scholarly journals Biochemical Methane Potential of Cork Boiling Wastewater at Different Inoculum to Substrate Ratios

2021 ◽  
Vol 11 (7) ◽  
pp. 3064
Author(s):  
Roberta Mota-Panizio ◽  
Manuel Jesús Hermoso-Orzáez ◽  
Luis Carmo-Calado ◽  
Gonçalo Lourinho ◽  
Paulo Sérgio Duque de Brito

The present study evaluates the digestion of cork boiling wastewater (CBW) through a biochemical methane potential (BMP) test. BMP assays were carried out with a working volume of 600 mL at a constant mesophilic temperature (35 °C). The experiment bottles contained CBW and inoculum (digested sludge from a wastewater treatment plant (WWTP)), with a ratio of inoculum/substrate (Ino/CBW) of 1:1 and 2:1 on the basis of volatile solids (VSs); the codigestion with food waste (FW) had a ratio of 2/0.7:0.3 (Ino/CBW:FW) and the codigestion with cow manure (CM) had a ratio of 2/0.5:0.5 (Ino/CBW:CM). Biogas and methane production was proportional to the inoculum substrate ratio (ISR) used. BMP tests have proved to be valuable for inferring the adequacy of anaerobic digestion to treat wastewater from the cork industry. The results indicate that the biomethane potential of CBWs for Ino/CBW ratios 1:1 and 2:1 is very low compared to other organic substrates. For the codigestion tests, the test with the Ino/CBW:CM ratio of 2/0.7:0.3 showed better biomethane yields, being in the expected values. This demonstrated that it is possible to perform the anaerobic digestion (AD) of CBW using a cosubstrate to increase biogas production and biomethane and to improve the quality of the final digestate.

Author(s):  
Zuhaib Siddiqui ◽  
N.J. Horan ◽  
Kofi Anaman

Biomethane production from processed industrial food waste (IFW) in admixture with sewage sludge (primary and waste activated sludge: PS and WAS) was evaluated at a range of C:N ratios using a standard biochemical methane potential (BMP) test. IFW alone had a C:N of 30 whereas for WAS it was 5.4 and thus the C:N ratio of the blends fell in that range. Increasing the IFW content in mix improves the methane potential by increasing both the cumulative biogas production and the rate of methane production. Optimum methane yield 239 mL/g VSremoved occurred at a C:N ratio of 15 which was achieved with a blend containing 11 percent (w/w) IFW. As the fraction of IFW in the blend increased, volatile solids (VS) destruction was increased and this led to a reduction in methane yield and amount of production. The highest destruction of volatile solids of 93 percent was achieved at C:N of 20 followed by C:N 30 and 15. A shortened BMP test is adequate for evaluating optimum admixtures.


2013 ◽  
Vol 827 ◽  
pp. 84-90 ◽  
Author(s):  
Maurizio Carlini ◽  
Sonia Castellucci ◽  
Silvia Cocchi

One of the most promising processes to exploit Solid Olive-Mill Waste (SOMW) for energy production is anaerobic digestion. An experimental study has been carried out on SOMW and inoculum, consisting of Cattle Slurry Digested (CSD) and coming from an anaerobic digestion plant. A substrate with an optimal supply ratio equal to 2:1 has been investigated in a reactor at 37°C by analysing the biogas production. The Biochemical Methane Potential (BMP) test has been carried out, monitoring pH, biogas production (amount and composition). According to the tests results, SOMWs needed to be diluted and inoculated, moreover the pH control is foundamental in order to obtain a significant biogas production. Anaerobic digestion plant of SOMW should be promoted in Mediterranean countries as an environmentally sound option for waste management and energy production, since olive mills are very widespread agro-industries in this area.


