scholarly journals Obtaining food dyes of the anthocyanin class from grape pomace: the mechanism of the extraction process

2020 ◽  
pp. 134-141
Author(s):  
M.V. Nikolenko ◽  
◽  
K.O. Elchaninova ◽  
V.O. Karabut ◽  
O.Yu. Vashkevych ◽  
...  
Keyword(s):  
Experimental Data ◽  
Raw Materials ◽  
Diffusion Mechanism ◽  
Extraction Process ◽  
Theoretical Description ◽  
Grape Pomace ◽  
Solution Temperature ◽  
Diffusion Controlled ◽  
Heterogeneous Processes ◽  
Limiting Stage

In order to determine the mechanism and factors of optimization of the process of extraction of anthocyanin dyes from crushed grape pomace, the kinetics of the process at the temperatures of 14 and 800C was studied using aqueous and aqueous-ethanolic solutions under conditions of intensive mixing. For the theoretical description of the kinetic data, a model of the extraction process from a porous solid body was used under conditions of relatively small values of constrained diffusion coefficients. It was established that the experimental data are well described by the equation for the internal diffusion mechanism of the extraction process. It was shown that the experimental data are also well described by the Yander equation proposed for modeling diffusion-controlled heterogeneous processes with constant parameters of the diffusion. It was concluded that both equations are similar to each other and differ only in the coefficients at the degrees of transformation, which is due to the assumptions that were made in their derivation. The conclusion about the nature of the limiting stage of the process of extraction of anthocyanin dyes was confirmed by calculations of the apparent activation energy, the value of which was 14.0 kJ mol–1. The obtained data allowed determining the factors of optimization of anthocyanin extraction process from grape pomace: particle size of raw materials, anthocyanin concentration in solution, temperature, ethanol content in solution, solution acidity, degree of plant cell destruction and ultrasonic treatment.

Textiles and perishable materials

2018 ◽  
Author(s):  
Johanna Banck-Burgess
Keyword(s):  
Experimental Data ◽  
Everyday Life ◽  
Iron Age ◽  
Raw Materials ◽  
Visual Representations ◽  
Detailed Knowledge ◽  
Textile Production ◽  
Funerary Rituals ◽  
The Status

This chapter challenges traditional views on Iron Age dress. Recent research has greatly enhanced our understanding of how textiles were manufactured in Iron Age Europe. The variety of qualities, textures, techniques, raw materials, colours, and cuts give insights into the detailed knowledge of the craftspeople involved. Textiles used for dress, blankets, or furniture fittings were appreciated not only for their appearance, but also for the quality of the work. In everyday life, their optical qualities were used to express and signal gender, social roles and status, while the labour expended on textiles found in wealthy burials underlines both the status of the deceased and the extent of conspicuous consumption in funerary rituals—for instance, for wrapping grave furniture and goods. The chapter also looks at experimental data showing how labour-intensive textile production was, and the types of clothing and accessories found in different archaeological contexts or depicted in visual representations.

Extraction Process of Amaranthine Pigment Keeping the Water Wax Fuit Biological Active

2013 ◽  
Vol 295-298 ◽  
pp. 150-154
Author(s):  
Feng Jie Wang ◽  
Xin Qiao Dong ◽  
Xiao Liu
Keyword(s):  
Citric Acid ◽  
Extraction Method ◽  
Raw Materials ◽  
Extraction Process ◽  
Extraction Yield ◽  
Extraction Temperature ◽  
Natural Pigment ◽  
Pigment Extraction ◽  
Acid Aqueous Solution ◽  
The Stability

Development natural pigment retained a variety of nutrition composition is extremely research value.Water Wax Trees Fruit was as raw materials,citric acid aqueous solution was as extracting agent.Amaranthine pigment extraction method were studied on fully grasping the stability of the natural amaranthine pigment and no damage to the water wax fruit biological activity.The effect of extraction yield were studied on Water Wax Trees Fruit natural amaranthine pigment.The results show that the better extraction conditions are extraction temperature at 70 °C, extraction time for 3h,citric acid concentration1.0 % , the material/liquid ration(g/ml) 1:5.The extraction yield is 2.95%.Ultraviolet absorption maximum wavelength is 280 nm.

