, Aerated concrete is one of the solutions by reducing the raw material quantity in concrete like sand and cement by introducing air without compromising in the volume. Day to day aerated concrete has become popular due to lightweight and high insulation against temperature and sound. This concrete is using in high raised buildings to reduce the self-weight of building to protect during earthquake situations. In this experimental study mainly performed the compressive strength of aerated concrete with replacement of sand by quarry dust. Also reducing the cement content with replacement of fly ash, GGBS and lime powder at various percentages that is ranging. the performance of aerated concrete was observed more satisfactory when compared with and without replacement of above-saided materials.

scholarly journals The use of secondary fish raw materials from silver carp in the technology of structuring agents

10.5219/1626 ◽  
2021 ◽  
Vol 15 ◽  
pp. 546-554
Author(s):  
Anastasiia Ivaniuta ◽  
Alina Menchynska ◽  
Natalia Nesterenko ◽  
Nataliia Holembovska ◽  
Viktor Yemtcev ◽  
...  
Keyword(s):  
Raw Materials ◽  
Silver Carp ◽  
Experimental Studies ◽  
Storage Conditions ◽  
Biologically Active ◽  
Raw Material ◽  
Dissolution Time ◽  
The Black Sea ◽  
Gelling Properties ◽  
Physical And Chemical

The expediency and prospects of using secondary fish raw materials from silver carp in the structuring agents technology have been substantiated. The combination of secondary fish raw materials and seaweed with different mechanisms of gelation has a targeted effect on the organoleptic, structural-mechanical, and physicochemical properties of food products. Accordingly, the expediency of adding the Black Sea alga cystoseira (2%) to optimize the mineral composition of the structuring agents and increase their jelly-making properties was established. Using experimental studies and multicriteria optimization, the optimal ratio of secondary fish raw materials – 40%; water – 60% and rational heat treatment – 150 min, at a temperature of 85 – 100 °C has been determined. An analysis and comparison of various preservation methods have confirmed the expediency of using the freeze-drying method of drying fish broths for the production of structuring agents, which allows to preserve of the original properties of the product, biologically active substances, reduce the mass of the dried product and increase the shelf life of the structuring agents. The optimal storage conditions have been determined – the ready-made structuring agents were packed in three-layer paper kraft bags and stored in a cool dry place at a temperature of 22 ±2 °C and relative humidity of no more than 70% for 12 months. It was found that the physical and chemical indicators of the structuring agents depend on the features of the structure, amino acid composition of fish collagen. The presence of the overwhelming number of high-molecular-weight molecules in the composition of the structuring agents and the preservation of the native structure determine high indicators of dynamic viscosity, dissolution time, and strength. As a result of the research, it was revealed that the high protein content largely depends on the amount of collagen in the secondary fish raw material, which has a positive effect on the gelling properties of the product being created.

scholarly journals KINETICS OF GRINDING OF VEGETABLE RAW MATERIALS DURING ELECTRIC DISCHARGE EXTRACTION

2021 ◽  
Vol 64 (6) ◽  
pp. 76-82
Author(s):  
Valery T. Kazub ◽  
Maria K. Kosheleva ◽  
Stanislav P. Rudobashta
Keyword(s):  
Electric Discharge ◽  
Raw Materials ◽  
Experimental Studies ◽  
Perforated Plate ◽  
Raw Material ◽  
Optimal Size ◽  
Filtration Time ◽  
Extraction Chamber ◽  
Kinetics Of

The influence of the degree of grinding of the particles of growing raw materials during electric discharge extraction on the quality of the obtained extracts was studied. Each discharge during electro-discharge extraction contributes to the grinding of a part of the raw material, which is confirmed by granulometric analysis. The particle size of the raw material should be controlled, since excessive grinding of the extracts results in cloudy, difficult to clarify and poorly filtered. The design of the extraction chamber is proposed, in which the grounded electrode is made in the form of a perforated plate, called a false bottom, with the optimal size of the holes and their density, which eliminates the over-grinding of the raw material particles, which leads to the production of turbid and difficult-to-filter extracts. Since the extraction of raw materials is carried out at a certain ratio of solid-liquid phases, the volume of the chamber from the sieve to the bottom does not significantly affect the kinetics of the extraction process itself, since it is intended for collecting the smallest particles of processed raw materials, the mass of which does not exceed 15-16% of the loaded mass of raw materials. The device of the extraction chamber, due to the high turbulence and intensive mixing of the suspension under the action of cavitation and shock waves initiated by the discharge in the liquid, allows you to remove small particles of raw materials less than 1 mm in size from the working area of the chamber. The results of the study show that the extraction of target components from various raw materials using a chamber with a false bottom can significantly reduce the content of the smallest particles of raw materials in the extract. It facilitates the filtration of the extract, reduces the filtration time, significantly reduces the likelihood of turbidity of the solution due to suspension, which improves the quality of the extract. Experimental studies of the developed electric discharge chamber with a false bottom, conducted with various types of plant raw materials, confirm the effectiveness of extraction in the chamber of the proposed design.

