scholarly journals From Sampling to Analysis: How to Achieve the Best Sample Throughput via Sampling Optimization and Relevant Compound Analysis Using Sum of Ranking Differences Method?

Foods ◽  
2021 ◽  
Vol 10 (11) ◽  
pp. 2681
Author(s):  
Dalma Radványi ◽  
Magdolna Szelényi ◽  
Attila Gere ◽  
Béla Péter Molnár
Keyword(s):  
Sampling Procedure ◽  
Optimal Sampling ◽  
Evaluation Time ◽  
Sum Of Ranking Differences ◽  
Different Types ◽  
Relevant Compound ◽  
Sampling Optimization ◽  
Sampling Procedures ◽  
Sampling Times

The determination of an optimal volatile sampling procedure is always a key question in analytical chemistry. In this paper, we introduce the application of a novel non-parametric statistical method, the sum of ranking differences (SRD), for the quick and efficient determination of optimal sampling procedures. Different types of adsorbents (Porapak Q, HayeSep Q, and Carbotrap) and sampling times (1, 2, 4, and 6 h) were used for volatile collections of lettuce (Lactuca sativa) samples. SRD identified 6 h samplings as the optimal procedure. However, 1 or 4 h sampling with HayeSep Q and 2 h sampling with Carbotrap are still efficient enough if the aim is to reduce sampling time. Based on our results, SRD provides a novel way to not only highlight an optimal sampling procedure but also decrease evaluation time.

Determination of optimal sampling times for a two blood sample clearance method using51Cr-EDTA in cats

2010 ◽  
Vol 12 (8) ◽  
pp. 577-583 ◽  
Author(s):  
Eva Vandermeulen ◽  
Carlos De Sadeleer ◽  
Amy Piepsz ◽  
Hamphrey R. Ham ◽  
André A. Dobbeleir ◽  
...  
Keyword(s):  
Blood Sample ◽  
Optimal Sampling ◽  
Sampling Times

Determination of Lead Content in Red Colored Lipsticks from Mandalay Market by Flame Atomic Absorption Spectrophotometer

2018 ◽  
Vol 30 (3) ◽  
pp. 167-173
Keyword(s):  
Sampling Procedure ◽  
The Body ◽  
Lead Content ◽  
Social Psychological ◽  
Allowable Limit ◽  
Flame Atomic Absorption ◽  
Therapeutic Benefits ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Exposure Levels

Red colored lipstick is the most widely used cosmetic product. Although lipstick gives a lot of social, psychological and therapeutic benefits, it may harm the consumers. Because some lipsticks contain a considerable amount of heavy metal especially lead. Lead is being used in lipstick mainly for the pigments required to obtain needed colors. Lead accumulates in the body over time and lead-containing lipstick applied several times a day, every day, combined with lead in water and other sources, could add up to significant exposure levels. Therefore, this study was aimed to determine lead content in red colored lipsticks from market. This study was laboratorybased, analytical study by using 25 lipstick samples. Red colored lipsticks were bought from Mandalay Market by random sampling procedure and they were completely coded to avoid the bias. Then, lead content in coded samples was determined by Flame AAS according to International Conference on Harmonization (ICH) guideline. Lead contents of 88% of the lipsticks samples were more than specified limit (20 ppm) of Food and Drug Administration, United States. All of them, lead content was highest in counterfeit lipsticks group. Among the tested lipstick samples, lipstick with lowest lead content was LE-RL 01 (15.74 ppm) and the lipstick with highest lead content was CF-RL 01(60.09 ppm). In conclusion, lead contents of red colored lipsticks (22 out of 25) from market samples were higher than allowable limit (20 ppm).

Characterization of Different Types of Biomass Wastes Using Thermogravimetric and ICP-MS Analyses

2020 ◽  
Vol 70 (12) ◽  
pp. 4594-4600
Keyword(s):  
Thermogravimetric Analysis ◽  
Food Industry ◽  
Wood Waste ◽  
Biomass Ash ◽  
Minor Elements ◽  
Ms Analysis ◽  
Icp Ms ◽  
Different Types

The purpose of this study was to characterize some types of biomass wastes resulted from different activities such as: agriculture, forestry and food industry using thermogravimetric and ICP-MS analyses. Also, it was optimized an ICP-MS method for the determination of As, Cd and Pb from biomass ash samples. The ICP-MS analysis revealed that the highest concentration of metals (As, Cd, Pb) was recorded in the wood waste ash sample, also the thermogravimetric analysis indicated that the highest amount of ash was obtained for the same sample (26.82%). The biomass wastes mentioned in this study are alternative recyclable materials, reusable as pellets and briquettes. Keywords: ash, biomass, ICP-MS, minor elements, TG

Studies on the Behavior Some Paints in Electro-insulating Fluid Based on Vegetable Esters

2018 ◽  
Vol 69 (5) ◽  
pp. 1139-1144
Author(s):  
Iosif Lingvay ◽  
Adriana Mariana Bors ◽  
Livia Carmen Ungureanu ◽  
Valerica Stanoi ◽  
Traian Rus
Keyword(s):  
Structural Changes ◽  
Oxidation Processes ◽  
High Oleic ◽  
Painting Materials ◽  
Insulating Paper ◽  
Different Types ◽  
Mechanism And Kinetics ◽  
Kinetics Of ◽  
Natural Ester