scholarly journals Intensification of the extraction process of phenolic compounds from Acorus calamus leaves

2021 ◽  
pp. 4-10
Author(s):  
Oleksiy Andryushayev ◽  
Olena Ruban ◽  
Yuliia Maslii ◽  
Inna Rusak
Keyword(s):  
Phenolic Compounds ◽  
Raw Materials ◽  
Extraction Process ◽  
Raw Material ◽  
Acorus Calamus ◽  
Optimal Conditions ◽  
Ultrasonic Action ◽  
Different Temperatures ◽  
Method Of Extraction ◽  
Temperature Time

The aim. To determine the intensified method of extraction of phenolic compounds from Acorus calamus leaves and optimal conditions for the process. Materials and methods. In order to develop the optimal intensified method of extraction samples were prepared in different conditions of raw materials-extractant ratio, temperature, time and multiplicity. As a raw materials spectrophotometrically pre-standardized Acorus calamus leaves were used. The extraction was carried out in a hermetically sealed ultrasonic extraction reactor PEX 1 (REUS, Contes, France). As the criteria of extraction efficiency were indicators of dry residue and total amount of flavonoids determined using methods described in State Pharmacopoeia of Ukraine. The amount of flavonoids was determined spectrophotometrically on a certified device Specord 200 (Analytik Jena, Germany). Results. According to our research results it was found that ultrasonic action and addition of surfactant significantly improves the efficiency of the extraction process. The optimal conditions for the process were determined. Experimentally proved that the rational raw material-extractant ratio is 1:15. Comparative study of the extraction process with different temperatures showed that the highest amount of extractives is achieved at temperature 70 °C and 45 min of duration. The optimal extraction multiplicity is 3. Conclusions. As a result of the study, the intensified extraction method for Acorus calamus leaves – re-maceration with ultrasound – was established. The conducted researches allowed to develop the method of extraction, expedient in the conditions of the modern pharmaceutical industry.

scholarly journals PRODUCTION OF EXTRACTS FROM VEGETABLE RAW MATERIALS BY CARBON DIOXIDE

2020 ◽  
Vol 14 (1) ◽  
Author(s):  
K. Gafurov ◽  
B. Muhammadiev ◽  
Sh. Mirzaeva ◽  
F. Kuldosheva
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Co2 ◽  
Raw Materials ◽  
Maximum Yield ◽  
Volumetric Flow Rate ◽  
Extraction Process ◽  
Raw Material ◽  
Critical Conditions ◽  
Plant Materials ◽  
Laboratory Setup

The unique properties of supercritical carbon dioxide as a solvent are widely used for extraction. In supercritical media, the dissolution of molecules of various chemical nature is possible. The purpose of this investigation was to study the extraction process and obtain extracts from valuable regional plant materials by applying CO2 extraction under pre- and supercritical conditions. The objects of research were: ground seeds of melon, pumpkin and licorice roots, as well as mint leaves, mulberry and jida flowers. For extraction, a laboratory setup was used that allows extraction when the CO2 is supplied by a high-pressure plunger pump in the sub- and supercritical state using a heat pump. The pressure range is 3-15 MPa, temperatures 295–330 K, and the volumetric flow rate above the critical CO2 is 800–900 g. Experiments with ground seeds of melon and pumpkin showed that as a result of 4 sequentially performed extraction cycles on a single load with supercritical CO2 parameters ( 315–330 K; 3–7.5 MPa) the decrease in the mass of melon seeds was 90 g (pumpkins 80 g). During the total extraction time (2.5 hours), 20 kg of CO2 were pumped through the reactor (25 l at 290 K and 6.8 MPa), while the average oil content in the extract was 4 g per 1 kg of CO2 (3.0 g per 1 l of SС-CO2) In experiments with jida flowers, the maximum amount of solid extractable substance (2% by weight of the raw material) was obtained at a temperature in the extractor of 308 K and a pressure of 7.5 MPa. Upon extraction under critical conditions in collection 2, the liquid phase was absent; only a yellow-green paste was released in it. According to the results of experiments with mint leaves, the maximum yield of a greenish liquid was observed at T = 315 K and P = 4 MPa., Mulberry - at T = 306 K and P = 6.0 MPa. The results of the extraction of oils and extracts from ground seeds of melon, pumpkin and licorice roots, as well as mint leaves, mulberries and jida flowers confirm that the maximum yield of the extracted substance is achieved with supercritical CO2 parameters in the extractor (310 K, 7.5 MPa). When liquid CO2 is extracted (300 K and 6-8 MPa), up to 2% of a yellow substance is extracted, which does not differ in appearance from a supercritical extract.