Shock Wave and Pulsation Aspects of Rank-Hilsch Effect in Vortex Tubes used in Gases Stratification

2020 ◽  
Vol 8 (1) ◽  
pp. 51-78
Author(s):  
Vladimir Devisilov ◽  
D. Zhidkov
Keyword(s):  
Shock Wave ◽  
Vortex Tube ◽  
Experimental Studies ◽  
Thermodynamic Characteristics ◽  
Present Moment ◽  
Hydrocarbon Gases ◽  
Associated Gas ◽  
Vortex Effect ◽  
Flow Vortex ◽  
Vortex Tubes

Vortex tubes based on Rank-Hilsch effect are widely used in gas separation technologies, cleaning of harmful gas emissions in the atmosphere protection, capture of oil-associated gas, cooling systems in chemical, petrochemical and other industries. However, up to the present moment in their design the calculation methods produce significant errors and require experimental improvement. Until now, existing theories of vortex effect don’t provide an adequate response to phenomena observed in experiments. In this paper have been presented examples of enthalpy balance disorders during operation of three-flow vortex tubes on hydrocarbon gases, as well as two-flow vortex tubes on air, based on analytical and critical analysis of a large number of various authors’ studies. Has been proposed shock wave and pulsation hypothesis for description of vortex effect and its main demonstrations. It has been shown that the proposed hypothesis can complement existing theories of vortex effect, and its accounting allows explain these processes. Have been presented thermodynamic characteristics of a bench double-flow vortex tube in laboratory experiment. Have been performed measurements of amplitude-frequency characteristics of vibrations performing external (mechanical) work under effect of gas-dynamic pulsations in vortex tubes. It has been demonstrated that vibration leads to gas kinetic energy dissipation into environment, resulting in enthalpy imbalance on the vortex tube. Has been performed analysis of additional cooling capacity, as well as heating of the vortex pipe mixed flow compared to throttling effect. The mechanism of shock wave and pulsation processes has been explained qualitatively based on analysis of a large number of various authors’ works and own experimental studies. It is emphasizing that the proposed qualitative mechanism requires further development and mathematical description based on the developed physical model.

Catalytic Dehydrogenation of Monoölefins to Diolefins. Source Materials for Synthetic Rubber and Resins

1940 ◽  
Vol 13 (3) ◽  
pp. 533-538
Author(s):  
Aristid V. Grosse ◽  
Jacque C. Morrell ◽  
Julian M. Mavity
Keyword(s):  
Raw Materials ◽  
Raw Material ◽  
Metallic Sodium ◽  
Catalytic Dehydrogenation ◽  
Hydrocarbon Gases ◽  
Present Contribution ◽  
Similar Work ◽  
Synthetic Rubber ◽  
Petroleum Resources ◽  
The One

Abstract Aside from the scientific value of the method described here for the catalytic dehydrogenation of monoölefins to diolefins, the present contribution has an important industrial, commercial, and military value, viz., as an economic source of raw material for synthetic rubber. The production of butenes from butanes and pentenes from pentanes has already been described. The present paper, showing the production of butadiene from butenes and isoprene from pentenes, is the connecting link between the billions of cubic feet of butanes present in natural and cracked gases and of butenes present in the latter, and the billions of gallons of pentanes available in natural gasoline and crude oil on the one hand, and the production of synthetic rubber from these raw materials on the other. The basic raw materials for the production of synthetic rubber therefore now include our tremendous resources of hydrocarbon oils, hydrocarbon gases, and coal to produce synthetic hydrocarbons, if and when our petroleum resources become exhausted. The production of synthetic rubber from butadiene and isoprene is well known. Wallach exposed isoprene to light and produced synthetic rubber. Matthews and Harries independently used metallic sodium to polymerize isoprene to rubber. Similar work has also been done bv others.

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