scholarly journals A Thermally Conductive Pt/AAO Catalyst for Hydrogen Passive Autocatalytic Recombination

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 491
Author(s):  
Alina E. Kozhukhova ◽  
Stephanus P. du Preez ◽  
Aleksander A. Malakhov ◽  
Dmitri G. Bessarabov
Keyword(s):  
Electron Microscopy ◽  
Particle Size ◽  
Combustion Temperature ◽  
Volume Fraction ◽  
Morphological Characteristics ◽  
Al Alloy ◽  
Impregnation Method ◽  
Case Scenario ◽  
Worst Case ◽  
Thermal Distribution

In this study, a Pt/anodized aluminum oxide (AAO) catalyst was prepared by the anodization of an Al alloy (Al6082, 97.5% Al), followed by the incorporation of Pt via an incipient wet impregnation method. Then, the Pt/AAO catalyst was evaluated for autocatalytic hydrogen recombination. The Pt/AAO catalyst’s morphological characteristics were determined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The average Pt particle size was determined to be 3.0 ± 0.6 nm. This Pt/AAO catalyst was tested for the combustion of lean hydrogen (0.5–4 vol% H2 in the air) in a recombiner section testing station. The thermal distribution throughout the catalytic surface was investigated at 3 vol% hydrogen (H2) using an infrared camera. The Al/AAO system had a high thermal conductivity, which prevents the formation of hotspots (areas where localized surface temperature is higher than an average temperature across the entire catalyst surface). In turn, the Pt stability was enhanced during catalytic hydrogen combustion (CHC). A temperature gradient over 70 mm of the Pt/AAO catalyst was 23 °C and 42 °C for catalysts with uniform and nonuniform (worst-case scenario) Pt distributions. The commercial computational fluid dynamics (CFD) code STAR-CCM+ was used to compare the experimentally observed and numerically simulated thermal distribution of the Pt/AAO catalyst. The effect of the initial H2 volume fraction on the combustion temperature and conversion of H2 was investigated. The activation energy for CHC on the Pt/AAO catalyst was 19.2 kJ/mol. Prolonged CHC was performed to assess the durability (reactive metal stability and catalytic activity) of the Pt/AAO catalyst. A stable combustion temperature of 162.8 ± 8.0 °C was maintained over 530 h of CHC. To confirm that Pt aggregation was avoided, the Pt particle size and distribution were determined by TEM before and after prolonged CHC.

The Effect of the Microstructure of Semisolid Al Alloy on its Rheology

2014 ◽  
Vol 490-491 ◽  
pp. 109-112
Author(s):  
De Wen Cao ◽  
Jia Huan Wang ◽  
Yu Qing Sun ◽  
Ke Hua Chen ◽  
Cheng Ming Yu ◽  
...  
Keyword(s):  
Particle Size ◽  
Rheological Behavior ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Alloy System ◽  
The State ◽  
Solid Particles ◽  
Al Alloy ◽  
Agglomerate Size ◽  
The One

In the present work, the effect of the microstructure of AlSi6Mg2 alloy on its macro-rheological behavior of the steady AlSi6Mg2 alloy is investigated. Specifically, the effect of particle size, packing mode and degree of the agglomeration of particles are analyzed. It can be seen that the apparent viscosity decreases with increasing the particle size (d) ifdis between a few μm and 200 μm, while the solid particle size does not affect viscosity except this region. This theoretical prediction is in qualitatively agreement with the experimental data. The trend of the variation of the average agglomerate size with the particle size is the same as the one of viscosity. The packing mode of solid particles in agglomerate is closely related to the solid volume fraction and the characteristics of the alloy system. Subsequently, the state of agglomeration of solid particles which determines the rheology of semisolid AlSi6Mg2 alloy, while the external flow conditions (such as shear rate) influence the viscosity by changing the state of agglomeration. Consequently, the particle size, the packing mode and the average agglomerate size have different effect on the rheological behavior of SSMS.