For the purpose of using three different types of painting materials for the inner protection of the transformer vats, their behavior was studied under actual conditions of operation in the transformer (thermal stress in electro-insulating fluid based on the natural ester in contact with copper for electro-technical use and electro-insulating paper). By comparing determination of the content in furans products (HPLC technique) and gases formed (by gas-chromatography) in the electro-insulating fluid (natural ester with high oleic content) thermally aged at 130 �C to 1000 hours in closed glass vessels, it have been found that the presence the investigated painting materials lead to a change in the mechanism and kinetics of the thermo-oxidation processes. These changes are supported by oxygen dissolved in oil, what leads to decrease both to gases formation CO2, CO, H2, CH4, C2H4 and C2H6) and furans products (5-HMF, 2-FOL, 2 -FAL and 2-ACF). The painting materials investigated during the heat treatment applied did not suffer any remarkable structural changes affecting their functionality in the electro-insulating fluid based on vegetable esters.

scholarly journals The Importance of Diet in Predicting the Remission of Urticaria—Determination of Allergen-Specific IgE

Medicina ◽  
2021 ◽  
Vol 57 (7) ◽  
pp. 679
Author(s):  
Monica Iuliana Ungureanu ◽  
Liliana Sachelarie ◽  
Radu Ciorap ◽  
Bogdan Aurelian Stana ◽  
Irina Croitoru ◽  
...  
Keyword(s):  
Predictive Value ◽  
Allergic Diseases ◽  
Specific Ige ◽  
Egg White ◽  
Food Allergens ◽  
Pediatric Hospital ◽  
Disease Remission ◽  
Specific Serum ◽  
Different Types

Background and Objectives: Different types of food introduced gradually in the diet will expose children to different food allergens, increasing the chance of developing allergic diseases. The aim of our study was to determine if allergen-specific IgE values can influence, depending on the diet, the prediction of remission of urticaria in children. Materials and Methods: This prospective study was conducted in 132 patients diagnosed over two years with urticaria, admitted to “Sf. Maria” Clinical Pediatric Hospital Iaşi. Total IgE assay was performed by ELISA, and determination of specific serum IgE by the CLA System Quanti Scan method (Innogenetics, Heiden, Germany). Data were gathered and statistical analysis was performed using statistical software SPSS, using descriptive and inferential statistics. Results: The determination of specific IgE to food allergens was performed on a total of 132 cases. The values of specific IgE were positive for one or more food allergens in 84 patients (63.64%). The most common allergens involved were: cow’s milk in 33.3% cases, egg white in 22.6% cases, and hazelnuts in 11.9% cases. The specific IgE values for the different types of food included in our study had a predictive value for disease remission. Conclusions: The determination of specific IgE confirms the presence of a particular food allergen and may have predictive value for the future development of an allergic manifestation.

scholarly journals Determination of dV/dt and dI/dt characteristics for high voltage 4H-SiC Schottky diodes with different types of metal-polymeric packages

2020 ◽  
Vol 1679 ◽  
pp. 022045
Author(s):  
S B Rybalka ◽  
E A Kulchenkov ◽  
A A Demidov ◽  
N A Zhemoedov ◽  
A Yu Drakin ◽  
...  
Keyword(s):  
High Voltage ◽  
Schottky Diodes ◽  
Different Types

scholarly journals Parametric Analysis of Rotational Effects in Seismic Design of Tall Structures

2021 ◽  
Vol 11 (2) ◽  
pp. 597
Author(s):  
Milan Sokol ◽  
Rudolf Ároch ◽  
Katarína Lamperová ◽  
Martin Marton ◽  
Justo García-Sanz-Calcedo
Keyword(s):  
Seismic Design ◽  
Parametric Study ◽  
Tall Buildings ◽  
Soil Parameters ◽  
Eurocode 8 ◽  
Tall Structures ◽  
Rotational Components ◽  
Different Types ◽  
Depth Study

This paper uses a parametric study to evaluate the significance of the rotational components of Earth’s motion in a seismic design. The parametric study is based on the procedures included in Eurocode 8, Part 6. Although the answer to the question of when the effects of rotational components are important is quite a complex one and requires a more in-depth study, our aim was to try to assess this question in a relatively quick manner and with acceptable accuracy. The first part of the paper is devoted to derivation of a simple formula that can be used for expressing the importance of rotational components in comparison with the classic seismic design without their usage. The quasi-static analysis, assuming inertial forces, is used. A crucial role plays the shape of the fundamental mode of the vibration. Due to simplicity reasons, well-known expression for estimation of the first eigenmode as an exponential function with different power coefficients that vary for different types of buildings is used. The possibility of changing the soil parameters is subsequently included into the formula for estimation of the fundamental frequency of tall buildings. In the next part, the overall seismic analyses of complex FEM models of 3D buildings and chimneys are performed. The results from those analyses are then compared with those from simplified calculations. The importance of the soil characteristics for determination of whether it is necessary to take into account the rotational effects is further discussed.

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