Liquid micronized CaCO3: an alternative to correct the pH of an acidic soil and improve pineapple development

2020 ◽  
Vol 13 (8) ◽  
Author(s):  
RIGOBERTO ZETINA LEZAMA ◽  
OSCAR HUGO TOSQUY VALLE ◽  
VALENTÍN A. ESQUEDA ESQUIVEL
Keyword(s):  
Analysis Of Variance ◽  
Soil Ph ◽  
Design Methodology ◽  
Low Dose ◽  
Acidic Soils ◽  
Vegetative Development ◽  
Fisher Test ◽  
Ph Values ◽  
Optimum Ph ◽  
Optimal Ph

Objective: to determine the effect of liquid micronized CaCO3 on soil pH and pineapple vegetative development in acidic soils at Isla, Veracruz. Design/Methodology/Approach: randomized blocks with four replications and four treatments: Non-liming control (T1), 2.0 t ha-1 of dolomite (T2), 10.0 (T3) and 20.0 (T4) L ha-1  of liquid CaCO3. The soil pH was measured, before liming and at 30, 60, 90 and 120 days after sowing, at depths of 0-5, 5-15 and 15-30 cm, and the biomass was determined at the 60, 90 and 120 dds. Analysis of variance and the 5% Fisher test were performed to separate means. Results: up to 90 dds, with dolomite, optimal pH values were reached for pineapple, significantly higher than those of CaCO3 in both doses. At 120 dds, with 20 L ha-1 CaCO3 the pH was higher than 5.0, similar to that of dolomite and higher than those of the low dose of CaCO3 and the control. At the last date, with 20 L ha-1 of CaCO3 1,346 g plant-1 biomass were produced, an amount similar to dolomite and the low dose of CaCO3 and significantly higher than that of the control. Findings/Conclusions: up to 120 dds, with 20 L ha-1 of liquid CaCO3, the optimum pH for pineapple was reached in the three strata, the values were similar to those of dolomite and higher than those of the low dose of CaCO3 and the control. CaCO3 (20 L ha-1) and dolomite (2 t ha-1) produced 33.1 and 20.9% more biomass than the control.

scholarly journals Variation in pH Optima of Hydrolytic Enzyme Activities in Tropical Rain Forest Soils

2010 ◽  
Vol 76 (19) ◽  
pp. 6485-6493 ◽  
Author(s):  
Benjamin L. Turner
Keyword(s):  
Soil Ph ◽  
Forest Soils ◽  
Extracellular Enzymes ◽  
Hydrolytic Enzyme ◽  
Hydrolytic Enzymes ◽  
Acidic Ph ◽  
Acidic Soils ◽  
Fluorogenic Substrates ◽  
Ph Values ◽  
Optimum Ph

ABSTRACT Extracellular enzymes synthesized by soil microbes play a central role in the biogeochemical cycling of nutrients in the environment. The pH optima of eight hydrolytic enzymes involved in the cycles of carbon, nitrogen, phosphorus, and sulfur, were assessed in a series of tropical forest soils of contrasting pH values from the Republic of Panama. Assays were conducted using 4-methylumbelliferone-linked fluorogenic substrates in modified universal buffer. Optimum pH values differed markedly among enzymes and soils. Enzymes were grouped into three classes based on their pH optima: (i) enzymes with acidic pH optima that were consistent among soils (cellobiohydrolase, β-xylanase, and arylsulfatase), (ii) enzymes with acidic pH optima that varied systematically with soil pH, with the most acidic pH optima in the most acidic soils (α-glucosidase, β-glucosidase, and N-acetyl-β-glucosaminidase), and (iii) enzymes with an optimum pH in either the acid range or the alkaline range depending on soil pH (phosphomonoesterase and phosphodiesterase). The optimum pH values of phosphomonoesterase were consistent among soils, being 4 to 5 for acid phosphomonoesterase and 10 to 11 for alkaline phosphomonoesterase. In contrast, the optimum pH for phosphodiesterase activity varied systematically with soil pH, with the most acidic pH optima (3.0) in the most acidic soils and the most alkaline pH optima (pH 10) in near-neutral soils. Arylsulfatase activity had a very acidic optimum pH in all soils (pH ≤3.0) irrespective of soil pH. The differences in pH optima may be linked to the origins of the enzymes and/or the degree of stabilization on solid surfaces. The results have important implications for the interpretation of hydrolytic enzyme assays using fluorogenic substrates.

scholarly journals Effects of pH and Magnetic Material on Immunomagnetic Separation of Cryptosporidium Oocysts from Concentrated Water Samples

