scholarly journals Thermogravimetric Analysis and Kinetic Calculation on the Combustion Characteristics of Two Typical Shenhua Chars

2021 ◽  
Author(s):  
Baixiang Xiang ◽  
Jun Huang ◽  
Houzhang Tan ◽  
Xiaohe Xiong ◽  
Yan Li ◽  
...  

Recently, a new ultra-low nitrogen combustion technology, pyrolysis and gasification coupling combustion, was proposed. The dependence on SCR or SNCR was reduced measurably with this technology. However, given the lower content of volatile matter in semi-chars, the burn-up ratio and combustion efficiency seemed to become lower. Thus, in this study, the combustion characteristics of the Shenhun and Carboniferous char were investigated under combustion conditions with the thermogravimetric method; meantime, kinetic calculation on the combustion characteristics were evaluated with Coats–Redfern method. Experiments indicated that Shenhun char showed good ignition and burnout characteristics when the pyrolysis temperature ranged from 973.15 K to1073.15 K; meanwhile, Carboniferous char showed good ignition and burnout characteristics when the pyrolysis temperature ranged from 873.15 K to 973.15 K. Besides, both the calculations and experiments indicated that Shenhun char showed better combustion characteristics than Carboniferous char.

2020 ◽  
Vol 04 ◽  
Author(s):  
Guohai Jia ◽  
Lijun Li ◽  
Li Dai ◽  
Zicheng Gao ◽  
Jiping Li

Background: A biomass pellet rotary burner was chosen as the research object in order to study the influence of excess air coefficient on the combustion efficiency. The finite element simulation model of biomass rotary burner was established. Methods: The computational fluid dynamics software was applied to simulate the combustion characteristics of biomass rotary burner in steady condition and the effects of excess air ratio on pressure field, velocity field and temperature field was analyzed. Results: The results show that the flow velocity inside the burner gradually increases with the increase of inlet velocity and the maximum combustion temperature is also appeared in the middle part of the combustion chamber. Conclusion: When the excess air coefficient is 1.0 with the secondary air outlet velocity of 4.16 m/s, the maximum temperature of the rotary combustion chamber is 2730K with the secondary air outlet velocity of 6.66 m/s. When the excess air ratio is 1.6, the maximum temperature of the rotary combustion chamber is 2410K. When the air ratio is 2.4, the maximum temperature of the rotary combustion chamber is 2340K with the secondary air outlet velocity of 9.99 m/s. The best excess air coefficient is 1.0. The experimental value of combustion temperature of biomass rotary burner is in good agreement with the simulation results.


Author(s):  
Masato Hiramatsu ◽  
Yoshifumi Nakashima ◽  
Sadamasa Adachi ◽  
Yudai Yamasaki ◽  
Shigehiko Kaneko

One approach to achieving 99% combustion efficiency (C.E.) and 10 ppmV or lower NOx (at 15%O2) in a micro gas turbine (MGT) combustor fueled by biomass gas at a variety of operating conditions is with the use of flameless combustion (FLC). This paper compares experimentally obtained results and CHEMKIN analysis conducted for the developed combustor. As a result, increase the number of stage of FLC combustion enlarges the MGT operation range with low-NOx emissions and high-C.E. The composition of fuel has a small effect on the characteristics of ignition in FLC. In addition, NOx in the engine exhaust is reduced by higher levels of CO2 in the fuel.


Author(s):  
Mihail V. Mal’ko ◽  
Sergej V. Vasilevich ◽  
Andrey V. Mitrofanov ◽  
Vadim E. Mizonov

The objective of the study is to examine the Coats-Redfern approximation and to propose an innovative kinetic calculation method for the complex process of the heavy tar thermal decomposition under non-isothermal process. The thermal decomposition process was examined using the thermogravimetric analysis. There are several kinetic models proposed to analyze pyrolysis mechanism in terms of the formal reaction. In this manner, the kinetic parameters of the pyrolysis process can be evaluated based on total mass loss (thermogravimetric analysis –TGA). The TGA procedures can be conducted with isothermal or non-isothermal conditions, but the experimental data obtained according to this procedure have to be transformed into appropriate correlation. The obtained results have shown that the reaction takes place within temperature range of 540 K to 700 K and the inductive period of the process is about 224 min. Kinetic parameters were estimated with using of the conventional Coats-Redfern method. A new kinetic calculation method has been designed to provide a less laboriousness of identifications procedures compared with Coats-Redfern approximation and to take into account an induction time of the process. As the outcome of this study, it was shown that the kinetic parameters estimated with using of the proposed model-fitted method gives the more appropriate correlation in comparison with the conventional Coats-Redfern method. The proposed method uses the Coats-Redfern algorithm for evaluation of the reaction mechanism, but the value of the constant rate is defined directly from experimental data on the conversion rate.