2005 ◽  
Vol 52 (1-2) ◽  
pp. 487-492 ◽  
Author(s):  
Y. Shang ◽  
B.R. Johnson ◽  
R. Sieger

A steady-state implementation of the IWA Anaerobic Digestion Model No. 1 (ADM1) has been applied to the anaerobic digesters in two wastewater treatment plants. The two plants have a wastewater treatment capacity of 76,000 and 820,000 m3/day, respectively, with approximately 12 and 205 dry metric tons sludge fed to digesters per day. The main purpose of this study is to compare the ADM1 model results with full-scale anaerobic digestion performance. For both plants, the prediction of the steady-state ADM1 implementation using the suggested physico-chemical and biochemical parameter values was able to reflect the results from the actual digester operations to a reasonable degree of accuracy on all parameters. The predicted total solids (TS) and volatile solids (VS) concentration in the digested biosolids, as well as the digester volatile solids destruction (VSD), biogas production and biogas yield are within 10% of the actual digester data. This study demonstrated that the ADM1 is a powerful tool for predicting the steady-state behaviour of anaerobic digesters treating sewage sludges. In addition, it showed that the use of a whole wastewater treatment plant simulator for fractionating the digester influent into the ADM1 input parameters was successful.


2013 ◽  
Vol 67 (2) ◽  
pp. 410-417 ◽  
Author(s):  
M. A. De la Rubia ◽  
V. Fernández-Cegrí ◽  
F. Raposo ◽  
R. Borja

Due to the chemical and physical structure of a lignocellulosic biomass, its anaerobic digestion (AD) is a slow and difficult process. In this paper, the results obtained from a batch biochemical methane potential (BMP) test and fed-batch mesophilic AD assays of sunflower oil cake (SuOC) are presented. Taking into account the low digestibility shown during one-stage experiments the methane yield decreased considerably after increasing the organic loading rate (OLR) from 2 to 3 g VS L−1 d−1, SuOC was subjected to a two-stage AD process (hydrolytic-acidogenic and methanogenic stages), in two separate reactors operating in series where the methanogenic stage became acidified (with >1,600 mg acetic acid L−1) at an OLR as low as 2 g VS L−1 d−1. More recently, BMP assays were carried out after mechanical, thermal, and ultrasonic pre-treatments to determine the best option on the basis of the methane yield obtained.


2012 ◽  
Vol 66 (7) ◽  
pp. 1416-1423 ◽  
Author(s):  
C. P. Pabón Pereira ◽  
G. Castañares ◽  
J. B. van Lier

A protocol was developed for determining the biochemical methane potential (BMP) of plant material using the OxiTop® system. NaOH pellets for CO2 absorption and different pretreatment methods were tested for their influence in the BMP test. The use of NaOH pellets in the headspace of the bottle negatively affected the stability of the test increasing the pH and inhibiting methanization. Sample comminution increased the biodegradability of plant samples. Our results clearly indicate the importance of test conditions during the assessment of anaerobic biodegradability of plant material, considering BMP differences as high as 44% were found. Guidelines and recommendations are given for screening plant material suitable for anaerobic digestion using the OxiTop® system.


Molecules ◽  
2020 ◽  
Vol 25 (2) ◽  
pp. 296 ◽  
Author(s):  
Georgia Antonopoulou ◽  
Dimitrios Vayenas ◽  
Gerasimos Lyberatos

Various pretreatment methods, such as thermal, alkaline and acid, were applied on grass lawn (GL) waste and the effect of each pretreatment method on the Biochemical Methane Potential was evaluated for two options, namely using the whole slurry resulting from pretreatment or the separate solid and liquid fractions obtained. In addition, the effect of each pretreatment on carbohydrate solubilization and lignocellulossic content fractionation (to cellulose, hemicellulose, lignin) was also evaluated. The experimental results showed that the methane yield was enhanced with alkaline pretreatment and, the higher the NaOH concentration (20 g/100 gTotal Solids (TS)), the higher was the methane yield observed (427.07 L CH4/kg Volatile Solids (VS), which was almost 25.7% higher than the BMP of the untreated GL). Comparing the BMP obtained under the two options, i.e., that of the whole pretreatment slurry with the sum of the BMPs of both fractions, it was found that direct anaerobic digestion without separation of the pretreated biomass was favored, in almost all cases. A preliminary energy balance and economic assessment indicated that the process could be sustainable, leading to a positive net heat energy only when using a more concentrated pretreated slurry (i.e., 20% organic loading), or when applying NaOH pretreatment at a lower chemical loading.