scholarly journals EXPLOITATION OF AGRI-FOOD SOLID WASTES FOR RECOVERY OF HIGH ADDED-VALUE COMPOUNDS: THE CASE OF GRAPE POMACE AND ONION PEELS

1970 ◽  
Vol 62 ◽  
Author(s):  
Papagiotis Kefalas ◽  
D. P. Makris
Keyword(s):  
Raw Materials ◽  
Reducing Power ◽  
Grape Pomace ◽  
Solid Wastes ◽  
Added Value ◽  
Waste Materials ◽  
Processing Plant ◽  
Food Ingredients ◽  
Pigment Extraction ◽  
Red Grape

Large quantities of both liquid and solid wastes are produced annually by the food processing industry. These waste materials contain principally biodegradable organic matter and their disposal creates serious environmental problems. The waste loads at the processing plant can be significantly reduced through the use of new or modified processing methods or through in-plant treatment and reuse and a variety of processes are being developed towards this direction, aiming at converting the waste materials into bio-fuels, food ingredients and other added-value bio-products. The scope of the present study was an examination on the possibilities of using non-toxic, cheap and readily available means of recovering phenolics from red pomace and onion peels. On such a basis, the solvent systems tested were composed of ethanol, a bio-solvent that can be obtained after fermentation of the sugar-containing raw materials and distillation. In the case of red grape pomace, simple media composed of 60% ethanol were shown to be ideal for recovery of extracts with increased polyphenol concentration and antiradical activity. Higher ethanol content (90%), however, was more effective for pigment extraction. For onion peels, extracts with high flavonol recovery and a reducing power were obtained with a similar medium (60% ethanol/ 0.1% HCl), while optimisation of the extraction conditions with regard to temperature and time, afforded higher yield and more active extracts.

scholarly journals CONCOMITANT EXTRACTION PROCESS OF NIOBIUM AT THE TITANIUM TETRACHLORIDE PRODUCTION

2020 ◽  
pp. 173-177
Author(s):  
Т.К. Sarsembekov ◽  
Т.B. Yanko ◽  
S.A. Sidorenko ◽  
M.M. Pylypenko
Keyword(s):  
Phase Transformations ◽  
Nuclear Power ◽  
Titanium Tetrachloride ◽  
Raw Materials ◽  
Extraction Process ◽  
By Products ◽  
Titanium Raw Materials

Development of the fundamentals of a technology for producing niobium by the concomitant extraction in the process of production of titanium tetrachloride from titanium raw materials. The paper provides data on the amount of niobium contained in the feedstock to produce titanium tetrachloride, the distribution of niobium during processing by products and waste. The forms of phase transformations and transitions of niobium during processing are considered. Schemes for processing niobium-containing chloride materials and technologies for their further application for producing alloys for nuclear power are proposed.

scholarly journals Emulsion Liquid Membrane Extraction of Turquoise Blue Reactive Dye–Study on Membrane Breakage and Swelling

2017 ◽  
Vol 11 (1) ◽  
Author(s):  
N. Othman ◽  
S. N. Zailani ◽  
N. Mili
Keyword(s):  
Liquid Membrane ◽  
Raw Materials ◽  
Extraction Process ◽  
Reactive Dye ◽  
Point Of View ◽  
Membrane Extraction ◽  
Hydrodynamic Condition ◽  
Emulsion Liquid Membrane ◽  
Liquid Membrane Extraction ◽  
Span 80