2002 ◽  
Vol 68 (4) ◽  
pp. 2066-2070 ◽  
Author(s):  
Ryan C. Kuhn ◽  
Channah M. Rock ◽  
Kevin H. Oshima
Keyword(s):  
Magnetic Material ◽  
Water Samples ◽  
Environmental Water ◽  
Immunomagnetic Separation ◽  
Deionized Water ◽  
Ph Values ◽  
Cryptosporidium Oocysts ◽  
Optimum Ph ◽  
Effects Of Ph ◽  
Optimal Ph

ABSTRACT In this study, we examined the effect that magnetic materials and pH have on the recoveries of Cryptosporidium oocysts by immunomagnetic separation (IMS). We determined that particles that were concentrated on a magnet during bead separation have no influence on oocyst recovery; however, removal of these particles did influence pH values. The optimal pH of the IMS was determined to be 7.0. The numbers of oocysts recovered from deionized water at pH 7.0 were 26.3% higher than those recovered from samples that were not at optimal pH. The results indicate that the buffers in the IMS kit did not adequately maintain an optimum pH in some water samples. By adjusting the pH of concentrated environmental water samples to 7.0, recoveries of oocysts increased by 26.4% compared to recoveries from samples where the pH was not adjusted.

Proteolytic activity of Trichoderma viride in mixed culture with Sclerotium rolfsii in soil

1978 ◽  
Vol 24 (4) ◽  
pp. 487-490 ◽  
Author(s):  
R. Rodriguez-Kabana ◽  
W. D. Kelley ◽  
E. A. Curl
Keyword(s):  
Mixed Culture ◽  
Proteolytic Activity ◽  
Soil Ph ◽  
Trichoderma Viride ◽  
Sclerotium Rolfsii ◽  
Ph Values ◽  
Optimal Ph

Cultures of Sclerotium rolfsii and Trichoderma viride together in autoclaved soil were assayed at intervals during 8 days of incubation for proteolytic activity (PA) of T. viride. Significant proteolytic activity was detected only in soil containing T. viride (i.e., T. viride alone or S. rolfsii + T. viride); greatest activity occurred between 3 and 4 days after infestation and declined rapidly thereafter. Maximal PA in the mixed-culture soil was accompanied by an increase in soil pH. Optimal pH values for PA was 5.5–6.5 with a maximum at 6.0.

Effect of lime application to strongly acidic soils on the growth of macadamia seedlings

1990 ◽  
Vol 30 (3) ◽  
pp. 421
Author(s):  
RL Aitken ◽  
RA Stephenson ◽  
EC Gallagher
Keyword(s):  
Seedling Growth ◽  
Soil Ph ◽  
Sandy Loam ◽  
Chemical Properties ◽  
Calcium Deficiency ◽  
Silty Clay ◽  
Micronutrient Deficiencies ◽  
Acidic Soils ◽  
Ph Values ◽  
Ph Range

Glasshouse experiments were undertaken to evaluate the effects of soil pH on macadamia (Macadamia integrifolia Maiden and Betche) seedlings and to examine seedling growth in relation to soil chemical properties in acidic soils. In one experiment, in which 13 rates of CaCO3 (0 to the equivalent of 12 000 kg/ha) were applied to a strongly acidic (pH 3.9, 1:5 in water) sandy loam, optimum seedling growth was obtained in the pH range 4.0-5.9. A second experiment, in which seedlings were grown in each of 3 strongly acidic soils amended with various rates of CaCO3, also showed that macadamia seedlings could grow satisfactorily at pH values of 4.0 (2 soils) and 4.5 (1 soil). Increased seedling growth on 2 soils (silty clay loam, experiment 1; sandy loam, experiment 2) treated with lime was due to amelioration of aluminium and/or manganese toxicity and not to the alleviation of calcium deficiency. The results indicate that soil pH measurement alone would not be a good indicator of seedling growth. In some soils, seedling growth was optimum at pH 3.9, whereas at pH 4.0 in another soil, growth was well below the maximum which was attained at pH 4.5. The significant (P<0.05) growth reductions that occurred on all soils limed to pH values >6.0 were attributed to induced micronutrient deficiencies.