Underfill Filler Settling Effect on the Die Backside Interfacial Stresses of Flip Chip Packages

2008 ◽  
Vol 130 (3) ◽  
Author(s):  
Cheng-fu Chen ◽  
Pramod C. Karulkar
Keyword(s):  
Flip Chip ◽  
Mechanical Response ◽  
Volume Fraction ◽  
Local Concentration ◽  
Case Scenario ◽  
Interfacial Shearing Stress ◽  
Worst Case ◽  
Interfacial Stresses ◽  
Filler Volume Fraction ◽  
Filler Particles

Underfill is usually modeled as an isotropic medium containing uniformly distributed filler particles. However, filler particles tend to settle (or segregate) and thus alter the mechanical response of the flip chip die attachment package. The integrity of such flip chip attachment is different from that with an ideal, isotropic underfill with very uniform distribution of filler. We analyzed the thermomechanical implications of filler settling to the stresses along the die/underfill interface by considering different profiles for the local concentration of filler and calculating their effective material properties by employing the Mori–Tanaka method. As the worst-case scenario, direct silicon die attach with solder bumps was assumed to analyze the interfacial stresses, which were predicted in trend by a simplified multilayered stack model and calculated in detail by finite element simulation. The filler settling has a localized but strong influence on the interfacial peeling stress near the edge of the die. The extent of this influence is determined by the profile of filler settling: (1) if the filler is assumed to settle in the form of a bilayer, then the peeling stress near the die’s edge increases and it is directly proportional to the average volume fraction of the filler; (2) if the filler is assumed to settle gradually, then the magnitude of the peeling stress near the edge of the die becomes smaller as the local filler volume fraction near the die interface increases. The filler settling has no significant effect on the other components of the interfacial stresses. The edge fillet of underfill in pure resin can locally reverse the direction of the interfacial peeling stress and increase the interfacial shearing stress near the die’s edge.

Effect of Egg Washing on the Cuticle Quality of Brown and White Table Eggs

2011 ◽  
Vol 74 (10) ◽  
pp. 1649-1654 ◽  
Author(s):  
S. LELEU ◽  
W. MESSENS ◽  
K. DE REU ◽  
S. DE PRETER ◽  
L. HERMAN ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Egg Laying ◽  
The European Union ◽  
Case Scenario ◽  
Worst Case ◽  
Consumer Safety ◽  
Washing Process ◽  
Scanning Electron

Egg washing is currently not permitted within the European Union, with few exceptions. This is mainly because there are concerns that cuticle damage could occur during or after the washing process, as a result of a suboptimal operation. In this study, the cuticle coverage levels of 400 washed or unwashed eggs, derived from either a brown or a white egg–laying flock at the end of lay, were compared. The eggs from older hens inherently have poorer cuticle coverage and as a result arguably constitute a greater risk to consumer safety if they are then washed. Thus, the effects of the washing procedure used in this study on cuticle quality were tested under the worst-case scenario. A standard Swedish egg washing process was used. The cuticle coverage of the eggs was assessed by a colorimeter by quantifying the color difference before and after staining with Tartrazine and Green S. The cuticle of an additional 30 eggs from each of the four groups was then visually assessed by scanning electron microscopy. The staining characteristics of the cuticle varied greatly within each group of eggs and showed that the washing process did not lead to cuticle damage. Scanning electron microscopy confirmed that there was no irreversible damage to the cuticle of the washed eggs and that it was not possible to correctly assign the treatment (washed or not) based on a visual assessment. In conclusion, no evidence could be found to suggest that the washing procedure used in this investigation irreversibly changed the quality of the cuticle.

Grain Refinement in Titanium-Erbium Alloys

1974 ◽  
Vol 32 ◽  
pp. 522-523
Author(s):  
B. B. Rath ◽  
J. E. O'Neal ◽  
R. J. Lederich
Keyword(s):  
Electron Microscopy ◽  
Size Distribution ◽  
Grain Refinement ◽  
Grain Growth ◽  
Volume Fraction ◽  
Pure Titanium ◽  
Systematic Investigation ◽  
Second Phase ◽  
Titanium Matrix ◽  
Average Size

Addition of small amounts of erbium has a profound effect on recrystallization and grain growth in titanium. Erbium, because of its negligible solubility in titanium, precipitates in the titanium matrix as a finely dispersed second phase. The presence of this phase, depending on its average size, distribution, and volume fraction in titanium, strongly inhibits the migration of grain boundaries during recrystallization and grain growth, and thus produces ultimate grains of sub-micrometer dimensions. A systematic investigation has been conducted to study the isothermal grain growth in electrolytically pure titanium and titanium-erbium alloys (Er concentration ranging from 0-0.3 at.%) over the temperature range of 450 to 850°C by electron microscopy.