Water ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 921 ◽  
Author(s):  
Jameson Filer ◽  
Huihuang H. Ding ◽  
Sheng Chang

Biochemical methane potential (BMP) tests are widely used for characterizing a substrate’s influence on the anaerobic digestion process. As of 2018, there continues to be a lack of standardization of units and techniques, which impacts the comparability and validity of BMP results. However, BMP methods continue to evolve, and key aspects are studied to further eliminate systematic errors. This paper aims to update these key aspects with the latest research progress both to introduce the importance of each variable to those new to BMP measurements and to show the complexity required to design an accurate BMP test.


2021 ◽  
Vol 924 (1) ◽  
pp. 012071
Author(s):  
N A Rohma ◽  
S Suhartini ◽  
I Nurika

Abstract Production of biogas from lignocellulosic biomass by anaerobic digestion (AD) has attracted much interest. Oil palm empty fruit bunches (OPEFB), one of lignocellulosic biomass, is highly abundant in Indonesia and has potential as feedstock for bioenergy production such as biogas or methane. Yet, pre-treatments are needed to improve biogas production due to its complex crystalline structures. Chemical pre-treatments with acid or alkaline solution were reported to increase cellulose or highly reduce the lignin content of OPEFB. This study aimed to evaluate the effect of acid and alkaline pre-treatments on the characteristics of OPEFB and methane potential. The acid pre-treatment experimental design was used factor of H2SO4 concentration (1, 1.3, and 1.6 (%v/v)) and NaOH concentration (1.8, 2.8, and 3.8 (%w/v)). Methane potential evaluation was carried out using the biochemical methane potential (BMP) test with the Automatic Methane Potential Test System (AMPTS) II under mesophilic condition (37°C), operated for 28 days. The results showed that both dilute acid and alkaline pre-treatment positively impact altering the characteristics of OPEFB, hence the specific methane potential. Alkaline pre-treatment with NaOH 3.8 (%w/v) gave the highest average SMP value of 0.161 ± 0.005 m3 CH4/kgVSadded.


2017 ◽  
Vol 75 (9) ◽  
pp. 2179-2193 ◽  
Author(s):  
Sri Suhartini ◽  
Lynsey Melville ◽  
Tony Amato

The efficacy of sonication as a pre-treatment to anaerobic digestion (AD) was assessed using thickened waste activated sludge (TWAS). Efficiency was measured in relation to solubilisation, dewaterability, and AD performance. Eighteen experimental conditions were evaluated at low frequency (20 kHz), duration (2–10 s), amplitude (∼8–12 μm) and applied pressure (0.5–3.0 barg), using a sonix™ patented titanium sonoprobe capable of delivering an instantaneous power of ∼6 kW provided by Doosan Enpure Ltd (DEL). An optimised experimental protocol was used as a pre-treatment for biochemical methane potential (BMP) testing and semi-continuous trials. Four digesters, with a 2-L working volume were operated mesophilically (37 ± 0.5 °C) over 22 days. The results showed that the sonix™ technology delivers effective sonication at very short retention times compared to conventional system. Results demonstrate that the technology effectively disrupts the floc structures and filaments within the TWAS, causing an increase in solubilisation and fine readily digestible material. Both BMP tests and semi-continuous trials demonstrated that sonicated TWAS gave higher biodegradability and methane potential compared to untreated TWAS. Partial-stream sonication (30:70 sonicated to untreated TWAS) resulted in a proportionate increase in biogas production illustrating the benefits of full-stream sonication.


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