Trans-sialidase Associated with Atherosclerosis: Defining the Identity of a Key Enzyme Involved in the Pathology

2019 ◽  
Vol 20 (9) ◽  
pp. 938-941
Author(s):  
Victor Y. Glanz ◽  
Veronika A. Myasoedova ◽  
Andrey V. Grechko ◽  
Alexander N. Orekhov
Keyword(s):  
Acid Metabolism ◽  
Research Subject ◽  
Disease Pathogenesis ◽  
Sialidase Activity ◽  
Ph Values ◽  
Ldl Particles ◽  
Optimum Ph ◽  
Key Enzyme ◽  
St6gal I

Atherosclerosis is associated with the increased trans-sialidase activity, which can be detected in the blood plasma of atherosclerosis patients. The likely involvement in the disease pathogenesis made this activity an interesting research subject and the enzyme that may perform such activity was isolated and characterized in terms of substrate specificity and enzymatic properties. It was found that the enzyme has distinct optimum pH values, and its activity was enhanced by the presence of Ca2+ ions. Most importantly, the enzyme was able to cause atherogenic modification of lowdensity lipoprotein (LDL) particles in vitro. However, the identity of the discovered enzyme remained to be defined. Currently, sialyltransferases, mainly ST6Gal I, are regarded as major contributors to sialic acid metabolism in human blood. In this mini-review, we discuss the possibility that atherosclerosis- associated trans-sialidase does, in fact, belong to the sialyltransferases family.

scholarly journals Critical importance of pH and collector type on the flotation of sphalerite and galena from a low-grade lead–zinc ore

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Abdolrahim Foroutan ◽  
Majid Abbas Zadeh Haji Abadi ◽  
Yaser Kianinia ◽  
Mahdi Ghadiri
Keyword(s):  
Iron Ore ◽  
Low Grade ◽  
Zinc Recovery ◽  
Flotation Process ◽  
Ph Values ◽  
Lead And Zinc ◽  
Optimum Ph ◽  
Iron And Zinc ◽  
Lead Zinc ◽  
Zinc Concentrate

AbstractCollector type and pulp pH play an important role in the lead–zinc ore flotation process. In the current study, the effect of pulp pH and the collector type parameters on the galena and sphalerite flotation from a complex lead–zinc–iron ore was investigated. The ethyl xanthate and Aero 3418 collectors were used for lead flotation and Aero 3477 and amyl xanthate for zinc flotation. It was found that maximum lead grade could be achieved by using Aero 3418 as collector at pH 8. Also, iron and zinc recoveries and grades were increased in the lead concentrate at lower pH which caused zinc recovery reduction in the zinc concentrate and decrease the lead grade concentrate. Furthermore, the results showed that the maximum zinc grade and recovery of 42.9% and 76.7% were achieved at pH 6 in the presence of Aero 3477 as collector. For both collectors at pH 5, Zinc recovery was increased around 2–3%; however, the iron recovery was also increased at this pH which reduced the zinc concentrate quality. Finally, pH 8 and pH 6 were selected as optimum pH values for lead and zinc flotation circuits, respectively.

scholarly journals Laccases: Versatile Biocatalysts for the Synthesis of Heterocyclic Cores

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3719
Author(s):  
Ana Catarina Sousa ◽  
Lígia O. Martins ◽  
M. Paula Robalo
Keyword(s):  
Membered Ring ◽  
Low Molecular Weight ◽  
Redox Potentials ◽  
Redox Mediators ◽  
Multicopper Oxidases ◽  
Phenothiazine Derivatives ◽  
Ph Values ◽  
Electron Shuttles ◽  
Specific Oxidation ◽  
Optimal Ph

Laccases are multicopper oxidases that have shown a great potential in various biotechnological and green chemistry processes mainly due to their high relative non-specific oxidation of phenols, arylamines and some inorganic metals, and their high redox potentials that can span from 500 to 800 mV vs. SHE. Other advantages of laccases include the use of readily available oxygen as a second substrate, the formation of water as a side-product and no requirement for cofactors. Importantly, addition of low-molecular-weight redox mediators that act as electron shuttles, promoting the oxidation of complex bulky substrates and/or of higher redox potential than the enzymes themselves, can further expand their substrate scope, in the so-called laccase-mediated systems (LMS). Laccase bioprocesses can be designed for efficiency at both acidic and basic conditions since it is known that fungal and bacterial laccases exhibit distinct optimal pH values for the similar phenolic and aromatic amines. This review covers studies on the synthesis of five- and six-membered ring heterocyclic cores, such as benzimidazoles, benzofurans, benzothiazoles, quinazoline and quinazolinone, phenazine, phenoxazine, phenoxazinone and phenothiazine derivatives. The enzymes used and the reaction protocols are briefly outlined, and the mechanistic pathways described.

