scholarly journals Modeling of CO2 Capture with Water Bubble Column Reactor

Energies ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 5793
Author(s):  
Eero Inkeri ◽  
Tero Tynjälä

The demand for carbon capture is increasing over time due to rising CO2 levels in the atmosphere. Even though fossil emission could be decreased or even eliminated, there is a need to start removing CO2 from the atmosphere. The removed CO2 could be either stored permanently to a reservoir (CCS, Carbon Capture and Storage) or utilized as a raw material in a long-lasting product (CCU, Carbon Capture and Utilization). The capture of CO2 could be done by direct air capture, or capturing CO2 from biogenic sources. Amine absorption is the state-of-the-art method to capture CO2, but it has some drawbacks: toxicity, high heat demand, and sorbent sensitivity towards impurities such as sulfur compounds and degradation in cyclic operation. Another potential solvent for CO2 could be water, which is easily available and safe to use in many applications. The problem with water is the poorer solubility of CO2, compared with amines, which leads to larger required flow rates. This study analyzed the technical feasibility of water absorption in a counterflow bubble column reactor. A dynamic, one-dimensional multiphase model was developed. The gas phase was modeled with plug flow assumption, and the liquid phase was treated as axially dispersed plug flow. CO2 capture efficiency, produced CO2 mass flow rate, and the product gas CO2 content were estimated as a function of inlet gas and liquid flow rate. In addition, the energy consumption per produced CO2-tonne was calculated. The CO2 capture efficiency was improved by increasing the liquid flow rate, while the CO2 content in product gas was decreased. For some of the studied liquid flow rates, an optimum gas flow rate was found to minimize the specific energy consumption. Further research is required to study the integration and dynamical operation of the system in a realistic operation environment.

2019 ◽  
Vol 1 (2) ◽  
pp. 55-57
Author(s):  
NUR FARHANA AJUA MUSTAFA ◽  
Azmi bin Mohd Shariff ◽  
WeeHorng Tay ◽  
Hairul Nazirah Abdul Halim ◽  
Siti Munirah Mhd Yusof

This article reports the absorption removal efficiency for carbon dioxide (CO2) capture from natural gas using an environmental friendly solvent, potassium carbonate promoted with glycine. Recently, CO2 capture using this solvent (with precipitating) was studied by previous researchers. However, the precipitates of the solvent increase the potential of blockage in the packing and piping thus result failure in absorption processes. Therefore, this study focused to assess the CO2 removal efficiency of non-precipitating potassium carbonate promoted with glycine. This green solvent contains aqueous blend of 20 wt% potassium carbonate and 8 wt% glycine. The absorption performance of the solvent was obtained by demonstrated a few experimental works using a bench scale packed absorption column. The packing type was Sulzer metal gauze and the column consisted of six sampling point which located equidistance along the packing The system was running over a range of liquid flow rate 1.81-7.22 m3/m2.h at fixed operating pressure (4 Mpa), CO2 inlet concentration (20%), gas flow rate (33 kmol/m2.h) and solvent temperature (60 . The effect of liquid flow rate was assessed in term of its CO2 removal efficiency and concentration profile along the packing. The study shows the increasing trend of CO2 removal as liquid flow rate increases. Higher liquid/molar flow rate gas (L/G) offers a better absorption performance compared to lower L/G ratio. This study demonstrated the efficient absorption up to 77 % using non-precipitating potassium carbonate promoted with glycine.


2015 ◽  
Vol 7 (9) ◽  
pp. 3981-3987 ◽  
Author(s):  
Wen-Chi Lin ◽  
Mark A. Burns

We have constructed micro-fabricated flow sensors that can measure water flow rates of 0.1 to 2.0 gallons per minute (GPM), and the experimental results we obtained are in good agreement with those from COMSOL simulations.