2021 ◽  
pp. 145-145
Author(s):  
Anna Matveeva ◽  
Andrey Komarovskikh ◽  
Artem Kuznetsov ◽  
Pavel Plyusnin ◽  
Vladimir Bukhtoyarov ◽  
...  

One of the aspects for optimizing the powdered biofuel combustion technology is to ensure proper relationship between powder production and its delivery into the reactor. This paper focuses on the effect of a time delay between production and use of powdered fuel on its combustion efficiency using pine sawdust as an example. It was established that the ignition delay time increases with an increasing delay between powdered fuel production and use (i.e., the effect of sample aging takes place). A correlation between the ignition delay time, the amount of lignin radicals, and the sample's ability to release volatile combustible matter is demonstrated.


Author(s):  
Han-Ping Chen ◽  
Xian-Hua Wang ◽  
Shi-Hong Zhang ◽  
De-Chang Liu ◽  
Yu-Hua Lai ◽  
...  

In China, there are a large number of pulverized coal-fired industrial boilers, whose steam capacities are usually relatively small. These boilers can burn only high-grade coal and have low combustion efficiency. Furthermore, the combustion emissions, such as SO2 and NOx, pollute the environment severely. Therefore it is very important and urgent to adopt economically efficient and environmentally friendly technologies to retrofit these boilers. At the same time, there are many industrial wastes, such as bagasse, wood waste, rubbish, petroleum coke and so on, need burning disposal in China. Fluidized bed combustion technology is a kind of clear combustion technology, which has many advantages, such as excellence fuel flexibility, high combustion efficiency, low pollutant emission and good turndown capability etc. So, adopting fluidized bed combustion technology, retrofitting pulverized coal-fired boiler into fluidized bed boiler can realize pure burning various wastes or co-firing with coal, which should have great economic benefits and social benefits. And the application prospect of the method is also extensive. The State Key Laboratory of Coal Combustion has successfully retrofitted a 25t/h pulverized coal-fired boiler into circulating fluidized bed boiler with in-bed tubes and downward exhaust cyclone. The retrofitted boiler can burn mixture of coal and bagasse and the steam capacity reaches 35t/h. This paper presents the retrofitting measures and the operation status of the boiler after retrofitting.


2021 ◽  
Vol 10 (4) ◽  
pp. 737-746
Author(s):  
Ukrit Samaksaman ◽  
Kanit Manatura

The co-combustion characteristics and kinetics of torrefied sugarcane bagasse (TB), lignite (L), and their blended samples were experimentally investigated using thermogravimetric analysis (TGA) and derivative thermogravimetry (DTG)based on the Coats-Redfern method for kinetic estimation.Their physicochemical properties were also investigated.Raw bagasse was thermally treated in a laboratory-scale torrefactor at 275 °C with a torrefaction time of 60 min under an inert nitrogen environment.Then, the torrefied bagasse was blended with Thai lignite as a co-fuel at ratios of 50:50 (TB50L50), 70;30(TB70L30), and 90:10 (TB90L10), respectively. Torrefaction improved the fuel properties and heating value of the raw bagasse as well as reducing the O/C and H/C ratios.In addition, the blending of torrefied bagasse with lignite improved the combustion behavior.The TGA and DTG results indicated that the ignition and burnout temperatures stepped downwards with different increasing ratios of torrefied bagasse.The co-combustion behavior at the maximum burning rate showed that the burnout temperatures of TB50L50, TB70L30, and TB90L10 were 532, 529, and 528 °C, respectively, indicating a slight decrease with an increasing torrefied bagasse blending ratio.These results were sufficient to provide comprehensive guidelines in terms of the design and operation of the combustion system for adding torrefied bagasse into the co-firing process.


2014 ◽  
Vol 14 (1) ◽  
pp. 9-15 ◽  
Author(s):  
Yongbin Lai ◽  
Bo Wang ◽  
Xiu Chen ◽  
Yinnan Yuan ◽  
Lei Zhong ◽  
...  

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