Aberrant Type C Virus Production in a Cell Line Derived from Balb/3T3

1972 ◽  
Vol 30 ◽  
pp. 286-287
Author(s):  
N. Savage ◽  
A. Hackett
Keyword(s):  
Electron Microscopy ◽  
Cell Line ◽  
Leukemia Virus ◽  
Morphological Characteristics ◽  
Virus Production ◽  
Oncogenic Viruses ◽  
Endogenous Virus ◽  
Virus Particles ◽  
Moloney Leukemia Virus ◽  
A Cell

A cell line, UC1-B, which was derived from Balb/3T3 cells, maintains the same morphological characteristics of the non-transformed parental culture, and shows no evidence of spontaneous virus production. Survey by electron microscopy shows that the cell line consists of spindle-shaped cells with no unusual features and no endogenous virus particles.UC1-B cells respond to Moloney leukemia virus (MLV) infection by a change in morphology and growth pattern which is typical of cells transformed by sarcoma virus. Electron microscopy shows that the cells are now variable in shape (rounded, rhomboid, and spindle), and each cell type has some microvilli. Virtually all (90%) of the cells show virus particles developing at the cell surface and within the cytoplasm. Maturing viruses, typical of the oncogenic viruses, are found along with atypical tubular forms in the same cell.

Analytical Electron Microscopy study of two vehicle-aged automotive exhaust catalysts having dissimilar activities

1989 ◽  
Vol 47 ◽  
pp. 272-273
Author(s):  
Sooho Kim ◽  
M. J. D’Aniello
Keyword(s):  
Electron Microscopy ◽  
Particle Size ◽  
Noble Metal ◽  
Catalyst Deactivation ◽  
Analytical Electron Microscopy ◽  
Microscopy Study ◽  
Metal Particles ◽  
Automotive Exhaust ◽  
Exhaust Catalysts ◽  
Analytical Electron

Automotive catalysts generally lose-agtivity during vehicle operation due to several well-known deactivation mechanisms. To gain a more fundamental understanding of catalyst deactivation, the microscopic details of fresh and vehicle-aged commercial pelleted automotive exhaust catalysts containing Pt, Pd and Rh were studied by employing Analytical Electron Microscopy (AEM). Two different vehicle-aged samples containing similar poison levels but having different catalytic activities (denoted better and poorer) were selected for this study.The general microstructure of the supports and the noble metal particles of the two catalysts looks similar; the noble metal particles were generally found to be spherical and often faceted. However, the average noble metal particle size on the poorer catalyst (21 nm) was larger than that on the better catalyst (16 nm). These sizes represent a significant increase over that found on the fresh catalyst (8 nm). The activity of these catalysts decreases as the observed particle size increases.

Reducing Probabilistic Weather Forecasts to the Worst Case Scenario: Anchoring Effects

2008 ◽  
Author(s):  
Sonia Savelli ◽  
Susan Joslyn ◽  
Limor Nadav-Greenberg ◽  
Queena Chen
Keyword(s):  
Case Scenario ◽  
Worst Case ◽  
Weather Forecasts ◽  
Worst Case Scenario ◽  
Anchoring Effects

EXPEDITION TO MALI, 2020

2020 ◽  
pp. 12-28
Author(s):  
D. V. Vaniukova ◽  
◽  
P. A. Kutsenkov ◽  
Keyword(s):  
Mass Murder ◽  
The State ◽  
Case Scenario ◽  
Worst Case ◽  
Traditional Art ◽  
Peter The Great ◽  
State Museum ◽  
Bobo Dioulasso ◽  
Oriental Studies ◽  
The Village

The research expedition of the Institute of Oriental studies of the Russian Academy of Sciences has been working in Mali since 2015. Since 2017, it has been attended by employees of the State Museum of the East. The task of the expedition is to study the transformation of traditional Dogon culture in the context of globalization, as well as to collect ethnographic information (life, customs, features of the traditional social and political structure); to collect oral historical legends; to study the history, existence, and transformation of artistic tradition in the villages of the Dogon Country in modern conditions; collecting items of Ethnography and art to add to the collection of the African collection of the. Peter the Great Museum (Kunstkamera, Saint Petersburg) and the State Museum of Oriental Arts (Moscow). The plan of the expedition in January 2020 included additional items, namely, the study of the functioning of the antique market in Mali (the “path” of things from villages to cities, which is important for attributing works of traditional art). The geography of our research was significantly expanded to the regions of Sikasso and Koulikoro in Mali, as well as to the city of Bobo-Dioulasso and its surroundings in Burkina Faso, which is related to the study of migrations to the Bandiagara Highlands. In addition, the plan of the expedition included organization of a photo exhibition in the Museum of the village of Endé and some educational projects. Unfortunately, after the mass murder in March 2019 in the village of Ogossogou-Pel, where more than one hundred and seventy people were killed, events in the Dogon Country began to develop in the worst-case scenario: The incessant provocations after that revived the old feud between the Pel (Fulbe) pastoralists and the Dogon farmers. So far, this hostility and mutual distrust has not yet developed into a full-scale ethnic conflict, but, unfortunately, such a development now seems quite likely.

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