2008 ◽  
Vol 2 (1) ◽  
pp. 15 ◽  
Author(s):  
Mohd Sobri Takriff ◽  
Zuhrina Masyitah

Oscillatory flow in a baffled tube/column is an efficient way to enhance mixing in a straight smooth column. However, liquid oscillation moving back and forth across the baffle causes backmixing which is a disadvantage when plug flow is desired. This paper presents results from a study conducted to reduce the backmixing rate in oscillatory flow in a baffled column with the use of a draft tube. Results of this study showed that backmixing increases with oscillation velocity and decreases with liquid flow rate. The use of a draft tube reduces backmixing. The backmixing reduction is proportional to the ratio of L/Do However, the draft tube can not be extended too long because it disrupts the flow behavior in the column and creates dead zones near the baffle region. The draft tube length is maximized by extending it to both sides of the baffle, provided that the L/De on each side of the baffle is at 0.67 or less.


2016 ◽  
Vol 859 ◽  
pp. 153-157
Author(s):  
Pao Chi Chen ◽  
Sheng Zhong Lin

This work uses a continuous bubble-column scrubber for the absorption of CO2 with a 5M MEA solution under a constant pH environment to explore the effect of the pH of the solution and gas-flow rate (Qg) on the removal efficiency (E), absorption rate (RA), overall mass-transfer coefficient (KGa), liquid flow rate (QL), gas-liquid flow ratio (γ), and scrubbing factors (φ). From the outlet CO2 concentration with a two-film model, E, RA, KGa, QL, γ, and φ can be simultaneously determined at the steady state. Depending on the operating conditions, the results show that E (80-97%), RA(2.91x10-4-10.0x10-4mol/s-L), KGa (0.09-0.48 1/s), QL(8.74-230.8mL/min), γ (0.19-5.39), and φ (0.031-0.74 mol/mol-L) are found to be comparable with other solvents. In addition, RA, KGa, E, and QL have been used to correlate with pH and Qg, respectively, with the results further explained.


2021 ◽  
Author(s):  
Serhii Matkivskyi ◽  
Liliia Khaidarova

The overwhelming majority of natural gas fields are at the final stage of development, which, along with other features, is characterized by selective watering of productive deposits and production wells. The difficulty of extracting residual gas reserves under such development conditions is associated with depletion of productive reservoirs, accumulation of fluid at the bottom of wells, corrosion of downhole equipment and the inability to reduce wellhead pressures due to restrictions on the supply and preparation of hydrocarbon products with the existing surface infrastructure. Production wells in conditions of formation water inflow into productive deposits are decommissioned after relatively small gas withdrawals. This is due both to the insufficient implementation of methods for intensifying the removal of fluid from the bottom of the wells, and to the peculiarities of the arrangement of fields, which are usually not designed for the collection and preparation of hydrocarbon products with a high liquid content. In order to remove the gas-liquid mixture from the bottom of the wells, many techniques and inventions have been developed that are widely used in production. The developed technologies are characterized by different efficiency and have a number of technological limitations, mainly due to the peculiarities of the geological structure of hydrocarbon deposits. Considering the above, there is a need for additional research in order to improve the existing and develop new technologies for the operation of water cut wells. Using the special software package, studies were carried out to optimize the operating conditions for a water cut well under conditions of active formation water inflow into gas-saturated horizons. The study was carried out for various depths of gas-lift valves (3500 m; 3000 m; 2500 m; 2000 m; 1500 m; 1000 m) and liquid flow rates (22.5 m3/day; 33.75 m3/day and 45 m3/day). Based on the research results, graphical dependences of gas flow rates and bottomhole pressure on the amount of gas-lift gas were built; the maximum gas flow rate and the required amount of gas-lift gas from the liquid flow rate; maximum gas flow rate versus liquid flow rate at different depths of gas-lift valve installation. Based on the results of statistical processing of the calculated data for each value of the liquid flow rate, the optimal value of the depth of the gas-lift valve was established. According to the results of the studies performed, to ensure the stable operation of high-water cut gas wells, it is effective to locate the gas-lift valve at a distance of 55-58 % from the wellhead of the tubing (2033-2137 m).