Soil acidity in 1970 and 1989 in a coniferous forest in southwest Finland

1998 ◽  
Vol 78 (3) ◽  
pp. 477-479 ◽  
Author(s):  
C. J. Westman ◽  
S. Jauhiainen
Keyword(s):  
Key Words ◽  
Soil Ph ◽  
Soil Acidity ◽  
Mineral Soil ◽  
Coniferous Forest ◽  
Soil Layers ◽  
Water Suspension ◽  
Ph Values ◽  
Humus Layer ◽  
Repeated Sampling

Forest soil pH in southwest Finland was measured with identical sampling and analysing methods in 1970 and 1989. The acidity of the organic humus layer increased significantly as pH values measured on water and on salt suspensions decreased between the two sampling dates. For the mineral soil layers, no unambiguous trend was found. pH values measured on salt suspension tended to be unchanged or lower, while pH on water suspension in some soil layers were even higher in 1989 than in 1970. Key words: pH, repeated sampling

scholarly journals Effect of alkaline pH on photosynthetic water oxidation and the association of extrinsic proteins with Photosystem Two

1989 ◽  
Vol 258 (2) ◽  
pp. 357-362 ◽  
Author(s):  
D J Chapman ◽  
J De Felice ◽  
K Davis ◽  
J Barber
Keyword(s):  
Water Splitting ◽  
Water Oxidation ◽  
Binding Sites ◽  
Partial Recovery ◽  
Alkaline Ph ◽  
Ph Values ◽  
Extrinsic Proteins ◽  
Reversible Phase ◽  
Photosynthetic Water Oxidation ◽  
Optimal Ph

Incubation of a membrane preparation enriched in Photosystem Two (PSII) at alkaline pH inhibited the water-splitting reactions in two distinct steps. Up to pH 8.5 the inhibition was reversible, whereas at higher alkalinities it was irreversible. It was shown that the reversible phase correlated with loss and rebinding of the 23 kDa extrinsic polypeptide. However, after mild alkaline treatments a partial recovery was possible without the binding of the 23 kDa polypeptide when the assay was at the optimal pH of 6.5 and in a medium containing excess Cl-. The irreversible phase was found to be closely linked with the removal of the 33 kDa extrinsic protein of PSII. Treatments with pH values above 8.5 not only caused the 33 kDa protein to be displaced from the PSII-enriched membranes, but also resulted in an irreversible modification of the binding sites such that the extrinsic 33 kDa protein could not reassociate with PSII when the pH was lowered to 6.5. The results obtained with these more extreme alkaline pH treatments support the notion that the 23 kDa protein cannot bind to PSII unless the 33 kDa protein is already bound. The differential effect of pH on the removal of the 23 kDa and 33 kDa proteins contrasted with the data of Kuwabara & Murata [(1983) Plant Cell Physiol. 24, 741-747], but this discrepancy was accounted for by the use of glycerol in the incubation media.

scholarly journals Adsorption of Heavy Metals on Soil Collected from Lixisol of Typical Karst Areas in the Presence of CaCO3 and Soil Clay and Their Competition Behavior

2020 ◽  
Vol 12 (18) ◽  
pp. 7315
Author(s):  
Guandi He ◽  
Zhenming Zhang ◽  
Xianliang Wu ◽  
Mingyang Cui ◽  
Jiachun Zhang ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Soil Sample ◽  
Soil Ph ◽  
Clay Content ◽  
Guizhou Province ◽  
Metal Exposure ◽  
Risk Area ◽  
High Risk Area ◽  
Ph Values ◽  
Pseudo Second Order

The content of heavy metals in the soil in Guizhou Province, which is a high-risk area for heavy metal exposure, is significantly higher than that in other areas in China. Therefore, the objective of this study was to evaluate the ability of CaCO3 and clay to accumulate heavy metals in topsoil sample collected from Lixisol using the method of indoor simulation. The results showed that the contents of Cu, Zn, Cd, Cr, Pb, Hg and As in the soil sample were 10.8 mg/kg, 125 mg/kg, 0.489 mg/kg, 23.5 mg/kg, 22.7 mg/kg, 58.3 mg/kg and 45.4 mg/kg, respectively. The soil pH values increased with the CaCO3 concentration in the soil, and the fluctuation of the soil pH values was weak after the CaCO3 concentrations reached 100 g/kg. The adsorption capacity of lime soil increased by approximately 10 mg/kg on average, and the desorption capacity decreased by approximately 300 mg/kg on average. The desorption of all heavy metals in this study did not change with increasing clay content. Pseudo-second-order kinetics were more suitable for describing the adsorption kinetics of heavy metals on the soil material, as evidenced by the higher R2 value. The Freundlich model can better describe the adsorption process of As on lime soil. The process of As, Cr, Cd and Hg adsorption on the soil sample was spontaneous and entropy-driven. Additionally, the process of Cu and Pb adsorption on the soil materials was spontaneous and enthalpy-driven. Generally, the adsorption and desorption of heavy metals in polluted soil increased and decreased, respectively, with increasing CaCO3 content. The effect of calcium carbonate on the accumulation of heavy metals in soil was greater than that of clay. In summary, CaCO3 and pH values in soil can be appropriately added in several areas polluted by heavy metals to enhance the crop yield and reduce the adsorption of heavy metals in soils.

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