Reactive dyes are the principal dyes used in batik industry in Malaysia. From the environmental point of view the dyes should be removed from wastewater because they are toxic in nature. Therefore, the removal and recovery of dyes from batik industry wastewater is absolute necessity in order to save raw materials and to protect environment from hazardous compounds. An experiment was carried out using emulsion liquid membrane (ELM) process in batch system to study the extraction behaviour of Turquoise Blue which is commonly used in batik industry. Several parameters have been studied such as carrier and surfactant/emulsifier concentrations, stripping agent and extraction time. The liquid membrane was formulated using kerosene as diluent, SPAN 80 as emulsifier and tri-dodecylamine (TDA) as a carrier. Hydrodynamic condition to generate extraction process was at 1:3 treat ratio and 250 rpm stirring speed for 10 minutes while the emulsification was done at 12000 rpm for 5 minutes using homogenizer. The result obtained shows that, more than 70% of Turquoise Blue was extracted at favourable condition of 0.07 M TDA, 7% (w/v) SPAN 80 and 0.5 M Thiourea in 1 M NaOH.

Extraction of Cu(II) with Acorga M5640 using hollow fibre liquid membrane

2015 ◽  
Vol 69 (5) ◽  
Author(s):  
Shiva Agarwal ◽  
M. Teresa A. Reis ◽  
M. Rosinda C. Ismael ◽  
Jorge M. R. Carvalho
Keyword(s):  
Experimental Data ◽  
Liquid Membrane ◽  
Extraction Process ◽  
Hollow Fibre ◽  
Copper Extraction ◽  
Flow Rates ◽  
Aqueous Layer ◽  
Feed Phase ◽  
Overall Mass Transfer Coefficient ◽  
Dispersion Technique

AbstractThe extraction of copper from sulphuric/sulphate solutions using a hollow fibre module as contactor was studied. The aldoxime Acorga M5640 was used as an extractant. The effects on the extraction rate of the flow-rates, the concentrations of copper and extractant, pH, and the presence of Na2SO4 in the feed phase were investigated. The overall mass transfer coefficient for copper extraction was calculated from the experimental data and was compared with the value evaluated by the resistance in the series model. The extraction process was found to be governed by the diffusion in the boundary aqueous layer and also by the chemical reaction. The kinetic data obtained were used to simulate the extraction of copper with the pseudo-emulsion-based hollow fibre with strip dispersion technique. The accordance between the results thus calculated and the experimental data was found to be satisfactory, particularly for dilute feed solutions.

CATIONIC COPOLYMERIZATION OF ISOBUTYLENE WITH ISOPRENE: KINETICS OF THE PROCESS AND DETERMINATION OF KINETIC CONSTANTS

2015 ◽  
Vol 88 (4) ◽  
pp. 574-583 ◽  
Author(s):  
N. V. Ulitin ◽  
K. A. Tereshchenco ◽  
D. A. Shiyan ◽  
G. E. Zaikov
Keyword(s):  
Experimental Data ◽  
Molecular Weight ◽  
Cationic Polymerization ◽  
Methyl Chloride ◽  
Theoretical Description ◽  
Kinetic Constants ◽  
Molecular Weight Characteristics ◽  
Cationic Copolymerization ◽  
Kinetics Of

ABSTRACT A theoretical description has been developed of the kinetics of isobutylene with isoprene (IIR) cationic polymerization in the environment of methyl chloride on aluminum trichloride as the catalyst. Based on experimental data on the kinetics of copolymerization (isobutylene conversion curve) and the molecular weight characteristics of the copolymer of IIR, kinetic constants for the process were found. Adequacy of the developed theoretical description of the kinetics of the IIR copolymerization process was confirmed by comparing the experimental molecular-weight characteristics calculated by this description, independent characteristics, and IIR unsaturation.

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