1986 ◽  
Vol 51 (10) ◽  
pp. 2127-2134 ◽  
Author(s):  
František Potůček ◽  
Jiří Stejskal

Absorption of oxygen into water and aqueous solutions of poly(acrylamides) was studied in an absorber with a wetted sphere. The effects of changes in the liquid flow rate and the polymer concentration on the liquid side mass transfer coefficient were examined. The results are expressed by correlations between dimensionless criteria modified for non-Newtonian liquids whose flow curve can be described by the Ostwald-de Waele model.


Author(s):  
Svetlana Rudyk ◽  
Sami Al-Khamisi ◽  
Yahya Al-Wahaibi

AbstractFactors limiting foam injection for EOR application are exceptionally low rock permeability and exceedingly high salinity of the formation water. In this regard, foam formation using internal olefin sulfonate is investigated over a wide salinity range (1, 5, 8, 10, and 12% NaCl) through 10 mD limestone. The relationships between pressure drop (dP), apparent viscosity, liquid flow rate, total flow rate, salinity, foam texture, and length of foam drops at the outlet used as an indicator of viscosity are studied. Foaming is observed up to 12% NaCl, compared to a maximum of 8% NaCl in similar core-flooding experiments with 50 mD limestone and 255 mD sandstone. Thus, the salinity limit of foam formation has increased significantly due to the low permeability, which can be explained by the fact that the narrow porous system acts like a membrane with smaller holes. Compared to the increasing dP reported for highly permeable rocks, dP linearly decreases in almost the entire range of gas fraction (fg) at 1–10% NaCl. As fg increases, dP at higher total flow rate is higher at all salinities, but the magnitude of dP controls the dependence of apparent viscosity on total flow rate. Low dP is measured at 1% and 10% NaCl, and high dP is measured at 5, 8, and 12% NaCl. In the case of low dP, the apparent viscosity is higher at higher total flow rate with increasing gas fraction, but similar at two total flow rates with increasing liquid flow rate. In the case of high dP, the apparent viscosity is higher at lower total flow rate, both with an increase in the gas fraction and with an increase in the liquid flow rate. A linear correlation is found between dP or apparent viscosity and liquid flow rate, which defines it as a governing factor of foam flow and can be considered when modeling foam flow.


Author(s):  
Yoshiyuki Iso ◽  
Xi Chen

Gas-liquid two-phase flows on the wall like liquid film flows, which are the so-called wetted wall flows, are observed in many industrial processes such as absorption, desorption, distillation and others. For the optimum design of packed columns widely used in those kind of processes, the accurate predictions of the details on the wetted wall flow behavior in packing elements are important, especially in order to enhance the mass transfer between the gas and liquid and to prevent flooding and channeling of the liquid flow. The present study focused on the effects of the change of liquid flow rate and the wall surface texture treatments on the characteristics of wetted wall flows which have the drastic flow transition between the film flow and rivulet flow. In this paper, the three-dimensional gas-liquid two-phase flow simulation by using the volume of fluid (VOF) model is applied into wetted wall flows. Firstly, as one of new interesting findings in this paper, present results showed that the hysteresis of the flow transition between the film flow and rivulet flow arose against the increasing or decreasing stages of the liquid flow rate. It was supposed that this transition phenomenon depends on the history of flow pattern as the change of curvature of interphase surface which leads to the surface tension. Additionally, the applicability and accuracy of the present numerical simulation were validated by using the existing experimental and theoretical studies with smooth wall surface. Secondary, referring to the texture geometry used in an industrial packing element, the present simulations showed that surface texture treatments added on the wall can improve the prevention of liquid channeling and can increase the wetted area.


Author(s):  
N.I. Mikheev ◽  
V.M. Molochnikov ◽  
D.V. Kratirov ◽  
O.A. Dushina ◽  
A.A. Paereliy ◽  
...  

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